This paper describes the operational experience in drying brines generated at a radioactive wastewater treatment facility. The brines are composed of aqueous ammonium sulfate/sodium sulfate and aqueous sodium nitrate/sodium sulfate, The brine feeds receive pretreatment to preclude dryer bridging and fouling. The dryer products are a distillate and a powder. The dryer is a vertical thin film type consisting of a steam heated cylinder with rotor. Maintenance on the dryer has been minimal. Although many operability problems have had to be overcome, dryer performance can now be said to be highly reliable.

The built-in electric field in polycrystalline CuInSe{sub 2} (CIS) near gold co-planar contacts was quantitatively revealed for the first time by the photomixing technique. A He-Ne laser beam was focused locally on the CIS sample near one of its contact. While both dc dark and photo-currents showed ohmic behavior, the high frequency ac current was non-zero for zero applied dc bias, which reveals a built-in electric field of {approx}1000V/cm. The capability of the photomixing technique to probe local charge transport properties is expected to be very useful for, e.g., the quantitative evaluation of the quality of ohmic contacts and the investigation of electric field induced p-n junction formation in CIS and related materials.

The growth of Cu Layers deposited on Ru(0001) substrates at temperatures between 500 K and 850 K was studied using surface x-ray diffraction. Results are consistent with a Stransky-Krastanov growth mode with a two layer critical thickness.

Secondary Neutral Mass Spectrometry using resonant laser ionization can provide for both high useful yields and high discrimination while maintaining high lateral and depth resolutions. An example of the power of the method is measurement of the isotopic composition of Mo and Zr in 1-5 {micro}m presolar SiC and graphite grains isolated from the Murchison CM2 meteorite for the first time. These grains have survived the formation of the Solar System and isotopic analysis reveals a record of the stellar nucleosynthesis present during their formation. Mo and Zr, though present at less than 10 ppm in some grains, are particularly useful in that among their isotopes are members that can only be formed by distinct nucleosynthetic processes known as s-, p-, and r-process. Successful isotopic analysis of these elements requires both high selectivity (since these are trace elements) and high efficiency (since the total number of atoms available are limited). Resonant Ionization Spectroscopy is particularly useful and flexible in this application. While the sensitivity of this t.edmique has often been reported in the past, we focus hereon the very low noise properties of the technique. We further demonstrate the efficacy of noise removal by two complimentary methods. First we use …

A brief historical perspective covering the most mature chemically-based metal ion separation methods is presented, as is a summary of the recommendations made in the 1987 National Research Council (NRC) report entitled ''Separation and Purification: Critical Needs and Opportunities''. A review of Progress in Metal Ion Separation and Preconcentration shows that advances are occurring in each area of need cited by the NRC. Following an explanation of the objectives and general organization of this book, the contents of each chapter are briefly summarized and some future research opportunities in metal ion separations are presented.

None

The goal of the U.S. Department of Energy (DOE) Wind Energy Program's wind resource assessment group located at the National Renewable Energy Laboratory (NREL) in Golden, Colorado, is to improve the characterization of the wind resource in many regions of the world in support of the U.S. wind energy industry. NREL characterizes the level of the available wind resource at wind turbine hub heights (typically 30 m to 50 m above ground level) using wind power density, expressed in units of Watts per square meter. Wind power density values are frequently used to classify the wind resource level with the higher wind power classes assigned to areas with high power density values. NREL has developed a wind assessment methodology to produce wind resource maps useful for wind prospecting and wind energy project implementation. The methodology integrates information from global climatic data sets and also involves a critical meteorologic analysis of the climatic data. It is in the context of the critical meteorological analysis and the automated mapping system that we plan to evaluate the usefulness of Reanalysis data for wind assessment purposes.

Grain growth experiments and simulations exhibit self-similar grain size distributions quite different from that derived via a mean field approach by Hillert [ 1]. To test whether this discrepancy is due to insufficient anneal times, two different two-dimensional grain structures with realistic topologies and Hillert grain size distributions are generated and subjected to grain growth via the Monte Carlo Potts Model (MCPM). In both cases, the observed self-similar grain size distributions deviate from the initial Hillert form and conform instead to that observed in MCPM grain growth simulations that start from a random microstructure. This suggests that the Hillert grain size distribution is not an attractor.

