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21-kW Thin-Film PV Technology Validation -- An NREL/Solar Energy Centre of India MOU Cooperative Project (open access)

21-kW Thin-Film PV Technology Validation -- An NREL/Solar Energy Centre of India MOU Cooperative Project

This paper summarizes findings during a one-week (27-31 October 2003) site visit to the Thin-Film Technology Test Bed at India's Solar Energy Centre (SEC) near New Delhi. The U.S. and Indian governments signed a Memorandum of Understanding in March 2000 to undertake a 50-50 cost-shared 21-kW thin-film PV technology validation project to evaluate the performance of thin-film photovoltaic (PV) modules under Indian climatic conditions. This project benefits Indian researchers by giving them experience with cost-effective PV materials, and it benefits the United States because data will be sent to the appropriate U.S. thin-film PV manufacturers for evaluation and analysis. During the visit, NREL personnel engaged in technical discussions regarding thin-film PV technologies with Ministry of Non-Conventional Energy Sources engineers and scientists. Issues included inspecting the newly constructed arrays, discussing better methods of electrically loading the PV arrays, taking I-V traces, and gathering baseline I-V data.
Date: January 1, 2005
Creator: McNutt, P. F. & Ullal, H. S.
System: The UNT Digital Library
2004 Sensory Transduction in Microorganisms Gordon Research Conference-January 11-16, 2004 (open access)

2004 Sensory Transduction in Microorganisms Gordon Research Conference-January 11-16, 2004

Research into the mechanisms involved in the sensing and responses of microorganisms to changes in their environment is currently very active in a large number of laboratories in the US, Europe, Japan, and Israel. A wide range of eukaryotic and prokaryotic species are being studies with regard to their sensing of chemical changes, light and redox signal and intercellular signaling, leading either to changes in motile behavior, gene expression or development. It has become increasingly apparent that the mechanisms involved in development have application in higher organisms while the sensing systems in bacteria are involved in a very wide range of physiological traits, from pathogenicity, through to biofilm formation. This is an area where a wide range of state of the art tools have been used and developed over the past few decades. Approaches include behavioral studies, electro-physiology, genetics, molecular biology, structural biology, biophysics and single molecule microscopy, immunocytochemistry and molecular and mathematical modeling, all of this helped by the large number of bacterial and eukaryotic microbial genome sequences now available. The central goal of this meeting is to bring together investigators using this wide range of approaches and different systems to compare data, share ideas and approaches and seeks …
Date: January 7, 2005
Creator: Storm, Judith Armitage Carlyle
System: The UNT Digital Library
3D Magnetotelluric characterization of the COSO GeothermalField (open access)

3D Magnetotelluric characterization of the COSO GeothermalField

Knowledge of the subsurface electrical resistivity/conductivity can contribute to a better understanding of complex hydrothermal systems, typified by Coso geothermal field, through mapping the geometry (bounds and controlling structures) over existing production. Three-dimensional magnetotelluric (MT) inversion is now an emerging technology for characterizing the resistivity structures of complex geothermal systems. The method appears to hold great promise, but histories exploiting truly 3D inversion that demonstrate the advantages that can be gained by acquiring and analyzing MT data in three dimensions are still few in number. This project will address said issue, by applying 3D MT forward modeling and inversion to a MT data set acquired over the Coso geothermal field. The goal of the project is to provide the capability to image large geothermal reservoirs in a single self-consistent model. Initial analysis of the Coso MT data has been carried out using 2D MT imaging technology to construct an initial 3D resistivity model from a series of 2D resistivity images obtained using the inline electric field measurements (Zxy impedance elements) along different measurement transects. This model will be subsequently refined through a 3D inversion process. The initial 3D resistivity model clearly shows the controlling geological structures possibly influencing well production …
Date: January 1, 2005
Creator: Newman, Gregory A.; Hoversten, Michael; Gasperikova, Erika & Wannamaker, Philip E.
System: The UNT Digital Library
469nm Fiber Laser Source (open access)

