The heat capacity of high purity electrotransport refined lutetium was measured between 1 and 20/sup 0/K. Results for theta/sub D/ were in excellent agreement with theta values determined from elastic constant measurements. The heat capacity of a series of lutetium-hydrogen solid solution alloys was determined and results showed an increase in ..gamma.. from 8.2 to about 11.3 mJ/g-atom-K/sup 2/ for hydrogen content increasing from zero to about one atomic percent. Above one percent hydrogen ..gamma.. decreased with increasing hydrogen contents. The C/T data showed an increase with temperature decreasing below about 2.5/sup 0/K for samples with 0.1 to 1.5 atomic percent hydrogen. This accounts for a large amount of scatter in theta/sub D/ versus hydrogen content in this range. The heat capacity of a bulk sample of lutetium dihydride was measured between 1 and 20/sup 0/K and showed a large increase in theta/sub D/ and a large decrease in ..gamma.. compared to pure lutetium.

The experimental verification of the two-step nature of energy dissipation of photon energy by a crystal is the subject of this dissertation. The ..cap alpha..(O,O) Davydov component of the lowest energy singlet transition in pure strain-free napthalene single crystals is shown to exhibit an increase in absorption with increasing temperature, due to an increase in polariton damping via polariton-phonon scattering processes. (GHT)

A chelating ion-exchange resin with N-(2-hydroxyethyl)ethylene-diaminetriacetic acid (HEDTA) used as the ligand chemically bonded to XAD-4 by an ester linkage, HEDTA-4, was synthesized. It is stable under normal experimental conditions with the liquid chromatograph. The structure of the resin was confirmed by an infrared spectrum, and by potentiometric titrations. The capacity of the resin was also obtained by potentiometric titration and by a nitrogen analysis. The resin was used to pack a column of 5 mm internal diameter and 5 cm long. The effect of pH on the retention of different metal ions on the resin was studied. It was found that the resin was most selective for chromium(III), copper(II), lead(II), mercury(II), uranium(VI), zirconium(IV) and zinc(II) at a pH of less than 3. Furthermore, the resin proves to be functioning with a chelating mechanism rather than ion-exchange, and it can concentrate trace metal ions in the presence of a large excess of calcium and magnesium. This makes the resin potentially useful for purifying and analyzing drinking water.

The electron microscope was used to study the biological processes involved in hydrocarbon production. The little desert shrub Guayule (Parthenium argentatum) was selected for study. This shrub can produce hydrocarbons (rubber) in concentrations up to 1/4 of its dry weight. It grows on semi-arid land and has been extensively studied. The potential of Guayule is described in detail. Results of an investigation into the morphology of Guayule at the electron microscope level are given. Experiments, which would allow the biosynthesis of hydrocarbon in Guayule to be followed, were designed. In order to do this, knowledge of the biochemistry of rubber formation was used to select a tracer, mevalonic acid. Mevalonic acid is the precursor of all the terpenoids, a large class of hydrocarbons which includes rubber. It was found that when high enough concentrations of mevalonic acid are administered to seedling Guayule plants, build-ups of metabolized products are found within the chloroplasts of the seedlings. Also, tritium labeled mevalonic acid was used as a precursor, and its metabolic progress was followed by using the technique of electron microscope autoradiography. The results of these experiments also implicated chloroplasts of the Guayule plant in hydrocarbon production. The final task was the development …

The critical stress for the reorientation of vanadium hydride was determined for the temperature range 180/sup 0/ to 280/sup 0/K using flat tensile samples containing 50 to 500 ppM hydrogen by weight. The critical stress was observed to vary from a half to a third of the macroscopic yield stress of pure vanadium over the temperature range. The vanadium hydride could not be stress induced to precipitate above its stress-free precipitation temperature by uniaxial tensile stresses or triaxial tensile stresses induced by a notch.

The electric mobility and effective valence of hydrogen and deuterium in vanadium, niobium, tantalum and three niobium-tantalum alloys were measured. A resistance technique was used to directly determine the electric mobility of hydrogen and deuterium at 30/sup 0/C while a steady-state method was used to measure the effective valence. The use of mass spectrographic techniques on a single specimen which contained both hydrogen and deuterium greatly increased the precision with which the isotope effect in the effective valence could be measured.

