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Experience base for Radioactive Waste Thermal Processing Systems: A preliminary survey (open access)

Experience base for Radioactive Waste Thermal Processing Systems: A preliminary survey

In the process of considering thermal technologies for potential treatment of the Idaho National Engineering Laboratory mixed transuranic contaminated wastes, a preliminary survey of the experience base available from Radioactive Waste Thermal Processing Systems is reported. A list of known commercial radioactive waste facilities in the United States and some international thermal treatment facilities are provided. Survey focus is upon the US Department of Energy thermal treatment facilities. A brief facility description and a preliminary summary of facility status, and problems experienced is provided for a selected subset of the DOE facilities.
Date: April 1, 1992
Creator: Mayberry, J.; Geimer, R.; Gillins, R.; Steverson, E.M.; Dalton, D. (Science Applications International Corp., Idaho Falls, ID (United States)) & Anderson, G.L. (EG and G Idaho, Inc., Idaho Falls, ID (United States))
System: The UNT Digital Library
The development of precipitated iron catalysts with improved stability (open access)

The development of precipitated iron catalysts with improved stability

The objective of this program is to identify the chemical principles governing the deactivation of precipitated iron catalysts during Fischer-Tropsch synthesis and to use these chemical principles in the design of catalysts suitable for slurry reactors. The performance targets are 88% CO+H{sub 2} conversion with less than 1% deactivation/day for 1 month and a methane and ethane selectivity of no more than 7% (based on hydrocarbons and oxygenates only) at a space velocity of at least 2 normal liters per hr per gram iron (NL/hr/gFe) using a synthesis gas with 0.5-1.0 H{sub 2}:CO ratio in a slurry reactor.
Date: May 6, 1992
Creator: Abrevaya, H.
System: The UNT Digital Library
Electrochemistry of Thiobacillus ferrooxidans reactions with pyrite (open access)

Electrochemistry of Thiobacillus ferrooxidans reactions with pyrite

The objective of this project is to provide the fundamental information on the mechanisms of bacterial leaching of pyrite. The knowledge of how bacterial leaching of pyrite functions is essential for design and development of a technology for coal cleaning with bacteria. The features of major electrochemical techniques will be examined to find out if any of them can provide a diagnostic information on the mechanisms of related reactions.
Date: January 1, 1992
Creator: Pesic, B.
System: The UNT Digital Library
Fuel performance annual report for 1989 (open access)

Fuel performance annual report for 1989

This annual report, the twelfth in a series, provides a brief description of fuel performance during 1989 in commercial nuclear power plants and an indication of trends. Brief summaries of fuel design changes, fuel surveillance programs, fuel operating experience, fuel problems, high-burnup fuel experience, and items of general significance are provided. References to more detailed information and related US Nuclear Regulatory Commission evaluations are included.
Date: June 1, 1992
Creator: Bailey, W.J.; Berting, F.M. (Pacific Northwest Lab., Richland, WA (United States)) & Wu, S. (Nuclear Regulatory Commission, Washington, DC (United States). Div. of Systems Technology)
System: The UNT Digital Library
Safety rod latch inspection (open access)

Safety rod latch inspection

During an attempt to raise control rods from the 100 K reactor in December, one rod could not be withdrawn. Subsequent investigation revealed that a small button'' in the latch mechanism had broken off of the lock plunger'' and was wedged in a position that prevented rod withdrawal. Concern that this failure may have resulted from corrosion or some other metallurgical problem resulted in a request that SRL examine six typical latch mechanisms from the 100 L reactor by use of radiography and metallography. During the examination of the L-Area latches, a failed latch mechanism from the 100 K reactor was added to the investigation. Fourteen latches that had a history of problems were removed from K-Area and sent to SRL for inclusion in this study the week after the original seven assemblies were examined, bringing the total of latch assemblies discussed in this report to twenty one. Results of the examination of the K-Area latch that initiated this study is not included in this report.
Date: February 1, 1992
Creator: Leader, D.R.
System: The UNT Digital Library
High temperature ceramic membrane reactors for coal liquid upgrading (open access)

