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3D Simulations of the NIF Indirect Drive Ignition Target Design (open access)

3D Simulations of the NIF Indirect Drive Ignition Target Design

The radiation hydrodynamics code Hydra is used to quantify the sensitivity of different NIF ignition point designs to several 3D effects. Each of the 48 NIF quads is included in the calculations and is allowed to have different power. With this model they studied the effect on imploded core symmetry of discrete laser spots (as opposed to idealized azimuthally-averaged rings) and random variations in laser power.
Date: January 5, 2010
Creator: Jones, O. S.; Milovich, J. L.; Callahan, D. A.; Edwards, M. J.; Landen, O. L.; Salmonson, J. D. et al.
System: The UNT Digital Library
COMPARISON OF OXALIC ACID CLEANING RESULTS AT SRS AND HANFORD AND THE IMPACT ON ENHANCED CHEMICAL CLEANING DEPLOYMENT (open access)

COMPARISON OF OXALIC ACID CLEANING RESULTS AT SRS AND HANFORD AND THE IMPACT ON ENHANCED CHEMICAL CLEANING DEPLOYMENT

Waste tanks must be rendered clean enough to satisfy very rigorous tank closure requirements. During bulk waste removal, most of the radioactive sludge and salt waste is removed from the waste tank. The waste residue on the tank walls and interior components and the waste heel at the bottom of the tank must be removed prior to tank closure to render the tank clean enough to meet the regulatory requirement for tank closure. Oxalic acid has been used within the DOE complex to clean residual materials from carbon steel tanks with varying degrees of success. Oxalic acid cleaning will be implemented at both the Savannah River Site and Hanford to clean tanks and serves as the core cleaning technology in the process known as Enhanced Chemical Cleaning. Enhanced Chemical Cleaning also employs a process that decomposes the spent oxalic acid solutions. The oxalic acid cleaning campaigns that have been performed at the two sites dating back to the 1980's are compared. The differences in the waste characteristics, oxalic acid concentrations, flushing, available infrastructure and execution of the campaigns are discussed along with the impact on the effectiveness of the process. The lessons learned from these campaigns that are being incorporated …
Date: January 5, 2010
Creator: Spires, R. & Ketusky, E.
System: The UNT Digital Library
Derivation and Solution of Multifrequency Radiation Diffusion Equations for Homogeneous Refractive Lossy Media (open access)

Derivation and Solution of Multifrequency Radiation Diffusion Equations for Homogeneous Refractive Lossy Media

Starting from the radiation transport equation for homogeneous, refractive lossy media, we derive the corresponding time-dependent multifrequency diffusion equations. Zeroth and first moments of the transport equation couple the energy density, flux and pressure tensor. The system is closed by neglecting the temporal derivative of the flux and replacing the pressure tensor by its diagonal analogue. The system is coupled to a diffusion equation for the matter temperature. We are interested in modeling annealing of silica (SiO{sub 2}). We derive boundary conditions at a planar air-silica interface taking account of reflectivities. The spectral dimension is discretized into a finite number of intervals leading to a system of multigroup diffusion equations. Three simulations are presented. One models cooling of a silica slab, initially at 2500 K, for 10 s. The other two are 1D and 2D simulations of irradiating silica with a CO{sub 2} laser, {lambda} = 10.59 {micro}m. In 2D, we anneal a disk (radius = 0.4, thickness = 0.4 cm) with a laser, Gaussian profile (r{sub 0} = 0.5 mm for 1/e decay).
Date: January 5, 2010
Creator: Shestakov, A I; Vignes, R M & Stolken, J S
System: The UNT Digital Library
Dihadron Azimuthal Correlation from Collins Effect in Unpolarized Hadron Collisions (open access)

Dihadron Azimuthal Correlation from Collins Effect in Unpolarized Hadron Collisions

We study the dihadron azimuthal correlation produced nearly back-to-back in unpolarized hadron collisions, arising from the product of two Collins fragmentation functions. Using the latest Collins fragmentation functions extracted from the global analysis of available experimental data, we make predictions for the azimuthalcorrelation of two-pion production in pp collisions at RHIC energies. We find that the correlation is sizable in the mid-rapidity region for moderate jet transverse momentum.
Date: January 5, 2010
Creator: Yuan, Feng
System: The UNT Digital Library
Elastic properties of Pu metal and Pu-Ga alloys (open access)