469nm Fiber Laser Source

We have demonstrated 466mW of 469nm light from a frequency doubled continuous wave fiber laser. The system consisted of a 938nm single frequency laser diode master oscillator, which was amplified in two stages to 5 Watts using cladding pumped Nd{sup 3+} fiber amplifiers and then frequency doubled in a single pass through periodically poled KTP. The 3cm long PPKTP crystal was made by Raicol Crystals Ltd. with a period of 5.9 {micro}m and had a phase match temperature of 47 degrees Centigrade. The beam was focused to a 1/e{sup 2} diameter in the crystal of 29 {micro}m. Overall conversion efficiency was 11% and the results agreed well with standard models. Our 938nm fiber amplifier design minimizes amplified spontaneous emission at 1088nm by employing an optimized core to cladding size ratio. This design allows the 3-level transition to operate at high inversion, thus making it competitive with the 1088nm 4-level transition. We have also carefully chosen the fiber coil diameter to help suppress propagation of wavelengths longer than 938 nm. At 2 Watts, the 938nm laser had an M{sup 2} of 1.1 and good polarization (correctable with a quarter and half wave plate to >10:1).
Date: January 20, 2005
Creator: Drobshoff, A; Dawson, J W; Pennington, D M; Payne, S A & Beach, R
System: The UNT Digital Library
Abundance of green tree frogs and insects in artificial canopy gaps in a bottomland hardwood forest. (open access)

Abundance of green tree frogs and insects in artificial canopy gaps in a bottomland hardwood forest.

Horn, Scott, James L. Hanula, Michael D. Ulyshen, and John C. Kilgo. 2005. Abundance of green tree frogs and insects in artificial canopy gaps in a bottomland hardwood forest. Am. Midl. Nat. 153:321-326. Abstract: We found more green tree frogs (Hyla cinerea) in canopy gaps than in closed canopy forest. Of the 331 green tree frogs observed, 88% were in canopy gaps. Likewise, higher numbers and biomasses of insects were captured in the open gap habitat. Flies were the most commonly collected insect group accounting for 54% of the total capture. These data suggest that one reason green tree frogs were more abundant in canopy gaps was the increased availability of prey and that small canopy gaps provide early successional habitats that are beneficial to green tree frog populations.
Date: January 1, 2005
Creator: Horn, Scott; Hanula, James L.; Ulyshen, Michael D. & Kilgo, John C.
System: The UNT Digital Library
Acoustic Monitor for Solids and Gas Measurements at Low Volume Fractions (open access)

Acoustic Monitor for Solids and Gas Measurements at Low Volume Fractions

This presentation was given at the DOE Office of Science-Environmental Management Science Program (EMSP) High-Level Waste Workshop held on January 19-20, 2005 at the Savannah River Site.
Date: January 19, 2005
Creator: Tavlarides, Lawrence L.
System: The UNT Digital Library
Activated type I TGFbeta receptor (Alk5) kinase confers enhancedsurvival to mammary epithelial cells and accelerates mammary tumorprogression (open access)

Activated type I TGFbeta receptor (Alk5) kinase confers enhancedsurvival to mammary epithelial cells and accelerates mammary tumorprogression

The transforming growth factor-betas (TGF{beta}s) are members of a large superfamily of pleiotropic cytokines that also includes the activins and the bone morphogenetic proteins (BMPs). Members of the TGF{beta} family regulate complex physiological processes such cell proliferation, differentiation, adhesion, cell-cell and cell-matrix interactions, motility, and cell death, among others (Massague, 1998). Dysregulation of TGF{beta} signaling contributes to several pathological processes including cancer, fibrosis, and auto-immune disorders (Massague et al., 2000). The TGF{beta}s elicit their biological effects by binding to type II and type I transmembrane receptor serine-threonine kinases (T{beta}RII and T{beta}RI) which, in turn, phosphorylated Smad 2 and Smad 3. Phosphorylated Smad 2/3 associate with Smad 4 and, as a heteromeric complex, translocate to the nucleus where they regulate gene transcription. The inhibitory Smad7 down regulates TGF{beta} signaling by binding to activated T{beta}RI and interfering with its ability to phosphorylate Smad 2/3 (Derynck and Zhang, 2003; Shi and Massague, 2003). Signaling is also regulated by Smad proteolysis. TGF{beta} receptor-mediated activation results in multi-ubiquitination of Smad 2 in the nucleus and subsequent degradation of Smad 2 by the proteasome (Lo and Massague, 1999). Activation of TGF{beta} receptors also induces mobilization of a Smad 7-Smurf complex from the nucleus to the cytoplasm; …
Date: January 2, 2005
Creator: Muraoka-Cook, Rebecca S.; Shin, Incheol; Yi, Jae Youn; Easterly,Evangeline; Barcellos-Hoff, Mary Helen; Yingling, Jonathan M. et al.
System: The UNT Digital Library
Adaptive mesh refinement in titanium (open access)

