In this article, the relative stability of different high-pressure phases of various cesium halides is studied from first principles and analyzed using the Landau theory of phase transitions.

Employing a previously developed formalism 1, we have performed ground-state and melting calculations of the expected crystalline beams in ion storage rings ASTRID and TSR.

We explore the feasibility of resurrecting the apparent magnitude-redshift relation for a 'standard candle' to measure the cosmological constant and mass density. We show that type Ia supernovae, if measured with 0.15 mag uncertainty out to a redshift of z = 1, may provide a good standard candle or calibrated candle for this purpose. The recent discovery of probable type Ia supernovae in the redshift range z = 0.3 to 0.5 (Perlmutter et al. 1994a, and 1994b) indicates that the flux of optical photons from these events can be measured this accurately. The 7 distant supernovae discovered to date do not by themselves distinguish between different cosmological models, however the further discovery of about 50 type Ia supernovae at redshifts in the range 0.5 < z {approx} 1.0 could strongly constrain the allowed range of these parameters. We estimate that the follow-up photometry necessary for this measurement would be on the order of 20 - 70 hours of time on a lO-meter class telescope at a site with good seeing.

Three volatile nitrogen-containing compounds, 3-ethenylpyridine (3-EP), pyridine and pyrrole, were investigated as potential tracers for determining the contribution of environmental tobacco smoke (ETS) to concentrations of volatile organic compounds (VOCs) in indoor environments with smoking. The source emission rates of the three tracers and ten selected VOCs in ETS were first measured in a room-size environmental chamber for a market-weighted selection of six commercial cigarettes. The ratios of the emission rates of the tracers to the emission rates of the selected VOCs were calculated and compared among the six brands. The utility of the tracers was then evaluated in a field study conducted in five office buildings. Samples for VOCs were collected in designated smoking areas and adjoining non-smoking areas, air change rates were measured, and smoking rates were documented. Concentrations of the three tracers in the smoking areas were calculated using a mass-balance model and compared to their measured concentrations. Based on this comparison, 3-EP was selected as the most suitable tracer for the volatile components of ETS, although pyrrole is also potentially useful. Using 3-EP as the tracer, the contributions of ETS to the measured concentrations of the selected VOCs in the smoking areas were estimated by apportionment. …

Photometric measurements show that, as a group, nearby Type Ia supernovae follow similar light curves and reach similar peak magnitudes (Branch & Tammann 1992). Thus, these supernovae may serve as standard candles or calibrated candles at cosmological distances. Magnitudes of local and distant supernovae, both in the same filter band, are compared using a K correction to account for the different spectral regions incident on that filter. A generalized approach compares magnitudes in different bands for the nearby and distant supernovae, bands that are selected to give sensitivity in corresponding regions of the unredshifted and redshifted spectra. Thus, R magnitudes for supernovae at z {approx} 0.5 are compared with B magnitudes of local supernovae. We compute these generalized K corrections over a range of redshifts and bandpass pairs and discuss their advantages over the traditional single-band K correction. In particular, errors near maximum light can be kept below 0.05 mag out to at least z = 0.6, whereas the traditional K correction is less accurate and can be difficult to determine beyond z > 0.2.

Our search for high-redshift Type Ia supernovae discovered, in its first years, a sample of seven supernovae. Using a 'batch' search strategy, almost all were discovered before maximum light and were observed over the peak of their light curves. The spectra and light curves indicate that almost all were Type Ia supernovae at redshifts z = 0.35 - 0.5. These high-redshift supernovae can provide a distance indicator and 'standard clock' to study the cosmological parameters q{sub 0}, {Lambda}, {Omega}{sub 0}, and H{sub 0}. This presentation and the following presentations of Kim et al. (1996), Goldhaber et al. (1996), and Pain et al. (1996) will discuss observation strategies and rates, analysis and calibration issues, the sources of measurement uncertainty, and the cosmological implications, including bounds on q{sub 0}, of these first high-redshift supernovae from our ongoing search.

We are designing an experiment to study physics, engineering, and costing issues of an extended Relativistic Klystron Two-Beam Accelerator (RK-TBA). The experiment is a prototype for an RK-TBA based microwave power source suitable for driving a 1 TeV linear collider. Major components of the experiment include a 2.5-MV, 1.5-kA electron source, a 11.4-GHz modulator, a bunch compressor, and a 8-m extraction section. The extraction section will be comprised of 4 traveling-wave output structures, each generating about 360 MW of rf power. Induction cells will be used in the extraction section to maintain the average beam energy at 5 MeV. Status of the design is presented.

