The objective of this work is to determine the range of conditions where the tank steel is susceptible to localized corrosion and SCC in simulants for waste in tanks AY-102 and AP-101.

This Report is about the description of the survival rate of charge 90+ uranium ions in the AGS vacuum.

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The solubility of CeO2 and ThO2 in aqueous NaNO3 solutions was studied as a function of pH and ionic strength, and the concentration of the organic ligands: citrate, EDTA, and oxalate. The main findings of the study are that these organic ligands increase the solubility of CeO2 markedly via the formation of complexes. On the other hand, the solubility of ThO2 was not affected by the presence of these ligands at levels of several hundred micromolar. These results have implications for the behavior of Pu(IV), for which Ce(IV) and Th(IV) are analogues.

This report summarizes the work done on the project over the duration of the project, from October 1, 2002 through December 31, 2003, which includes a three month no-cost extension. Effort was directed in the following areas: (1) Fabrication of Sr-doped LaCoO3 (LSC) dense and porous samples. (2) Design and construction of a conductivity relaxation apparatus for the estimation of surface exchange coefficient, k{sub chem}, which depends on adsorption, and oxygen chemical diffusion coefficient, {tilde D}{sub 0}, the parameters which are thought to describe the cathodic activation polarization (overall charge transfer) in mixed ionic electronic conducting (MIEC) cathodes. (3) The measurement of and K{sub chem} and {tilde D}{sub 0} on LSC by conductivity relaxation, as a function of temperature and oxygen partial pressure, p{sub O{sub 2}}. (4) Fabrication of YSZ electrolyte discs with patterned LSM and LSC electrodes with three-phase boundary (TPB) length, l{sub TPB}, varying between 50 and 1200 cm{sup -1}. (5) The measurement of charge transfer resistance, R{sub ct}, and estimation of the charge transfer resistivity, {rho}{sub ct}, as a function of temperature and p{sub O{sub 2}}, and the incorporation of the adsorption step in the analysis. (6) Preliminary cell tests with oxidants having different inert gas diluents; …

A goal of the Department of Energy project management system is to ensure that projects are necessary to fulfill mission needs and are cost effective. This requires that the Department justify each project and explore competitive alternatives. The objective of this audit was to assess the need to construct protective force training facilities at the Department`s Pantex Plant. Our audit disclosed that (1) construction of a physical training facility was not necessary to fulfill mission needs, and (2) the Department did not consider all viable alternatives to constructing a weapons tactics and training facility. These conditions occurred, in part, because a Justification for New Start was never prepared and approved for the Security Enhancements Major System Acquisition, which included these two projects. We recommended that the Manager, Albuquerque Operations Office, cancel construction of the physical training facility, make needed repairs and upgrades to the existing facilities, and reduce the cost of the Security Enhancements Major System Acquisition accordingly. Implementation of this recommendation will save about $1.7 million. We also recommended that the Manager direct Mason & Hanger to perform economic analyses of all viable alternatives to constructing a weapons tactics and training facility before proceeding with construction. Such analyses could …

Functional requirements and specifications document for system to replace tank farm computer automated waste tank surveillance system.

This systems Engineering Management and Implementation Plan (SEMIP) describes the Project W-211 implementation of the Tank Farm Contractor Systems Engineering Management Plan (TFC SEMP). The SEMIP defines the systems engineering products and processes used by the project to comply with the TFC SEMP, and provides the basis for tailoring systems engineering processes by applying a graded approach to identify appropriate systems engineering requirements for W-211.

A redesign of the LOFT instrument penetration necessitated a reanalysis of the thermal conditions existing in the nozzle and flange during a Loss of Coolant Experiment (LOCE). The maximum temperature gradient existing in the instrument flange will be used to determine the thermal stresses and maximum number of allowable cycles for the instrument flange. Based upon the specification and thermal conditions predicted by RELAP4/MOD5, the maximum temperature gradient through the flange will not exceed 216/sup 0/F. The thermal conditions predicted by RELAP4/MOD2 for the nozzle head penetration assembly were less severe than those used in the original thermal-stress analysis, so only the flange was analyzed here. If the thermal stresses are marginal with the 216/sup 0/F ..delta..T, a more detailed analysis should be done as the heat slab model used in RELAP is only one dimensional. Conservative hand calculations were performed for a heatup rate of 100/sup 0/F per hour and it was determined that the worst temperature gradient through the flange will be less than 81/sup 0/F.

A hydrologic test system has been designed to measure the intrinsic permeabilities of individual fractures in crystalline rock. This system is used to conduct constant pressure-declining flow rate and pressure pulse hydraulic tests. The system is composed of four distinct units: (1) the Packer System, (2) Injection system, (3) Collection System, and (4) Electronic Data Acquisition System. The apparatus is built in modules so it can be easily transported and re-assembled. It is also designed to operate over a wide range of pressures (0 to 300 psig) and flow rates (0.2 to 1.0 gal/min). This system has proved extremely effective and versatile in its use at the Climax Facility, Nevada Test Site.

