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Mary/merry and horse/hoarse: Mergers in Southern American English (open access)

Mary/merry and horse/hoarse: Mergers in Southern American English

Phonetic mergers in American English have been studied throughout the last half century. Previous research has contributed social and phonetic explanations to the understanding of front and back vowel mergers before /l/, front vowel mergers before nasals and phonetically unconditioned back vowel mergers. Using data from the Linguistic Atlas of the Gulf States (LAGS) and the Linguistic Atlas of the Middle and South Atlantic States (LAMSAS), this thesis examines the spread of the front vowel mergers in Mary and merry and the back vowel mergers in horse and hoarse. The two complementary sources of data allow for a social and phonetic approach to the examination of the merger.
Date: May 2004
Creator: Ehrhardt, Brooke
System: The UNT Digital Library
An Investigation of the Traditional  Cante Jondo as the Inspiration for the Song Cycle  Five Poems of Garcia Lorca by Elisenda Fabregas (open access)

An Investigation of the Traditional Cante Jondo as the Inspiration for the Song Cycle Five Poems of Garcia Lorca by Elisenda Fabregas

The traditional cante jondo is a song unique to Andalusia as it developed from the "mosaic" of cultures that have inhabited its borders, including Arabs, Jews and Gypsies. The genre expresses the history of the region, reveals the typography of the landscape and cries the tears of its people. "Deep song," the translation for cante jondo, is the forerunner of the flamenco, but it is a communication of a dark soul rather than an exuberant entertainment. The original folk idiom is a medium less concerned with beauty than the cathartic release of pain of every day life. It expresses the soul of Andalusia. This study explores the history and the poetic and musical forms Andalusian cante jondo as the inspiration for the poetry of Federico Garcia Lorca set by Elisenda Fabregas in the song cycle, Five Poems of Garcia Lorca (1992). Lorca felt the validity of "deep song" and he was disturbed that it was being corrupted by commercialism and was afraid it would be lost to posterity. His goal was to preserve the essence of the song and lift it to an artistic plain. He saw folk music as the core of the national musical and literary identity in …
Date: May 2004
Creator: Hobbs, Mary Etta
System: The UNT Digital Library
Primary Caregiving Father's Perceptions of Leisure (open access)

Primary Caregiving Father's Perceptions of Leisure

The purpose of this study was to evaluate the impact the primary caregiving role had on men's perceptions of leisure. The Assessment of Leisure and Recreation Involvement (Ragheb, 2002) was used to examine men's leisure. Twenty-five stay-at-home dad groups were solicited via e-mail; 81 men submitted usable responses to an online survey. Respondents considered themselves the primary caregiver for children in the household and at least one child was younger than 12. Descriptive data were collected about the experience of being a primary caregiving father, demographics, and how the caregiving role affects the men's perceptions of leisure. Caregiving fathers in the sample resembled the perceptions of many primary caregiving mothers. Perhaps the "caregiving" role, rather than gender, is a more distinct variable explaining perceptions of leisure by parents.
Date: May 2004
Creator: Hall, Rebecca
System: The UNT Digital Library
Studies on actomyosin crossbridge flexibility using a new single molecule assay. (open access)

Studies on actomyosin crossbridge flexibility using a new single molecule assay.

Several key flexure sites exist in the muscle crossbridge including the actomyosin binding site which play important roles in the actomyosin crossbridge cycle. To distinguish between these sources of flexibility, a new single molecule assay was developed to observe the swiveling of rod about a single myosin. Myosins attached through a single crossbridge displayed mostly similar torsional characteristics compared to myosins attached through two crossbridges, which indicates that most of the torsional flexibility resides in the myosin subfragment-2, and thus the hinge between subfragment-2 and light meromyosin should contribute the most to this flexibility. The comparison of torsional characteristics in the absence and presence of ADP demonstrated a small but significant increase in twist rates for the double-headed myosins but no increase for single-headed myosins, which indicates that the ADP-induced increase in flexibility arises due to changes in the myosin head and verifies that most flexibility resides in myosin subfragment-2.
Date: May 2004
Creator: Gundapaneni, Deepika
System: The UNT Digital Library
Exploring flow among Division I and intramural athletes. (open access)

Exploring flow among Division I and intramural athletes.

