Twenty-four catalysts were prepared by either evaporation of metal nitrate-citric acid solutions, by impregnation of methanol synthesis catalysts or by coprecipitation with KOH. Seventeen catalysts were tested in either the Berty gradientless reactor or the plug-flow reactor. These catalysts have been characterized into the five groups. A CuCoZn/sub 0/ /sub 125/Fe/sub 0/ /sub 1/Th/sub 0/ /sub 5/K/sub 0/ /sub 11/ catalyst produced by evaporation of metal nitrate-citric acid solutions resulted in an oxygenates selectivity of about 50% (CO/sub 2/-free basis) at total CO conversions of the order of 5 to 15% per pass. The alcohols (including about 2% aldehydes) distribution was 48.2% C/sub 1/; 33.4% C/sub 2/; 10.7% C/sub 3/; 5.3% C/sub 4/ and 2.3% C/sub 5/. The calculated heating value of this Alkanol mixture is about 78,000 Btu/gal (20% higher than that of methanol). The estimated clear Research Octane Number (RONC) of this mixture is 109. The estimated octane quality (RONC) of a mixture of 80% unleaded gasoline having an 80 RONC and 20% of the Alkanols is about 91.

Fourteen catalysts were prepared by either evaporation of metal nitrate-citric acid solutions or by impregnation of inert supports with metal nitrate-citric acid solutions. Fourteen catalysts were tested in either the Berty gradientless reactor or the plug-flow reactor. These catalysts have been characterized intto the following five groups: Group I - catalysts containing Cu, Zn, Co, Cr and alkali; Group II - catalysts of Group I without Zn or Co or Cr; Group III - modified methanol synthesis catalysts of substituted by transition metals such as Fe, Mn, Ti, Th, etc; and Group V - catalysts of Groups I, II or IV supported on refractory cements such as silica or titania. Although none of the catalysts tested this quarter resulted in reaching the targetted oxygenates selectivities and space time yields, the following relevant observations were made: Transition metals in a catalyst having the general atomic formula CuZn/sub 0/ /sub 125/CoK/sub 0/ /sub 11/M and produced by evaporation of metal nitrate - citric acid solution affect oxygenates selectivity as indicated below (in descending order), Fe approx. Cr > V >> Mn; Potassium in a catalyst having the formula Cu Zn/sub 0/ /sub 125/CoA/sub 0/ /sub 11/ is a better alkali promoter than …

Praxis is the practice of the programming art, science, and skill. It is a high-order language designed for the efficient programming of control and systems applications. It is a comprehensive, strongly typed, block-structured language in the tradition of Pascal, with much of the power of the Mesa and Ada languages. It supports the development of systems composed of separately compiled modules, user-defined data types, exception handling, detailed control mechanisms, and encapsulated data and routines. Direct access to machine facilities, efficient bit manipulation, and interlocked critical regions are provided within Praxis.

Weekly newsletter discussing natural resources, parks, hunting and fishing, and other information related to the outdoors in Texas.

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Fabrication techniques and improved a-Si:H film processing have been achieved to produce a short circuit current density of 7.5 mA/cm/sup 2/ and open circuit voltage of 740 mV on large area (2cm/sup 2/) a-Si cells by the deposition of an inexpensive semitransparent metal (Cr) as a top electrode on a N-I-P structure. This corresponds to a 2% efficiency using AMl illumination. A V/sub oc/ of 830 mV and fill factor of 0.54 have also been separately obtained. A relatively simple and inexpensive deposition technique using a one pumpdown vacuum system, Al grid and thin metal film structure have been applied to reduce the cost of a-Si:H cell fabrication. A SEM study of a-Si film quality shows the substrate texture to greatly influence the film morphology. This in turn serves to influence the uniformity of photovoltaic response on completed solar cells. The studies of optical transmittance of various thin metal films promote the utilization of Cr and Cu as a top electrode. Dark and illuminated I-V characteristics show that current conduction mechanisms and recombination pheonomena are not the same under dark and illuminated conditions. Furthermore, spectral response analysis and reverse illuminated saturation current under different illumination levels show photoconductivity and collection …

Work is continuing on: chromosomal inversions and Robertsonians; cytology of inversions; translocations; mutagen test validation; meiotic pairing; and the characterization of induced lethals. (PSB)

Fluidized bed combustors operate in the large-particle (> 1 mm) high-velocity (> 1 m/s) fluidization regime which differs from most previous applications. These characteristics foster a distinctive volatiles evolution structure in the vicinity of the coal injectors of bottom-fed atmospheric fluidized beds (AFBC). The evolution of coal volatiles associated with bottom-fed AFBC was defined as the focal point. The major effort of the work was concerned with a group combustion model of dense gas/solids mixtures of devolatilizing coal being injected into the bottom of an AFBC. Critical development needs were defined in the area of solids circulation and injector design which impact both basic FBC design and NO/sub x/ emissions. Results of model calculations identified important new physical-chemical mechanisms influencing NO/sub x/ emissions.