A semiconductor laser has certain properties which makes its use desirable as a continuous monitor of atmospheric pollutants. Its energy output is concentrated in widely separated energy modes of very narrow bandwidths (less than 10/sup -5/ cm/sup -1/) which can be centered on one infrared absorption line of one gas. This makes the laser quite selective. The energy in each mode is typically greater than 200 ..mu.. watts, and, because of the laser's small size, its light energy can be collimated over large distances with minimal optical losses and be easily detected. One can rapidly measure the decrease in transmission of the light due to the absorption of the light by the gas being monitored, and, using certain analytical parameters, which are different for each absorption line, one can determine the concentration of the gas in question immediately. In addition to the line center (nu/sub 0/), these analytical parameters are the intensity (S) and the half width at half maximum (..gamma..). The intensity (S) is dependent only on temperature when expressed in a per concentration basis and ..gamma.. is dependent on pressure. The Lorentzian lineshape equation K(nu) + S/..pi gamma..(((nu - nu/sub 0/)/..gamma..)/sup 2/ + 1)/sup -1/ is the equation …

The simultaneous determination of up to 20 trace elements in various oil matrices by inductively coupled plasma-atomic emission spectrometry is reported. The oil matrices investigated were lubricating oils (for wear metals), fuel oil, centrifuged coal liquefaction product, crude soybean oil, and commercial edible oils. The samples were diluted with appropriate organic solvents and injected into the plasma as an aerosol generated by a pneumatic nebulization technique. Detection limits of the 28 elements studied ranged from 0.0006 to 9 ..mu..g/g with the majority falling in the 0.01 to 0.1 ..mu..g/g range. Analytical calibration curves were linear over at least two orders of magnitude and for some elements this linearity extended over 4.5 orders of magnitude. Relevant data on precision and accuracy are included. Because metals often occur as particles in lubricating oil and coal liquefaction products, the effect of particles on the analytical results was examined. Wear metal particles in used oil did not appear to affect the analytical results. However, incomplete recovery relative to organometallic reference solutions was obtained for iron particles with a nominal mean diameter of 3.0 ..mu..m suspended in oil. It was shown that the following factors contributed to incomplete recovery for the particles: settling of the …

A dibutyl amide resin is used for the separation of uranium(VI), thorium(IV), and zirconium(IV) from each other and several other metal ions. Uranium(VI) and thorium(IV) are determined in the presence of large excesses of foreign metal ions and anions. A practical application of the amide resin is studied by determining uranium in low grade uranium ores. The amide resin is also used for the selective concentration of gold(III) from sea water.

Niobium foils of moderate purity were examined for the morphology of dislocations or defect clusters in the deformed or neutron-irradiated state by transmission electron microscopy. New evidence has been found for the dissociation of screw dislocations into partials on the (211) slip plane according to the Crussard mechanism: (a/2) (111) ..-->.. (a/3) (111) + (a/6) (111).

This research is concerned with the solvent extraction into chloroform of the lanthanides, using 2,5-dimethyl-2-hydroxyhexanoic acid (DMHHA). This acid is the first ..cap alpha..-hydroxy aliphatic acid to be studied as an extracting agent for the lanthanides. The chloroform-water DMHHA partition constant was determined to be 1.0 (at 0.1 M ionic strength and 25/sup 0/C). The acid dimerizes in chloroform with a constant of 56. The light lanthanides can be extracted into chloroform by forming complexes with the DMHHA anions. The extracted metal species is highly aggregated. This extraction has a solubility limit which increases with the addition of unionized acid. The resultant extract is also highly aggregated. At unionized acid-to-metal ratios greater than one, extractions first occur followed by the slow precipitation of the lanthanide. At the tracer level, neodymium is extracted primarily as NdA/sub 3/(HA)/sub 5/ and (NdA/sub 3/)/sub 2/(HA)/sub q/. Very small amounts of (NdA/sub 3/)/sub 2/ and other metal aggregates are also present. The heavy lanthanides do not extract from solutions of DMHHA and its potassium salt, but form aqueous emulsions and precipitates. In the presence of the organic soluble tetrabutylammonium ion the heavy lanthanides can be extracted, presumably as ion pairs. The stability constants of the …