Adaptive mesh refinement in titanium

In this paper, we evaluate Titanium's usability as a high-level parallel programming language through a case study, where we implement a subset of Chombo's functionality in Titanium. Chombo is a software package applying the Adaptive Mesh Refinement methodology to numerical Partial Differential Equations at the production level. In Chombo, the library approach is used to parallel programming (C++ and Fortran, with MPI), whereas Titanium is a Java dialect designed for high-performance scientific computing. The performance of our implementation is studied and compared with that of Chombo in solving Poisson's equation based on two grid configurations from a real application. Also provided are the counts of lines of code from both sides.
Date: January 21, 2005
Creator: Colella, Phillip & Wen, Tong
System: The UNT Digital Library
Advanced Heat Transfer and Thermal Storage Fluids (open access)

Advanced Heat Transfer and Thermal Storage Fluids

The design of the next generation solar parabolic trough systems for power production will require the development of new thermal energy storage options with improved economics or operational characteristics. Current heat-transfer fluids such as VP-1?, which consists of a eutectic mixture of biphenyl and diphenyl oxide, allow a maximum operating temperature of ca. 300 C, a limit above which the vapor pressure would become too high and would require pressure-rated tanks. The use of VP-1? also suffers from a freezing point around 13 C that requires heating during cold periods. One of the goals for future trough systems is the use of heat-transfer fluids that can act as thermal storage media and that allow operating temperatures around 425 C combined with lower limits around 0 C. This paper presents an outline of our latest approach toward the development of such thermal storage fluids.
Date: January 1, 2005
Creator: Moens, L. & Blake, D.
System: The UNT Digital Library
Advanced Indoor Module Light-Soaking Facility (open access)

Advanced Indoor Module Light-Soaking Facility

An overview of the accelerated, indoor light-soaking test station is presented in this paper, along with data obtained for six modules that underwent exposure. The station comprises a climate-controlled chamber equipped with a solar simulator that allows 1-sun light intensity exposure. Concurrently, we monitor the electrical characteristics of multiple PV modules and exercise active control over their electrical bias using programmable electronic loads, interfaced to a data acquisition system that acquires power-tracking and current-voltage data. This capability allows us to the test different bias conditions and to cyclically alternate between them. Additionally, we can vary the light intensity and module temperatures to garner realistic temperature coefficients of module performance. Data obtained on cadmium telluride (CdTe) and amorphous silicon (a-Si) modules are presented.
Date: January 1, 2005
Creator: del Cueto, J. A.; Osterwald, C. & Pruett, J.
System: The UNT Digital Library
Advances in Solar Radiometry and Metrology (open access)

Advances in Solar Radiometry and Metrology

The Solar Radiometry and Metrology task at the National Renewable Energy Laboratory (NREL) provides traceable optical radiometric calibrations and measurements to photovoltaic (PV) researchers and the PV industry. Traceability of NREL solar radiometer calibrations to the World Radiometric Reference (WRR) was accomplished during the NREL Pyrheliometer Comparison in October 2003. The task has calibrated 10 spectral and more than 180 broadband radiometers for solar measurements. Other accomplishments include characterization of pyranometer thermal offset errors with laboratory and spectral modeling tools; developing a simple scheme to correct pyranometer data for known responsivity variations; and measuring detailed spectral distributions of the NREL High Intensity Pulsed Solar Simulator (HIPSS) as a function of lamp voltage and time. The optical metrology functions support the NREL Measurement and Characterization Task effort for ISO 17025 accreditation of NREL Solar Reference Cell Calibrations. Optical metrology functions have been integrated into the NREL quality system and audited for ISO17025 compliance.
Date: January 1, 2005
Creator: Myers, D.; Andreas, A.; Reda, I.; Gotseff, P.; Wilcox, S.; Stoffel, T. et al.
System: The UNT Digital Library
Advances in the In-House CdTe Research Activities at NREL (open access)

Advances in the In-House CdTe Research Activities at NREL

NREL in-house CdTe research activities have impacted a broad range of recent program priorities. Studies aimed at industrially relevant applications have produced new materials and processes that enhance the performance of devices based on commercial materials (e.g., soda-lime glass, SnO2:F). Preliminary tests of the effectiveness of these novel components using large-scale processes have been encouraging. Similarly, electro- and nano-probe techniques have been developed and used to study the evolution and function of CdTe grain boundaries. Finally, cathodoluminescence (CL) and photoluminescence (PL) studies on single-crystal samples have yielded improved understanding of how various processes may combine to produce important defects in CdTe films.
Date: January 1, 2005
Creator: Gessert, T.; Wu, X.; Dhere, R.; Moutinho, H.; Smith, S.; Romero, M. et al.
System: The UNT Digital Library
[After a Fashion, January 2005] (open access)

