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3-Center-4-Electron Bonding in [(silox)2Mo=NtBu]2(μ-Hg) Controls Reactivity while Frontier Orbitals Permit a Dimolybdenum π-Bond Energy Estimate (open access)

3-Center-4-Electron Bonding in [(silox)2Mo=NtBu]2(μ-Hg) Controls Reactivity while Frontier Orbitals Permit a Dimolybdenum π-Bond Energy Estimate

Article describing research on 3-center-4-electron bonding in [(silox)2Mo=NtBu]2(mu-Hg).
Date: May 18, 2005
Creator: Rosenfeld, Devon C.; Wolczanski, Peter T.; Barakat, Khaldoon A.; Buda, Corneliu & Cundari, Thomas R., 1964-
System: The UNT Digital Library
8 GeV H- ions: Transport and injection (open access)

8 GeV H- ions: Transport and injection

Fermilab is working on the design of an 8 GeV superconducting RF H{sup -} linac called the Proton Driver. The energy of H{sup -} beam will be an order of magnitude higher than the existing ones. This brings up a number of technical challenges to transport and injection of H{sup -} ions. This paper will focus on the subjects of stripping losses (including stripping by blackbody radiation, field and residual gas) and carbon foil stripping efficiency, along with a brief discussion on other issues such as Stark states lifetime of hydrogen atoms, single and multiple Coulomb scattering, foil heating and stress, radiation activation, collimation and jitter correction, etc.
Date: May 1, 2005
Creator: Chou, W.; Bryant, H.; Drozhdin, A.; Hill, C.; Kostin, M.; Macek, R. et al.
System: The UNT Digital Library
53 MHz beam loading compensation for slip stacking in the Fermilab Main Injector (open access)

53 MHz beam loading compensation for slip stacking in the Fermilab Main Injector

Recently In-Phase and Quadrature (I&Q) was added to both the 53 MHz Feedback and Feedforward Beam Loading Compensation for Slip Stacking in the Fermilab Main Injector. With 53 MHz Feedback, we can now turn the 18 Radio Frequency (RF) Stations off down to below 100 V. In using I&Q on Feedforward, beam loading compensation to the beam on both the upper and lower frequencies of Slip Stacking can be applied as we slip the beam. I&Q theory will be discussed.
Date: May 1, 2005
Creator: Dey, J. & Kourbanis, I.
System: The UNT Digital Library
27Al and 1H Solid State NMR Studies Show Evidence of TiAl3 and TiH2 in Ti-doped NaAlH4 (open access)

27Al and 1H Solid State NMR Studies Show Evidence of TiAl3 and TiH2 in Ti-doped NaAlH4

Previous X-ray Diffraction (XRD) and Nuclear Magnetic Resonance (NMR) studies on Ti-doped NaAlH{sub 4} revealed the reaction products of two heavily doped (33.3 at.%) samples that were solvent-mixed and mechanically-milled. This investigation revealed that nano-crystalline or amorphous Al{sub 2}O{sub 3} forms from the possible coordination of aluminum with oxygen atom of the furan ring system from added tetrahydrofuran (THF) in the solvent-mixed sample, and that TiAl{sub 3} forms in mechanically-milled samples. The present paper provides a more sophisticated NMR investigation of the these materials. On heavily doped (33.3 at.%) solvent-mixed samples, {sup 27}Al Magic Angle Spinning (MAS) NMR {sup 27}Al multiple quantum MAS (MQMAS) indicates the presence of an oxide layer of Al{sub 2}O{sub 3} on the surfaces of potentially bulk nanocrystalline Ti, nanocrystalline TiAl{sub 3}, and/or metallic aluminum. The {sup 1}H MAS NMR data also indicate the possible coordination of aluminum with the oxygen atom in the THF. On heavily doped samples that were mechanically milled, {sup 27}Al MAS NMR and static NMR confirms the presence of TiAl{sub 3}. In addition, the {sup 1}H MAS NMR and {sup 1}H spin-lattice relaxation (T{sub 1}) measurements are consistent with the presence of TiH{sub 2}. These results are in agreement with recent …
Date: May 26, 2005
Creator: Herberg, J; Maxwell, R & Majzoub, E
System: The UNT Digital Library
A 3d Parallel Beam Dynamics Code for Modeling High BrightnessBeams in Photoinjectors (open access)

A 3d Parallel Beam Dynamics Code for Modeling High BrightnessBeams in Photoinjectors