Elastic properties of Pu metal and Pu-Ga alloys

We present elastic properties, theoretical and experimental, of Pu metal and Pu-Ga ({delta}) alloys together with ab initio equilibrium equation-of-state for these systems. For the theoretical treatment we employ density-functional theory in conjunction with spin-orbit coupling and orbital polarization for the metal and coherent-potential approximation for the alloys. Pu and Pu-Ga alloys are also investigated experimentally using resonant ultrasound spectroscopy. We show that orbital correlations become more important proceeding from {alpha} {yields} {beta} {yields} {gamma} plutonium, thus suggesting increasing f-electron correlation (localization). For the {delta}-Pu-Ga alloys we find a softening with larger Ga content, i.e., atomic volume, bulk modulus, and elastic constants, suggest a weakened chemical bonding with addition of Ga. Our measurements confirm qualitatively the theory but uncertainties remain when comparing the model with experiments.
Date: January 5, 2010
Creator: Soderlind, P; Landa, A; Klepeis, J E; Suzuki, Y & Migliori, A
System: The UNT Digital Library
Environmental sensor networks and continuous data quality assurance to manage salinity within a highly regulated river basin (open access)

Environmental sensor networks and continuous data quality assurance to manage salinity within a highly regulated river basin

This paper describes a new approach to environmental decision support for salinity management in the San Joaquin Basin of California that focuses on web-based data sharing using YSI Econet technology and continuous data quality management using a novel software tool, Aquarius.
Date: January 5, 2010
Creator: Quinn, N.W.T.; Ortega, R. & Holm, L.
System: The UNT Digital Library
Phases of Augmented Hadronic Light-Front Wave Functions (open access)

Phases of Augmented Hadronic Light-Front Wave Functions

It is an important question whether the final/initial state gluonic interactions which lead to naive-time-reversal-odd single-spin asymmetries and diffraction at leading twist can be associated in a definite way with the light-front wave function hadronic eigensolutions of QCD. We use light-front time-ordered perturbation theory to obtain augmented light-front wave functions which contain an imaginary phase which depends on the choice of advanced or retarded boundary condition for the gauge potential in light-cone gauge. We apply this formalism to the wave functions of the valence Fock states of nucleons and pions, and show how this illuminates the factorization properties of naive-time-reversal-odd transverse momentum dependent observables which arise from rescattering. In particular, one calculates the identical leading-twist Sivers function from the overlap of augmented light-front wavefunctions that one obtains from explicit calculations of the single-spin asymmetry in semi-inclusive deep inelastic lepton-polarized nucleon scattering where the required phases come from the final-state rescattering of the struck quark with the nucleon spectators.
Date: January 5, 2010
Creator: Yuan, Feng; Brodsky, S.J.; Pasquini, B. & Xiao, B.-W.
System: The UNT Digital Library
POST-FIRE REVEGETATION AT HANFORD (open access)

POST-FIRE REVEGETATION AT HANFORD

Range fires on the Hanford Site can have a long lasting effect on native plant communities. Wind erosion following removal of protective vegetation from fragile soils compound the damaging effect of fires. Dust storms caused by erosion create health and safety hazards to personnel, and damage facilities and equipment. The Integrated Biological Control Program (IBC) revegetates burned areas to control erosion and consequent dust. Use of native, perennial vegetation in revegetation moves the resulting plant community away from fire-prone annual weeds, and toward the native shrub-steppe that is much less likely to burn in the future. Over the past 10 years, IBC has revegetated major fire areas with good success. IBC staff is monitoring the success of these efforts, and using lessons learned to improve future efforts.
Date: January 5, 2010
Creator: Roos, R. C.; Johnson, A. R.; Caudill, J. G.; Rodriguez, J. M. & Wilde, J. W.
System: The UNT Digital Library
Terrestrial biogeochemical feedbacks in the climate system: from past to future (open access)