An empirical study was conducted to evaluate cutting fluids for Single Point Diamond Turning (SPDT) of single crystal silicon. The pH of distilled waster was adjusted with various additives the examine the effect of pH on cutting operations. Fluids which seemed to promote ductile cutting appeared to increase tool wear as well, an undesirable tradeoff. High Ph sodium hydroxide solutions showed promise for further research, as they yielded the best combination of reduced tool wear and good surface finish in the ductile regime. Negative rake tools were verified to improve the surface finish, but the negative rake tools used in the experiments also showed much higher wear than conventional 0{degree} rake tools. Effects of crystallographic orientation on SPDT, such as star patterns of fracture damage forming near the center of the samples, were observed to decrease with lower feedrates. Silicon chips were observed and photographed, indicative of a ductile materials removal process.

In the last 5 years, significant technology advances have been made in the performance, size, and cost of solid-state diode-pumped lasers. These developments enable the use of compact Q-switched Nd:YAG lasers as a beam diagnostic for high current H{sup {minus}} beams. Because the threshold for photodetachment is only 0.75 eV, and the maximum detachment cross section is 4 {times} 10{sup {minus}17} cm{sup 2} at 1.5 eV, a 50 mJ/pulse Q-switched Nd:YAG laser can neutralize a significant fraction of the beam in a single 10-ns wide pulse. The neutral beam maintains nearly identical parameters as the parent H{sup {minus}} beam, including size, divergence, energy, energy spread, and phase spread. A dipole magnet can separate the neutral beam from the H{sup {minus}} beam to allow diagnostics on the neutral beam without intercepting the high-current H{sup {minus}} beam. Such a laser system can also be used to extract a low current proton beam, or to induce fluorescence in partially stripped heavy ion beams. Possible beamline diagnostic systems will be reviewed, and the neutral beam yields will be calculated.

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste, stored in Tank 241-BX-111. This report supports the requirements of the Tri-Party Agreement Milestone M-44-ISB.

The general objectives are to (1) to identify and develop gelled polymer systems which have potential to improve reservoir conformance of fluid displacement processes, (2) to determine the performance of these systems in bulk and in porous media, and (3) to develop methods to predict the capability of these systems to recover oil from petroleum reservoirs. This work focuses on three types of gel systems - an aqueous polysaccharide (KUSP1) system that gels as a function of pH, the chromium(III)-polyacrylamide system and the aluminum citrate-polyacrylamide system. Laboratory research is directed at the fundamental understanding of the physics and chemistry of the gelation process in bulk form and in porous media. This knowledge will be used to develop conceptual and mathematical models of the gelation process. Mathematical models will then be extended to predict the performance of gelled polymer treatments in oil reservoirs. Technical progress of Task III, mechanisms of in situ gelation is presented in this progress report.

The French and British nuclear programs have prepared a series of natural uranium oxide fuel samples spiked with small amounts of the individual fission products which makeup a large fraction of the total neutron absorption by fission products in spent nuclear fuel. Both programs have utilized these samples in experimental reactors and have inferred the worth of the individual fission products. These results have been used to validate the cross sections used in criticality safety calculations. These measurements constitute a major element in support of spent fuel burnup credit in these countries.

Two one-segment core samples from tank 241-U-203 (U-203) were received by the 222-S Laboratories and underwent safety screening analysis, consisting of differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and total alpha activity. In addition to the safety screening requirements, inductively coupled plasma (ICP) spectrographic analysis for lithium was performed to determine the extent of hydrostatic head fluid contamination during the sampling event. No notification limits were exceeded for these analyses.

Tank 241-C-108 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in Program Plan for the Resolution of Tank Vapor Issues (Osborne and Huckaby 1994). Tank 241-C-108 was vapor sampled in accordance with Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution (Osborne et al., 1994).

This report documents a finite element code designed to model subsurface flow and contaminant transport, named FACT. FACT is a transient three-dimensional, finite element code designed to simulate isothermal groundwater flow, moisture movement, and solute transport in variably saturated and fully saturated subsurface porous media.

Tank 241-BY-107 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues{close_quotes}. Tank 241-BY-107 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution{close_quotes}.

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Most chemistry in nature occurs within a closed and confined space. In contrast to this time-evolved [m?] organic chemists have focused their interests in developing reaction methods in solution. The price for this is paid in terms of non-selectivity in product formation, expensive reagents, and enormous wastes. Eventually 'man-developed' solution methods to make molecules have to be replaced by more selective, more environmentally friendly, and less expensive strategies. One approach in this direction would be to use controlled environments. The project focused towards developing energy efficient methods to prepare energy rich molecules that were useful to the public. In this context synthetic zeolites, the counterpart of naturally occurring minerals, were explored as the reaction media.

Crossflow filtration will be used to filter radioactive waste slurry as part of the Late Wash Process.

Purpose of this document is to define the system requirements necessary to improve computer support for the WHC backlog waste business process through enhancements to the backlog waste function of the SWITS system. This SRS document covers enhancements to the SWITS system to support changes to the existing Backlog Waste screens including new data elements, label changes, and new pop-up screens. The pop-ups will allow the user to flag the processes that a waste container must have performed on it, and will provide history tracking of changes to data. A new screen will also be provided allowing Acceptable Services to perform mass updates to specific data in Backlog Waste table. The SWITS Backlog Waste enhancements in this document will support the project goals in WHC-SD-WM-003 and its Revision 1 (Radioactive Solid Waste Tracking System Conceptual Definition) for the control, tracing, and inventory management of waste as the packages are generated and moved through final disposal (cradle-to-grave).