In this paper we report on IMPACT-T, a 3D beam dynamics code for modeling high brightness beams in photoinjectors and rf linacs. IMPACT-T is one of the few codes used in the photoinjector community that has a parallel implementation, making it very useful for high statistics simulations of beam halos and beam diagnostics. It has a comprehensive set of beamline elements, and furthermore allows arbitrary overlap of their fields. It is unique in its use of space-charge solvers based on an integrated Green function to efficiently and accurately treat beams with large aspect ratio, and a shifted Green function to efficiently treat image charge effects of a cathode. It is also unique in its inclusion of energy binning in the space-charge calculation to model beams with large energy spread. Together, all these features make IMPACT-T a powerful and versatile tool for modeling beams in photoinjectors and other systems. In this paper we describe the code features and present results of IMPACT-T simulations of the LCLS photoinjectors. We also include a comparison of IMPACT-T and PARMELA results.
Date: May 16, 2005
Creator: Qiang, J.; Lidia, S.; Ryne, R. & Limborg, C.
System: The UNT Digital Library
3D-Simulation Studies of SNS Ring Doublet Magnets (open access)

3D-Simulation Studies of SNS Ring Doublet Magnets

The accumulator ring of the Spallation Neutron Source (SNS) at ORNL employs in its straight sections closely packed quadrupole doublemagnets with large aperture of R=15.1 cm an relatively short iron-to-iron distance of 51.4 cm. These quads have much extended fringe field, and magnetic interferences among them in the doublet assemblies is not avoidable. Though each magnet in the assemblies has been individually mapped to high accuracy of lower than 0.01 percent level, the experimental data including the magnetic interference effect will not be available. We have performed 3D computing simulations on a quadrupole doublet model in order to assess the degree of the interference and to obtain relevant data for the SNS commissioning and operation.
Date: May 5, 2005
Creator: Wang, J. G.; N., Tsoupas & Venturini, M.
System: The UNT Digital Library
AB Initio Calculations of Elastic Constants of BCC V-NB System at High Pressures (open access)

AB Initio Calculations of Elastic Constants of BCC V-NB System at High Pressures

First-principles total energy calculation based on the exact muffin-tin orbital and full potential linear muffin-tin orbital methods were used to calculate the equation of state and shear elastic constants of bcc V, Nb, and the V{sub 95}Nb{sub 05} disordered alloy as a function of pressure up to 6 Mbar. We found a mechanical instability in C{sub 44} and a corresponding softening in C at pressures {approx} 2 Mbar for V. Both shear elastic constants show softening at pressures {approx} 0.5 Mbar for Nb. Substitution of 5 at. % of V with Nb removes the instability of V with respect to trigonal distortions in the vicinity of 2 Mbar pressure, but still leaves the softening of C{sub 44} in this pressure region. We argue that the pressure induced shear instability (softening) of V (Nb) originates from the electronic system and can be explained by a combination of the Fermi surface nesting, electronic topological transition, and band Jahn-Teller effect.
Date: May 2, 2005
Creator: Landa, A; Klepeis, J; Soderlind, P; Naumov, I; Velikokhatnyi, O; Vitos, L et al.
System: The UNT Digital Library
Acceleration of Polarized Protons in the Ags With Two Helical Partial Snakes. (open access)

Acceleration of Polarized Protons in the Ags With Two Helical Partial Snakes.

The RHIC spin program requires 2 x 10{sup 11} proton/bunch with 70% polarization. As the injector to RHIC, AGS is the bottleneck for preserving polarization: there is no space for a full snake to overcome numerous depolarizing resonances. An ac dipole and a partial snake have been used to preserve beam polarization in the past few years. Two helical snakes have been built and installed in the AGS. With careful setup of optics at injection and along the ramp, this combination can eliminate all depolarizing resonances encountered during acceleration. This paper presents the setup and preliminary results.
Date: May 16, 2005
Creator: Huang, H.; Ahrens, L.; Bai, M.; Brown, K.; Courant, E. D.; Gardner, C. et al.
System: The UNT Digital Library
Accelerator and Ion Beam Tradeoffs for Studies of Warm Dense Matter (open access)

Accelerator and Ion Beam Tradeoffs for Studies of Warm Dense Matter

One approach for heating a target to ''Warm Dense Matter'' conditions (similar, for example, to the interiors of giant planets or certain stages in Inertial Confinement Fusion targets), is to use intense ion beams as the heating source (see refs.[6] and [7] and references therein for motivation and accelerator concepts). By consideration of ion beam phase space constraints, both at the injector, and at the final focus, and consideration of simple equations of state and relations for ion stopping, approximate conditions at a target foil may be calculated. Thus target temperature and pressure may be calculated as a function of ion mass, ion energy, pulse duration, velocity tilt, and other accelerator parameters. We connect some of these basic parameters to help search the extensive parameter space (including ion mass, ion energy, total charge in beam pulse, beam emittance, target thickness and density).
Date: May 13, 2005
Creator: Barnard, J. J.; Briggs, R. J.; Callahan, D. A.; Davidson, R. C.; Friedman, A.; Grisham, L. et al.
System: The UNT Digital Library
An Accelerator Control Middle Layer Using MATLAB (open access)

