This sampling and analysis plan (SAP) identifies the type, quantity, and quality of data needed to support characterization of the sludge that remains in Tank 241-2-361. The procedures described in this SAP are based on the results of the 241-2-361 Sludge Characterization Data Quality Objectives (DQO) (BWHC 1999) process for the tank. The primary objectives of this project are to evaluate the contents of Tank 241-2-361 in order to resolve safety and safeguards issues and to assess alternatives for sludge removal and disposal.

A sol-gel granulation method was developed to prepare spherical {gamma}-alumina granular supports and supported CuO granular sorbents for flue gas desulfurization. The prepared {gamma}-alumina supported CuO sorbents exhibit desirable pore structure and excellent mechanical properties. The sorbents contain higher loading (30-40 wt. %) of CuO dispersed in the monolayer or sub-monolayer form, giving rise to a larger SO{sub 2} sorption capacity ({gt}20 wt.%) and a faster sorption rate as compared to similar sorbents reported in the literature. With these excellent sulfation and mechanical properties, the sol-gel derived {gamma}-alumina supported CuO granular sorbents offer great potential for use in the dry, regenerative flue gas desulfurization process. Research efforts were also made to prepare DAY zeolite supported sorbents with various CuO contents by the microwave and conventional thermal dispersion methods at different conditions. Monolayer or sub-monolayer coating of Cu(NO{sub 3})sub 2 or CuO was achieved on several DAY supported sorbents by the microwave heating method but not by the conventional thermal dispersion method. The DAY zeolite supported CuO sorbents prepared by the microwave heating method can adsorb up to 15 wt.% of SO{sub 2}. The results obtained have demonstrated the feasibility of effective preparation of zeolite supported CuO sorbents by the microwave …

Coal solubilization under aerobic conditions results in oxygenated coal product which, in turn, makes the coal poorer fuel than the starting material. A novel approach has been made in this project is to remove oxygen from coal by reductive decarboxylation. In Wyodak subbituminous coal the major oxygen functionality is carboxylic groups which exist predominantly as carboxylate anions strongly chelating metal cations like Ca{sup 2+} and forming strong macromolecular crosslinks which contribute in large measure to network polymer structure. Removal of the carboxylic groups at ambient temperature by anaerobic organisms would unravel the macromoleculer network, resulting in smaller coal macromolecules with increased H/C ratio which has better fuel value and better processing prospects. These studies described here sought to find biological methods to remove carboxylic functionalities from low rank coals under ambient conditions and to assess the properties of these modified coals towards coal liquefaction. Efforts were made to establish anaerobic microbial consortia having decarboxylating ability, decarboxylate coal with the adapted microbial consortia, isolate the organisms, and characterize the biotreated coal products. Production of CO{sup 2} was used as the primary indicator for possible coal decarboxylation.

Neural networks were used to determine the sensitivity of 39 selected Melter/Melter Off Gas and Melter Feed System process parameters as related to the Defense Waste Processing Facility (DWPF) Melter Pour Spout Pressure during the overall analysis and resolution of the DWPF glass production and pouring issues. Two different commercial neural network software packages were used for this analysis. Models were developed and used to determine the critical parameters which accurately describe the DWPF Pour Spout Pressure. The model created using a low-end software package has a root mean square error of {+-} 0.35 inwc (< 2% of the instrument`s measured range, R{sup 2} = 0.77) with respect to the plant data used to validate and test the model. The model created using a high-end software package has a R{sub 2} = 0.97 with respect to the plant data used to validate and test the model. The models developed for this application identified the key process parameters which contribute to the control of the DWPF Melter Pour Spout pressure during glass pouring operations. The relative contribution and ranking of the selected parameters was determined using the modeling software. Neural network computing software was determined to be a cost-effective software tool …

Measurements of dielectric breakdown during high-field electrical stress are typically performed at or near room temperature via constant voltage or current stress methods. In this summary they explore whether useful information might also be obtained by performing current measurements during a temperature ramp at high electric field.

This document includes the calculations needed to quantify the risk associated with unmitigated and mitigated pressurized spray releases from tank farm transfer equipment inside transfer enclosures. The calculations within this document support the spray leak accident analysis reported in the TWRS FSAR.

Key component in the CDA instrument is the differential capacitive force sensor. The CDA instrument has four basic components: OEM analytical balance, flexure point and capacitor plates, gas confinement tower and high-voltage bias electrodes, and the furnace. Phyton is in position to purchase an OEM analytical balance; negotations are underway for obtaining the feedback control circuitry for the differential capacitive force sensor. Progress with the differential capacitive force sensor is reviewed.

Joints for the ITER superconducting Central Solenoid should perform in rapidly varying magnetic field with low losses and low DC resistance. This paper describes the design of the ITER joint and presents its assembly process. Two joints were built and tested at the PTF facility at MIT. Test results are presented; losses in transverse and parallel field and the DC performance are discussed. The developed joint demonstrates sufficient margin for baseline ITRR operating scenarios.