This study explores the flow experiences of collegiate athletes. NCAA Division I athletes and intramural athletes (N = 180) completed a series of measures on their flow experiences. Comparisons were made regarding the characteristics of flow, the perceived facilitators of flow, the frequency of flow experiences, and explored the role of perceived ability. Using a person by situation interaction framework, this study singles out perceived ability as a person factor and competitive level as a situational factor to more clearly examine flow experiences. Results indicated distinctions between the two groups. Mainly, the intramural athletes reported experiencing the merging of action and awareness, autotelic experience, transformation of time and having clear goals more frequently than the NCAA Division I athletes. No group differences were found for flow frequency or flow facilitators. Perceived ability was found to have a weak, but significant relationship with specific flow facilitators and characteristics.
Date: May 2004
Creator: Peterson, Ryan J.
System: The UNT Digital Library
Sibelius's Seventh Symphony: Genesis, Design, Structure, and Meaning (open access)

Sibelius's Seventh Symphony: Genesis, Design, Structure, and Meaning

This study explores Sibelius's last and, perhaps, most enigmatic Symphony from historical (source-critical), Schenkerian, and transtextual perspectives. Through a detailed study of its genesis, musical architecture, and meaning, the author maintains that the Seventh, its composer, and its generative process, can best be understood as a series of verges: conceptual points of interaction between two or more forces. Verges between Sibelius's nature mysticism and the dramatic biographical circumstances of the period (1914-1924), between inspired and reasoned modes of composition, between genres (symphony and fantasy), between various form types, between tragic despair and hopeful yearning, between innovation and classicism, and between a host of other seeming oppositions, all define the Seventh Symphony and illuminate various facets of the composer's life and thought.
Date: May 2004
Creator: Pavlak, F. William
System: The UNT Digital Library
Analysis of Perceptional Differences Among Department Chairs, Faculty, and Instructors Toward the Barrier to Using Multiple Teaching Strategies in Two-Year Technical and Community College Electronics Courses (open access)

Analysis of Perceptional Differences Among Department Chairs, Faculty, and Instructors Toward the Barrier to Using Multiple Teaching Strategies in Two-Year Technical and Community College Electronics Courses

The purpose of this study was to identify and analyze perceptional differences among department chairs, faculty, and instructors toward the barrier to using multiple teaching strategies in two-year technical and community college electronics courses. The literature review focused on defining multiple teaching strategies and identifying and discussing four major perceived barriers to implementing them in the electronics classroom: student, resources, classroom environmental, and teacher training/teaching technology. The targeted population consisted of 150 out of 231 electronics teaching technical and community college department chairs, faculty, and instructors throughout the state of Texas. In actuality, the targeted population's breakdown consisted of 36 full-time electronics teaching department chairs, 96 full-time electronics teaching faculty and instructors, and 18 part-time electronics teaching faculty and instructors who were actively involved in the delivery of instruction in their respective schools. Analysis of the data revealed that: (1) there are no significant differences among the perceptions of department chair people, faculty, and instructors toward the four perceived barriers to implementing multiple teaching strategies in a post-secondary electronics program; and (2) there are no significant differences in the perceptions electronics faculty members categorized by years teaching experience toward each of the four perceived barrier categories to implementing multiple teaching …
Date: May 2004
Creator: Hutyra, Jerry Emil
System: The UNT Digital Library
Enhancing skill maintenance through relapse prevention strategies: a comparison of two models. (open access)

Enhancing skill maintenance through relapse prevention strategies: a comparison of two models.

In a quasi-experimental field study, two posttraining interventions composed of relapse prevention (RP) strategies were compared and tested for the effects on participant transfer outcomes. Participant retention of training content, skill maintenance, use of relapse prevention strategies, and self-efficacy served as the dependent variables. Self-efficacy was also tested as a mediator between the experimental treatment levels and both participant skill maintenance and participant use of RP strategies. Participants (n = 39) included managers, directors, and supervisors from various departments within a multi-national telecommunications organization located in a large southern city. After participating in a four-hour leadership development training, two of the three groups participated in a 30-40 minute training where they received one of two RP interventions. One intervention included the steps of (1) identifying potential obstacles to positive training transfer, (2) predicting the first lapse to pretraining behavior, and (3) applying relevant coping strategies to thwart a lapse. The alternative RP intervention included the same steps in addition to a goal setting step. Descriminant descriptive analysis was used to test for group differences across the response variables and to identify on which variables the groups differed. Three separate regression equations were used to test for the mediating relationship of …
Date: May 2004
Creator: Hutchins, Holly M.
System: The UNT Digital Library
Learning from each other - Building a bridge between two unique cultural approaches to design education. (open access)

Learning from each other - Building a bridge between two unique cultural approaches to design education.