Uranium alloys are candidates for the fuel phase in aluminum matrix dispersion fuels requiring high uranium loading. Certain uranium alloys have been shown to have good irradiation performance at intermediate burnup. Previous studies have shown that acceptable fission gas swelling behavior and fuel-aluminum interaction is possible only if the fuel alloy can be maintained in the high temperature body-centered-cubic {gamma}-phase during fabrication and irradiation, i.e., at temperatures at which {alpha}-U is the equilibrium phase. Transition metals in Groups V through VIII are known to allow metastable retention of the gamma phase below the equilibrium isotherm. These metals have varying degrees of effectiveness in stabilizing the gamma phase. Certain alloys are metastable for very long times at the relatively low fuel temperatures seen in research reactor operation. In this paper, the existing data on the gamma stability of binary and ternary uranium alloys is analyzed. The mechanism and kinetics of decomposition of the gamma phase are assessed with the help of metal alloy theory. Alloys with the highest possible uranium content, good gamma-phase stability, and good neutronic performance are identified for further metallurgical studies and irradiation tests. Results from theory will be compared with experimentally generated data.

It is sometimes necessary to deploy, transport and store weapons containing high explosives (HE) in proximity. Accident analyses of these activities may include nearby explosion scenarios in which fragments from an exploding (donor) weapon impact a second (acceptor) weapon. Weapon arrays are designed to miti- gate consequences to potential acceptor weapons, but unless initiation of an accep- tor's HE is impossible, outcomes such as detonation must be considered. This paper describes an approach for estimating upper bound probabilities for fragment- dominated scenarios in which outcomes are expected to be rare events. Other aspectsl,z of nearby explosion problems were addressed previously. An example scenario is as follows. A donor weapon is postulated to detonate, and fragments of the donor weapon casing are accelerated outward. Some of the fragments may strike a nearby acceptor weapon whose HE is protected by casing materials. Most impacts are not capable of initiating the acceptor's HE. However, a sufficiently large and fast fragment could produce a shock-to-detonation transi- tion (SDT), which will result in detonation of the acceptor. Our approach will work for other outcomes of fragment impact, but this discussion focuses on detonation. Experiments show that detonating weapons typically produce a distribution of casing fragment …

This paper describes the progress achieved by the Reduced Enrichment for Research and Test Reactors (RERTR) Program in collaboration with its many international partners since its inception in 1978. A brief summary of the results that the program had attained by the end of 1997 is followed by a detailed review of the major events, findings, and activities that took place in 1998. The past year was characterized by exceptionally important accomplishments and events for the RERTR program. Four additional shipments of spent fuel from foreign research reactors were accepted by the U.S. Altogether, 2,231 spent fuel assemblies from foreign research reactors have been received by the U.S. under the acceptance policy. Fuel development activities began to yield solid results. Irradiations of the first two batches of microplates were completed. Preliminary postirradiation examinations of these microplates indicate excellent irradiation behavior of some of the fuel materials that were tested. These materials hold the promise of achieving the pro am goal of developing LEU research reactor fuels with uranium density in the 8-9 g /cm{sup 3} range. Progress was made in the Russian RERTR program, which aims to develop and demonstrate the technical means needed to convert Russian-supplied research reactors to …

We have developed and are continuing to refine semi-automated technology for the detection and inspection of surface and bulk defects and damage in large laser optics Different manifestations of the DAMOCLES system (Damage and Artifact Mapping Of Coherent-Laser-Exposed Substrates) provide an effective and economical means of being able to detect, map and characterize surface and bulk defects which may become precursors of massive damage in optics when subjected to high-fluence laser irradiation Subsequent morphology and evolution of damage due to laser irradiation can be tracked efficiently The strength of the Damocles system is that it allows for immediate visual observation of defects in an entire optic, which can range up to l-meter dimensions, while also being able to provide digital map and magnified images of the defects with resolutions better than 5 µm.