An Accelerator Control Middle Layer Using MATLAB

Matlab is an interpretive programming language originally developed for convenient use with the LINPACK and EISPACK libraries. Matlab is appealing for accelerator physics because it is matrix-oriented, provides an active workspace for system variables, powerful graphics capabilities, built-in math libraries, and platform independence. A number of accelerator software toolboxes have been written in Matlab -- the Accelerator Toolbox (AT) for model-based machine simulations, LOCO for on-line model calibration, and Matlab Channel Access (MCA) to connect with EPICS. The function of the MATLAB ''MiddleLayer'' is to provide a scripting language for machine simulations and on-line control, including non-EPICS based control systems. The MiddleLayer has simplified and streamlined development of high-level applications including configuration control, energy ramp, orbit correction, photon beam steering, ID compensation, beam-based alignment, tune correction and response matrix measurement. The database-driven Middle Layer software is largely machine-independent and easy to port. Six accelerators presently use the software package with more scheduled to come on line soon.
Date: May 15, 2005
Creator: Portmann, Gregory J.; Corbett, Jeff & Terebilo, Andrei
System: The UNT Digital Library
Accelerator Structure Bead Pull Measurement at SLAC (open access)

Accelerator Structure Bead Pull Measurement at SLAC

Microwave measurement and tuning of accelerator structures are important issues for the current and next generation of high energy physics machines. Application of these measurements both before and after high power processing can reveal information about the structure but may be misinterpreted if measurement conditions are not carefully controlled. For this reason extensive studies to characterize the microwave measurements have been made at SLAC. For the bead pull a reproducible measurement of less than 1 degree of phase accuracy in total phase drift is needed in order to resolve issues such as phase changes due to structure damage during high power testing. Factors contributing to measurement errors include temperature drift, mechanical vibration, and limitations of measurement equipment such as the network analyzer. Results of this continuing effort will be presented.
Date: May 13, 2005
Creator: Lewandowski, J. R.; Bowden, G.; Miller, R. H. & Wang, J. W.
System: The UNT Digital Library
Accounting Procedures for Foreign-owned Nuclear Material Located Temporarily in the Russian Federation (open access)

Accounting Procedures for Foreign-owned Nuclear Material Located Temporarily in the Russian Federation

None
Date: May 31, 2005
Creator: Pitel, V. A.; Kasumova, L. A. & Babcock, R. A.
System: The UNT Digital Library
Accurate Iterative Analysis of the K-V Equations (open access)

Accurate Iterative Analysis of the K-V Equations

Those working with alternating-gradient (A-G) systems look for simple, accurate ways to analyze A-G performance for matched beams. The useful K-V equations are easily solved in the smooth approximation. This approximate solution becomes quite inaccurate for applications with large focusing fields and phase advances. Results of efforts to improve the accuracy have tended to be indirect or complex. Their generalizations presented previously gave better accuracy in a simple explicit format. However, the method used to derive their results (expansion in powers of a small parameter) was complex and hard to follow; also, reference 7 only gave low-order correction formulas. The present paper uses a straightforward iteration method and obtains equations of higher order than shown in their previous paper.
Date: May 9, 2005
Creator: Anderson, O. A.
System: The UNT Digital Library
Achieving Large Dynamic Aperture in the ILC Damping Rings (open access)

Achieving Large Dynamic Aperture in the ILC Damping Rings

The Damping Rings for the International Linear Collider have challenging requirements for the acceptance, because of the high average injected beam power and the large beam produced from the positron source. At the same time, the luminosity goals mean that the natural emittance must be very small, and this makes it particularly difficult to achieve a good dynamic aperture. We describe design approaches and lattice designs that meet the emittance specification and have very promising dynamic aperture.
Date: May 27, 2005
Creator: Wolski, A.; Cai, Y & /LBL, Berkeley /SLAC
System: The UNT Digital Library
Adsorption of lanthanum to goethite in the presence of gluconate (open access)