[After a Fashion, January 2005]

Article about the Golden Globe Awards, Erin Elmore, and the author's receipt of the Media Correspondent Award from Philanthropy World magazine.
Date: January 2005
Creator: Moser, Stephen MacMillan
System: The UNT Digital Library
Age validation of quillback rockfish (Sebastes maliger) using bomb radiocarbon (open access)

Age validation of quillback rockfish (Sebastes maliger) using bomb radiocarbon

Rockfishes (Sebastes spp.) support one of the most economically important fisheries of the Pacific Northwest and it is essential for sustainable management that age estimation procedures be validated for these species. Atmospheric testing of thermonuclear devices during the 1950s and 1960s created a global radiocarbon ({sup 14}C) signal in the ocean environment that scientists have identified as a useful tracer and chronological marker in natural systems. In this study, we first demonstrated that fewer samples are necessary for age validation using the bomb-generated {sup 14}C signal by emphasizing the utility of the time-specific marker created by the initial rise of bomb-{sup 14}C. Second, the bomb-generated {sup 14}C signal retained in fish otoliths was used to validate the age and age estimation methodology of the quillback rockfish (Sebastes maliger) in the waters of southeast Alaska. Radiocarbon values from the first year's growth of quillback rockfish otoliths were plotted against estimated birth year producing a {sup 14}C time series spanning 1950 to 1985. The initial rise of bomb-{sup 14}C from pre-bomb levels ({approx} -90 {per_thousand}) occurred in 1959 {+-} 1 year and {sup 14}C levels rose relatively rapidly to peak {Delta}{sup 14}C values in 1967 (+105.4 {per_thousand}), with a subsequent declining trend …
Date: January 5, 2005
Creator: Kerr, L A; Andrews, A H; Munk, K; Coale, K H; Frantz, B R; Cailliet, G M et al.
System: The UNT Digital Library
Analysis of eddy current distributions in the CMS magnet yoke during the solenoid discharge (open access)

Analysis of eddy current distributions in the CMS magnet yoke during the solenoid discharge

Flux loops have been installed on selected segments of the magnetic flux return yoke of the 4 T superconducting coil of the Compact Muon Solenoid (CMS) detector under construction at CERN. Voltages induced in the loops during discharge of the solenoid will be sampled on-line during the entire discharge and integrated off-line to provide a measurement of the initial magnetic flux density in steel at the maximum field to an accuracy of a few percent. Although the discharge of the solenoid is rather slow (190 s time constant), the influence of eddy currents induced in the yoke elements should be estimated. The calculation of eddy currents is performed with Vector Fields program ELEKTRA. The results of calculations are reported.
Date: January 1, 2005
Creator: Klyukhin, V. I.; Campi, D.; Cure, B.; Gaddi, A.; Gerwig, H.; Grillet, J. P. et al.
System: The UNT Digital Library
Analysis of the habitat of Henslow's sparrows and Grasshopper sparrows compared to random grassland areas (open access)

Analysis of the habitat of Henslow's sparrows and Grasshopper sparrows compared to random grassland areas

Henslow's Sparrows are endangered prairie birds, and Grasshopper Sparrows are considered rare prairie birds. Both of these birds were abundant in Illinois, but their populations have been declining due to loss of the grasslands. This begins an ongoing study of the birds habitat so Fermilab can develop a land management plan for the Henslow's and Grasshoppers. The Henslow's were found at ten sites and Grasshoppers at eight sites. Once the birds were located, the vegetation at their sites was studied. Measurements of the maximum plant height, average plant height, and duff height were taken and estimates of the percent of grass, forbs, duff, and bare ground were recorded for each square meter studied. The same measurements were taken at ten random grassland sites on Fermilab property. Several t-tests were performed on the data, and it was found that both Henslow's Sparrows and Grasshopper Sparrows preferred areas with a larger percentage of grass than random areas. Henslow's also preferred areas with less bare ground than random areas, while Grasshoppers preferred areas with more bare ground than random areas. In addition, Grasshopper Sparrows preferred a lower percentage of forbs than was found in random areas and a shorter average plant height than …
Date: January 1, 2005
Creator: Maier, Kristen; Walton, Rod & Kasper, Peter
System: The UNT Digital Library
Analytical Methodologies for Detection of Gamma-Valerolactone, Delta-Valerolactone, Acephate and Azinphos Methyl and Their Associated Metabolites in Complex Biological Matrices (open access)

