Electrochemical cell having cyclindircal electrode elements (open access)

Electrochemical cell having cyclindircal electrode elements

A secondary, high temperature electrochemical cell especially adapted for lithium alloy negative electrodes, transition metal chalcogenide positive electrodes and alkali metal halide or alkaline earth metal halide electrolyte is disclosed. The cell is held within an elongated cylindrical container in which one of the active materials is filled around the outside surfaces of a pluraity of perforate tubular current collectors along the length of the container. Each of the current collector tubes contain a concentric atubular layer of electrically insulative ceramic as an interelectrode separator. The active material of opposite polarity in elongated pin shape is positioned longitudinally within the separator layer. A second electrically conductive tube with perforate walls can be swagged or otherwise bonded to the outer surface of the pin as a current cllector and the electrically insulative ceramic layer can be coated or otherwise layered onto the outer surface of this second current collector. Alternatively, the central pin electrode can include an axial core as a current collector.
Date: March 5, 1981
Creator: Nelson, P.A. & Shimotake, H.
System: The UNT Digital Library
Nuclear reactor fuel-assembly duct-tube-to-handling-socket attachment system. [LMFBR] (open access)

Nuclear reactor fuel-assembly duct-tube-to-handling-socket attachment system. [LMFBR]

A reusable system is described for removably attaching the upper end of a nuclear reactor duct tube to the lower end of a nuclear reactor fuel assembly handling socket. A transition ring, fixed to the duct tube's upper end, has an interior-threaded section with a first locking hole segment. An adaptor ring, fixed to the handling socket's lower end has an outside-threaded section with a second locking hole segment. The inside and outside threaded sections match and can be joined so that the first and second locking hole segments can be aligned to form a locking hole. A locking ring, with a locking pin, slides over the adaptor ring so that the locking pin fits in the locking hole. A swage lock or a cantilever finger lock is formed from the locking cup collar to fit in a matching groove in the locking ring to prevent the locking ring's locking pin from backing out of the locking hole.
Date: March 5, 1981
Creator: unknown
System: The UNT Digital Library
Chloromethyl chlorosulfate as a voltage delay inhibitor in lithium cells (open access)

Chloromethyl chlorosulfate as a voltage delay inhibitor in lithium cells

Chloromethyl chlorosulfate (CMCS) is used as a passive film growth inhibitor in electrochemical cells to minimize voltage delay and low-voltage discharge. Film growth on lithium anodes is significantly diminished when CMCS is added to SOCl{sub 2} and SO{sub 2}Cl{sub 2} electrolytes of lithium batteries. The CMCS also has the effect of extending the shelf-life of Li/SOCl{sub 2} and Li/SO{sub 2}Cl{sub 2} batteries.
Date: April 5, 1991
Creator: Delnick, F. M.
System: The UNT Digital Library
Oxidation resistant alloys, method for producing oxidation resistant alloys (open access)

Oxidation resistant alloys, method for producing oxidation resistant alloys

A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800 C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800 C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700 C. at a low cost
Date: November 5, 2002
Creator: Dunning, John S. & Alman, David E.
System: The UNT Digital Library
Method and apparatus for aligning a solar concentrator using two lasers (open access)

Method and apparatus for aligning a solar concentrator using two lasers

A method and apparatus are provided for aligning the facets of a solar concentrator. A first laser directs a first laser beam onto a selected facet of the concentrator such that a target board positioned adjacent to the first laser at approximately one focal length behind the focal point of the concentrator is illuminated by the beam after reflection thereof off of the selected facet. A second laser, located adjacent to the vertex of the optical axis of the concentrator, is used to direct a second laser beam onto the target board at a target point thereon. By adjusting the selected facet to cause the first beam to illuminate the target point on the target board produced by the second beam, the selected facet can be brought into alignment with the target point. These steps are repeated for other selected facets of the concentrator, as necessary, to provide overall alignment of the concentrator.
Date: October 5, 2000
Creator: Diver, Richard Boyer Jr.
System: The UNT Digital Library
Method for Making a Uranium Chloride Salt Product (open access)

Method for Making a Uranium Chloride Salt Product

The subject apparatus provides a means to produce UCl3, in large quantities without incurring corrosion of the containment vessel or associated apparatus. Gaseous Cl is injected into a lower layer of Cd where CdCl2 is formed. Due to is lower density, the CdCl2 rises through the Cd layer into a layer of molten LiCl-KCL salt where a rotatable basket containing uranium ingots is suspended. The CdCl2 reacts with the uranium to form UCl, and Cd. Due to density differences, the Cd sinks down to the liquid Cd layer and is reused. The UCl3 combines with the molten salt. During production the temperature is maintained at about 600 degrees C. while after the uranium has been depleted the salt temperature is lowered, the molten salt is pressure siphoned from the vessel, and the salt product LiCl-KCl-30 mol% UCl3 is solidified.
Date: October 5, 2004
Creator: Miller, William F. & Tomczuk, Zygmunt
System: The UNT Digital Library
Control Coil Arrangement for a Rotating Machine Rotor (open access)