Adsorption of lanthanum to goethite in the presence of gluconate

Adsorption of Lanthanum to Goethite in the Presence of Gluconic Acid L. C. HULL,1 S. E. PEPPER2 AND S. B. CLARK2 1Idaho National Engineering and Environmental Laboratory, Idaho Falls, ID (hulllc@inel.gov) 2Washington State University, Pullman, WA (spepper@wsu.edu), (s_clark@wsu.edu) Lanthanide and trivalent-actinide elements in radioactive waste can pose risks to humans and ecological systems for many years. Organic complexing agents, from natural organic matter or the degradation of waste package components, can alter the mobility of these elements. We studied the effect of gluconic acid, as an analogue for cellulose degradation products, on the adsorption of lanthanum, representing lanthanide and trivalent-actinide elments, to goethite, representing natural iron minearals and degradation products of waste packages. Batch pH adsorption edge experiments were conducted with lanthanum alone, and with lanthanum and gluconate at a 1:1 mole ratio. Lanthanum concentrations studied were 0.1, 1, and 10 mM, covering a range from 10% to 1000% of the calculated available adsorption sites on goethite. In the absence of gluconate, lanthanum was primarily present in solution as free lanthanum ion. With gluconate present, free lanthanum concentration in solution decreased with increasing pH as step-wise deprotonation of the gluconate molecule increased the fraction lanthanum complexed with gluconate. Adsorption to …
Date: May 1, 2005
Creator: Hull, Laurence C.; Pepper, Sarah & Clark, Sue
System: The UNT Digital Library
Advanced Electric and Magnetic Material Models for FDTD Electromagnetic Codes (open access)

Advanced Electric and Magnetic Material Models for FDTD Electromagnetic Codes

The modeling of dielectric and magnetic materials in the time domain is required for pulse power applications, pulsed induction accelerators, and advanced transmission lines. For example, most induction accelerator modules require the use of magnetic materials to provide adequate Volt-sec during the acceleration pulse. These models require hysteresis and saturation to simulate the saturation wavefront in a multipulse environment. In high voltage transmission line applications such as shock or soliton lines the dielectric is operating in a highly nonlinear regime, which require nonlinear models. Simple 1-D models are developed for fast parameterization of transmission line structures. In the case of nonlinear dielectrics, a simple analytic model describing the permittivity in terms of electric field is used in a 3-D finite difference time domain code (FDTD). In the case of magnetic materials, both rate independent and rate dependent Hodgdon magnetic material models have been implemented into 3-D FDTD codes and 1-D codes.
Date: May 5, 2005
Creator: Poole, B. R.; Nelson, S. D. & Langdon, S.
System: The UNT Digital Library
Advances in the understanding and operations of superconducting colliders (open access)

Advances in the understanding and operations of superconducting colliders

Chromaticity drift during injection is a well-known phenomenon in superconducting colliders, such as the Tevatron, HERA and RHIC. Imperfect compensation of the drift effects can contribute to beam loss and emittance growth. It is caused by the drift of the sextupole component in the dipole magnets due to current redistribution in its superconducting coils. Recently extensive studies of chromaticity drift were conducted at the Tevatron, aiming at the improvement of the luminosity performance in the ongoing run II. These studies included not only beam experiments, but also extensive off-line magnetic measurements on spare Tevatron dipoles. Less known, until recently, is that chromaticity drift is often accompanied by tune and coupling drift. This was recently discovered in the Tevatron. We believe that these effects are the product of systematic beam offset in conjunction with the sextupole drifts (and their compensation in the chromaticity correctors). These discoveries are most relevant to the upcoming LHC, where the drift effects will have even more dramatic consequences given the high beam current. It is therefore not a surprise that CERN has been the source of major advances in the understanding of dynamic effects during the LHC superconducting magnet development. The following will briefly review the …
Date: May 1, 2005
Creator: Annala, G.; Bauer, P.; Bottura, L.; Martens, M. A.; Sammut, N.; Velev, G. et al.
System: The UNT Digital Library
AEM Analysis of SCC in Alloy 690 Tested in 10% Caustic and 10% Caustic + PbO (open access)

AEM Analysis of SCC in Alloy 690 Tested in 10% Caustic and 10% Caustic + PbO

This report talks about AEM Analysis of SCC in Alloy 690 Tested in 10% Caustic and 10% Caustic + PbO.
Date: May 9, 2005
Creator: Lewis, N.; Shei, S.; Pica, P.; Bussert, B. & Hermer, R.
System: The UNT Digital Library
[After a Fashion, May 19, 2005] (open access)

[After a Fashion, May 19, 2005]

Article about Arthouse's "5x7 Art Splurge and Exhibition," popular culture, a birthday party at the Broken Spoke, and Ballet Austin's Fete 2005.
Date: May 19, 2005
Creator: Moser, Stephen MacMillan
System: The UNT Digital Library
Analysis of Positron Collection in the Linear Collider (open access)