The longevity of high gain GaAs photoconductive semiconductor switches (PCSS) has been extended to over 50 million pulses. This was achieved by improving the ohmic contacts through the incorporation of a doped layer beneath the PCSS contacts which is very effective in the suppression of filament formation and alleviating current crowding to improve the longevity of PCSS. Virtually indefinite, damage-free operation is now possible at much higher current levels than before. The inherent damage-free current capacity of the switch depends on the thickness of the doped layers and is at least 100A for a dopant diffusion depth of 4pm. The contact metal has a different damage mechanism and the threshold for damage ({approximately}40A) is not further improved beyond a dopant diffusion depth of about 2{micro}m. In a diffusion-doped contact switch, the switching performance is not degraded when contact metal erosion occurs. This paper will compare thermal diffusion and epitaxial growth as approaches to doping the contacts. These techniques will be contrasted in terms of the fabrication issues and device characteristics.

Los Alamos National Laboratory (LANL) is a multidisciplinary, multiprogram laboratory with a mission to enhance national military and economic security through science and technology. Its mission is to reduce the nuclear danger through stewardship of the nation`s nuclear stockpile and through its nonproliferation and verification activities. An important secondary mission is to promote US industrial competitiveness by working with US companies in technology transfer and technology development partnerships. Los Alamos is involved in partnerships and collaborations with other federal agencies, with industry (including New Mexico businesses), and with universities worldwide. For this report, the reference period is FY 1998 (October 1, 1997, through September 30, 1998). It includes two major impact analysis: the impact of LANL activities on north-central New Mexico and the economic impacts of LANL on the state of New Mexico. Total impact represents both direct and indirect responding by business, including induced effects (responding by households). The standard multipliers used in determining impacts result from the inter-industry, input-output models developed for the three-county region and the state of New Mexico.

The U.S. Department of Energy (DOE) provides a major source of economic benefits in New Mexico, second only to the activities of the U.S. Department of Defense. The agency's far-reaching economic influence within the state is the focus of this report. Economic benefits arising from the various activities and functions of both the Department and its contractors have accrued to the state continuously for over 50 years. For several years, DOE/Albuquerque Operations Office (AL) and New Mexico State University (NMSU) have maintained inter-industry, input-output modeling capabilities to assess DOE's impacts on the state of New Mexico and the other substate regions most directly impacted by DOE activities. One of the major uses of input-output techniques is to assess the effects of developments initiated outside the economy such as Federal DOE monies that flow into the state, on an economy. The information on which the models are based is updated periodically to ensure the most accurate depiction possible of the economy for the period of reference. For this report, the reference periods are Fiscal Year (FY) 1997 (October 1, 1996, through September 30, 1997), and FY 1998 (October 1, 1997, through September 30, 1998). Total impact represents both direct and indirect …

Low temperature electrical performance characteristics of A and T, Moli, and Panasonic 18650 Li-ion cells are described. Ragone plots of energy and power data of the cells for different temperatures from 25 C to {minus}40 C are compared. Although the electrical performance of these cells at and around room temperature is respectable, at temperatures below 0 C the performance is poor. For example, the delivered power and energy densities of the Panasonic cells at 25 C are {approximately}800 W/l and {approximately}100 Wh/l respectively and those at {minus}40 C are &lt;10 W/l and {approximately}5 Wh/l. In order to identify the source for this poor performance at subambient temperatures, both 2- and 3-electrode impedance studies were made on these cells. The 2-electrode impedance data suggests that the cell ohmic resistance remains nearly constant from 25 C to {minus}20 C but increases modestly at {minus}40 C while the overall cell impedance increases by an order of magnitude over the same temperature range. The 3-electrode impedance data of the A and T cells show that the increase in cell resistance comes mostly from the cathode electrolyte interface and very little either from the anode electrolyte interface or from the ohmic resistance of the cell. …

Organically modified alkoxy silanes play an important role in tailoring different properties of silica produced by the sol-gel method. Changes in the size and functionality of the organic group allows control of both physical and chemical properties of the resulting gel, with the kinetics of the polymerization process playing an important role in the design of new siloxane materials. High resolution {sup 29}Si NMR has proven to be valuable tool for monitoring the polymerization reaction, and has been used to investigate a variety of organically modified alkoxy silane systems.

This document is a hard copy of the CY 1995 airborne and liquid effluent data contained in the Environmental Release Summary (ERS) computer database.