As China is opening its doors to the world and getting more involved in the global market, it is facing great challenges and competition with other countries and cultures. In order to make Chinese graphic design industry more competitive and help Chinese businesses and industries have better success in the global market, I believed Chinese college-level design educators and students should learn more from advanced American graphic design processes and marketing methods to achieve a better understanding of Western design culture and make communication more successful. At the same time, I believed American college-level graphic design educators and students should become aware of strengths and weaknesses that exist in their own design education and learn from Chinese formal tradition.
Date: May 2004
Creator: Huang, Ye
System: The UNT Digital Library
Rachmaninoff's Rhapsody on a Theme by Paganini, Op.43; Analysis and Discourse (open access)

Rachmaninoff's Rhapsody on a Theme by Paganini, Op.43; Analysis and Discourse

This dissertation on Rachmaninoff's Rhapsody on a Theme by Paganini, Op.43 is divided into four parts: 1) historical background and the state of the sources, 2) analysis, 3) semantic issues related to analysis (discourse), and 4) performance and analysis. The analytical study, which constitutes the main body of this research, demonstrates how Rachmaninoff organically produces the variations in relation to the theme, designs the large-scale tonal and formal organization, and unifies the theme and variations as a whole. The selected analytical approach is linear in orientation - that is, Schenkerian. In the course of the analysis, close attention is paid to motivic detail; the analytical chapter carefully examines how the tonal structure and motivic elements in the theme are transformed, repeated, concealed, and expanded throughout the variations. As documented by a study of the manuscripts, the analysis also facilitates insight into the genesis and structure of the Rhapsody. How Rachmaninoff develops his ideas through several notebooks - including sketches and drafts - is described. Later parts of the dissertation deal with programmatic aspects of the Rhapsody. Related to the composer's significant use of the Dies Irae melody, semantic issues concerning "love and death" are taken into account and closely related …
Date: May 2004
Creator: Kang, Heejung
System: The UNT Digital Library
A Comparison of the Status of Widows in Eighteenth-Century England and Colonial America. (open access)

A Comparison of the Status of Widows in Eighteenth-Century England and Colonial America.

This thesis compares the status of upper-class widows in England to Colonial America. The common law traditions in England established dower, which was also used in the American colonies. Dower guaranteed widows the right to one-third of the land and property of her husband. Jointure was instituted in England in 1536 and enabled men to bypass dower and settle a yearly sum on a widow. The creation of jointure was able to proliferate in England due to the cash-centered economy, but jointure never manifested itself in Colonial America because of the land centered economy. These two types of inheritance form the background for the argument that upper-class women in Colonial America had more legal and economical freedoms than their brethren in England.
Date: May 2004
Creator: Jones, Sarah E.
System: The UNT Digital Library
Dissolved Organic Carbon Assessment on Selected Creeks and Rivers within the Elmfork Subwatersheds of Denton, Texas (open access)

Dissolved Organic Carbon Assessment on Selected Creeks and Rivers within the Elmfork Subwatersheds of Denton, Texas

The primary focus of the study was to compare dissolved organic carbon (DOC) at baseline stream flow to DOC at a higher post-rain stream flow, with a secondary focus on comparison of DOC between sites. Comparisons were also done on suspended solids at baseline flow to those of the higher post-rain flow, as well as suspended solids between sites. Significant differences did exist between DOC sampled at baseline flow and DOC in samples taken at peak flow. The study found no difference in suspended solids among sites neither on either baseflow sampling nor on the post rain event sampling.
Date: May 2004
Creator: Jackson, Pamela J.
System: The UNT Digital Library
Analysis of Leadership Perceptions Using Multirater Feedback. (open access)

Analysis of Leadership Perceptions Using Multirater Feedback.