High energy runaway electrons in the Oak Ridge tokamak ORMAK have been investigated through measurement of the bremsstrahlung produced when these electrons leave the discharge and strike the limiting aperture of the torus. The experimental results have been interpreted in terms of a classical single-particle model appropriate for collisionless particles in a tokamak, and it has been found that most of the confinement properties of high energy runaways in ORMAK can be understood on this basis. An experiment designed to directly test this model has disclosed an anomalous transport which has been described by a runaway diffusion coefficient D approximately 10/sup 2/ to 10/sup 4/ cm/sup 2//sec appropriate for runaways near the outside of the plasma. A discussion of the possible mechanisms for this anomalous transport is given.

Off-line experiments indicated that fluorides of As, Se, Br, Kr, Zr, Nb, Mo, Tc, Ru, Sb, Te, I and Xe could be volatilized, but except for Br, Kr, I and Xe, none of these elements were observed after mass separation in the on-line experiments. The results of the on-line experiments indicated a very low level of hydride contamination at ambient temperature and consequently, uranium tetrafluoride replaced uranyl stearate as the primary gaseous fission product target. Possible reasons for the failure of the heated target system to yield non-rare gas activities are discussed and suggestions for designing a new heated target system are presented.

The feasibility of calculating Wagner self-interaction parameters from binary phase diagrams was examined. The self-interaction parameters of 22 non-ferrous liquid solutions were calculated utilizing an equation based on the equality of the chemical potentials of a component in two equilibrium phases. Utilization of the equation requires the evaluation of the first and second derivatives of various liquidus and solidus data at infinite dilution of the solute component. Several numerical methods for evaluating the derivatives of tabular data were examined. A method involving power series curve fitting and subsequent differentiation of the power series was found to be the most suitable for the interaction parameter calculations. Comparison of the calculated self-interaction parameters with values obtained from thermodynamic measurements indicates that the Wagner self-interaction parameter can be successfully calculated from binary phase diagrams.

Energy curves are determined for the lowest singlet and triplet states of the HNO molecule. The geometry is varied in that the hydrogen moves through 13 positions around the NO core to describe the isomerization reaction HNO yields HON. Quantitatively determined are the stable and metastable equilibrium positions in both states, the energy differences between these two equilibrium positions and between the two states, and the barriers with respect to isomerization. The calculations are carried out using a novel configuration interaction approach called the Full Optimized Reaction Space method, which involves multiconfigurational self-consistent field calculations as an integral part. In order to interpret the bonding changes occurring during the reaction, a novel type of orbital is developed and calculated. These are called Directed Localized Reaction Orbitals. With their help it proves possible to give an interpretation of the isomerization in terms of concepts which fit chemical intuition.

A unique phonon progression in the phosphorescence spectrum of pyrene-PMDA (Py-PMDA) in naphthalene-PMDA (N-PMDA) is reported. Calculations of the electron-phonon coupling strength parameter for the ground and excited states indicate strong coupling for the fractional CT contribution of Py-PMDA to the observed phosphorescent state. Model calculations indicate that the observed low frequency phonon mode corresponds to a low energy rotation of the rigid guest complex and not a symmetric donor-acceptor stretch. The unusual reduction of the phonon mode frequency in the excited ground state is explained in terms of a contracted complex that can more easily rotate in a larger cavity. A brief phonon progression is also observed for the mixed crystal A-PMDA in N-PMDA. For both mixed crystals, Py-PMDA in N-PMDA and A-PMDA in N-PMDA, the energy spacing between the zero-phonon vibrational bands in the mixed CT crystal phosphorescence spectrum are very similar to those obtained from the phosphorescence spectrum of the pure donor in a rigid matrix. There is a large blue shift between the origin band of the mixed CT crystal phosphorescence spectrum and the origin band of the pure donor phosphorescence spectrum for the A-PMDA mixed crystal, but not for the Py-PMDA mixed crystal. The structureless …

