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Most US coals contain sulfur concentrations that prevent their being burned without some form of sulfur removal. Current coal-cleaning technology can only remove the fairly reactive pyritic (inorganic) and aliphatic (organic) sulfur. A process which removes the more refractory hetero-aromatic sulfur could substantially increase the amount of coal reserves amenable to chemical cleaning. Sodium metal dispersions convert refractor model compounds into lighter desulfurized products and non-volatile sulfur-rich char. When treated with sodium, coal-derived solids show substantial desulfurization. The same treatment applied to coal-derived liquids, when combined with vacuum distillation of the reaction product, yields a desulfurized light distillate, an increase in absolute amount of distillate, and retention of sulfur in the vacuum residue. The presence of sodium in the residue allows fixation of the residual sulfur as Na/sub 2/SO/sub 4/ upon combustion, eliminating production of SO/sub 2/ in the flue gas. Intimate contacting of sodium salts with high sulfur coal also fixes 97 to 99% of the sulfur as Na/sub 2/SO/sub 4/ upon combustion. This technique takes advantage of the high energy available for carbon-sulfur bond cleavage during combustion and the reaction of SO/sub 2/ to form Na/sub 2/SO/sub 4/ to provide an inexpensive method for complete coal desulfurization.

Twentieth-century science proves that heredity and environment function similarly in all named living species except one--Homo sapiens. Man alone, through his intellect, forms language and culture, thereby affecting his environment so that he participates in the process of his own creation. This participation so links humans that each man extends outside himself creating of the human race a single, whole fabric. C. P. Snow, aware of this communal reality, notes the present lack of communication between scientists and humanists. He contends that this lack, described as the two-cultures split, endangers both the practical survival of Western civilization and mankind's understanding of its own humanity. This study analyzes modern scientific reality and shows that Snow's articles, lectures, and novels articulate that reality and confirm the merit of Snow's observations.

The condensed polynuclear aromatic clusters of coal are believed to be linked principally by straight-chain aliphatic bridges varying from 0 to 4 carbon atoms in length and the cleavage of these linkages is expected to be an important step in the coal liquefaction process. This study focuses on the means by which Lewis acid catalysts, specifically AlCl/sub 3/ and ZnCl/sub 2/, promote the cleavage of these linkages. To facilitate product identification and interpretation of reaction mechanisms, organic compounds which model the aliphatic bridges were used on substrates. All experiments were performed in a magnetically stirred autoclave under either an H/sub 2/ or N/sub 2/ atmosphere at elevated pressure to determine the role of H/sub 2/. Reaction temperatures ranging from 200 to 350/sup 0/C were used to avoid the complication of pyrolysis reactions. Reaction products were identified with the aid of gas chromatography/mass spectrometry, and quantitative product yields were determined by gas chromatography. Experiments with AlCl/sub 3/ and the substrates containing two phenyl rings linked by 0 to 4 carbon atoms showed that AlCl/sub 3/ catalyzed cleavage of all the aliphatic bridges. ZnCl/sub 2/ was totally inactive in cleaving the alkyl bridges in these compounds. Substitution of a phenyl group by …

The purpose of this paper is to illustrate the use of the computer in solving complex real time scheduling problems. This problem involves the airline industry and is concerned with the local scheduling of security personnel to the gate areas for outgoing flights from one terminal at Dallas-Fort Worth airport. The purpose of this type of program is to enhance personnel efficiency and management control over a large group of people while cutting the cost of lower management.

The scientific subroutine package is one of the most important parts of the software for the scientific industry. By now, most big computers have scientific packages, but applying such a software package in microprocessors requires consideration of the microprocessor's facilities, such as limited main memory, slow execution time, and only a few small registers. In any scientific package, the trigonometric functions are the ones more widely used. This paper discusses a method for implementing several trigonometric function programs in a scientific package in microprocessors. These programs will contain routines for computing sin, cos, tan, and cot of any angle within the range of (-360°,+360°).

Thesis. The optical absorption spectra of Ho/sup 3+/ in the rare earth salt HoF/sub 3/ is studied. Such optical region studies (visible radiation) are easily performed with standard light sources and optical arrangements. Since the energy range of visible light coincides with the excitation energy range for a number of electronic transitions within the rare earth salts, the studies theoretically provide considerable information about rare earth electronic energy levels. Data are compiled for the effects of an applied magnetic field upon the spectra and the effect of sample temperature on the observed absorption spectra. 61 references. (MCW)

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Ribavirin, a synthetic nucleoside, was found to inhibit the replication of Rous sarcoma viruses (RSV) and subsequent cell transformation in chick embryo fibroblasts (CEF). It also blocked the transformation of normal rat kidney (NRK) cells infected with temperature-sensitive mutants of RSV. The action of Ribavirin was found to be reversible as removal of the drug from the NRK cells reversed the effects on cell transformation. Ribavirin appears to have a static effect on cell growth of both NRK and CEF cells. In addition, guanosine, xanthosine and inosine altered the effect of Ribavirin on cell growth.

Thesis. Submitted by J. Lorrain. Theoretical analyses of interphase processes involving vapors and liquids are presented. Monoatomic and reacting vapors were considered in situations such as condensation, evaporation and heat transfer between the vapor and its liquid. These developments are believed to be the most accurate to date in describing such processes. The implications of the presence of diatomic and heavier naolecules in liquid metal vapors in their condensation heat transfer are discussed. It is shown that some assumed detailed mechanisms of condensation of these species can explain the low experimental condensation heat transfer coefficients of liquid metals. Results of an experimental investigation of the condensation mechanism and condensation heat transfer of nitrogen tetroxide vapor are presented. From measurements of temperature profiles in the vapor near the vapor-llquid interface during condensation it was concluded that both major components of the vapor (nitrogen dioxide and nitrogen tetroxide) condense at comparable rates. This mechanism is in qualitative agreement with the experimental condensation heat transfer coefficients, which were found to be 10 to 20% higher than predicted by Nusselt's theory. This is apparentiy the first determination of a detailed condensation mechanism at moderate pressures where traditional methods (e.g., vacuum evaporation techniques) can not …

>Thesis. The modeling of the Ames Laboratory Research Reactor core region and the input required to utilize the Monte Carlo computer code KENO for criticality calculations are described. Reactivity calculations in terms of k- effective were made for various reactor configurations and compared to measurements made on the actual reactor. (16 references) (auth)

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Thesis. The specific heat was measured from 2.55 to 15.7 deg K, first with no external magnetic field, and then with magnetic fields along the c-axis and a-axis of intensity of 1000, 3000, and 5800 Oe. Two specific heat anomalies were observed: a Schottky anomaly caused by the ground state exchange splitting of the Yb/sup 3+/, and spin reorientation of the Fe sublattice. (DLC)

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