During the next two years, the Fermilab Tavatron is expected to deliver approximately 100pb{sup {minus}1} of integrated luminosity. We describe improvements to the CDF detector since the 1988--89 collider run and discuss the prospects for the discovery of the top quark during the 1992--93 collider runs.

Article on the equivalence of dipole correction and Coulomb cutoff techniques in supercell calculations. In this work, the authors compare the dipole correction and Coulomb cutoff methods under the same conditions in the framework of plane-wave based density-functional theory.

A breeding ratio of at least 1.2 was a design goal for CRBRP. The value for the initial core (using plutonium with 11% /sup 240/Pu) calculated with ENDF/B-IV data is 1.27. Engineering mock-up studies for CRBRP were made in ZPPR-11. Analysis of ZPPR-11 using ENDF/B-IV data showed consistent underprediction of K/sub eff/ by about 1.5% and overpredictions of the /sup 238/U capture to /sup 239/Pu fission ratio (C8/F9) between 5% and 8%. These results are typical for all LMFBR critical assemblies at ANL. The following approach was used to determine the breeding ratio: sensitivity analysis of a range of fast reactor benchmarks and a fit to the experimental data by data adjustment; tests of the adjusted data against experiments in ZPPR-11; calculations for CRBRP with ENDF/B-IV data and the adjusted data to predict the breeding ratio bias; and estimates of k/sub eff/ and breeding ratio uncertainties using data sensitivities for CRBRP.

Article on librarians and technology and things to consider.

This article provides comments on "Study of Molecular Interactions in Binary Mixtures of Formamide with 2-Methoxyethanol and 2-Ethoxyethanol at Varying Temperatures," published in 'Physics and Chemistry of Liquids,' 2013.

An all-inorganic photocatalytic unit consisting of a binuclear TiOCr charge-transfer chromophore coupled to an Ir oxide nanocluster has been assembled on the pore surface of mesoporous silica AlMCM-41. In situ FT-Raman and EPR spectroscopy of an aqueous suspension of the resulting IrxOy-TiCr-AlMCM-41 powder reveal the formation of superoxide species when exciting the Ti(IV)OCr(III) --> Ti(III)OCr(IV) metal-to-metal charge-transfer chromophore with visible light. Use of H218O confirms that the superoxide species originates from oxidation of water. Photolysis in the absence of persulfate acceptor leads to accumulation of Ti(III) instead. The results are explained by photocatalytic oxidation of water at Ir oxide nanoclusters followed by trapping of the evolving O2 by transient Ti(III) centers to yield superoxide. Given the flexibility to select donor metals with appropriate redox potential, photocatalytic units consisting of a binuclear charge-transfer chromophore coupled to a water oxidation catalyst shown here constitute a step towards thermodynamically efficient visible light water oxidation units.

The Association for Women in Mathematics (AWM) in cooperation with the Society for Industrial and Applied Mathematics (SIAM) and with funding from the Department of Energy initiated a new lecture series. The purpose of the lecture series is to increase the visibility of women who have made significant contributions in applied or computational mathematics. The AWM-SIAM Sonia Kovalevsky Lecture is presented at the SIAM Annual Meeting which is a national conference. The lecturer is a woman who has made distinguished contributions in applied or computational mathematics. The lecturer is determined by the Selection Committee which consists of two members of AWM and two members of SIAM, appointed by the presidents of these organizations. The committee may solicit nominations from other members of the scientific and engineering community. The lectureship may be awarded to any woman in the scientific or engineering community.

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Evidence is presented concerning the effect of surfaces on the segmental motion of PEO-based polymer electrolytes in lithium batteries. For dry systems with no moisture the effect of surfaces of nano-particle fillers is to inhibit the segmental motion and to reduce the lithium ion transport. These effects also occur at the surfaces in composite electrodes that contain considerable quantities of carbon black nano-particles for electronic connection. The problem of reduced polymer mobility is compounded by the generation of salt concentration gradients within the composite electrode. Highly concentrated polymer electrolytes have reduced transport properties due to the increased ionic cross-linking. Combined with the interfacial interactions this leads to the generation of low mobility electrolyte layers within the electrode and to loss of capacity and power capability. It is shown that even with planar lithium metal electrodes the concentration gradients can significantly impact the interfacial impedance. The interfacial impedance of lithium/PEO-LiTFSI cells varies depending upon the time elapsed since current was turned off after polarization. The behavior is consistent with relaxation of the salt concentration gradients and indicates that a portion of the interfacial impedance usually attributed to the SEI layer is due to concentrated salt solutions next to the electrode surfaces …