Control Coil Arrangement for a Rotating Machine Rotor

A rotating machine (e.g., a turbine, motor or generator) is provided wherein a fixed solenoid or other coil configuration is disposed adjacent to one or both ends of the active portion of the machine rotor for producing an axially directed flux in the active portion so as to provide planar axial control at single or multiple locations for rotor balance, levitation, centering, torque and thrust action. Permanent magnets can be used to produce an axial bias magnetic field. The rotor can include magnetic disks disposed in opposed, facing relation to the coil configuration.
Date: May 5, 1999
Creator: Shah, Manoj R. & Lewandowski, Chad R.
System: The UNT Digital Library
Stator for Rotating Electrical Machine Having Multiple Controlwindings (open access)

Stator for Rotating Electrical Machine Having Multiple Controlwindings

A rotating electric machine is provided which includes multiple independent control windings for compensating for rotor imbalances and for levitating/centering the rotor. The multiple independent control windings are placed at different axial locations along the rotor to oppose forces created by imbalances at different axial locations along the rotor. The multiple control windings can also be used to levitate/center the rotor with a relatively small magnetic field per unit area since the rotor and/or the main power winding provides the biasfield.
Date: May 5, 1999
Creator: Shah, Manoj R. & Lewandowski, Chad R.
System: The UNT Digital Library
Fabrication of Photonic band gap Materials (open access)

Fabrication of Photonic band gap Materials

A method for forming a periodic dielectric structure exhibiting photonic band gap effects includes forming a slurry of a nano-crystalline ceramic dielectric or semiconductor material and monodisperse polymer microsphere, depositing a film of the slurry on a substrate, drying the film, and calcining the film to remove the polymer microsphere there from. The film may be cold-pressed after drying and prior to calcining. The ceramic dielectric or semiconductor material may be titania, and the polymer microsphere may be polystyrenemicrosphere.
Date: January 5, 2000
Creator: Constant, Kristen; Subramania, Ganapathi S.; Biswas, Rana & Ho, Kai-Ming
System: The UNT Digital Library
Reduction of B-Integral Accumulation in Lasers (open access)

Reduction of B-Integral Accumulation in Lasers

A pulsed laser is provided wherein the B-integral accumulated in the laser pulse is reduced using a semiconductor wafer. A laser pulse is generated by a laser pulse source. The laser pulse passes through a semiconductor wafer that has a negative nonlinear index of refraction. Thus, the laser pulse accumulates a negative B-integral. The laser pulse is then fed into a laser amplification medium, which has a positive nonlinear index of refraction. The laser pulse may make a plurality of passes through the laser amplification medium and accumulate a positive B-integral during a positive non-linear phase change. The semiconductor and laser pulse wavelength are chosen such that the negative B-integral accumulated in the semiconductor wafer substantially cancels the positive B-integral accumulated in the laser amplification medium. There may be additional accumulation of positive B-integral if the laser pulse passes through additional optical mediums such as a lens or glass plates. Thus , the effects of self-phase modulation in the laser pulse are substantially reduced.
Date: June 5, 1998
Creator: Meyerhofer, David D. & Konoplev, Oleg A.
System: The UNT Digital Library
Polymer Coating for Immobilizing Soluble Ions in a Phosphate Ceramic Product (open access)

Polymer Coating for Immobilizing Soluble Ions in a Phosphate Ceramic Product

A polymer coating is applied to the surface of a phosphate ceramic composite to effectively immobilize soluble salt anions encapsulated within the phosphate ceramic composite. The polymer coating is made from ceramic materials, including at least one inorganic metal compound, that wet and adhere to the surface structure of the phosphate ceramic composite, thereby isolating the soluble salt anions from the environment and ensuring long-term integrity of the phosphate ceramic composite.
Date: May 5, 1999
Creator: Singh, Dileep; Wagh, Arun S. & Patel, Kartikey D.
System: The UNT Digital Library
Method for Producing Chemically Bonded Phosphate Ceramics and for Stabilizing Contaminants Encapsulated therein Utilizing Reducing Agents (open access)

Method for Producing Chemically Bonded Phosphate Ceramics and for Stabilizing Contaminants Encapsulated therein Utilizing Reducing Agents

Known phosphate ceramic formulations are improved and the ability to produce iron-based phosphate ceramic systems is enabled by the addition of an oxidizing or reducing step during the acid-base reactions that form the phosphate ceramic products. The additives allow control of the rate of the acid-base reactions and concomitant heat generation. In an alternate embodiment, waste containing metal anions is stabilized in phosphate ceramic products by the addition of a reducing agent to the phosphate ceramic mixture. The reduced metal ions are more stable and/or reactive with the phosphate ions, resulting in the formation of insoluble metal species within the phosphate ceramic matrix, such that the resulting chemically bonded phosphate ceramic product has greater leach resistance.
Date: May 5, 1999
Creator: Singh, Dileep; Wagh, Arun S. & Jeong, Seung-Young
System: The UNT Digital Library
Method for the Removal of Ultrafine Particulates from an Aqueous Suspension (open access)

Method for the Removal of Ultrafine Particulates from an Aqueous Suspension

A method of separating ultra-fine particulate from an aqueous suspension such as a process stream or a waste stream. The method involves the addition of alkali silicate and an organic gelling agent to a volume of liquid, from the respective process or waste stream, to form a gel. The gel then undergoes syneresis to remove water and soluble salts from the gel-containing the particulate, thus, forming a silica monolith. The silica monolith is then sintered to form a hard, nonporous waste form.
Date: March 5, 1999
Creator: Chaiko, David J.; Kopasz, John P. & Ellison, Adam J. G.
System: The UNT Digital Library