High temperature ceramic membrane reactors for coal liquid upgrading

In this project we intend to study a novel process concept, i.e, the use of ceramic membranes reactors in upgrading of coal derived liquids. Membrane reactors have been used in a number of catalytic reaction processes in order to overcome the limitations on conversion imposed by thermodynamic equilibrium. They have, furthermore, the inherent capability for combining reaction and separation in a single step. Thus they offer promise for improving and optimizing yield, selectivity and performance of processes involving complex liquids, as those typically found in coal liquid upgrading. Ceramic membranes are a new class of materials, which have shown promise in a variety of industrial applications. Their mechanical and chemical stability coupled with a wide range of operating temperatures and pressures make them suitable for environments found in coal liquid upgrading. In this project we will evaluate the performance of Sol-Gel alumina membranes in coal liquid upgrading processes under realistic temperature and pressure conditions and investigate the feasibility of using such membranes in a membrane reactor based coal liquid upgrading process. In addition, the development of novel ceramic membranes with enhanced catalytic activity for coal-liquid upgrading applications, such as carbon-coated alumina membranes, will be also investigated.
Date: January 1, 1992
Creator: Tsotsis, T.T.
System: The UNT Digital Library
Site Specific Verification Guidelines. (open access)

Site Specific Verification Guidelines.

The Bonneville Power Administration (BPA) and the Northwest region have moved from energy surplus to a time when demand for energy is likely to exceed available supplies. The Northwest Power Planning Council is calling for a major push to acquire new resources.'' To meet anticipated loads in the next decade, BPA and the region must more than double that rate at which we acquire conservation resources. BPA hopes to achieve some of this doubling by programs independently designed and implemented by utilities and other parties without intensive BPA involvement. BPA will accept proposals for programs using performance-based payments, in which BPA bases its reimbursement to the sponsor on measured energy savings rather than program costs. To receive payment for conservation projects developed under performance-based programs, utilities and other project developers must propose verification plans to measure the amount of energy savings. BPA has traditionally used analysis of billing histories, before and after measure installation, adjusted by a comparison group on non-participating customers to measure conservation savings. This approach does not work well for all conversation projects. For large or unusual facilities the comparison group approach is not reliable due to the absence of enough comparable non-participants to allow appropriate statistical …
Date: May 1, 1992
Creator: Harding, Steve; Gordon, Frederick M. & Kennedy, Mike
System: The UNT Digital Library
Repair Welding of Fusion Reactor Components (open access)

Repair Welding of Fusion Reactor Components

Recent experimental investigations indicate that the repair welding of irradiated materials containing greater than 1 to 2.5 appm helium leads to catastrophic cracking in the heat affected zone of the weld. The high temperatures and cooling tensile stresses which occur during the welding process lead to enhanced helium bubble growth in the heat affected zone region, resulting in catastrophic cracking upon cooling. An investigation is proposed which seeks to determine the effect of stress state on the helium bubble growth process and develop engineering modifications to the welding process based upon this understanding in an attempt to alleviate or eliminate the weld cracking problem in type 316 stainless steel materials.
Date: May 20, 1992
Creator: Chin, Bryan A.
System: The UNT Digital Library
Optical properties of flyash (open access)

Optical properties of flyash

The general aims of this research are to provide a fundamental scientific basis for the physical understanding and reliable calculation of heat transfer in coal combustion systems, particularly as it is influenced by the presence of inorganic constituents deriving from mineral matter in coal. (VC)
Date: April 1, 1992
Creator: Self, S.A.
System: The UNT Digital Library
Biological Production of Ethanol From Coal (open access)

Biological Production of Ethanol From Coal

Research is continuing in an attempt to increase both the ethanol concentration and product ratio using C. ljungdahlii. The purpose of this report is to present data utilizing a medium prepared especially for C. ljungdahlii. Medium development studies are presented, as well as reactor studies with the new medium in batch reactors. CSTRs and CSTRs with cell recycle. The use of this new medium has resulted in significant improvements in cell concentration, ethanol concentration and product ratio.
Date: January 1, 1992
Creator: unknown
System: The UNT Digital Library
The demand-side management program development process: A utility perspective (open access)

The demand-side management program development process: A utility perspective

This report describes an aspect of DSM that has received little attention, namely, how utilities develop DSM programs. The selection of utilities to study purposely was biased in favor of those with reputations for being experienced DSM program developers so as to optimize the chances to obtain detailed information. The DSM planning process is affected by organizational factors and external influences: (1) the location of the demand-side planning department within the utility; (2) the demand-side planning group's functional responsibilities; (3) upper management participation in the DSM program development process; and (4) the organizational relationship between (or, separation of) supply-side and demand-side planning. Organizational factors reflect utilities' views of DSM programs and thus can affect the adoption of a technology- or customer-oriented approach. Despite repeated claims of the uniqueness of the demand- side planning process and its resistance to standardization, two general approaches to program development were discerned, namely technology- or customer-orientation. Although utilities consider customer related and technological factors in their DSM program development process, utilities can be differentiated by their emphasis on one or the other approach. 25 refs.
Date: March 1, 1992
Creator: Wolfe, A.K. (Oak Ridge National Lab., TN (United States)) & Yourstone, N.E. (Yourstone (Evelin), Albuquerque, NM (United States))
System: The UNT Digital Library
Simulation of hanging file experiments with CALOR89 (open access)