The compound (bpy)2MnIII(mu-O)2MnIV(bpy)2, a structural model relevant for the photosynthetic water oxidation complex, was coupled to single CrVI charge-transfer chromophores in the channels of the nanoporous oxide AlMCM-41. Mn K-edge EXAFS spectroscopy confirmed that the di-mu-oxo dinuclear Mn core of the complex is unaffected when loaded into the nanoscale pores. Observation of the 16-line EPR signal characteristic of MnIII(mu-O)2MnIV demonstrates that the majority of the loaded complexes retained their nascent oxidation state in the presence or absence of CrVI centers. The FT-Raman spectrum upon visible light excitation of the CrVI-OII --> CrV-OI ligand-to-metal charge-transfer reveals electron transfer from MnIII(mu-O)2MnIV (Mn-O stretch at 700 cm-1) to CrVI, resulting in the formation of CrV and MnIV(mu-O)2MnIV (Mn-O stretch at 645 cm-1). All initial and final states are directly observed by FT-Raman or EPR spectroscopy, and the assignments corroborated by X-ray absorption spectroscopy measurements. The endoergic charge separation products (DELTA Eo = -0.6 V) remain after several minutes, which points to spatial separation of CrV and MnIV(mu-O)2MnIV as a consequence of hole (OI) hopping as a major contributing mechanism. This is the first observation of visible light-induced oxidation of a potential water oxidation complex by a metal charge-transfer pump in a nanoporous environment. …

This paper discusses the use of a free-electron laser amplifier as a means of converting the kinetic energy of an electron beam into coherent radiation. In particular, the use of an induction linear accelerator is discussed. The motion of the elections in the tapered and untapered wiggler magnets is discussed as well as the beam emittance, and the radiation fields involved. (LSP)

This paper describes a fast rise, low-impedance pulse generator that has been developed at the Lawrence Livermore National Laboratory. The design specifications of this generator are: 50-kV operating voltage, 1-ohm output impedance, subnanosecond rise time, and a 2 to 10 nanosecond pulse length. High repetition rate is not required. The design chosen is a parallel-plate, folded Blumlein generator. A tack switch is utilized for its simple construction and high performance. The primary diagnostic is a capacitive voltage divider with a B probe used to measure the current waveform.

The impact of the nuclear equation of state on the properties of rotating neutron stars from two different sources, stable rotation at the general relativistic Kepler period and rotation at the gravitational radiation-reaction driven instability mode, is analyzed. For this purpose models of rotating neutron stars are constructed in the framework of Einstein's theory of general relativity by applying a refined version of Hartle's perturbative stellar structure equations. The investigation is based on a representative collection of a total of seventeen nuclear equations of state, covering both non-relativistic as well as relativistic ones. 41 refs., 3 figs., 2 tabs.

The TMX-U data system is a general-purpose system for acquiring, analyzing, and output of TMX-U data, and can also apply to any pulsed controlled thermonuclear experiment. In its present implementation, it routinely acquires 3 Mbytes of data per shot at an average rate of one shot every 8 minutes. For increased throughput, the system uses 5 CPUs accessing shared disk memory with a capacity of about 500 Mbytes. All acquisition, analysis, and output of data is handled by a collection of standard program modules (processors), which can be linked together to form chained calculations. Processing for various shots may be allowed to overlap, with higher priority results being available quickly, while lower priority results being allowed to lag behind and catch up in natural lulls in the experiment. Selection of tasks (processor invokations) is done independently by each of the 5 CPUs in the system, and each task can run in any suitable CPU.

Mathematical models and numerical methods for a two-dimensional porous body simulation of steady state and transient thermal-hydraulics conditions in LMFBR subassemblies resulting in the TWIST computer code are presented. Comparison of calculated results to steady state and transient out-of-pile sodium experiments show good agreement for cross-assembly temperature distributions for a wide range of heat transfer and flow conditions.

The current situation concerning supernova simulations and the theory of neutron star structure are studied with respect to what they tell about the equation of state. A new mechanism that could help power supernovae is suggested.

Sensitivity analysis of practical problems can be performed systematically and very efficiently by using adjoint functions. In areas of interest to nuclear reactors, this efficiency has been amply demonstrated on several widely used codes for neutronics and/or thermal hydraulic calculations. Applications of the adjoint method of sensitivity analysis to models involving phase transitions, where non-differentiability occurs, do not seem to have been reported to date. The purpose of this paper is to report results from a successful adjoint sensitivity analysis of a space- and time-dependent system where phase transition occurs due to boiling. The specific model chosen for this analysis is a simplified but representative model of a BWR pump-trip-type accident. This model is of particular importance to BWR safety, since pump failure is one of the most limiting hypothetical accidents in BWR's. This model simulates an exponential flow decay of initially subcooled FREON-114 flowing through a heated channel and undergoing boiling transition.