Treatment of [Fe(OEP)]20 with trichloroacetic acid results in ruffled formation of (octaethylporphinato trichloroacetato)iron(HI). Various crystalline solvates can be isolated, depending on the crystallization solvent. Initial crystallization with CHC13/hexanes resulted in the isolation of an unsolvated form. [Fe(OEP)(02C2C13 )]. This form contains distinct porphyrin core conformations at the same site: one is domed and the other is ruffled. Crystal data for [Fe(OEP)(02C2C13 )]: Q = 14.734(4) .4. b = 13.674(1) .\. c = 17..541 [,.5] .~. 3 = 90.67(1)0, V = 35-!5.8(14) .\3. monoclinic. space group R1/ n. Z = 4. Subsequent crystallization with CHC13/hexanes resulted in a new crystalline form, [Fe(OEP)(OzC2C13 )~.- CHC13; the porphyrin core is slightly ruffled. Crystal data for [Fe(OEP)(OoC2C13 )]. CHC13: a =12.323(1) .~, 6 = 13.062(3) .\. C = 14.327(2) .$, Q = 89.32(1)", .3 = 113.36(2)0. :~ = 105.26(1)'. V = `2031.3(6) .\3. triclinic. space group Pi. Z = 2. Crystallization with CH2C12/hexanes resulted in the isolation of yet another form, [Fe(OEP) (02 C2C13)]. H02C2C13. which contains two independent molecules in the unit cell: molecule is slightly saddled and molecule B is modestly ruffled. Crystal data for [Fe(OEP)(02ClC13 )]. H02C2C13: a = 13.148(3) .\, b = 13.45.5(3) A, c = Q3.761(5) -& ~ = …

The Advanced Photon Source (APS) linac beam position monitors can be used to monitor the position of a positron beam also containing electrons. To accomplish this task, both the signal at the bunching frequency of 2856 MHz and the signal at 2 x 2856 MHz are acquired and processed for each stripline. The positron beam position is obtained by forming a linear combination of both 2856- and 5712-MHz signals for each stripline and then performing the standard difference over sum computation. The required linear combination of the 2856- and 5712-MHz signals depends on the electrical calibration of each stripline/cable combination. In this paper, the calibration constants for both 2856-MHz and 5712-MHz signals for each stripline are determined using a pure beam of electrons. The calibration constants are obtained by measuring the 2856- and 5712-MHz stripline signals at various electron beam currents and positions. Finally, the calibration constants measured using electrons are used to determine positron beam position for the mixed beam case.

This presentation covers the strategy and analysis of an experiment to characterize a gas tungsten arc welding process. The experiment combined four uncontrolled noise factors and four controlled process parameters. A nontraditional response surface design was employed. Multiple responses were modeled. Optimal settings for the process parameters to successfully weld the widest range of the pertinent product features were identified. Thus, the process was made ''robust'' against ''noise'' factors. Comparisons are made between the experimental and analytical approach taken versus the Taguchi style of experimentation and analysis. This comparison is mainly done with respect to the information gained, such as product design criteria, incoming material specifications, and process adjustments for nonconforming material.

Article discussing structural dichotomy in six-coordinate d⁰ complexes and trigonal prismatic (ᵗBu₃SiC≡C)₆Ta⁻ and octahedral (ᵗBu₃SiC≡C)₆M²⁻ (M ≡ Zr, Hf).

A new design for a single junction, thin film Si solar cell is presented. The cell design is compatible with low-temperature processing required for the use of a low-cost glass substrate, and includes effective light trapping and impurity gettering. Elements of essential process steps are discussed.

In 1993 the U.S. Environmental Protection Agency (EPA) introduced ENERGY STAR (registered trademark), a voluntary labeling program designed to identify and promote energy-efficient products. Since then EPA, now in partnership with the U.S. Department of Energy (DOE), has introduced programs for more than twenty products, spanning office equipment, residential heating and cooling equipment, new homes, commercial and residential lighting, home electronics, and major appliances. We present potential energy, dollar and carbon savings forecasts for these programs for the period 1998 to 2010. Our target market penetration case represents our best estimate of future ENERGY STAR savings. It is based on realistic market penetration goals for each of the products. We also provide results under the assumption of 100% market penetration; that is, we assume that all purchasers buy ENERGY STAR-compliant products instead of standard efficiency products throughout the analysis period. Finally, we assess the sensitivity of our target penetration case forecasts to greater or lesser marketing success by EPA and DOE, lower-than-expected future energy prices, and higher or lower rates of carbon emission by electricity generators. The potential savings of ENERGY STAR are substantial. If all purchasers chose Energy Star-compliant products instead of standard efficiency products over the next 15 …

In order to prevent activation of the beam pipe walls and components of a high power ion accelera- tor: beam loss must be minimized. Here we present self-consistent, 3D particle-in-cell simulations of longi- tudinally mismatched beams including the effects of rf non-linearities using parameters based on the Acceler- ator Production of Tritium linac design. In particular, we explore the evolution of the longitudinal halo distri- bution, i.e., the distribution of particles in longitudinal phase space with oscillation amplitudes significantly larger than amplitudes of particles in the main body or ''core'' of the beam. When a particle reaches a suf- ficiently large amplitude longitudinally it can he lost from the rf bucket and consequently loses synchro- nism with thr rf wave. Such particles will lose energy and so be poorly matched to the transverse focusing field and consequently can be lost transversely. We compare the present simulations in which all particles contribute self-consistently to the self-field to predic- tions of a core/test particle model in which the core distribution has uniformly distributed charge and does not evolve self-consistently. Effects of self-consistent, non-linear space-charge forces, non-linear rf focusing on envelope mismatch induced beam halo are explored through comparisons of both models.