Simulation of hanging file experiments with CALOR89

This note presents the comparison of CALOR89 simulation with the hanging file'' test measurements conducted at Fermilab during the period of Sep 91--Jan 92. The purpose of this study is to benchmark CALOR89 code against the experimental data to enhance its reliability and predictive power. Seven hanging file configurations were simulated. The measured values of e/{pi} ratio (the ratio of electron to pion signal at the same energy), hadronic and electromagnetic resolutions were compared with the simulations. The depth profiles of the hadronic and electromagnetic showers are also compared.
Date: January 1, 1992
Creator: Job, P.K.; Price, L.E.; Proudfoot, J. (Argonne National Lab., IL (United States). High Energy Physics Div.); Handler, T. (Tennessee Univ., Knoxville, TN (United States)) & Gabriel, T.A. (Oak Ridge National Lab., TN (United States))
System: The UNT Digital Library
Synergistic capture mechanisms for alkali and sulfur species from combustion (open access)

Synergistic capture mechanisms for alkali and sulfur species from combustion

This report presents work done on a laboratory combustor in an attempt to identify mechanisms that govern the simultaneous capture of alkali and sulfur species using sorbent injection techniques. The mechanisms of capture fall into two broad categories i.e. Physical transport of alkali species (in vapor or condensed phase) to the sorbent surface and surface reaction between the alkali species and the sorbents. Water solubility, though not specific, has been used to get an indication of relative significance of these two broad mechanisms. It is assumed that the physically adsorbed alkali species on sorbents are predominantly water soluble while the chemically reacted alkali content is predominantly water insoluble. In order to infer possible dominant mechanisms, specific parameters has been varied during experimentation. Such parameters include, speciation, particle time-temperature history, and furnace burning conditions.
Date: April 23, 1992
Creator: Peterson, T.W.; Shadman, F.; Wendt, J.O.L. & Mwabe, P.O.
System: The UNT Digital Library
(The relationship between microstructure and magnetic properties in high-energy permanent magnets characterized by polytwinned structures) (open access)

(The relationship between microstructure and magnetic properties in high-energy permanent magnets characterized by polytwinned structures)

This report summarizes the results of a study of the relationship between microstructure and magnetic properties in a unique genre of ferromagnetic material characterized by a polysynthetically twinned structure which arises during solid state transformation. These results stem from the work over a period of approximately 27 months of a nominal 3 year grant period. The report also contains a proposal to extend the research project for an additional 3 years. The polytwinned structures produce an inhomogeneous magnetic medium in which the easy axis of magnetization varies quasi-periodically giving rise to special domain configurations which are expected to markedly influence the mechanism of magnetization reversal and hysteresis behavior of these materials in bulk or thin films. The extraordinary permanent magnet properties exhibited by the well-known Co-Pt alloys as well as the Fe-Pt and Fe-Pd systems near the equiatomic composition derive from the formation of a polytwinned microstructure.
Date: January 1, 1992
Creator: unknown
System: The UNT Digital Library
Facilities evaluation report (open access)

Facilities evaluation report

The Buried Waste Integrated Demonstration (BWID) is a program of the Department of Energy (DOE) Office of Technology Development whose mission is to evaluate different new and existing technologies and determine how well they address DOE community waste remediation problems. Twenty-three Technical Task Plans (TTPs) have been identified to support this mission during FY-92; 10 of these have identified some support requirements when demonstrations take place. Section 1 of this report describes the tasks supported by BWID, determines if a technical demonstration is proposed, and if so, identifies the support requirements requested by the TTP Principal Investigators. Section 2 of this report is an evaluation identifying facility characteristics of existing Idaho National Engineering Laboratory (INEL) facilities that may be considered for use in BWID technology demonstration activities.
Date: April 1, 1992
Creator: Sloan, P.A. & Edinborough, C.R.
System: The UNT Digital Library
Experimental study of weak interactions by precision measurement of rare kaon decay, Task B (open access)

Experimental study of weak interactions by precision measurement of rare kaon decay, Task B