Performance improvement intervention begins with assessment. How that assessment is interpreted can mean the difference between success and failure. Previous research of 360-degree feedback instruments has tried to reconcile the differences between multiple rater groups. Rather than searching for agreement, this research proposes to understand the meaning of the differences using multirater feedback. Individuals determine ratings based upon their own perspective and building upon the understanding of rater perspective may result in improved assessments. Data from an existing data set was processed using a second-order CFA in structural equation modeling. Covariance between the second-order factors and rater groups determined the difference in how each rater group perceived the leader.
Date: May 2004
Creator: Bradley, Thomas P.
System: The UNT Digital Library
Clockwork Plums (open access)

Clockwork Plums

Based on a story by Joshua Forehand with additional lyrics by Joshua Bradford, Clockwork Plums is an original musical work that integrates techniques and ideas from composers and different cultures. The accompanying essay about the work includes a summary of the story, "Clockwork Plums," some historical background covering 30 years of pop music, an analysis focusing on the use of African and Reichian compositional devices, and discussion about controlled improvisation and use of the voice as compositional tools. The music consists of three sections scored for 5 voices (lead male vocalist and SATB), flute (doubling tenor saxophone), Bb clarinet (doubling baritone saxophone), violin, cello, piano, electronic keyboard, electric guitar, electric bass, drum set, and percussion.
Date: May 2004
Creator: Bradford, Joshua
System: The UNT Digital Library
The Effects of Rate Contingent Consequences and Charting on Response Rates for Two Children with Autism. (open access)

The Effects of Rate Contingent Consequences and Charting on Response Rates for Two Children with Autism.

This study investigated the effects of a precision teaching package on response rates of children with autism. Prior to both experiments a preference assessment was conducted to identify high preference activities for each participant. Experiment 1 investigated whether response rates would shift as a function of rate-contingent consequences during an academic task. Different activities were associated with different rates of responding. The experimental package of 1 minute timings, rate contingent consequences, and charting was successful in increasing the rates of responding when the most highly preferred activity was associated with high rates of responding. When the contingencies were switched and the most highly preferred activity was contingent on lower rates of responding, the participant's responding did not decrease. Experiment 2 was an attempt to replicate the results of Experiment 1 using a multiple baseline across tasks. The experimental package was not successful in increasing the rate of responding.
Date: May 2004
Creator: Berman, Christine M.
System: The UNT Digital Library
The Concept of Collision Strength and Its Applications (open access)

The Concept of Collision Strength and Its Applications

Collision strength, the measure of strength for a binary collision, hasn't been defined clearly. In practice, many physical arguments have been employed for the purpose and taken for granted. A scattering angle has been widely and intensively used as a measure of collision strength in plasma physics for years. The result of this is complication and unnecessary approximation in deriving some of the basic kinetic equations and in calculating some of the basic physical terms. The Boltzmann equation has a five-fold integral collision term that is complicated. Chandrasekhar and Spitzer's approaches to the linear Fokker-Planck coefficients have several approximations. An effective variable-change technique has been developed in this dissertation as an alternative to scattering angle as the measure of collision strength. By introducing the square of the reduced impulse or its equivalencies as a collision strength variable, many plasma calculations have been simplified. The five-fold linear Boltzmann collision integral and linearized Boltzmann collision integral are simplified to three-fold integrals. The arbitrary order linear Fokker-Planck coefficients are calculated and expressed in a uniform expression. The new theory provides a simple and exact method for describing the equilibrium plasma collision rate, and a precise calculation of the equilibrium relaxation time. It generalizes …
Date: May 2004
Creator: Chang, Yongbin
System: The UNT Digital Library
Transfer of Mand Topographies to Tact Relations and Vice Versa in Two Vocal-Verbal Children with Autism (open access)

Transfer of Mand Topographies to Tact Relations and Vice Versa in Two Vocal-Verbal Children with Autism

Skinner (1957) suggested that verbal responses learned as mands are not necessarily emitted in tact relations and vice versa. Previous empirical research has found that newly acquired mands and tacts can be functionally independent. The present study investigated 1) whether novel responses taught in mand relations would be emitted as tacts when opportunity for tacting was presented; 2) whether novel responses taught in tact relations would be emitted as mands when opportunity for manding was presented; and 3) whether the size of pre-experimental mand and tact repertoires affected the rate of acquisition and/or transfer. Two vocal-verbal children with autism were taught three novel responses as mands and three other responses as tacts. Mand topographies transferred to tact relations and tact topographies transferred to mand relations for both participants. Overall acquisition as well as transfer of mands and tacts was faster for the participant with an entering repertoire of approximately 175 mands and 175 tacts than for the participant with a repertoire of approximately 100 mands and 100 tacts.
Date: May 2004
Creator: Castellani, Jill E.
System: The UNT Digital Library
Maxwell's Equations from Electrostatics and Einstein's Gravitational Field Equation from Newton's Universal Law of Gravitation Using Tensors (open access)

Maxwell's Equations from Electrostatics and Einstein's Gravitational Field Equation from Newton's Universal Law of Gravitation Using Tensors