We have designed, built, and characterized uv preilluminated gas switches for a trigger circuit and a low inductance discharge circuit. These switches have been incorporated into a 54 x 76 x 150 cm pulser module to produce a 1 Ma output current rising at 5 x 10/sup 12/ amps/sec with 1 ns jitter. Twenty such modules will be used on the Nova Inertial Confinement Fusion Laser System for plasma retropulse shutters.

During the next two years, the Fermilab Tavatron is expected to deliver approximately 100pb{sup {minus}1} of integrated luminosity. We describe improvements to the CDF detector since the 1988--89 collider run and discuss the prospects for the discovery of the top quark during the 1992--93 collider runs.

The conceptual design of an Radioisotope Thermoelectric Generator (RTG) Facility Transportation System which is part of the overall RTG Transportation System has been completed and is described in detail. The Facility Transportation System serves to provide locomotion, cooling, shock protection and data acquisition for the RTG package during loading and unloading sequences. The RTG Facility Transportation System consists of a Transporter Subsystem, a Package Cooling Subsystem, and a Shock Limiting Transit Device Subsystem. The Transporter Subsystem is a uniquely designed welded steel cart combined with a pneumatically-driven hand tug for locomotion. The Package Cooling Subsystem provides five kilowatts of active liquid cooling via an on-board refrigeration system. The Shock limiting Transit Device Subsystem consists of a consumable honeycomb transit frame which provides shock protection for the 3855 kg (8500 LB) RTG package. These subsystems have been combined into an integrated system which will facilitate the unloading and loading of the RTG , of the Transport Trailer as well as meet ALARA radiation Package into and out exposure guidelines.

We present results from searches for top quark production in p{bar p} collisions at the Tevatron collider based on an integrated luminosity of 7.5 pb{sup {minus}1} obtained during the 1992--1993 ran. The present results are confined to decay modes where both the top and anti-top quarks in the event decay semi-leptonically to the ee and e{mu} channels. A lower limit of 103 (99) GeV/c{sup 2} is obtained at 95% confidence level for the top quark mass from the absence of events consistent with standard model top quark decays with background subtraction (no background subtraction). We do however observe one event in the e{mu} channel which cannot be explained by the known backgrounds. While we make no claim that this event is due to top quark decay, it is not inconsistent with a top quark mass in the range 130--170 GeV/c{sup 2}

This paper presents scaling results based on simulations with the CALE hydrodynamics code of aluminum projectile impacts on typical aluminum Whipple shields at speeds of 6 to 14 km/s. The objective was to determine the extent of projectile and target material melting. The approach was to perform a matrix of computer simulations varying the impact speed from 6 to 14 km/s and varying the areal density of the shield from 5 percent to 80 percent of the centerline areal density of the projectile. The projectile radius was fixed at 9.5 mm (mass = 1.27 grams). The melt state of the projectile material and the shield material was assessed after release of the initial shock. The post-release specific energy in the projectile and in the shield was compared with the enthalpy of incipient melt and the enthalpy of complete melt provided in the Hultgren Tables. Material with specific energy greater than the enthalpy of complete melt was assumed to be fully melted; material with specific energy greater than the enthalpy of incipient melt but less than that of complete melt was assumed to be partially solid and partially melted mixed phase material with no strength; and material with specific energy less …

Accurate multi-dimensional modeling of detonation waves in solid HE materials is a difficult task. To treat applied problems which contain detonation waves one must consider reacting flow with a wide range of length-scales, non-linear equations of state (EOS), and material interfaces at which the detonation wave interacts with other materials. To be useful numerical models of detonation waves must be accurate, stable, and insensitive to details of the modeling such as the mesh spacing, and mesh aspect ratio for multi-dimensional simulations. Studies we have performed show that numerical simulations of detonation waves can be very sensitive to the form of the artificial viscosity term used. The artificial viscosity term is included in our ALE hydrocode to treat shock discontinuities. We show that a monotonic, second order artificial viscosity model derived from an approximate Riemann solver scheme can strongly damp unphysical oscillations in the detonation wave reaction zone, improving the detonation wave boundary wall interaction. These issues are demonstrated in 2D model simulations presented of the 'Bigplate' test. Results using LX-I 7 explosives are compared with numerical simulation results to demonstrate the affects of the artificial viscosity model.

We present results from searches for top quark production in p[bar p] collisions at the Tevatron collider based on an integrated luminosity of 7.5 pb[sup [minus]1] obtained during the 1992--1993 ran. The present results are confined to decay modes where both the top and anti-top quarks in the event decay semi-leptonically to the ee and e[mu] channels. A lower limit of 103 (99) GeV/c[sup 2] is obtained at 95% confidence level for the top quark mass from the absence of events consistent with standard model top quark decays with background subtraction (no background subtraction). We do however observe one event in the e[mu] channel which cannot be explained by the known backgrounds. While we make no claim that this event is due to top quark decay, it is not inconsistent with a top quark mass in the range 130--170 GeV/c[sup 2]