With the advent of more sophisticated techniques for control of tokamak plasmas comes the requirement for increasingly more accurate models of plasma processes and tokamak systems. Development of accurate models for DIII-D power systems, vessel, and poloidal coils is already complete, while work continues in development of general plasma response modeling techniques. Increased accuracy in estimates of parameters to be controlled is also required. It is important to ensure that errors in supporting systems such as diagnostic and command circuits do not limit the accuracy of plasma parameter estimates or inhibit the ability to derive accurate plasma/tokamak system models. To address this issue, we have developed more formal power systems change control and power system/magnetic diagnostics calibration procedures. This paper discusses our approach to consolidating the tasks in these closely related areas. This includes, for example, defining criteria for when diagnostics should be re-calibrated along with required calibration tolerances, and implementing methods for tracking power systems hardware modifications and the resultant changes to control models.

A nonequilibrium continuum mixture model has been incorporated into the CTH shock physics code to describe deflagration-to-detonation transition in granular energetic materials. This approach treats multiple thermodynamic and mechanics fields including the effects of relative material motion, rate-dependent compaction and interphase exchange of mass, momentum and energy. A finite volume description is formulated and internal state variables are solved using an operator-splitting method. Numerical simulations of low-velocity impact on a weakly-confined porous propellant bed are presented which display lateral wall release leading to curved compaction and reaction wave behavior.

Thin platinum films were deposited at several different deposition rates and with varying thickness on (001)-cut MgO single crystal substrates by electron beam evaporation. A mixture of two epitaxial Pt orientations were detected in the films by X-ray diffraction and planar ion channeling experiments: (001)[100]Pt // (001)[100]MgO (the [open quotes]cube-on-cube[close quotes] orientation) and (111)[110]Pt // (001)[110]MgO. The effect of deposition rate on film orientation indicated the (111)Pt orientation was preferred under conditions of high driving force for nucleation. The volume fraction of the films occupied by the (111) orientation increased with nominal film thickness, at a constant substrate temperature and deposition rate. This result indicates crystallites having the (111)Pt orientation grew more quickly following nucleation than the (001). The mosaic spread of the Pt orientation decreased markedly as the nominal film thickness increased from [approximately] 1.5 nm (isolated islands) to 20 nm (continuous film).

Both the Intelligent Transportation Systems (ITS) and National Information Infrastructure (NU) efforts have ambitious goals that are expected to improve the fundamental infrastructure, commerce, and society of the United States. Achieving these goals will require rapid development and deployment of information compatibility methods through technical and institutional standards. These standards will have to be scaleable and flexible to support new, and as-yet-undiscovered, data. Yet they will also need to accommodate our valuable data reserves. The area of geospatial data, and thus the creation of a National Spatial Data Infrastructure (NSDI), is particularly challenging due to the profoundly different forms, evolutionary histories, and meanings attached to spatial data. We discuss technical issues resulting from the different natures and inaccuracy of existing geodata, and areas where federal policy could lead the way to greater compatibility.

We show how non-instantaneous nonlinearities can be used to characterize an ultrashort pulse in an extension of the Frequency-Resolved Optical Gating technique. We demonstrate this principle using the Raman effect in fused silica.

Silicon solar cell efficiencies of 17.1%, 16.4%, 14.8%, and 14.9% have been achieved on FZ, Cz, multicrystalline (mc-Si), and dendritic web (DW) silicon, respectively, using simplified, cost-effective rapid thermal processing (RTP). These represent the highest reported efficiencies for solar cells processed with simultaneous front and back diffusion with no conventional high-temperature furnace steps. Appropriate diffusion temperature coupled with the added in-situ anneal resulted in suitable minority-carrier lifetime and diffusion profiles for high-efficiency cells. The cooling rate associated with the in-situ anneal can improve the lifetime and lower the reverse saturation current density (J{sub 0}), however, this effect is material and base resistivity specific. PECVD antireflection (AR) coatings provided low reflectance and efficient front surface and bulk defect passivation. Conventional cells fabricated on FZ silicon by furnace diffusions and oxidations gave an efficiency of 18.8% due to greater short wavelength response and lower J{sub 0}.