Terrestrial biogeochemical feedbacks in the climate system: from past to future

The terrestrial biosphere plays a major role in the regulation of atmospheric composition, and hence climate, through multiple interlinked biogeochemical cycles (BGC). Ice-core and other palaeoenvironmental records show a fast response of vegetation cover and exchanges with the atmosphere to past climate change, although the phasing of these responses reflects spatial patterning and complex interactions between individual biospheric feedbacks. Modern observations show a similar responsiveness of terrestrial biogeochemical cycles to anthropogenically-forced climate changes and air pollution, with equally complex feedbacks. For future conditions, although carbon cycle-climate interactions have been a major focus, other BGC feedbacks could be as important in modulating climate changes. The additional radiative forcing from terrestrial BGC feedbacks other than those conventionally attributed to the carbon cycle is in the range of 0.6 to 1.6 Wm{sup -2}; all taken together we estimate a possible maximum of around 3 Wm{sup -2} towards the end of the 21st century. There are large uncertainties associated with these estimates but, given that the majority of BGC feedbacks result in a positive forcing because of the fundamental link between metabolic stimulation and increasing temperature, improved quantification of these feedbacks and their incorporation in earth system models is necessary in order to develop …
Date: January 5, 2010
Creator: Arneth, A.; Harrison, S. P.; Zaehle, S.; Tsigaridis, K.; Menon, S.; Bartlein, P. J. et al.
System: The UNT Digital Library
THERMODYNAMICS OF PARTIALLY FROZEN COOLING LAKES (open access)

THERMODYNAMICS OF PARTIALLY FROZEN COOLING LAKES

The Rochester Institute of Technology (RIT) collected visible, SWIR, MWIR and LWIR imagery of the Midland (Michigan) Cogeneration Ventures Plant from aircraft during the winter of 2008-2009. RIT also made ground-based measurements of lake water and ice temperatures, ice thickness and atmospheric variables. The Savannah River National Laboratory (SRNL) used the data collected by RIT and a 3-D hydrodynamic code to simulate the Midland cooling lake. The hydrodynamic code was able to reproduce the time distribution of ice coverage on the lake during the entire winter. The simulations and data show that the amount of ice coverage is almost linearly proportional to the rate at which heat is injected into the lake (Q). Very rapid melting of ice occurs when strong winds accelerate the movement of warm water underneath the ice. A snow layer on top of the ice acts as an insulator and decreases the rate of heat loss from the water below the ice to the atmosphere above. The simulated ice cover on the lake was not highly sensitive to the thickness of the snow layer. The simplicity of the relationship between ice cover and Q and the weak responses of ice cover to snow depth over the …
Date: January 5, 2010
Creator: Garrett, A.; Casterline, M. & Salvaggio, C.
System: The UNT Digital Library
Unvail the Mysterious of the Single Spin Asymmetry (open access)

Unvail the Mysterious of the Single Spin Asymmetry

Single transverse-spin asymmetry in high energy hadronic reaction has been greatly investigated from both experiment and theory sides in the last few years. In this talk, I will summarize some recent theoretical developments, which, in my opinion, help to unvail the mysterious of the single spin asymmetry.
Date: January 5, 2010
Creator: Yuan, Feng
System: The UNT Digital Library
Analytical Validation of Accelerator Mass Spectrometry for Pharmaceutical Development: the Measurement of Carbon-14 Isotope Ratio. (open access)

Analytical Validation of Accelerator Mass Spectrometry for Pharmaceutical Development: the Measurement of Carbon-14 Isotope Ratio.

Accelerator mass spectrometry (AMS) is an isotope based measurement technology that utilizes carbon-14 labeled compounds in the pharmaceutical development process to measure compounds at very low concentrations, empowers microdosing as an investigational tool, and extends the utility of {sup 14}C labeled compounds to dramatically lower levels. It is a form of isotope ratio mass spectrometry that can provide either measurements of total compound equivalents or, when coupled to separation technology such as chromatography, quantitation of specific compounds. The properties of AMS as a measurement technique are investigated here, and the parameters of method validation are shown. AMS, independent of any separation technique to which it may be coupled, is shown to be accurate, linear, precise, and robust. As the sensitivity and universality of AMS is constantly being explored and expanded, this work underpins many areas of pharmaceutical development including drug metabolism as well as absorption, distribution and excretion of pharmaceutical compounds as a fundamental step in drug development. The validation parameters for pharmaceutical analyses were examined for the accelerator mass spectrometry measurement of {sup 14}C/C ratio, independent of chemical separation procedures. The isotope ratio measurement was specific (owing to the {sup 14}C label), stable across samples storage conditions for at …
Date: February 5, 2010
Creator: Keck, B D; Ognibene, T & Vogel, J S
System: The UNT Digital Library
Frequency stabilization via the mixed mode in three mode HeNe lasers (open access)