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By the end of June 1999, about 250 megawatts of wind generation will have been dedicated in the state of Iowa. This represents the beginning of what is likely to be significant wind capacity development during the next 20 years in the state, as a result of possible public and governmental mandates and consumers' desire for sustainable sources of energy. As the utility industry in the United States moves towards a new structure, renewable energy sources continue to be an important part of new resource development. In this paper, we consider the predicted trends in load growth in Iowa. After accounting for the retirement of nuclear and older fossil fuel facilities over the next 15 years, we estimate Iowa's potential renewable generating capacity through the year 2015 and anticipate the contribution of wind energy to Iowa's portfolio. The Iowa Wind Energy Institute (IWEI) has been monitoring the wind resource in Iowa since June 1994 to obtain wind speed averages at 10, 33 and 50 meters above ground at fourteen geographically dispersed potential wind farm sites. Winds in the Midwest are primarily generated by fronts moving through the region. The Northwest Buffalo Ridge area of Iowa typically has wind speed averages …

Plasmas generated by irradiating targets with {approx}20 kJ of laser energy are routinely created in inertial confinement fusion research. X-ray spectroscopy provides one of the few methods for diagnosing the electron temperature and electron density. For example, electron densities approaching 10{sup 24} cm{sup -3} have been diagnosed by spectral linewidths. However, the accuracy of the spectroscopic diagnostics depends on the population kinetics, the radiative transfer, and the line shape calculations. Analysis for the complex line transitions has recently been improved and accelerated by the use of a database where detailed calculations can be accessed rapidly and interactively. Examples of data from Xe and Ar doped targets demonstrate the current analytic methods. First we will illustrate complications that arise from the presence of a multitude of underlying spectral lines. Then, we will consider the Ar He-like 1s{sup 2}({sup 1}S{sub 0}) - 1s3p({sup 1}P{sub 0}) transition where ion dynamic effects may affect the profile. Here, the plasma conditions are such that the static ion microfield approximation is no longer valid; therefore in addition to the width, the details of the line shape can be used to provide additional information. We will compare the data to simulations and discuss the possible pitfalls involved …

Femtosecond lasers enable materials processing of most any material with extremely high precision and negligible shock or thermal loading to the surrounding area. Applications ranging from drilling teeth to cutting explosives to precision cuts in composites are possible by using this technology. For material removal at reasonable rates, we have developed a fully computer-controlled 15-Watt average power, 100-fs laser machining system.

The purpose of the Mark 22 Flow Excursion Follow-On testing was to investigate the theory that approximately 15% of the flow bypassed the primary flow channels in previous testing, whereas the design called for only a 3% bypass. The results of the follow-on tests clearly confirmed this theory. The testing was performed in two phases. During the first phase, characterization tests performed during the earlier test program were repeated.

The purpose of the Mark 22 Flow Excursion Follow-On testing was to investigate the theory that approximately 15% of the flow bypassed the primary flow channels in previous testing, whereas the design called for only a 3% bypass. The results of the follow-on tests clearly confirmed this theory. The testing was performed in two phases. During the first phase, characterization tests performed during the earlier test program were repeated.

The left-right cross section asymmetry for Z boson production in e{sup +} e{sup {minus}} annihilation (A{sub LR}) is being measured at E{sub cm} 91.5 GeV with the SLD detector at the SLAC Linear Collider (SLC) using a longitudinally polarized electron beam. The electron polarization is continually monitored with a Compton scattering polarimeter, and is typically 22%. At the current time, we have accumulated a sample of 4779 Z events. We find that A{sub LR} = 0.02 {double_bond} 0.07 {doteq} 0.001 where the first error is statistical and the second is systematic. Using this very preliminary measurement, we determine the weak mixing angle defined at the Z boson pole to be sin{sup 2}{sub W}{sup olept} = 0.247 {plus_minus} 0.009.

The left-right cross section asymmetry for Z boson production in e[sup +] e[sup [minus]] annihilation (A[sub LR]) is being measured at E[sub cm] 91.5 GeV with the SLD detector at the SLAC Linear Collider (SLC) using a longitudinally polarized electron beam. The electron polarization is continually monitored with a Compton scattering polarimeter, and is typically 22%. At the current time, we have accumulated a sample of 4779 Z events. We find that A[sub LR] = 0.02 [double bond] 0.07 [doteq] 0.001 where the first error is statistical and the second is systematic. Using this very preliminary measurement, we determine the weak mixing angle defined at the Z boson pole to be sin[sup 2][sub W][sup olept] = 0.247 [plus minus] 0.009.

The generalized perturbation method, commonly used in connection with the band energy contribution to the energy of a solid to approximate the total energy of an ordered configuration of an alloy, is reformulated with respect to total energy. The connection of the results derived here to those obtained based on the band energy is pointed out, and possible applications of the method is discussed.

The Waste Isolation Pilot Plant (WIPP) is the first nuclear waste repository certified by the United States Environmental Protection Agency. Success in regulatory compliance resulted from an excellent natural setting for such a repository, a facility with multiple, redundant safety systems, and from a rigorous, transparent scientific and technical evaluation. The WIPP story, which has evolved over the past 25 years, has generated a library of publications and analyses. Details of the multifaceted program are contained in the cited references. Selected geotechnical highlights prove the eminent suitability of the WIPP to serve its congressionally mandated purpose.