Performance of electric vehicles (EVs) is being studied in an ongoing Site Operator Program, as part of the Electric and Hybrid Vehicle Program supported by the U.S. Department of Energy (DOE). More than 200 EVs are being operated by Site Operators in various geographical and climatic regions of the United States. Cold-weather operation of EVs is of particular interest. As expected, low temperatures affect a battery`s ability to accept a charge, which decreases EV range and increases operating costs. Battery types other than lead-acid are being evaluated such as nickel-iron, gelled electrolyte lead-acid, nickel-cadmium, and sodium-sulfur. Also, improved methods of collecting EV performance data are being implemented, thermal management systems are being tested, and a prototype ultracapacitor is being tested as a possible alternative to conventional batteries.

This analysis of the plutonium oxide/metal storage containers is in support of the design and testing project The results from the dynamic analysis show some important facts that have not been considered before. The internal bagless transfer can will have higher stress than the primary container. The quasi-static analysis provides a conservative solution. In both vertical upright drop (dynamic) and inclined upside down drop (quasi-static) the containers are structurally sound.

Sampling during environmental drilling is essential to fully characterize the spatial distribution and migration of near surface contaminants. However, the analysis of these samples is not only expensive, but can take weeks or months when sent to an off-site laboratory. In contrast, measurement-while-drilling (MWD) screening capability could save money and valuable time by quickly distinguishing between contaminated and uncontaminated areas. Real-time measurements provided by a MVM system would enable on-the-spot decisions to be made regarding sampling strategies, enhance worker safety, and provide the added flexibility of being able to ``steer`` the drill bit in or out hazardous zones. During measurement-while-drilling, down-hole sensors are located behind the drill bit and linked by a rapid data transmission system to a computer at the surface. As drilling proceeds, data are collected on the nature and extent of the subsurface contamination in real-time. The down-hole sensor is a Geiger-Mueller tube (GMT) gamma radiation detector. In addition to the GMT signal, the MWD system monitors these required down-hole voltages and two temperatures associated with the detector assembly. The Gamma Ray Detection System (GRDS) and electronics package are discussed in as well as the results of the field test. Finally, our conclusions and discussion of future …

In this paper we investigate the physical controls upon the rate of vaporization of liquid as it is injected into a porous layer containing superheated vapor. We develop a simple model of the process and show that if liquid is injected at a relatively high rite, a small fraction of the liquid vaporizes and the porous layer becomes filled with hot liquid. In contrast, at low rates of injection a large fraction of the liquid may vaporize. We also describe a new and fundamental instability that can develop at a migrating liquid-vapour interface if the rite of injection is sufficiently small. This phenomenon is manifest in the form of liquid fingers growing from a liquid-vapour interface and is investigated through the use of analytical, experimental and numerical techniques.

SEMATECH and the Department of Energy have established a Contamination Free Manufacturing Research Center (CFMRC) located at Sandia National Laboratories. One of the programs underway at the CFMRC is directed towards defect reduction in semiconductor process reactors by the application of computational modeling. The goal is to use fluid, thermal, plasma, and particle transport models to identify process conditions and tool designs that reduce the deposition rate of particles on wafers. The program is directed toward defect reduction in specific manufacturing tools, although some model development is undertaken when needed. The need to produce quantifiable improvements in tool defect performance requires the close cooperation among Sandia, universities, SEMATECH, SEMATECH member companies, and equipment manufacturers. Currently, both plasma (e.g., etch, PECVD) and nonplasma tools (e.g., LPCVD, rinse tanks) are being worked on under this program. In this paper the authors summarize their recent efforts to reduce particle deposition on wafers during plasma-based semiconductor manufacturing.

Maintaining proficiency in carrying out mission goals is fundamental to the success of any organization. The definitive mission of the Waste Management and Remedial Action Division (WMRAD) of Oak Ridge National Laboratory (ORNL) is {open_quotes}to conduct waste management activities in a compliant, publicly acceptable, technically sound, and cost-efficient manner{close_quotes}. In order to effectively fulfill this mission, must meet or exceed several standards in respect to our customers. These include: (1) identifying current and future customer expectations; (2) managing our relationships with our customers; (3) ensuring our commitment to our customers; and (4) measuring our success m customer satisfaction. Our customers have a great variety of requirements and expectations. Many of these are in the form of local, state, and federal regulations and environmental standards. Others are brought to our attention through inquires made to the Department of Energy (DOE).Consumer surveys have proven to be effective tools which have been used to make improvements, enhance certain program elements, and identify beneficial areas in already existing programs. In addition, national working groups, technology transfer meetings, and manager/contractor`s meeting offer excellent opportunities to assess our activities.

