Corrosion is much less predictable in organic or mixed-solvent environments than in aqueous process environments. As a result, US chemical companies face greater uncertainty when selecting process equipment materials to manufacture chemical products using organic or mixed solvents than when the process environments are only aqueous. Chemical companies handle this uncertainty by overdesigning the equipment (wasting money and energy), rather than by accepting increased risks of corrosion failure (personnel hazards and environmental releases). Therefore, it is important to develop simulation tools that would help the chemical process industries to understand and predict corrosion and to develop mitigation measures. To create such tools, we have developed models that predict (1) the chemical composition, speciation, phase equilibria, component activities and transport properties of the bulk (aqueous, nonaqueous or mixed) phase that is in contact with the metal; (2) the phase equilibria and component activities of the alloy phase(s) that may be subject to corrosion and (3) the interfacial phenomena that are responsible for corrosion at the metal/solution or passive film/solution interface. During the course of this project, we have completed the following: (1) Development of thermodynamic modules for calculating the activities of alloy components; (2) Development of software that generates stability diagrams …

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The Model 9977 Packaging was initially issued a Certificate of Compliance (CoC) by the Department of Energy’s Office of Environmental Management (DOE-EM) for the transportation of radioactive material (RAM) in the Fall of 2007. This first CoC was for a single radioactive material and two packing configurations. In the five years since that time, seven Addendums have been written to the Safety Analysis Report for Packaging (SARP) and five Letter Amendments have been written that have authorized either new RAM contents or packing configurations, or both. This paper will discuss the process of updating the 9977 SARP to include all the contents and configurations, including the addition of a new content, and its submittal for recertification.

For the transportation of Radioactive Material (RAM) packages, the requirements for the maximum allowed dose rate at the package surface and in its vicinity are given in Title 10 of the Code of Federal Regulations, Section 71.47. The regulations are based on the acceptable dose rates to which the public, workers, and the environment may be exposed. As such, the regulations specify dose rates, rather than quantity of radioactive isotopes and require monitoring to confirm the requirements are met. 10CFR71.47 requires that each package of radioactive materials offered for transportation must be designed and prepared for shipment so that under conditions normally incident to transportation the radiation level does not exceed 2 mSv/h (200 mrem/h) at any point on the external Surface of the package, and the transport index does not exceed 10. Before shipment, the dose rate of the package is determined by measurement, ensuring that it conforms to the regulatory limits, regardless of any analyses. This is the requirement for all certified packagings. This paper discusses the requirements for establishing the dose rates when shipping RAM packages and the precedents for meeting these requirements by measurement.

The H1700 Package is based on the DOE-EM Certified 9977 Packaging. The H1700 will be certified by the Packaging Certification Division of the National Nuclear Security Administration for the shipment of plutonium by air by the United Stated Military both within the United States and internationally. The H1700 is designed to ship radioactive contents in assemblies of Radioisotope Thermoelectric Generators (RTGs) or arrangements of nested food-pack cans. The RTG containers are designed and tested to remain leaktight during transport, handling, and storage; however, their ability to remain leaktight during transport in the H1700 is not credited. This paper discusses the design and special operation of the H1700.

National Security Technologies’ High Energy X-ray (HEX) Facility is unique in the U.S. Department of Energy complex. The HEX provides fluorescent X-rays of 5 keV to 100 keV with fluence of 10^5–10^6 photons/cm^2/second at the desired line energy. Low energy lines can be filtered, and both filters and fluorescers can be changed rapidly. We present results of calibrating image plates (sensitivity and modulation transfer function), a Bremsstrahlung spectrometer (stacked filters and image plates), and the National Ignition Facility’s Filter- Fluorescer Experiment (FFLEX) high energy X-ray spectrometer. We also show results of a scintillator light yield and alignment study for a neutron imaging system.