An experimental investigation was carried out to improve the froth flotation method of separating coal pyrite. The effect of several surface active agents on the floatability of an Iowa coal and its associated pyrite was studied in both the presence and absence of methyl isobutyl carbinol (MIBC), a commonly used frother. The effectiveness of a special method of chemical pretreatment for depressing pyrite was also investigated. The zeta potential of the same coal and pyrite was measured under the same conditions used in the flotation tests (in the absence of frother). In the absence of MIBC, the floatability of coal and pyrite was low, and appeared to depend on pH. The maximum recovery of pyrite was obtained at a pH of 4.5 with recovery being less at higher or lower pH. The addition of a small amount of MIBC significantly increased the recovery of coal and pyrite with the increase in the recovery of coal being much greater than the increase in the recovery of pyrite. Also in the presence of MIBC, the floatability of coal and pyrite seemed to be affected more by pH than in the absence of MIBC. On the other hand, several potential pyrite depressants were …

The magnetic properties of quenched and annealed powder specimens of MnPt were investigated using x-ray diffraction, magnetization measurements and neutron diffraction techniques. Thin films of MnPt were prepared by rf sputtering techniques and the films were investigated by x-ray diffraction and magnetization measurements. The powder specimens of MnPt were found to be typically antiferromagnetic in an L1/sub 0/ structure with Mn atoms occupying the (001) planes. The Mn moments were antiparallel to their nearest neighbors in the (001) planes. The atomic moment of Mn is (4.1 +- .2) ..mu../sub B/ for the annealed specimens and (3.9 +- .2) ..mu../sub B/ for the quenched specimens. Neutron data failed to determine whether or not Pt carries a moment. Assuming a moment associated with the Pt atoms, the maximum value is 0.2 ..mu../sub B/ per atom. The quenched specimens contained small ferromagnetic regions probably with a composition of 18-32 at. percent Mn. The sputtered films of MnPt were highly disordered in all but one specimen, which was amorphous. The films were ferromagnetic with the deduced Mn moment of (3.0 +- .3) ..mu../sub B/ per atom, which may not represent the true value because the films were not entirely ferromagnetic.

A detailed interpretation is presented of E-field ratio telluric, bipole-dipole resistivity mapping, and dipole-dipole resistivity data obtained in the course of geophysical exploration of the Leach Hot Springs area of Grass Valley, Nevada. Several areas are singled out as being worthy of further investigation of their geothermal potential. Comparison of the three electrical exploration techniques indicates that: the bipole-dipole resistivity mapping method is the least useful; the dipole-dipole resistivity method can be very useful, but is, for practical purposes, exceptionally expensive and difficult to interpret; the E-field ratio telluric method can be a highly successful reconnaissance technique for delineating structures and relating the resistivities of different regions within the survey area.

Four sialon-type materials using volcanic ash as a raw material were characterized and some of their properties were determined. The M3 and M4 materials were identified as ..beta../sup 1/--Si/sub 3/N/sub 4/ sialons; their principal constituent is silicon. The M2 material was identified as a 15R-A1N polytype sialon whose principal constituent is aluminum. The M1 material is a mixture of the two types. An overview of results showing the general structural formulae and the relative order of the materials with respect to various properties as determined by the investigation is presented. It is concluded that of the materials tested, the M2 material shows the most promise as a candidate for meeting some of the current needs for high-temperature materials. It is also concluded that more research is needed in order to explain the low resistance of these materials to thermal shock since their coefficients of thermal expansion are relatively low.