Frequency stabilization via the mixed mode in three mode HeNe lasers

This paper describes a three mode HeNe laser frequency stabilization technique using the mixed mode frequency to obtain a fractional frequency stability of 2 x 10{sup -11}. The mixed mode frequency occurs due to optical nonlinear interactions with the adjacent modes at each of the three modes. In precision displacement interferometry systems, the laser source frequency must be stabilized to provide an accurate conversion ratio between phase change and displacement. In systems, such as lithography applications, which require high speed, high accuracy and low data age uncertainty, it is also desirable to avoid periodic nonlinearities, which reduces computation time and errors. One method to reduce periodic nonlinearity is to spatially separate the measurement and reference beams to prevent optical mixing, which has been shown for several systems. Using spatially separated beams and the proper optical configuration, the interferometer can be fiber fed, which can increase the interferometer's stability by reducing the number of beam steering optical elements. Additionally, as the number of measurement axes increases, a higher optical power from the laser source is necessary.
Date: February 5, 2010
Creator: Ellis, J D; Joo, K; Buice, E S; Spronck, J W & Munnig Schmidt, R H
System: The UNT Digital Library
Laser Systems for Orbital Debris Removal (open access)

Laser Systems for Orbital Debris Removal

The use of a ground based laser for space debris cleaning was investigated by the ORION project in 1996. Since that study the greatest technological advance in the development of high energy pulsed laser systems has taken place within the NIF project at LLNL. The proposed next laser system to follow the NIF at LLNL will be a high rep rate version of the NIF based on diode-pumping rather than flashlamp excitation; the so called 'LIFE' laser system. Because a single 'LIFE' beamline could be built up in a few year time frame, and has performance characteristics relevant to the space debris clearing problem, such a beamline could enable a near term demonstration of space debris cleaning. Moreover, the specifics of debris cleaning make it possible to simplify the LIFE laser beyond what is required for a fusion drive laser, and so substantially reduce its cost. Starting with the requirements for laser intensity on the target, and then considering beam delivery, we will flow back the laser requirements needed for space debris cleaning. Using these derived requirements we will then optimize the pulse duration, the operational regime, and the output pulse energy of the laser with a focus of simplifying …
Date: February 5, 2010
Creator: Rubenchik, A M; Barty, C P; Beach, R J; Erlandson, A C & Caird, J A
System: The UNT Digital Library
NEUTRON MULTIPLICITY AND ACTIVE WELL NEUTRON COINCIDENCE VERIFICATION MEASUREMENTS PERFORMED FOR MARCH 2009 SEMI-ANNUAL DOE INVENTORY (open access)

NEUTRON MULTIPLICITY AND ACTIVE WELL NEUTRON COINCIDENCE VERIFICATION MEASUREMENTS PERFORMED FOR MARCH 2009 SEMI-ANNUAL DOE INVENTORY

The Analytical Development (AD) Section field nuclear measurement group performed six 'best available technique' verification measurements to satisfy a DOE requirement instituted for the March 2009 semi-annual inventory. The requirement of (1) yielded the need for SRNL Research Operations Department Material Control & Accountability (MC&A) group to measure the Pu content of five items and the highly enrich uranium (HEU) content of two. No 14Q-qualified measurement equipment was available to satisfy the requirement. The AD field nuclear group has routinely performed the required Confirmatory Measurements for the semi-annual inventories for fifteen years using sodium iodide and high purity germanium (HpGe) {gamma}-ray pulse height analysis nondestructive assay (NDA) instruments. With appropriate {gamma}-ray acquisition modeling, the HpGe spectrometers can be used to perform verification-type quantitative assay for Pu-isotopics and HEU content. The AD nuclear NDA group is widely experienced with this type of measurement and reports content for these species in requested process control, MC&A booking, and holdup measurements assays Site-wide. However none of the AD HpGe {gamma}-ray spectrometers have been 14Q-qualified, and the requirement of reference 1 specifically excluded a {gamma}-ray PHA measurement from those it would accept for the required verification measurements. The requirement of reference 1 was a new …
Date: February 5, 2010
Creator: Dewberry, R.; Ayers, J.; Tietze, F. & Klapper, K.
System: The UNT Digital Library
A novel heterodyne displacement interferometer with no detectable periodic nonlinearity and optical resolution doubling (open access)

A novel heterodyne displacement interferometer with no detectable periodic nonlinearity and optical resolution doubling

This paper describes a novel heterodyne laser interferometer with no significant periodic nonlinearity for linear displacement measurements. Moreover, the optical configurations have the benefit of doubling the measurement resolution when compared to its respective traditional counterparts. Experimental results show no discernable periodic nonlinearity for a retro-reflector interferometer and plane mirror interferometer configurations with a noise level below 20 pm. The incoming laser beams of the interferometers are achieved by utilizing two single mode optical fibers. To determine the stability of the optical fiber couplers a fiber delivery prototype was also built and tested.
Date: February 5, 2010
Creator: Joo, K; Ellis, J D; Buice, E S; Spronck, J W & Munnig Schmidt, R H
System: The UNT Digital Library
Paleoclimatic implications of glacial and postglacial refugia for Pinus pumila in western Beringia (open access)