Maxwell's equations are obtained from Coulomb's Law using special relativity. For the derivation, tensor analysis is used, charge is assumed to be a conserved scalar, the Lorentz force is assumed to be a pure force, and the principle of superposition is assumed to hold. Einstein's gravitational field equation is obtained from Newton's universal law of gravitation. In order to proceed, the principle of least action for gravity is shown to be equivalent to the maximization of proper time along a geodesic. The conservation of energy and momentum is assumed, which, through the use of the Bianchi identity, results in Einstein's field equation.
Date: May 2004
Creator: Burns, Michael E.
System: The UNT Digital Library
Effects of Methanol, Atrazine, and Copper on the Ultrastructure of Pseudokirchneriella Subcapitata (Selenastrum Capricornutum). (open access)

Effects of Methanol, Atrazine, and Copper on the Ultrastructure of Pseudokirchneriella Subcapitata (Selenastrum Capricornutum).

The toxicity of methanol, atrazine, and copper to Pseudokirchneriella subcapitata (Korshikov) Hindák historically referred to as Selenastrum capricornutum Printz were determined following 96 hrs growth in a modified Goram's growth media. Methanol and atrazine inhibited fluorescence readings in the cultures by 50% (IC50) at concentrations of 2% and 82 µg/l respectively. These toxicity values compared favorably to other published reports. The IC50 for copper was 160 µg/l which is substantially higher than reported values. This is understandable because of the high chelating capacity of Goram's media. The use of stereologically derived relative volume in the chloroplasts, mitochondria, lipid bodies, phosphate bodies, and nucleus was investigated to determine if it could be used as a sensitive endpoint in toxicity tests. The volume fractions for the chloroplasts and mitochondria were normally distributed in control cells while the nuclei, phosphate bodies, and lipid bodies were not. The chloroplasts were the most dominate organelle occupying a mean relative volume of 46% and mitochondria occupied a mean relative volume of 3%. The nucleus and phosphate bodies occupied a median relative volume of 7% and 2% respectively. The lipid bodies were rare in section profile and no meaningful median relative volume could be calculated. Up to …
Date: May 2004
Creator: Garrett, David C.
System: The UNT Digital Library
Op. 34: Evidence of Arnold Schoenberg's Musikalische Gedanke (open access)

Op. 34: Evidence of Arnold Schoenberg's Musikalische Gedanke

Composition for Arnold Schoenberg is a comprehensible presentation of a musical idea (musikalische Gedanke); the totality of a piece represents the idea. For tonal works, he defines Gedanke as a process of resolving the "tonal relation" or "tonal problem." Contrary to the numerous tonal examples illustrating the notion of Gedanke, Schoenberg hardly expounds on the Gedanke principle for his atonal and twelve-tone repertoires. This study reevaluates Schoenberg's compositional philosophy and aesthetics including Gedanke, comprehensibility, Grundgestalt, and developing variation in light of his compositional practices in Begleitungsmusik zu einer Lichtspielszene, Op. 34. Although Schoenberg denies the existence of a tonal problem and hierarchy among pitches in twelve-tone compositions, the registral placement found in Op. 34 indicates certain functionality assigned to each pitch-class, producing a sense of "departure and return." The approach here elucidates the "idea" of Op. 34, in which the large-scale formal organization unfolds through contextually emphasized tonal relations. This study also explores Schoenberg's concept of the multi-dimensional presentation of a musical idea. Even though Schoenberg's discussion of musical coherence is usually limited to the immediate musical surface, I believe that he was also aware of an extended realization of foreground motives in the sense of Heinrich Schenker's "concealed motivic …
Date: May 2004
Creator: Fukuchi, Hidetoshi
System: The UNT Digital Library
Sunlight readability and luminance characteristics of light-emitting diode push button switches. (open access)

Sunlight readability and luminance characteristics of light-emitting diode push button switches.