Seismic surface-wave generation by underground nuclear explosions releasing tectonic strain is studied through a series of synthetic radiation-pattern calculations based on the earthquake-trigger model. From amplitude and phase radiation patterns for 20-s Rayleigh waves, inferences are made about effects on surface-wave magnitude, M/sub s/, and waveform character. The focus of this study is a comparison between two mechanisms of tectonic strain release: strike-slip motion on vertical faults and thrust motion on 45/sup 0/ dipping faults. The results of our calculations show that Rayleigh-wave amplitudes of the dip-slip model at F values between 0.75 and 1.5 are significantly lower than amplitudes of the strike-slip model or of the explosion source alone. This effect translates into M/sub s/ values about 0.5 units lower than M/sub s/ of the explosion alone. Waveform polarity reversals occur in two of four azimuthal quadrants for the strike-slip model and in all azimuths of the dip-slip-thrust model for F values above about 3. A cursory examination of waveforms from presumed explosions in eastern Kazakhstan suggests that releases of tectonic strain are accompanying the detonation of many of these explosions. Qualitatively, the observations seem to favor the dip-slip-thrust model, which, in the case of a few explosions, must …

This paper explores tHe observational consequences of models for Type I supernovae based on the detonation (or deflagration) of the degenerate cores of white dwarfs or intermediate mass (approx. = 9 M/sub sun/) stars. Such nuclear burning can be initiated either at the center of the core or near its edge. The model examined in most detail is that of a 0.5M/sub sun/ C/O white dwarf which undergoes an edge-lit He/C/O detonation after accreting 0.62 M/sub sun/ of he at 10/sup -8/ M/sub sun//yr. The light curve resulting from this model is found to be in excellent agreement with those observed for Type I supernovae, particularly those in the fast subclass. The physical processes involved in the detailed numerical calculations which lead to this conclusion are quantitatively elucidated by simple analytic models, and effects of uncertainties in the input physics are explored.

A cumulative-strain-damage criterion is used to predict the initiation and propagation of fracture in ductile materials. The model is consistent with a model of ductile rupture that involves void growth and coalescence. Two- and three-dimensional finite difference computer codes, which use incremental-plasticity theory to describe large strains with rotation, are used to trace the history of damage in a material due to external forces. Fracture begins when the damage exceeds a critical value over a critical distance and proceeds as the critical-damage state is reached elsewhere. This unified approach to failure prediction can be applied to an arbitrary geometry if the material behavior has been adequately characterized. The damage function must be calibrated for a particular material using various material property tests. The fracture toughness of 6061-T651 aluminum is predicted.

The Mirror Fusion Test Facility (MFTF) has been in construction at Lawrence Livermore National Laboratory (LLNL) for 3 years, and most of the major subsystems are nearing completion. Recently, the scope of this project was expanded to meet new objectives, principally to reach plasma conditions corresponding to energy break-even. To fulfill this promise, the single-cell minimum-B mirror configuration will be replaced with a tandem mirror configuration (MFTF-B). The facility must accordingly be expanded to accomodate the new geometry. This paper briefly discusses the status of the major MFTF subsystems and describes how most of the technological objectives of MFTF will be demonstrated before we install the additional systems necessary to make the tandem. It also summarizes the major features of the expanded facility.

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.

Hardware design for laser fusion experimental machines has led to a combination of engineering technologies that are critical to the successful operation of these machines. These large opto-mechanical systems are dependent on extreme cleanliness, accommodation to efficient maintenance, and high stability. These three technologies are the primary mechanical engineering criteria for laser fusion devices.

Micro-channel plate multipliers have been used to detect the passage of relativistic charged particles. Measurements of the detection efficiency and pulse height response versus micro-channel plate gain are presented for one, two and three micro-channel plate arrays. The probability of detecting an avalanche on the detector anode per one channel of MCP crossed by the relativistic particle was calculated. Temporal response and time jitter were measured and are reported. The track images of beam particles crossing the detector are shown.