Paleoclimatic implications of glacial and postglacial refugia for Pinus pumila in western Beringia

Palynological results from Julietta Lake currently provide the most direct evidence to support the existence of a glacial refugium for Pinus pumila in mountains of southwestern Beringia. Both percentages and accumulation rates indicate the evergreen shrub survived until at least {approx}19,000 14C yr B.P. in the Upper Kolyma region. Percentage data suggest numbers dwindled into the late glaciation, whereas pollen accumulation rates point towards a more rapid demise shortly after {approx}19,000 14C yr B.P. Pinus pumila did not re-establish in any great numbers until {approx}8100 14C yr B.P., despite the local presence {approx}9800 14C yr B.P. of Larix dahurica, which shares similar summer temperature requirements. The postglacial thermal maximum (in Beringia {approx}11,000-9000 14C yr B.P.) provided Pinus pumila shrubs with equally harsh albeit different conditions for survival than those present during the LGM. Regional records indicate that in this time of maximum warmth Pinus pumila likely sheltered in a second, lower-elevation refugium. Paleoclimatic models and modern ecology suggest that shifts in the nature of seasonal transitions and not only seasonal extremes have played important roles in the history of Pinus pumila over the last {approx}21,000 14C yr B.P.
Date: February 5, 2010
Creator: Anderson, P M; Lozhkin, A V; Solomatkina, T B & Brown, T A
System: The UNT Digital Library
Partial Defect Verification of the Pressurized Water Reactor Spent Fuel Assemblies (open access)

Partial Defect Verification of the Pressurized Water Reactor Spent Fuel Assemblies

The International Atomic Energy Agency (IAEA) has the responsibility to carry out independent inspections of all nuclear material and facilities subject to safeguards agreements in order to verify compliance with non-proliferation commitments. New technologies have been continuously explored by the IAEA and Member States to improve the verification measures to account for declared inventory of nuclear material and detect clandestine diversion and production of nuclear materials. Even with these efforts, a technical safeguards challenge has remained for decades for the case of developing a method in identifying possible diversion of nuclear fuel pins from the Light Water Reactor (LWR) spent fuel assemblies. We had embarked on this challenging task and successfully developed a novel methodology in detecting partial removal of fuel from pressurized water reactor spent fuel assemblies. The methodology uses multiple tiny neutron and gamma detectors in the form of a cluster and a high precision driving system to obtain underwater radiation measurements inside a Pressurized Water Reactor (PWR) spent fuel assembly without any movement of the fuel. The data obtained in such a manner can provide spatial distribution of neutron and gamma flux within a spent fuel assembly. The combined information of gamma and neutron signature is used …
Date: February 5, 2010
Creator: Ham, Young S. & Sitaraman, Shivakumar
System: The UNT Digital Library
SOLAR PUMPED LASER MICROTHRUSTER (open access)

SOLAR PUMPED LASER MICROTHRUSTER

The development of microsatellites requires the development of engines to modify their orbit. It is natural to use solar energy to drive such engines. For an unlimited energy source the optimal thruster must use a minimal amount of expendable material to minimize launch costs. This requires the ejected material to have the maximal velocity and, hence, the ejected atoms must be as light as possible and be ejected by as high an energy density source as possible. Such a propulsion can be induced by pulses from an ultra-short laser. The ultra-short laser provides the high-energy concentration and high-ejected velocity. We suggest a microthruster system comprised of an inflatable solar concentrator, a solar panel, and a diode-pumped fiber laser. We will describe the system design and give weight estimates.
Date: February 5, 2010
Creator: Rubenchik, A M; Beach, R; Dawson, J & Siders, C W
System: The UNT Digital Library
Comparison of the Growth of Pore and Shear Band Driven Detonations (open access)