Lighted push button switches and indicators serve many purposes in cockpits, shipboard applications and military ground vehicles. The quality of lighting produced by switches is vital to operators' understanding of the information displayed. Utilizing LED technology in lighted switches has challenges that can adversely affect lighting quality. Incomplete data exists to educate consumers about potential differences in LED switch performance between different manufacturers. LED switches from four different manufacturers were tested for six attributes of lighting quality: average luminance and power consumption at full voltage, sunlight readable contrast, luminance contrast under ambient sunlight, legend uniformity, and dual-color uniformity. Three of the four manufacturers have not developed LED push button switches that meet lighting quality standards established with incandescent technology.
Date: May 2004
Creator: Fitch, Robert J.
System: The UNT Digital Library
The Impact of Gender on Domestic Human Rights Abuse (open access)

The Impact of Gender on Domestic Human Rights Abuse

This study develops three models of human rights determinants with the inclusion an untested variable, women in parliaments. The research is conducted on pooled cross-sectional time-series data from 130 countries between 1978 and 1996. For the purpose of analysis the Prais-Winsten Regression method with Panel Corrected Standard Errors was used. The women in power variable is hypothesized to be significantly, positively correlated with a state's propensity toward respect for human rights and is operationalized as percentage of women in parliaments. Three models incorporating as control variables previously identified correlates of human rights abuse were utilized to asses the impact of percentages of women in parliaments on two individual subsets of human rights: personal integrity rights and socio-economic rights. Two models were designed to measure the subset of rights categorized as personal integrity rights using two separate measures: State Department Scores and Amnesty International Scores. Model number three utilized the Physical Quality of Life Index to measure levels of socio-economic rights. Statistical significance was demonstrated by the women in parliament variable in all three models.
Date: May 2004
Creator: Godwin, Donna D.
System: The UNT Digital Library
An Assessment of the Effectiveness of the CHAMPS/Life Skills Program at the University of North Texas: A Pilot Study (open access)

An Assessment of the Effectiveness of the CHAMPS/Life Skills Program at the University of North Texas: A Pilot Study

This study seeks to determine the effectiveness of the Challenging Athletes Minds for Personal Success (CHAMPS)/Life Skills program at the University of North Texas, as perceived by the student athletes who participate or participated in this program. The study attempts to measure the extent to which the student athletes feel that the program had value; if they received helpful information to support them through their college career to career transition; if the student athletes felt that the program provided them with skills to encourage better self-esteem; and if they believed that the CHAMPS/Life Skills program provided them with leadership and character education. The study, conducted in the Fall of 2003, had 163 respondents. An instrument was developed to determine student athletes' perceptions of the effectiveness of the CHAMPS/Life Skills program at UNT. The instrument consisted of 30 questions using a Likert-type scale. A Mann-Whitney U, a non-parametric t-Test, was utilized to analyze the data. This type of t-Test was used because it is specifically designed to compare the means of the same variable with two different groups and account for non-homogeneous groups. The lack of homogeneity was very likely influenced by the unequal group sizes. Generally, all aspects of the …
Date: May 2004
Creator: Goddard, Michael
System: The UNT Digital Library
Reactivity of Oxide Surfaces and Metal-Oxide Interfaces: Effects of Water Vapor Pressure on Ultrathin Aluminum Oxide Films, and Studies of Platinum Growth Modes on Ultrathin Oxide Films and Their Effects on Adhesion (open access)

Reactivity of Oxide Surfaces and Metal-Oxide Interfaces: Effects of Water Vapor Pressure on Ultrathin Aluminum Oxide Films, and Studies of Platinum Growth Modes on Ultrathin Oxide Films and Their Effects on Adhesion

The reactivity of oxide surfaces and metal-oxide interfaces play an important role in many technological applications such as corrosion, heterogeneous catalysis, and microelectronics. The focus of this research was (1) understanding the effects of water vapor exposure of ultrathin aluminum oxide films under non-ultrahigh vacuum conditions (>10-9 Torr) and (2) characterization of Pt growth modes on ultrathin Ta silicate and silicon dioxide films and the effects of growth modes on adhesion of a Cu overlayer. These studies were conducted with X-ray photoelectron spectroscopy (XPS). Ni3Al(110) was oxidized (10-6 Torr O2, 800K) followed by annealing (1100K). The data indicate that the annealed oxide film is composed of NiO, Al2O3 and an intermediate phase denoted here as "AlOx". Upon exposure of the oxide film at ambient temperature to increasing water vapor pressure (10-6 - 5 Torr), a shift in both the O(1s) and Al(2p)oxide peak maxima to lower binding energies is observed. In contrast, exposure of Al2O3/Al(polycrystalline) to water vapor under the same conditions results in a high binding energy shoulder in the O(1s) spectra which indicates hydroxylation. Spectral decomposition provides further insight into the difference in reactivity between the two oxide films. The corresponding trends of the O(1s)/Ni0(2p3/2) and Al(2p)/Ni0(2p3/2) spectral …
Date: May 2004
Creator: Garza, Michelle
System: The UNT Digital Library