This report discusses research on the following decay schemes and parameters: {epsilon}{prime}/{epsilon}; {Phi}{sub 00} {minus} {Phi}+{minus}; K{sub L} {yields} {pi}{sup 0}e{sup +}e{sup {minus}}; K{sub L} {yields} {pi}{sup 0}{delta}{delta}; {pi}{sup 0} {yields} e{sup +}e{sup {minus}}; K{sub LS} {yields} {pi}{sup +}{pi}{sup {minus}}{delta}; K{sub e4}; K{sub e3}; K{sub L} {yields} 3{pi}{sup 0} decay constant.
Date: April 1, 1992
Creator: Winston, Roland
System: The UNT Digital Library
High temperature ceramic membrane reactors for coal liquid upgrading (open access)

High temperature ceramic membrane reactors for coal liquid upgrading

In this project we will study a novel process concept, i.e., the use of ceramic membrane reactors in upgrading of coal model compounds and coal derived liquids. In general terms, the USC research team is responsible for constructing and operating the membrane reactor apparatus and for testing various inorganic membranes for the upgrading of coal derived asphaltenes and coal model compounds. The USC effort will involve the principal investigator of this project and two graduate research assistants. The ALCOA team is responsible for the preparation of the inorganic membranes, for construction and testing of the ceramic membrane modules, and for measurement of their transport properties. The ALCOA research effort will involve Dr. Paul K. T. Liu, who is the project manager of the ALCOA research team, an engineer and a technician. UNOCAL's contribution will be limited to overall technical assistance in catalyst preparation and the operation of the laboratory upgrading membrane reactor and for analytical back-up and expertise in oil analysis and materials characterization. UNOCAL is a no-cost contractor but will be involved in all aspects of the project, as deemed appropriate.
Date: January 1, 1992
Creator: Tsotsis, T.T.
System: The UNT Digital Library
Rapid quenching of molten lithium-aluminum jets in water under loss-of-control-rod-cooling conditions (open access)

Rapid quenching of molten lithium-aluminum jets in water under loss-of-control-rod-cooling conditions

A series of fifteen tests were performed to investigate the thermal interactions between molten LiAl control rod material and water under conditions prototypic of the loss-of-control-rod-cooling (LCRC) accident scenario. The experimental parameters such as melt mass, stream diameter, melt temperature and flowrate, water depth and water temperature were controlled or varied to agree with analytically determined conditions, thus insuring prototypicality of the experiments and applicability of the results. Experiments were performed in an actual Q-septifoil with web insert; the test section was one meter tall. Natural triggers were investigated in selected tests, to evaluate the self-triggering potential of this system. The self-triggering mechanisms that were investigated were thermal stratification of the water pool, two-phase flow in the water pool, and simultaneous drop of a control rod in parallel channel. Only benign interactions were observed during these tests with some evidence of pressurization in the tests with deepest and hottest water pools. There was no evidence of any explosive interactions in any of the tests, even those with natural triggers. The molten LiAl jets was found to undergo jet breakup and fragmentation; in some cases the debris hung up in the web, in other cases the debris settled into a loose …
Date: January 1, 1992
Creator: Greene, G. A.; Finfrock, C. C.; Schwarz, C. E.; Allison, D. K. & Hyder, M. L.
System: The UNT Digital Library
An organizational survey of the Strategic Petroleum Reserve. [Organizational survey in preparation for an upcoming Tiger Team Assessment] (open access)

An organizational survey of the Strategic Petroleum Reserve. [Organizational survey in preparation for an upcoming Tiger Team Assessment]

At the request of the management of the Strategic Petroleum Reserve (SPR), an Organizational Survey (OS), identical to the one that has been used prior to Tiger Team Assessments at other Department Energy facilities, was administered at SPR independent of a Tiger Team Assessment. The OS measured employees' opinions on subjects such as organizational culture, communication, commitment, group cohesion, coordination, safety, environmental issues, and job satisfaction. The result of this work was a quantitative measure of these variables at the SPR site. SPR management intends to utilize these results in their self-assessment process in preparation for an upcoming Tiger Team Assessment. This report presents these results and discusses their interpretation.
Date: January 1, 1992
Creator: Shurberg, D.A. & Haber, S.B.
System: The UNT Digital Library
Costs and benefits of automotive fuel economy improvement: A partial analysis (open access)