Radiation-induced changes in composition are studied because these changes can degrade failure of materials irradiated in nuclear reactors. In this work, the effect of alloy composition on radiation-induced segregation, hardening, and void swelling is presented. Five alloys, Fe-18Cr-8Ni, Fe-16Cr-13Ni, Fe-18Cr-40Ni, Fe-16Cr-13Ni+Mo, and Fe-16Cr-13Ni+Mo+P (all compositions in wt. %), were irradiated with 3.2 MeV protons at 400 C to a dose of 0.5 displacements per atom. The change in grain boundary composition was measured using field emission gun scanning transmission electron microscopy and the hardening was measured using Vickers indentation. Void swelling is calculated from the void size distribution measured using transmission electron microscopy. After irradiation, Cr depletes and Ni enriches at grain boundaries. Increasing bulk Ni concentration causes greater Cr depletion and Ni enrichment at grain boundaries. For alloys with 16 Cr, the addition of P reduces the Cr depletion and Ni enrichment. Hardening does not directly correlate with composition, but a framework for isolating the effect of hardening and segregation on cracking is suggested. The amount of void swelling in the irradiated material is shown to correspond inversely with segregation. Those alloys with greater segregation tend to swell less.

To assess the effects of long-term, low-dose-rate neutron exposure, tensile, hardness, and fracture properties were measured and microstructural characterization performed on irradiated 20% cold-worked Type 316 stainless steel. Samples were prepared from reactor core components retrieved from the EBR-II reactor following final shutdown. Sample locations were chosen to cover a dose range of 1-56 dpa at temperatures from 371-390 C and dose rates from 0.8-3.3 x 10{sup -7} dpa/s. Irradiation caused hardening, with the ultimate tensile strength (UTS) reaching about 800 MPa near 20 dpa and appearing to saturate at higher doses. The yield strength (YS) follows approximately the same trend as the ultimate tensile strength. At higher dose, the difference between the UTS and YS decreases, suggesting the work-hardening capability of the material is decreasing with increasing dose. The hardness and yield strength increases occur roughly over the same range of dose. While the material retained respectable ductility at 20 dpa, the uniform and total elongation decreased to <1 and <3%, respectively, at 47 dpa. Fracture in the 30 dpa specimen is mainly ductile but with local regions of mixed-mode failure, consisting mainly of dimples and microvoids. The fracture surface of the higher-exposure 47 dpa specimen displays more brittle …

Comparisons of the multicycle results demonstrate that the correlation coefficients based on the CASMO3 data were implemented correctly and that the Linear Reactivity Model is acceptably accurate for missed reloads containing both uranium and weapons plutonium fuel. The expanded set of correlation coefficients make BRACC a useful tool for performing multi-cycle in-core fuel management studies of PWR cores containing weapons plutonium.

A three-dimensional thermal analysis has been performed using finite difference techniques to determine the near-field response of a baseline spent fuel repository in a deep geologic salt medium. A baseline design incorporates previous thermal modeling experience and OWI recommendations for areal thermal loading in specifying the waste form properties, package details, and emplacement configuration. The base case in this thermal analysis considers one 10-year old PWR spent fuel assembly emplaced to yield a 36 kw/acre (8.9 w/m/sup 2/) loading. A unit cell model in an infinite array is used to simplify the problem and provide upper-bound temperatures. Boundary conditions are imposed which allow simulations to 1000 years. Variations studied include a comparison of ventilated and unventilated storage room conditions, emplacement packages with and without air gaps surrounding the canister, and room cool-down scenarios with ventilation following an unventilated state for retrieval purposes. At this low power level ventilating the emplacement room has an immediate cooling influence on the canister and effectively maintains the emplacement room floor near the temperature of the ventilating air. The annular gap separating the canister and sleeve causes the peak temperature of the canister surface to rise by 10/sup 0/F (5.6/sup 0/C) over that from a …

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Iron-aluminum alloys with 28 at.% Al and 5 at.% Cr were shown to be susceptible to hydrogen embrittlement by exposure to both gaseous hydrogen and water vapor. This study examined the effect of the addition of zirconium and carbon on the moisture-induced hydrogen embrittlement of an Fe{sub 3}Al,Cr alloy through the evaluation of tensile properties and fatigue crack growth resistance in hydrogen gas and moisture-bearing air. Susceptibility to embrittlement was found to vary with the zirconium content while the carbon addition was found to only affect the fracture toughness. Inherent fatigue crack growth resistance and fracture toughness, as measured in an inert environment, was found to increase with the addition of 0.5 at.% Zr. The combined addition of 0.5 at.% Zr and carbon only increased the fracture toughness. The addition of 1 at.% Zr and carbon was found to have no effect on the crack growth rate when compared to the base alloy. Susceptibility to embrittlement in moisture-bearing environments was found to decrease with the addition of 0.5 at.% Zr. In gaseous hydrogen, the threshold value of the Zr-containing alloys was found to increase above that found in the inert environment while the crack growth resistance was much lower. By …

New houses designed by Mercedes Homes in Melbourne, Florida, with technical support from the U.S. Department of Energy's Building America Program, save their homeowners money by using energy efficient features such as a high performance heat pump and solar control glazing to reduce cooling costs.

