Section I introduces the material contained in the rest of the report. Section II presents the origin and characteristics of humic materials as we understand them today and outlines the methods that have been used to separate and analyze these substances. Section III focuses on the general problem of metal-organic interactions and treats some of the factors that are important in chelating and complexing of metal ions by humic substances. Section IV deals specifically with the complexing of radionuclides by organic substances, treated from the standpoint of both empirical and experimental studies.

The Nevada Nuclear Waste Storage Investigations (NNWSI) project is investigating the volcanic tuff beds of Yucca Mountain, Nevada, as a potential location for a high-level radioactive waste repository. This report describes a test method (Phase II) that has been developed to measure the release of radionuclides from the waste package under simulated repository conditions, and provides information on materials interactions that may occur in the repository. The results of 13 weeks of testing using the method are presented, and an analog test is described that investigates the relationship between the test method and expected repository conditions.

Tutorial description of the Warren machine with a basic introduction to the motivation of the machine and the instructions that define it. Discussion of the fairly limited extensions required to extend the machine for more general use outside of implementations of logic programming. Substantial speedups will occur due to improvements in the implementation of the basic algorithms.

This report provides a summary of theoretical and experimental studies of actinide spectra in condensed phases. Much of the work was accomplished at Argonne National Laboratory, but references to related investigations by others are included. Spectroscopic studies of the trivlent actinides are emphasized, as is the use of energy level parameters, evaluated from experimental data, to investigate systematic trends in electronic structure and other properties. Some reference is made to correlations with atomic spectra, as well as with spectra of the (II), (IV), and higher valence states.

This report contains historical information on the Li-alloy/FeS system that will be useful in its future applications. This document includes the following: (1) the chemical and electrochemical reactions for the Li-alloy/FeS system, accomplishments in past cell development efforts, and performance attained by state-of-the-art cells vs performance goals; (2) detailed drawings of state-of-the-art cell designs, documentation of cell fabrication techniques, and comparisons of alternative types of cell components (such as BN felt vs MgO powder separators, stainless vs low-carbon steel cell housings) and fabrication techniques (such as charged vs uncharged electrodes); (3) results of post-test cell analyses, including cell failure mechanisms, electrode morphology and active material distribution, and in-cell corrosion rates; (4) data from trade-off studies between specific power and energy; (5) discussion of battery design considerations (e.g., volumetric energy density, battery charger, and high-efficiency thermal insulation); (6) results of cost studies, which include materials and manufacturing costs of cells and batteries and heating costs involved in battery operation; and (7) projections of cell designs having the greatest potential for meeting electric-vehicle performance requirements.

Current status of epidemiological studies of the late effects of internal radium in humans, and mechanistic investigations of those effects.

Report on studies of advanced batteries, aqueous batteries, advanced fuel cells, coal utilization, methodologies for recovery of energy from municipal waste, solid and liquid desiccants, nuclear technology related to waste management, and physical chemistry of selected materials in environments simulating those of fission, fusion, and other energy systems.

A set of programs, gathered from major Argonne computer users, was run on the current generation of supercomputers: the CRAY X-MP-4, Fujitsu VP-200, and Hitachi S-810/20. The results show that a single processor of a CRAY X-MP-4 is a consistently strong performer over a wide range of problems. The Fujitsu and Hitachi excel on highly vectorized programs and offer an attractive opportunity to sites with IBM-compatible computers.

Report of the activities of the physics division at Argonne including the successful completion of Argonne Tandem-Linac Accelerator System.

This report reviews the research activities in the Mathematics and Computer Science Division at Argonne National Laboratory for the period April 1, 1984, through March 31, 1985. The body of the report discusses various projects carried out in four major areas of research: applied analysis, computational mathematics, software engineering, and advanced computing. Information on section staff, visitors, workshops, and seminars is found in the appendices.

Annual report of the environmental monitoring program at Argonne National Laboratory, discussing activities and findings of the group.

Quarterly report discussing fuel cell research and development work at Argonne National Laboratory (ANL). This report describes activitiesdirected toward seeking alternative cathode materials to NiO for molten carbonate fuel cells.

Quarterly report discussing fuel cell research and development work at Argonne National Laboratory (ANL). This report describes studies directed toward seeking alternative cathode materials to NiO for molten carbonate fuel cells.