Costs and benefits of automotive fuel economy improvement: A partial analysis

This paper is an exercise in estimating the costs and benefits of technology-based fuel economy improvements for automobiles and light trucks. Benefits quantified include vehicle cots, fuel savings, consumer's surplus effects, the effect of reduced weight on vehicle safety, impacts on emissions of CO{sub 2} and criteria pollutants, world oil market and energy security benefits, and the transfer of wealth from US consumes to oil producers. A vehicle stock model is used to capture sales, scrappage, and vehicle use effects under three fuel price scenarios. Three alternative fuel economy levels for 2001 are considered, ranging from 32.9 to 36.5 MPG for cars and 24.2 to 27.5 MPG for light trucks. Fuel economy improvements of this size are probably cost-effective. The size of the benefit, and whether there is a benefit, strongly depends on the financial costs of fuel economy improvement and judgments about the values of energy security, emissions, safety, etc. Three sets of values for eight parameters are used to define the sensitivity of costs and benefits to key assumptions. The net present social value (1989$) of costs and benefits ranges from a cost of $11 billion to a benefit of $286 billion. The critical parameters being the discount …
Date: March 1, 1992
Creator: Greene, D.L. (Oak Ridge National Lab., TN (United States)) & Duleep, K.G. (Energy and Environmental Analysis, Inc., Arlington, VA (United States))
System: The UNT Digital Library
(NLUF user-application of a high-density gas laser target to the physics x-ray lasers and coronal plasmas) (open access)

(NLUF user-application of a high-density gas laser target to the physics x-ray lasers and coronal plasmas)

None
Date: March 13, 1992
Creator: unknown
System: The UNT Digital Library
Applications of mesoscopic physics (open access)

Applications of mesoscopic physics

This report discusses the following topics: Acoustical nondestructive evaluation of heterogeneous materials in the multiple scattering regime. Classical and quantum superdiffusion in a time-dependent random potential. Negative Magnetoresistance in Variable Range Hopping Conduction. Reproducible Conductance Fluctuations in Macroscopic Anderson Insulators. Feasibility of far-infared lasers using multiple semiconductor quantum wells.
Date: January 1, 1992
Creator: Feng, Shechao.
System: The UNT Digital Library
Milliwatt Generator Project (open access)

Milliwatt Generator Project

This report covers progress on the Milliwatt Generator Project from April 1986 through March 1988. Activities included fuel processing and characterization, production of heat sources, fabrication of pressure-burst test units, compatibility studies, impact testing, and examination of surveillance units. The major task of the Los Alamos Milliwatt Generator Project is to fabricate MC2893A heat sources (4.0 W) for MC2730A radioisotope thermoelectric generators (RTGS) and MC3599 heat sources (4.5 W) for MC3500 RTGs. The MWG Project interfaces with the following contractors: Sandia National Laboratories, Albuquerque (designer); E.I. du Pont de Nemours and Co. (Inc.), Savannah River Plant (fuel); Monsanto Research Corporation, Mound Facility (metal hardware); and General Electric Company, Neutron Devices Department (RTGs). In addition to MWG fabrication activities, Los Alamos is involved in (1) fabrication of pressure-burst test units, (2) compatibility testing and evaluation, (3) examination of surveillance units, and (4) impact testing and subsequent examination of compatibility and surveillance units.
Date: May 1, 1992
Creator: Latimer, T.W. & Rinehart, G.H.
System: The UNT Digital Library
Lecture notes for criticality safety (open access)

Lecture notes for criticality safety

These lecture notes for criticality safety are prepared for the training of Department of Energy supervisory, project management, and administrative staff. Technical training and basic mathematics are assumed. The notes are designed for a two-day course, taught by two lecturers. Video tapes may be used at the options of the instructors. The notes provide all the materials that are necessary but outside reading will assist in the fullest understanding. The course begins with a nuclear physics overview. The reader is led from the macroscopic world into the microscopic world of atoms and the elementary particles that constitute atoms. The particles, their masses and sizes and properties associated with radioactive decay and fission are introduced along with Einstein's mass-energy equivalence. Radioactive decay, nuclear reactions, radiation penetration, shielding and health-effects are discussed to understand protection in case of a criticality accident. Fission, the fission products, particles and energy released are presented to appreciate the dangers of criticality. Nuclear cross sections are introduced to understand the effectiveness of slow neutrons to produce fission. Chain reactors are presented as an economy; effective use of the neutrons from fission leads to more fission resulting in a power reactor or a criticality excursion. The six-factor formula …
Date: March 1, 1992
Creator: Fullwood, R.
System: The UNT Digital Library