The one- and two-dimensional Ginzburg-Landau equations are numerically integrated in a slab geometry, which is appropriate for comparison to experimental work done on films. When two-dimensional variations become energetically favorable, a vortex is found to nucleate and move to the center of the film with the Gibbs free energy decreasing during the process. An important process by which the energy is lowered during this nucleation procedure is found to be the savings in condensation energy arising from the shrinking size of the vortex core as it moves to the center of the film. The solutions of the Ginzburg-Landau equations are used to explain anomalies observed experimentally in the tunneling characteristics of thin films of PbIn. Excellent agreement between theory and experiment is found with the Ginzburg-Landau equations correctly predicting the field at which flux would first enter the films. We then use the Clem model of an isolated vortex to model vortex nucleation and dynamics under the influence of a transport current. The entry fields predicted by the model are found to be off by almost a factor of two but have the advantage of requiring simple computer programs for their solution, while the Ginzburg-Landau solutions require substantially more numerical …

The polarized absorption spectra for K/sub 2/PtBr/sub 4/ . 2H/sub 2/O, (N(C/sub 2/H/sub 5/)/sub 4/)/sub 2/PtBr/sub 6/, and Mo/sub 2/(O/sub 2/CCH/sub 2/NH/sub 3/)/sub 4/(SO/sub 4/)/sub 2/ . 4H/sub 2/O have been recorded at 300 and 15/sup 0/K. In K/sub 2/PtBr/sub 4/ . 2H/sub 2/O the bands at 24,000 and 27,000 cm/sup -1/ in both a- and b-polarizations appear to be vibronically induced. The energy spacing of the vibrational structure was noted to be somewhat higher at 180 cm/sup -1/ than for the analogous structure of K/sub 2/PtBr/sub 4/. The presence of a Pt/sub 2/Br/sub 6//sup 2 -/ impurity gave rise to red sections, which evidently were due to the electron transfer, Pt(IV)/reverse arrow/Pt(II), occurring in c-polarization. Very weak spin-forbidden bands were observable in all three polarizations below 23,500 cm/sup -1/. In the crystal spectra of (N(C/sub 2/H/sub 5/)/sub 4/)/sub 2/Pt/sub 2/Br/sub 6/ the transitions were defined with respect to the three molecular axes of the Pt/sub 2/Br/sub 6//sup 2 -/ ion. Excited states were assigned under the D/sub 2//sub h/ point group symmetry of the ion. The delocalization of the d electrons gave rise to strongly enhanced intensities for both spin-forbidden and spin-allowed d/reverse arrow/d transitions. The M/reverse arrow/L charge-transfer …

A special hydriding system was designed and constructed to satisfy conditions for hydriding niobium. This system controlled the temperature and hydrogen atmosphere surrounding the niobium while ultrasonic measurements were recorded. Ultrasonic wave velocities were determined by measurement of the times for ultrasonic pulses to transit and then echo through known dimensions of test specimens. The method which was employed is commonly known as the pulse-echo-overlap method. This study confirmed the general trends of earlier investigations. In this study C' continued to decrease and C/sub 44/ continued to increase up to 4.69 atomic percent hydrogen which is the maximum concentration which has yet been examined. In the case of the niobium-hydrogen system the Snoek effect may well be a contributory factor to the decrease of C' with increasing hydrogen concentration. However, crystallographic considerations preclude this effect from contributing a concentration dependence to C/sub 44/ or B. The observation of the present work implies that other factors must also be contributing to the overall behavior.

The development of a unique type of large superconducting solenoid magnet, characterized by very high current density windings and a two-phase helium tubular cooling system is described. The development of the magnet's conceptual design and the construction of two test solenoids are described. The successful test of the superconducting coil and its tubular cooling refrigeration system is presented. The safety, environmental and economic impacts of the test program on future developments in high energy physics are shown. Large solid angle particle detectors for colliding beam physics will analyze both charged and neutral particles. In many cases, these detectors will require neutral particles, such as gamma rays, to pass through the magnet coil with minimum interaction. The magnet coils must be as thin as possible. The use of superconducting windings allows one to minimize radiation thickness, while at the same time maximizing charged particle momentum resolution and saving substantial quantities of electrical energy. The results of the experimental measurements show that large high current density solenoid magnets can be made to operate at high stored energies. The superconducting magnet development described has a positive safety and environmental impact. The use of large high current density thin superconducting solenoids has been proposed …