Analysis of Positron Collection in the Linear Collider

In the Linear Collider, the positron capture system includes a positron production target, an adiabatic matching device (AMD), and a linac to accelerate positrons up to the injection energy of the positron damping ring. Efficiency of the positron collector is defined by the number of positrons accepted into the damping ring. Analysis of the positron collection system is performed using a conventional scheme, where positrons are produced by a high-energy electron beam hitting the high-Z target. The collection system has been optimized to insure high positron capture into the 6-dimensional acceptance of the damping ring. Various parameters affecting the positron capture are analyzed.
Date: May 27, 2005
Creator: Batygin, Yuri K.af SLAC
System: The UNT Digital Library
Analysis of the Use of Wind Energy to Supplement the Power Needs at McMurdo Station and Amundsen-Scott South Pole Station, Antarctica (Poster) (open access)

Analysis of the Use of Wind Energy to Supplement the Power Needs at McMurdo Station and Amundsen-Scott South Pole Station, Antarctica (Poster)

This poster summarizes the analysis of the inclusion of wind-driven power generation technology into the existing diesel power plants at two U.S. Antarctic research stations, McMurdo and Amundsen-Scott South Pole Station. Staff at the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) conducted the analysis. Available data were obtained on the wind resources, power plant conditions, load, and component cost. We then used NREL's Hybrid2 power system modeling software to analyze the potential and cost of using wind turbine generators at the two aforementioned facilities.
Date: May 1, 2005
Creator: Baring-Gould, E. I.; Robichaud, R. & McLain, K.
System: The UNT Digital Library
Angular dependence of the magnetization reversal in exchangebiased Fe/MnF2 (open access)

Angular dependence of the magnetization reversal in exchangebiased Fe/MnF2

A detailed study of exchange-biased Fe/MnF{sub 2} bilayers using magneto-optical Kerr Effect shows that the magnetization reversal occurs almost fully through domain wall nucleation and propagation for external fields parallel to the exchange bias direction. For finite angles {phi} between bias and external field the magnetization is aligned perpendicular to the field cooling direction for a limited field range for decreasing fields. For external fields perpendicular to the bias direction the magnetization aligns with the field cooling direction for descending and ascending fields before fully reversing. The field range for which the magnetization is close to perpendicular to the external field can be estimated using a simple effective field model.
Date: May 1, 2005
Creator: Arenholz, Elke & Liu, Kai
System: The UNT Digital Library
Anisotropic Shock Propagation in Single Crystals (open access)

Anisotropic Shock Propagation in Single Crystals

Most single-crystal shock experiments have been performed in high-symmetry directions while the nature of shock propagation in low-symmetry directions remains relatively unstudied. It is well known that small-amplitude, linear acoustic waves propagating in low-symmetry directions can focus and/or form caustics (Wolfe, 1995). In this report we provide evidence for similar focusing behavior in nonlinear (shock) waves propagating in single crystals of silicon and diamond. Using intense lasers, we have driven non-planar (divergent geometry) shock waves through single-crystals of silicon or diamond and into an isotropic backing plate. On recovery of the backing plates we observe a depression showing evidence of anisotropic plastic strain with well-defined crystallographic registration. We observe 4-, 2-, and 3-fold symmetric impressions for [100], [110], and [111] oriented crystals respectively.
Date: May 26, 2005
Creator: Eggert, J.; Hicks, D.; Celliers, P.; Bradley, D.; Cox, J.; Unites, W. et al.
System: The UNT Digital Library
Application of independent component analysis for beam diagnosis (open access)

Application of independent component analysis for beam diagnosis

The independent component analysis (ICA) is applied to analyze simultaneous multiple turn-by-turn beam position monitor (BPM) data of synchrotrons. The sampled data are decomposed to physically independent source signals, such as betatron motion, synchrotron motion and other perturbation sources. The decomposition is based on simultaneous diagonalization of several unequal time covariance matrices, unlike the model independent analysis (MIA), which uses equal-time covariance matrix only. Consequently the new method has advantage over MIA in isolating the independent modes and is more robust under the influence of contaminating signals of bad BPMs. The spatial pattern and temporal pattern of each resulting component (mode) can be used to identify and analyze the associated physical cause. Beam optics can be studied on the basis of the betatron modes. The method has been successfully applied to the Booster Synchrotron at Fermilab.
Date: May 1, 2005
Creator: Huang, X.; Lee, S. Y.; Prebys, Eric & Tomlin, Ray
System: The UNT Digital Library