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Electrochemical Membrane Incinerator (open access)

Electrochemical Membrane Incinerator

Electrochemical incineration of benzoquinone was evaluated as a model for the mineralization of carbon in toxic aromatic compounds. A Ti or Pt anode was coated with a film of the oxides of Ti, Ru, Sn and Sb. This quaternary metal oxide film was stable; elemental analysis of the electrolyzed solution indicated the concentration of these metal ions to be 3 {micro}g/L or less. The anode showed good reactivity for the electrochemical incineration of benzoquinone. The use of a dissolved salt matrix as the so-called ''supporting electrolyte'' was eliminated in favor of a solid-state electrolyte sandwiched between the anode and cathode.
Date: December 8, 1998
Creator: Johnson, Dennis C.; Houk, Linda L. & Feng, Jianren
System: The UNT Digital Library
Titanium Carbide Bipolar Plate for Electrochemical Devices (open access)

Titanium Carbide Bipolar Plate for Electrochemical Devices

Titanium carbide comprises a corrosion resistant, electrically conductive, non-porous bipolar plate for use in an electrochemical device. The process involves blending titanium carbide powder with a suitable binder material, and molding the mixture, at an elevated temperature and pressure.
Date: May 8, 1998
Creator: LaConti, Anthony B.; Griffith, Arthur E.; Cropley, Cecelia C. & Kosek, John A.
System: The UNT Digital Library
Method for Plutonium-Gallium Separation by Anodic Dissolution of a Solid Plutonium-Gallium Alloy (open access)

Method for Plutonium-Gallium Separation by Anodic Dissolution of a Solid Plutonium-Gallium Alloy

Purified plutonium and gallium are efficiently recovered from a solid plutonium-gallium (Pu-Ga) alloy by using an electrorefining process. The solid Pu-Ga alloy is the cell anode, preferably placed in a moving basket within the electrolyte. As the surface of the Pu-Ga anode is depleted in plutonium by the electrotransport of the plutonium to a cathode, the temperature of the electrolyte is sufficient to liquify the surface, preferably at about 500 C, resulting in a liquid anode layer substantially comprised of gallium. The gallium drips from the liquified surface and is collected below the anode within the electrochemical cell. The transported plutonium is collected on the cathode surface and is recovered.
Date: December 8, 1998
Creator: Miller, William E. & Tomczuk, Zygmunt
System: The UNT Digital Library
Cyanoethylated Compounds as Additives in Lithium/Lithium Ion Batteries (open access)

Cyanoethylated Compounds as Additives in Lithium/Lithium Ion Batteries

The power loss of lithium/lithium ion battery cells is significantly reduced, especially at low temperatures, when about 1% by weight of an additive is incorporated in the electrolyte layer of the cells. The usable additives are organic solvent soluble cyanoethylated polysaccharides and poly(vinyl alcohol). The power loss decrease results primarily from the decrease in the charge transfer resistance at the interface between the electrolyte and the cathode.
Date: May 8, 1998
Creator: Nagasubramanian, Ganesan
System: The UNT Digital Library