Quarterly report on activities of Argonne National Laboratory's Nuclear Technical Programs, including management of nuclear waste.

Quarterly report on activities of Argonne National Laboratory's Nuclear Technical Programs, including results of studies to measure the degradation of backfill materials after their exposure to temperature and humidity expected in high-level nuclear waste repositories.

Quarterly report on activities of Argonne National Laboratory's Nuclear Technical Programs, including a review of studies of the ability of backfill to inhibit groundwater flow in a nuclear waste repository.

This report describes logic programming approaches to two graph theoretical problems relevant to reactor and logic circuit analysis: those of cut-set verification and subsystem detection.

As multiprocessors become commercially available, a great deal of concern is being focused on the problems involved in writing and debugging software for such machines. Earlier work described the use of monitors implemented by macro processors to attain portable code. This work formulates a general-purpose monitor which simplifies the programming of a wide class of numeric algorithms. We believe that the approach of describing a set of schedulable units of computation advocated by Brown offers a real simplification for the applications programmer. In this paper, we propose a straight-forward programming paradigm for describing schedulable units of computation that allows the description of many algorithms with very little effort.

Report on solving problems with shell-and-tube heat exchangers resulting from recent trends toward higher flowrates, larger size, and optimized designs.

Report on research in carcinogenesis, human radiobiology, low-level radiation, molecular biology, and toxicology.

Fluid excitation forces are measured in a water loop for two circular cylinders arranged in tandem and normal to flow. The Strouhal number and fluctuating drag and lift coefficients for both cylinders are presented for various spacings and incoming flow conditions. Results show the effects of Reynolds number, pitch ratio, and upstream turbulence on the fluid excitation forces.

In 1973, Argonne National Laboratory began consolidating and upgrading its plutonium-handling operations with the result that the research fuel-fabrication facility located in Building 350 was shut down and declared surplus. Sixteen of the twenty-three gloveboxes which comprised the system were disassembled and relocated for reuse or placed into controlled storage during 1974 but, due to funding constraints, full-scale decommissioning did not start until 1978. Since that time the fourteen remaining contaminated gloveboxes, including all internal and external equipment as well as the associated ventilation systems, have been assayed for radioactive content, dismantled, size reduced to fit acceptable packaging and sent to a US Department of Energy (DOE) transuranic retrievable-storage site or to a DOE low-level nuclear waste burial ground. The project which was completed in 1983, required 5 years to accomplish, 32 man years of effort, produced some 540 cubic meters (19,000 cubic ft) of radioactive waste of which 60% was TRU, and cost 2.4 million dollars.

A data bank of field experiences with heat exchanger tube vibration reveals numerous cases of tube failures at, or near, the baffle. The objective of this study is to provide qualitative impact/fretting wear information for heat exchanger tubes through the performance of a series of tests involving the pertinent parameters: impact force level, between the tube and its support; tube to support plate hole clearance; tube support plate thickness; and tube vibration frequency. The characteristics of impact/fretting wear relative to tube motion pattern, material combination and surrounding fluid were also investigated. The test apparatus consists of a cantilevered tube with a simulated tube support plate at the ''free end''. Tube vibration is induced by an electromagnetic exciter to simulate the flow-induced tube motion occurring in a real heat exchanger at the tube/tube support plate interface. Tests are conducted in air, water, and oil, all at room temperature. Wear rate increases significantly with the magnitude of the impact force between the tube and its support plate; the degree and trend of the wear rates are highly dependent on the mechanical and metallurgical properties of the tube/support material combination; the rate of impact/fretting wear decreases with increasing frequency. An empirical formula is …

Pre and postprocessors have been written for an established hydraulic program (COMMIX-IHX) which enables prediction of the internal crossflow field for each tube of Argonne's Test Heat Exchanger and identification of those tubes most likely to experience fluid-elastic instability, together with the instability vibration mode. While the direct use of the HXVA method is limited to single pass, single-segmentally baffled tube bundle configurations, its algorithms and methods can be applied to any type of heat exchanger which can be analyzed by COMMIX-IHX. The processors are explained and an example problem is given along with comparisons of experimental results.