Chemical probes have been developed to provide insight into the geometrical structure of isolated transition metal clusters. By determining as a function of cluster size the number of adsorbate molecules that saturate a cluster, and/or the binding energy of molecules to cluster surfaces, it is often possible to propose geometrical structures consistent with the experimental observations. The authors review recent studies of the reactions of cobalt, nickel, and copper clusters with ammonia, water, and nitrogen that provide structural information. It is found that small (between 50 and 150 atoms) cobalt, nickel, and copper clusters generally adopt icosahedral packing. However, for even smaller (less than 20 atoms) clusters, cobalt and nickel differ in their structure. The authors also see evidence for adsorbate-induced structural changes. These changes may allow the properties of materials fabricated from such clusters to be tailored to specific needs. A preliminary illustration of the dramatic effect that heteroatoms can have on metal cluster chemical properties is presented.

We present magnetoluminescence data which provides a quantitative measure of the energy-band dispersion curves of novel compound semiconductor optoelectronic materials. Data for a n-type strained-layer InGaAs/GaAs (quantum-well width {approximately} 8 nm) and a n-type 4.5-nm-wide GaAs/AlGaAs lattice-matched single-quantum well are presented. We find that the -conduction-bands are almost parabolic, with a mass of about 0.068m{sub 0} for InGaAs/GaAs and 0.085m{sub 0} for the GaAs/AlGaAs structure. The valence-bands are nonparabolic with wave vector dependent in-plane valence-band masses varying from about 0.1 m{sub 0} at zone center to about 0.3 m{sub 0} for 20 meV energies.

Inertial force damping control by micro manipulator modulation is proposed to suppress the vibrations of a micro/macro manipulator system. The proposed controller, developed using classical control theory, is added to the existing control system. The proposed controller uses real-time measurements of macro manipulator flexibility to adjust the motion of the micro manipulator to counteract structural vibrations. Experimental studies using an existing micro/macro flexible link manipulator testbed demonstrate the effectiveness of the proposed approach to suppression of vibrations in the macro/micro manipulator system using micro-manipulator-based inertial active damping control.

The effect of the pump, signal, and idler wave phases on three-wave nonlinear parametric mixing is investigated in a series of single-pass-gain experiments. Measurements are made with two angle-tuned KTP crystals in a 532 nm pumped, walkoff-compensated, optical parametric amplifier that is seeded by an 800 nm cw diode laser. In one of the measurements the second crystal is orientated to have its effective nonlinearity d{sub eff.} of opposite sign to that of the first crystal, so that all mixing that occurred in the first crystal is cancelled by the second when the phase mismatch {Delta}k{sub crystal 1} = {Delta}k{sub crystal 2} = 0. Efficient two-crystal amplification is subsequently restored by selecting the correct phase relationship for the three waves entering the crystal by inserting a dispersive plate between the crystals. The experimental results are explained in a straightforward manner with diagrams involving the three input wave polarizations. These results demonstrate that walkoff-compensated geometries require phase correction to achieve efficient mixing in the second crystal whenever the nonlinear interaction involves two extraordinary waves (e-waves). One practical application of this work may be lower oscillation thresholds and enhanced performance in walkoff-compensated optical parametric oscillators which use two e-waves.

ELIPGRID-PC, a new personal computer program, has been developed to provide easy access to Singer`s ELIPGRID algorithm for hot-spot detection probabilities. Three features of the program are the ability to determine: (1) the grid size required for specified conditions, (2) the smallest hot spot that can be sampled with a given probability, and (3) the approximate grid size resulting from specified conditions and sampling cost. ELIPGRID-PC also provides probability of detection versus cost data for graphing with spreadsheets or graphics software. The program has been successfully tested using Singer`s published ELIPGRID results. An apparent error in the published ELIPGRID code has been uncovered and an appropriate modification incorporated into the new program.