Information is given on each of the following topics: (1) magnet description, (2) superconducting manufacture, (3) mechanical behavior of conductor winding, (4) coil winding, (5) thermal analysis, (6) cryogenic system, (7) power supply system, (8) structural analysis, (9) structural finite element analysis refinement, (10) structural case fault analysis, and (11) structural metallurgy. (MOW)

Weekly newsletter discussing natural resources, parks, hunting and fishing, and other information related to the outdoors in Texas.

Security systems and security procedures for the AFRRI reactor, the University of Maryland TRIGA reactor, and the University of Virginia CAVALIER and UVAR reactors are described.

Reaction kinetic measurements on the hydrochlorination of SiCl/sub 4/ and mg silicon metal in the presence of a copper catalyst were last reported as a function of reaction temperature, reactor pressure and H/sub 2//SiCl/sub 4/ ratio, 3 SiCl/sub 4/ + 2 H/sub 2/ + Si ..-->.. 4 SiHCl/sub 3/. The same reaction was repeated at a lower catalyst loading of 2 wt%. In the presence of 2 wt% cuprous chloride (based on silicon metal), the hydrochlorination reaction rate is doubled to give about the same performance as those obtained at a higher copper catalyst loading. The effect of particle size distribution of the mg silicon metal on the hydrochlorination reaction rate was studied. Reaction kinetic measurements were made on 150 x 400 mesh Si and on 32 x 65 mesh Si in addition to the standard 65 x 150 mesh Si used in previous studies. Results of these experiments show that the reaction rate is essentially independent of the silicon metal particle size. Thus, the reaction occuring on the Si metal surface is the rate-determining step. Mass transfer via diffusion of reactants and product is not rate-limiting. A plausible mechanism of the hydrochlorination reaction is discussed.

Weekly report of the Texas Crop and Livestock Reporting Service on turkey poult numbers in Texas and compared with other states. It includes compiled statistics across six consecutive weeks during two years for turkey eggs set and poults hatched.

Methods of removing fluorides from water are reviewed and recommendations are made for treating geothermal water used by the Boise Geothermal Project, Boise, Idaho. The Boise geothermal water except for its high fluoride content would be high quality, suitable for primary drinking water. Fluoride ranges from about 15 to 25 mg/l in water from various wells in the Boise region where the Project plans to obtain hot water. Four techniques for removing fluorides from water have been studied extensively during the past 15 years or so. Electrodialysis and reverse osmosis are useful in reducing total dissolved solids from brackish water, but are nonspecific and are too expensive for treatment of the Boise geothermal water. Selective precipitation is a widely used technique for treating water, but would also prove expensive for the Boise geothermal water because of the relatively high solubility of fluoride salts and consequently high concentration (and cost) of precipitants required to reduce the fluorides to an acceptable level. Ion-exchange separation using activated alumina as the exchange medium appears to be the most promising technique and we recommend that some laboratory and pilot studies be conducted to establish suitability and operating boundaries.

Several practical aspects of rf acceleration (by a MEQALAC accelerator, for example) of positive and negative ions for MFE neutral injection were considered. The beam transport, gas flow, differential pumping, and compatibility with MFE beam lines were examined. It was found that rf acceleration has several advantages over dc acceleration, especially if high energy (over 100 keV) and/or high purity (over 99%) is required. Therefore rf acceleration should be considered especially in connection with negative ions, which also have competitive advantages under such requirements. Beam densities for rf may be lower than dc beam densities because of space charge limitations and electrode transparency. However, the overall dimensions of an rf system are competitive with or smaller than the dimensions of a dc system of equal current and voltage because the gas pumping and electrical insulation are included within the rf electrode assembly. Ion source development is required to produce an array of many small beams suitable for injection into a MEQALAC.

Rutherford scattering of neutral particles by plasma ions is examined as a method for determining plasma ion in the central cell fo the Tandem Mirror Experiment (TMX). When a scattering configuration, consisting of a 20-keV-, 10-A-deuterium neutral beam and an energy analyzer with a 1% resolution, is arranged such that only neutral particles scattered by plasma ions over an angle of 10/sup 0/ are accepted, central-cell ion temperatures in the 30- to 1000-eV range can be measured. The count rate registered by the detector(s) is estimated to be 2000 counts/ms. Consequently, good statistical accuracy and time resolution are attainable simultaneously. The results of the calculation are presented such that the scaling of the count rates and the energy broadening with scattering angle, neutral-beam energy, ion temperature, and plasma density can easily be deduced. Neutral helium beams are also considered; they have some advantages over deuterium beams. The background signal, caused by neutral particles entering the detector after two successive charge-exchange collisions, is examined and ways to completely eliminate this background are indicated.

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.