Resource Type

(Development of a Human Genome Data Base) (open access)

(Development of a Human Genome Data Base)

This report describes managerial aspects and briefly some technical accomplishments a Human Genome Database in Baltimore.
Date: January 1, 1992
Creator: unknown
System: The UNT Digital Library
The Unstable Species and the Isotope Effect in the Pyrolysis of Diborane in a Shock Tube (open access)

The Unstable Species and the Isotope Effect in the Pyrolysis of Diborane in a Shock Tube

From American Chemical Society 145th National Meeting, New York, Sept. 1963. The pyrolysis of diborane was examined using a chemical shock tube as a reactor. Additional evidence for the existence of hexaborane-12 and heptaborane- 11 and -13 was obtained. The presence of a large net normal isotope effect in the formation of tetraborane and hexaborane and a net inverse isotope effect in the formation of pentaborane-9 are observed. A mechanism, consisting of a series of competitive reactions and eqailibria, in which tetraboraue is the precursor of pentaborane-11 and hexaborane but not of pentaborane-9 is shown to be compatible with the observed isotope effect. Data obtained by examining the pyrolysis of various mixtures of boron hydrides are also consistent with the mechanism. (auth)
Date: January 1, 1963
Creator: Fehlher, T P & Koski, W S
System: The UNT Digital Library
Investigation of the processes controlling the flame generation of refractory materials. Progress report, July 1, 1991--June 30, 1992 (open access)

Investigation of the processes controlling the flame generation of refractory materials. Progress report, July 1, 1991--June 30, 1992

The processes involved in the formation of mixed oxides powders were studied using the counterflow diffusion flame burner. Powders of different morphologies were obtained by varying the flame conditions (temperature, residence time) and the concentration ratio of the oxides precursors. In-situ particle size and number density were determined using dynamic light scattering and 90{degrees} light scattering. A thermophoretic sampling method and a larger scale powder collection device also was used to collect particles, and their size and morphology examined using transmission electron microscopy, X-ray diffraction and surface area measurement by gas absorption (BET). Our emphasis has been on TiO{sub 2}-SiO{sub 2}, SiO{sub 2}-GeO{sub 2} and Al{sub 2}O{sub 3}-TiO{sub 2}. The powders had a core-mantle-like (one oxide coated by the other) at low elevations in the burner and uniform mixture at higher elevations. They form chain-like structures in a low temperature flame and spherical particles in a higher temperature flame. Nanometer sized homogeneous particles of Aluminum Titanate could be obtained using Al(CH{sub 3}){sub 3} and TiCl{sub 4} as precursors both in a hydrogen fueled and a methane fueled counterflow diffusion flame burner, as well as in a hydrogen fueled parallel-flow diffusion flame burner.
Date: January 1, 1992
Creator: Katz, J. L.
System: The UNT Digital Library