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CARBON AND DEUTERIUM NUCLEAR MAGNETIC RESONANCE IN SOLIDS (open access)

CARBON AND DEUTERIUM NUCLEAR MAGNETIC RESONANCE IN SOLIDS

In Chapter I we present the results on a study of cross polarization dynamics, between protons and carbon-13 in adamantane, by the direct observation of the dilute, carbon-13, spins. These dynamics are an important consideration in the efficiency of proton enhancement double-resonance techniques and they also provide good experimental models for statistical theories of cross relaxation. In order to test these theories we present a comparison of the experimental and theoretical proton dipolar fluctuation correlation time {tau}{sub c}, which is experimentally 110 {+-} 15 {micro}sec and theoretically 122 {micro}sec for adamantane. These double resonance considerations provide the background for extensions to deuterium and double quantum effects discussed in Chapter II. In Chapter II an approach to high resolution nmr of deuterium in solids is described. The m = 1 {yields} -1 transition is excited by a double quantum process and the decay of coherence Q({tau}) is monitored. Fourier transformation yields a deuterium spectrum devoid of quadrupole splittings and broadening. If the deuterium nuclei are dilute and the protons are spin decoupled, the double-quantum spectrum is a high resolution one and yields information on the deuterium chemical shifts {Delta}{omega}. The relationship Q({tau}) {approx} cos 2{Delta}{omega}{tau} is checked and the technique is …
Date: July 1, 1976
Creator: Shattuck, Thomas Wayne
System: The UNT Digital Library
Karg-Elert’s Own Clues to the Thirty Caprices for Flute, Opus 107 (open access)

Karg-Elert’s Own Clues to the Thirty Caprices for Flute, Opus 107

This paper discusses and analyzes the music and methodology of Sigfrid Karg-Elert's Thirty Caprices for Flute, Opus 107. Jon Novi examines how Karg-Elert provides clues and instruction in The Logical Development, a paper appended to the Thirty Caprices.
Date: July 1976
Creator: Novi, Jon
System: The UNT Digital Library