Abstract: "A method is described for the identification and quantitative determination of trace amounts of rare earths in graphite by measurement of the energies and decays of the activities induced by neutron irradiation. The specific rare earth elements identified are europium and samarium. During the development of this method, the half-lives of Eu-152 and Sm-153 were determined. These are reported as 9.32 +/- 0.04 hours and 46.34 +/- 0.23 respectively."

From introduction: "This report is concerned with exploratory experiments designed to studies the efficiency of a number of scavengers for zirconium and niobium adsorption and to provide preliminary information on the best conditions to employ on the most satisfactory of those scavengers studied, namely Super Filtrol FO. The data in this report include data obtained through October, 1949, and are by no means considered to be final. The investigation is currently being actively continued."

Introduction: In order to determine the relative corrosion resistance of welded mild and stainless steels in Redox Stream IAW neutralized to pH 0, 2, and 10 a test program, described below, has been carried out.

Report describing the methods, discrepancies, accuracy of methods, and conclusions of two different analytical methods of spectrochemical analysis of plutionium.

Introduction: "The need for a method of acid determination which could be used for small samples and easily adapted to remote control led to the investigation of the use of electrolytically generated base for the titration of acid in certain solutions. The use of electrolytically generated base for the titration of acetic acid in the presence of nitric acid has been reported (1)."

From introduction: "The following report presents a body of information obtained in the Health Instrument Development Laboratory from September, 1948, to the present, and is intended to be a preliminary review of [the study of electrodeposition of plutonium]. Many improvements in technique and methods and investigations along lines not explored are suggested by the present work. These will be undertaken as time permits, and reported at a later time."

Objective: "The laboratory equilibrium study RC-E-1 described in this report was carried out to obtain uranium equilibrium curves at various concentrations of nitric acid and of TBP."

Introduction: "When uranium slugs are irradiated in the Hanford piles, one of the many substances formed is U-237. It arises primarily from the reaction: U-238 (n,2n) U-237. This uranium isotope is a beta and gamma emitter with a half-life of 6.7 days. Because it is isotopic with U-238, it accompanies the uranium recovered by the Redox Process, and its concentration is, of course, not diminished by the fission-product decontamination cycles. As a consequence, the maximum total decontamination of irradiated uranium which can be achieved depends upon the quantity of U-237 present in the processed uranium."

"The following is an alphabetical listing of terms and units in common usage at Hanford Atomic Products Operation. Other terms and definitions may be added as the need becomes apparent or as revisions or additional terms are issued by the NCRP and ICRP."

Abstract: The data obtained from the radioassay of fish collected in vicinity of the Hanford Works between April, 1948 and June, 1950 are presented. Most of the radioactivity in the fish resulted from the concentration of p32 in the scales, bone, and certain visceral organs. The level of activity density in the fish was influenced by size, feeding habits and metabolic rate in addition to the activity density of the water. Changes in operation of nuclear reactors have resulted in progressive increases in activity densities of fish from one year to the next. The levels of radioactivity are not sufficiently high to be hazardous to either the fish or persons eating them.

Report discussing several reactions that occur during the Redox process and involve hexone. Discussion of each reaction and experimental data is included.

Introduction:"A corrosion test program to determine the effect TBP process streams, which contain chlorides, have upon the corrosion resistance of several construction materials, was completed. Data are presented on the performance of Carpenter 20, T-309SCb, T-347. T-316 and tantalum in the RAF and RAW process streams and on the performance of titanium and zirconium in the RAW stream."

This report provides data on production test 105-329-P and solid graphite samples used to analyze damage obtained from controlled natural erosion tests. The data provided will help establish current ideas on the status of filler block graphite and interpretation of the data will assist in establishing pile operating temperature limits based on stored energy.

Report discussing the properties of plutonium and plutonium's distribution between hexone and aqueous phases, which relates to the function of Redox plants

This report discusses studies regarding the distribution and other properties of uranyl nitrate, nitric acid, plutonium (IV) and plutonium (VI) as part of the Redox Process that separates plutonium, uranium, and fission products.