The engineering team of the National Ignition Facility (NIF) has developed a highly optimized hardware design that satisfies stringent cost, performance and schedule requirements. After a 3-year effort, the design will culminate at the end of FY98 with the completion of major Title II design reviews. Every element of the facility from optic configuration, facility layout and hardware specifications to material selection, fabrication techniques and part tolerancing has been examined to assure the minimum cost per joule of laser energy delivered on target. In this paper, the design of the major subsystems will be discussed from the perspective of this optimization emphasis. Focus will be placed on the special equipment hardware which includes laser, beam transport, opto-mechanical , system control and target area systems. Some of the unique features in each of these areas will be discussed to highlight how significant cost savings have been achieved while maintaining reasonable and acceptable performance risk. Key to the success has also been a vigorous development program that commenced nearly 4 years ago and has been highly responsive to the specific needs of the NIF project. Supporting analyses and prototyping work that evolved from these parallel activities will also be discussed.

Business needs have driven the development of commercial database systems since their inception. As a result, there has been a strong focus on supporting many users, minimizing the potential corruption or loss of data, and maximizing performance metrics like transactions per second, or TPC-C and TPC-D results. It turns out that these optimizations have little to do with the needs of the scientific community, and in particular have little impact on improving the management and use of large-scale high-dimensional data. At the same time, there is an unanswered need in the scientific community for many of the benefits offered by a robust DBMS. For example, tying an ad-hoc query language such as SQL together with a visualization toolkit would be a powerful enhancement to current capabilities. Unfortunately, there has been little emphasis or discussion in the VLDB community on this mismatch over the last decade. The goal of the paper is to identify the specific issues that need to be resolved before large-scale scientific applications can make use of DBMS products. This topic is addressed in the context of an evaluation of commercial DBMS technology applied to the exploration of data generated by the Department of Energy`s Accelerated Strategic Computing …

Recently both the Alcator C-Mod and DIII-D tokamaks observed significant recombination of major ion species in the divertor region during detachment. For sufficiently low temperatures the mixture of neutral atoms and ions can be optically thick to line radiation. The optical depth of the recombined region to Ly{alpha} radiation can be very large and opacity effects and radiation trapping can dramatically change the heat flux to the divertor walls. This paper presents an analysis of the effect of line radiation on volume recombination using CRETIN, a multi-dimensional, non-local thermodynamic equilibrium simulation code that includes the atomic kinetics and radiative transport processes necessary to model this complex environment.

Junction formation in CuInSe2 (CIS) has been studied by exposing thin films and single-crystal samples to solutions containing NH4OH and CdSO4. The treated samples were analyzed by secondary ion mass spectrometry to determine the amount and distribution of Cd deposited on the surface of the films. Cadmium is found to react with the surface for all the solution exposure times and temperatures studied. The reaction rapidly approaches the endpoint and remains relatively unchanged for subsequent solution exposure. Cadmium in-diffusion, as measured by secondary ion mass spectrometry, is obscured by topography effects in the thin-film samples and by ion-beam mixing and topography in the single-crystal sample.

The importance of the parallel flow of primary and impurity ions in the Scrape-Off layer (SOL) of divertor tokamaks has been recognized recently. Impurity accumulation on the closed flux surfaces is determined in part by their parallel flow in the SOL. In turn, the parallel transport of the impurity ions is determined in part by drag from the primary ion flow. Measurement of flow in the DIII-D tokamak has begun recently. We describe initial results of modeling plasma ion flow using the 2-D code UEDGE in this paper. We assume the impurity (carbon) arises from chemical and physical sputtering from the walls surrounding the DIII-D plasma. We include six charge states of carbon in our simulations. We make detailed compaison with a multitude of SOL plasma diagnostics, including the flow measurement, to verify the UEDGE physics model. We begin the paper with a brief description of the plasma and neutral models in the UEDGE code in Section 2. We then present initial results of flow simulations and compare them with experimental measurement in Section 3. We conclude with a discussion of the dominant physics processes identified in the modeling in Section 4.