Comparison of the Growth of Pore and Shear Band Driven Detonations

The authors examine the effect of ignition site topology on the rate of reaction of a detonating material. The hot plane, hot line, and hot finite patch topologies are added to previous work on hot spot ignition. The hot plane and hot patch ignition forms would arise from ignition due to shear banding, and the hot line ignition form is shown to complete the topological set. The limiting behavior of instantaneous ignition is considered and used to construct simple reaction rate vs. extent of reaction forms. they fit simple form factor reaction rates, as might be available in most hydro codes with reactive flow modes, to the simple topologies. The difference between the rate vs. extent forms are examined with the objective that one should be able to use this information to distinguish between the different topological ignition forms.
Date: March 5, 2010
Creator: Nichols, A. L.
System: The UNT Digital Library
Fracture Induced Sub-Band Absorption as a Precursor to Optical Damage on Fused Silica Surfaces (open access)

Fracture Induced Sub-Band Absorption as a Precursor to Optical Damage on Fused Silica Surfaces

The optical damage threshold of indentation induced flaws on fused silica surfaces was explored. Mechanical flaws were characterized by laser damaged testing, SEM, optical, and photoluminescence microscopy. Localized polishing, chemical etching, and the control of indentation morphology were used to isolate the structural features which limit optical damage. A thin defect layer on fracture surfaces, including those smaller than the wavelength of visible light, was found to be the dominant source of laser damage initiation during illumination with 355nm, 3ns laser pulses. Little evidence was found that either displaced or densified material or fluence intensification plays a significant role in optical damage at fluences >35J/cm{sup 2}. Elimination of the defect layer was shown to increase the overall damage performance of fused silica optics.
Date: March 5, 2010
Creator: Miller, P E; Bude, J D; Suratwala, T I; Shen, N; Laurence, T A; Steele, W A et al.
System: The UNT Digital Library
High-Power Electrostatic Discharges in PETN: Threshold and Scaling Experiments (open access)

High-Power Electrostatic Discharges in PETN: Threshold and Scaling Experiments

There is a considerable set of data establishing the safety of PETN-based detonators that are insulted by electrostatic discharge (ESD) from a human body. However, the subject of ESD safety has garnered renewed interest because of the sparse data on high-power, low-impedance discharges that result when the source is a metallic object such as a tool. Experiments on as-built components, using pin-to-cap fault circuits through PETN-based detonators, showed significant evidence of a power dependence but with a very broad energy threshold and some uncertainty in the breakdown path. We have performed a series of experiments using a well-defined arc discharge path and a well-characterized source that is capable of independent variation of energy and power. Studies include threshold variation with power, arc length, powder surface area, and surface vs. bulk discharge paths. We find that an energy threshold variation with power does not appear to exist in the tested range of fractions to tens of MW, and that there are many subtleties to proper energy and power bookkeeping. We also present some test results for PBX 9407.
Date: March 5, 2010
Creator: Liou, W.; McCarrick, J. F.; Hodgin, R. L. & Phillips, D. F.
System: The UNT Digital Library
Improved Modeling and Understanding of Diffusion-Media Wettability on Polymer-Electrolyte-Fuel-Cell Performance (open access)

Improved Modeling and Understanding of Diffusion-Media Wettability on Polymer-Electrolyte-Fuel-Cell Performance

A macroscopic-modeling methodology to account for the chemical and structural properties of fuel-cell diffusion media is developed. A previous model is updated to include for the first time the use of experimentally measured capillary pressure -- saturation relationships through the introduction of a Gaussian contact-angle distribution into the property equations. The updated model is used to simulate various limiting-case scenarios of water and gas transport in fuel-cell diffusion media. Analysis of these results demonstrate that interfacial conditions are more important than bulk transport in these layers, where the associated mass-transfer resistance is the result of higher capillary pressures at the boundaries and the steepness of the capillary pressure -- saturation relationship. The model is also used to examine the impact of a microporous layer, showing that it dominates the response of the overall diffusion medium. In addition, its primary mass-transfer-related effect is suggested to be limiting the water-injection sites into the more porous gas-diffusion layer.
Date: March 5, 2010
Creator: Weber, Adam
System: The UNT Digital Library
Pressure-induced isostructural transition in PdN2 (open access)

Pressure-induced isostructural transition in PdN2

We show that a synthesized Pd-N compound crystallize into the pyrite structure by comparison of experimental and calculated Raman intensities. The decreasing Raman intensities with decreasing pressure is explained by a closing of the fundamental band gap. We further discuss the experimental decomposition of this compound at 11 GPa in terms of an isostructural transition within the pyrite structure.
Date: March 5, 2010
Creator: Aberg, D; Erhart, P; Crowhurst, J; Zaug, J M; Goncharov, A F & Sadigh, B
System: The UNT Digital Library