The work described in this report was done to determine the path of decomposition of plutonium (IV) oxalate and to determine the factors affecting the reactivity of the oxide with the hydrogen fluoride.

Contemplated higher tube power for future reactor operation will probably require a fuel element jacketing material more corrosion resistant than presently available aluminum alloys. Zirconium and its alloys are generally regarded as the most promising jacketing candidates for high temperature operation, particularly for exposures of long duration. In order to obtain assembly, welding, and corrosion data, twenty Al-Si bonded and twenty unbonded Zircaloy fuel elements were prepared for KER loop testing. This report describes the technique developed to weld Zircaloy jacketed fuel elements and presents the results of end closure corrosion testing and metallographic examination.

Past experience has shown that the demand for increase separations plant capacity comes up very regularly. One of the variables which greatly affects plant capacity is cross-sectional area of the individual vessels. Larger areas permit greater flow rates as well as more space for the installation of heat transfer piping (shell and tube concentrators). Design considerations of the separations plants vessels have been based on both circular cylinder and slab geometries. A study has been made to determine other vessel geometries that will result in safe vessels from a nuclear safety standpoint and at the same time offer larger cross-sectional areas than right circular cylinders. Vessels of elliptic as well as annular cross sections have been considered. It is neither the intent of this study to discuss the effects of intersection, vessel piping, etc., nor the pros and cons of fabricating feasibility and structural strength of these different shaped vessels. The main purpose is to make comparisons of cross-sectional areas (capacity parameter) of safe vessels so that vessel shape may be evaluated as one of the parameters in any design study for separation plants.

An experiment designed to evaluate the in-pile performance of the U-Mg fuel material when irradiated to high burnups has been completed. Twelve specimens of the fuel material which contained uranium particles that packed 50 volume per cent, (91.5 weight per cent), uranium in a magnesium matrix were canned in Zircaloy cans and irradiated in the Materials Testing Reactor to 0.1 (1000 MWD/T), 0.3 (5000 MWD/T), 1.0 (10000 MWD/T) and 2.0 20000 MWD/T) per cent burnup of the total uranium atoms; more exactly, 1 MWD/T = 1.16 x 10⁻⁴ per cent burnup of the total uranium atoms. Irradiation of the twelve capsules began on August 1, 1954. The burnup figures used in this report are calculated values assuming a conversion ratio for the capsules of 1.0. Because of the lack of confirmed experimental burnup data for exposures of this magnitude, there is a possible error in the calculated values of about 20 per cent at 2.0 per cent burnup. However, recent results based on chemical analysis for cesium indicate that the calculated values of burnup agree quite closely for the higher exposures. Burnup estimates based on the results of the chemical analysis will be published when they become available. Six of …

The purpose of this program is to determine the effects of neutron radiation and reactor gaseous atmospheres on the structural integrity of candidate materials for the PRTR gas-cooled loop. An exploratory investigation is being conducted to select a high temperature resistant alloy for the fabrication of tubes and supporting appliances for the PRTR gas-cooled loop. In addition to a low neutron cross section, the material must be able to withstand the operating conditions outlined in Table 1.

A report which is the ninth report of the research and development activities of the radiological sciences department, Hanford Works, which includes some items charged to control but include for for general interest.

A report intended to correlate the RA and RC Column uranium equilibrium data presented in the reports cited in the introduction.

This report has been prepared to review the status of design for buried waste line and presents the major factors involved in support of the conclusions. This report is the second in a series reporting on the general subject of underground corrosion. The first on cathodic protection of waste lines noted the technology of stainless steel and its effect on existing waste line and recommended continued use of the cathodic protection. Experience with buried stainless pipe had shown that, unless protected, such installations are subject to severe pit corrosion. As designs developed the use of encasements has become a standardized approach. This discussion will evaluate this trend.

Equations are developed for the computation of MPC's for radioisotopes assuming the excretion or retention to follow a power law rather than an exponential law. Computations are made for four isotopes on which some human data are available. Uncertainties in the initial data due to the use of intravenous injection to obtain the primary data, the definition of retention and the effects of age and diet are discussed.