The candidate division Korarchaeota comprises a group of uncultivated microorganisms that, by their small subunit rRNA phylogeny, may have diverged early from the major archaeal phyla Crenarchaeota and Euryarchaeota. Here, we report the initial characterization of a member of the Korarchaeota with the proposed name,"Candidatus Korarchaeum cryptofilum," which exhibits an ultrathin filamentous morphology. To investigate possible ancestral relationships between deep-branching Korarchaeota and other phyla, we used whole-genome shotgun sequencing to construct a complete composite korarchaeal genome from enriched cells. The genome was assembled into a single contig 1.59 Mb in length with a G + C content of 49percent. Of the 1,617 predicted protein-coding genes, 1,382 (85percent) could be assigned to a revised set of archaeal Clusters of Orthologous Groups (COGs). The predicted gene functions suggest that the organism relies on a simple mode of peptide fermentation for carbon and energy and lacks the ability to synthesize de novo purines, CoA, and several other cofactors. Phylogenetic analyses based on conserved single genes and concatenated protein sequences positioned the korarchaeote as a deep archaeal lineage with an apparent affinity to the Crenarchaeota. However, the predicted gene content revealed that several conserved cellular systems, such as cell division, DNA replication, and tRNA …

The Soudan 1 experiment has obtained additional evidence for underground muons associated with the x-ray pulsar Cygnus X-3. We report the preliminary analysis of data recorded during the October 1985 radio outburst of Cygnus X-3, which show a significant excess of muons for a narrow range of Cygnus X-3 phases.

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Since radiation fields of space contain many-fold more protons than high atomic number, high energy (HZE) particles, cells in astronaut crews will experience on average several proton hits before an HZE hit. Thus radiation regimes of proton exposure before HZE particle exposure simulate space radiation exposure, and measurement of the frequency of neoplastic transformation of human primary cells to anchorage-independent growth simulates in initial step in cancer induction. Previously our group found that exposure to 20 cGy 1 GeV/n protons followed within about 1 hr by a HZE ion (20 cGy 1 GeV/n Fe or Ti ions) hit gave about a 3-fold increase in transformation frequency ([1]). To provide insight into the H-HZE induced increased transformation frequencies, we asked if split doses of the same ion gave similar increased transformation frequencies. However, the data show that the split dose of 20 cGy plus 20 cGy of either H or HZE ions gave about the same effect as the 40 cGy uninterrupted dose, quite different from the effect of the mixed ion H + HZE irradiation. We also asked if lower proton doses than 20 cGy followed 15 minutes later by 20 cGy of HZE ions gave greater than additive transformation …

A process model was used to better understand the controls on the chemical evolution of drainage in a historic mining district. At the Pecos Mine Operable Unit, New Mexico, drainage near the waste rock pile is acidic (pH varies from 3.0--5.0) and carries high concentrations of Zn, Al, Cu and Pb. As drainage flows toward the Pecos River, pH increases to greater than 7 and heavy metal content decreases. A process model of natural attenuation in this drainage shows the main controls on pH are reaction with a local bedrock that contains limestone, and concurrent mixing with tributary streams. Models that account for both calcite dissolution and mixing reproduce the observed decrease in aqueous metal concentrations with increasing pH. Contaminant concentrations attenuate primarily via two distinct pathways: Al, Cu, Fe and Pb precipitate directly from solution, whereas Zn, Mg, Mn and SO{sub 4} concentrations decrease primarily through dilution. Additionally, Pb adsorbs to precipitating hydroxide surfaces.