Analytical Methodologies for Detection of Gamma-Valerolactone, Delta-Valerolactone, Acephate and Azinphos Methyl and Their Associated Metabolites in Complex Biological Matrices

Non-invasive biomonitoring for chemicals of interest in law enforcement and similar monitoring of pesticides, together with their metabolites, can not only save money but can lead to faster medical attention for individuals exposed to these chemicals. This study describes methods developed for the analysis of gamma-valerolactone (GVL), delta-valerolactone (DVL), acephate, and azinphos methyl in saliva and serum. Liquid chromatography/mass spectrometry (LC/MS) operated in the negative and positive ion mode and gas chromatography/mass spectrometry (GC/MS) were used to analyze GVL and DVL. Although both analytical techniques worked well, lower detection limits were obtained with GC/MS. The lactones and their corresponding sodium salts were spiked into both saliva and serum. The lactones were isolated from saliva or serum using newly developed extraction techniques and then subsequently analyzed using GC/MS. The sodium salts of the lactones are nonvolatile and require derivatization prior to analysis by this method. N-methyl-N-(t-butyldimethylsilyl)-trifluoroacetamide (MTBSTFA) was ultimately selected as the reagent for derivatization because the acidic conditions required for reactions with diazomethane caused the salts to undergo intramolecular cyclization to the corresponding lactones. In vitro studies were conducted using rat liver microsomes to determine other metabolites associated with these compounds. Azinphos methyl and acephate are classified as organophosphate pesticides, …
Date: January 1, 2005
Creator: Zink, Erica; Clark, Ryan; Grant, Karen; Campbell, James & Hoppe, Erik
System: The UNT Digital Library
Application of Combinatorial Tools for Solar Cell Improvement -- New High Performance Transparent Conducting Oxides (open access)

Application of Combinatorial Tools for Solar Cell Improvement -- New High Performance Transparent Conducting Oxides

Transparent conducting oxides (TCOs) can serve a variety of important functions in thin film photovoltaics such as transparent electrical contacts, antireflection coatings and chemical barriers. Two areas of particular interest are TCOs that can be deposited at low temperatures and TCOs with high carrier mobilities. We have employed combinatorial high-throughput approaches to investigate both these areas. Conductivities of s = 2500 W-1-cm-1 have been obtained for In-Zn-O (IZO) films deposited at 100 C and s > 5000 W-1-cm-1 for In-Ti-O (ITiO) and In-Mo-O (IMO) films deposited at 550 C. The highest mobility obtained was 83 cm2/V-sec for ITiO deposited at 550 C.
Date: January 1, 2005
Creator: Perkins, J.; Taylor, M.; van Hest, M.; Teplin, C.; Alleman, J.; Dabney, M. et al.
System: The UNT Digital Library
Application of deuteron-deuteron (d-d) fusion neutrons to 40ar/39/ar geochronology (open access)

Application of deuteron-deuteron (d-d) fusion neutrons to 40ar/39/ar geochronology

This report talks about Application of deuteron-deuteron (d-d) fusion neutrons to 40ar/39/ar geochronology
Date: January 1, 2005
Creator: Renne, P.; Knight, K. B.; Nomade, S.; Leung, K. N. & Lou, T. P.
System: The UNT Digital Library
Application of independent component analysis to Fermilab Booster (open access)

Application of independent component analysis to Fermilab Booster

Autocorrelation is applied to analyze sets of finite-sampling data such as the turn-by-turn beam position monitor (BPM) data in an accelerator. This method of data analysis, called the independent component analysis (ICA), is shown to be a powerful beam diagnosis tool for being able to decompose sampled signals into its underlying source signals. They find that the ICA has an advantage over the principle component analysis (PCA) used in the model-independent analysis (MIA) in isolating independent modes. The tolerance of the ICA method to noise in the BPM system is systematically studied. The ICA is applied to analyze the complicated beam motion in a rapid-cycling booster synchrotron at the Fermilab. Difficulties and limitations of the ICA method are also discussed.
Date: January 1, 2005
Creator: Huang, X. B.; Lee, S. Y.; Prebys, E. & Tomlin, R.
System: The UNT Digital Library
Applications of mineral carbonation to geological sequestration of CO2 (open access)

Applications of mineral carbonation to geological sequestration of CO2

Geological sequestration of CO2 is a promising near-term sequestration methodology. However, migration of the CO2 beyond the natural reservoir seals could become problematic, thus the identification of means to enhance the natural seals could prove beneficial. Injection of a mineral reactant slurry could provide a means to enhance the natural reservoir seals by supplying the necessary cations for precipitation of mineral carbonates. The subject study evaluates the merit of several mineral slurry injection strategies by conduct of a series of laboratory-scale CO2 flood tests on whole core samples of the Mt. Simon sandstone from the Illinois Basin.
Date: January 1, 2005
Creator: O'Connor, William K. & Rush, G.E.
System: The UNT Digital Library
Applying Current Human Factors Engineering Guidance to Control Room Design (open access)

Applying Current Human Factors Engineering Guidance to Control Room Design

The Westinghouse Savannah River Company, a contractor to the Department of Energy, has compared Revisions 1 and 2 of NUREG-0700-Human System Interface Design Review Guideline, from the United States Nuclear Regulatory Commission Nuclear Regulatory Guide. The comparison has been made with respect to which guidelines remained the same, the guidelines that were reformatted or reworded, additional guidelines, and deleted guidelines. This comparison was made in preparation of revising the previously developed Human Factors Engineering Analysis Tool for automating the review, analysis, and evaluation of human system interface designs. This tool has been described at previous conferences on human factors and the merits and benefits of the tool described. The tool has been successfully applied to over eight facilities at WSRC. This paper describes the methodology and results of the comparison and the plans to enhance the already successful automation tool. The number of criteria in NUREG-0700 increased from approximately 1650 in Revision 1 to almost 2200 in Revision 2. Approximately 1600 criteria remained the same, though they were significantly reorganized; while about 100 were reworded or reformatted to clarify or expand the guidance provided. Around 600 guidelines were added and approximately 70 deleted. The majority of the changes and additions …
Date: January 31, 2005
Creator: Leo, Geary
System: The UNT Digital Library
Arc Flash Boundary Calculations Using Computer Software Tools (open access)

Arc Flash Boundary Calculations Using Computer Software Tools

Arc Flash Protection boundary calculations have become easier to perform with the availability of personal computer software. These programs incorporate arc flash protection boundary formulas for different voltage and current levels, calculate the bolted fault current at each bus, and use built in time-current coordination curves to determine the clearing time of protective devices in the system. Results of the arc flash protection boundary calculations can be presented in several different forms--as an annotation to the one-line diagram, as a table of arc flash protection boundary distances, and as printed placards to be attached to the appropriate equipment. Basic arc flash protection boundary principles are presented in this paper along with several helpful suggestions for performing arc flash protection boundary calculations.
Date: January 7, 2005
Creator: Gibbs, M. D.
System: The UNT Digital Library
Arsenic Sulfide Nanowire Formation on Fused Quartz Surfaces (open access)

Arsenic Sulfide Nanowire Formation on Fused Quartz Surfaces

Arsenic sulfide (AsxSy) nanowires were synthesized by an evaporation-condensation process in evacuated fused quartz ampoules. During the deposition process, a thin, colored film of AsxSy was deposited along the upper, cooler portion of the ampoule. The ampoule was sectioned and the deposited film analyzed using scanning electron microscopy (SEM) to characterize and semi-quantitatively evaluate the microstructural features of the deposited film. A variety of microstructures were observed that ranged from a continuous thin film (warmer portion of the ampoule), to isolated micron- and nano-scale droplets (in the intermediate portion), as well as nanowires (colder portion of the ampoule). Experiments were conducted to evaluate the effects of ampoule cleaning methods (e.g. modify surface chemistry) and quantity of source material on nanowire formation. The evolution of these microstructures in the thin film was determined to be a function of initial pressure, substrate temperature, substrate surface treatment, and initial volume of As2S3 glass. In a set of two experiments where the initial pressure, substrate thermal gradient, and surface treatment were the same, the initial quantity of As2S3 glass per internal ampoule volume was doubled from one test to the other. The results showed that AsxSy nanowires were only formed in the test with …
Date: January 1, 2005
Creator: Olmstead, J.; Riley, B. J.; Johnson, B. R. & Sundaram, S. K.
System: The UNT Digital Library