This report is the second of a two-part study by BerkeleyLab of a DER (distributed energy resources) system at Navy Base VenturaCounty (NBVC). First, a preliminary assessment ofthe cost effectivenessof distributed energy resources at Naval Base Ventura County (NBVC)Building 1512 was conducted in response to the base s request for designassistance to the Federal Energy Management Program (Bailey and Marnay,2004). That report contains a detailed description of the site and theDER-CAM (Consumer Adoption Model) parameters used. This second reportcontains sensitivity analyses of key parameters in the DER system modelof Building 1512 at NBVC and additionally considers the potential forabsorption-powered refrigeration.The prior analysis found that under thecurrent tariffs, and given assumptions about the performance andstructure of building energy loads and available generating technologycharacteristics, installing a 600 kW DER system with absorption coolingand recovery heat capabilities could deliver cost savings of about 14percent, worth $55,000 per year. However, under current conditions, thisstudy also suggested that significant savings could be obtained ifBuilding 1512 changed from its current direct access contract to a SCETOU-8 (Southern California Edison time of use tariff number 8) ratewithout installing a DER system. Evaluated on this tariff, the potentialsavings from installation of a DER system would be about 4 …

In 2002, the EPA amended 40 CFR 61 Subpart H and 40 CFR 61 Appendix B Method 114 to include requirements from ANSI/HPS N13.1-1999 Sampling and Monitoring Releases of Airborne Radioactive Substances from the Stack and Ducts of Nuclear Facilities for major emission points. Additionally, the WDOH amended the Washington Administrative Code (WAC) 246-247 Radiation protection-air emissions to include ANSI/HPS N13.1-1999 requirements for major and minor emission points when new permitting actions are approved. A result of the amended regulations is the requirement to prepare a written technical basis for the radiological air emission sampling and monitoring program. A key component of the technical basis is the Potential Impact Category (PIC) assigned to an emission point. This paper discusses the PIC assignments for the Pacific Northwest National Laboratory (PNNL) Integrated Laboratory emission units; this revision includes five PIC categories.

The distribution of galaxies in position and velocity around the centers of galaxy clusters encodes important information about cluster mass and structure. Using the maxBCG galaxy cluster catalog identified from imaging data obtained in the Sloan Digital Sky Survey, we study the BCG--galaxy velocity correlation function. By modeling its non-Gaussianity, we measure the mean and scatter in velocity dispersion at fixed richness. The mean velocity dispersion increases from 202 {+-} 10 km s{sup -1} for small groups to more than 854 {+-} 102 km s{sup -1} for large clusters. We show the scatter to be at most 40.5{+-}3.5%, declining to 14.9{+-}9.4% in the richest bins. We test our methods in the C4 cluster catalog, a spectroscopic cluster catalog produced from the Sloan Digital Sky Survey DR2 spectroscopic sample, and in mock galaxy catalogs constructed from N-body simulations. Our methods are robust, measuring the scatter to well within one-sigma of the true value, and the mean to within 10%, in the mock catalogs. By convolving the scatter in velocity dispersion at fixed richness with the observed richness space density function, we measure the velocity dispersion function of the maxBCG galaxy clusters. Although velocity dispersion and richness do not form a true …

Introduction: Shock-dispersed fuel (SDF) explosives use a small chemical charge to disperse a combustible fuel that burns in the post-detonation environment. The energy released in the combustion process has the potential for generating higher pressures and temperatures than conventional explosives. However, the development of these types of novel explosive systems requires a detailed understanding of all of the modes of energy release. Objective: The objective of this project is develop a simulation capability for predicting explosion and combustion phase of SDF charges and apply that capability to quantifying the behavior of these types of explosives. Methodology: We approximate the dynamics of an SDF charge using high Reynolds number, fast chemistry model that effectively captures the thermodynamic behavior of SDF charges and accurately models the key modes of energy release. The overall computational model is combined with Adaptive Mesh Refinement (AMR) , implemented in a parallel adaptive framework suited to the massively parallel computer systems. Results: We have developed a multiphase version of the model and used it to simulate an SDF charge in which the dispersed fuel is aluminum flakes. Flow visualizations show that the combustion field is turbulent for the chamber and tunnel cases studied. During the 3 milli-seconds …

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A kinetic study of the accumulation of C{sup 14} in the intermediates of steady state photosynthesis in C{sup 14}O{sub 2} provides information regarding the sequence of reactions involved. The work described applied the radio-chromatographic technique for analysis of the labeled early products. The simultaneous carboxylation reaction resulting in malic acid as well as phosphoglycerate is demonstrated in experiments at high light intensity. A comparison of radioactivities in a number of phosphorylated sugars as a function of time reveals concurrent synthesis of fructose and sedoheptulose phosphates followed by that of ribulose phosphates and later by that of glucose phosphates. The possibility that the cleavage of C{sub 4} compounds to C{sub 2} carbon dioxide acceptors may involve C{sub 7} and C{sub 5} sugars and evidence for this mechanism is presented.