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The impact of thermal loading on repository performance at Yucca Mountain (open access)

The impact of thermal loading on repository performance at Yucca Mountain

In the unsaturated zone at Yucca Mountain, liquid flow along preferential fracture pathways is the only credible mechanism capable of bringing water to waste packages and transporting radionuclide to the water table. Three categories of features or mechanisms will mitigate the impact of flow along preferential fracture pathways: (1) discontinuity in fracture pathways, (2) liquid-phase dispersion in fracture networks, and (3) fracture-matrix interaction. For repository areal power densities (APDs) that are too low to result in significant boiling or rock dry-out effects, the primary mode of fracture-matrix interaction is matrix imbibition. For high APDs, boiling and enhanced matrix imbibition due to rock dry-out significantly add to the capacity of the unsaturated zone to retard fracture-dominated flow. With the use of V-TOUGH code, hydrothermal flow calculations are made for a range of APDs and spent fuel ages. For APD > 20 kW/acre, repository-heat-generated flow of vapor and liquid in fractures is found to dominate the ambient hydrological system. For high APDs, boiling conditions can persist for 10,000 yr or longer and rock-dry benefits for at least 100,000 yr.
Date: January 15, 1992
Creator: Buscheck, T. A. & Nitao, J. J.
System: The UNT Digital Library
Does Alkyl Substitution Affect the Si-H Bond Strength in Silane? Kinetic Studies of the Reactions of Atomic Chlorine and Bromine with Trimethylsilane and an ab Initio Investigation (open access)

Does Alkyl Substitution Affect the Si-H Bond Strength in Silane? Kinetic Studies of the Reactions of Atomic Chlorine and Bromine with Trimethylsilane and an ab Initio Investigation

Article on kinetics studies of the reactions of atomic chlorine and bromine with trimethylsilane and an ab initio investigation.
Date: July 1, 1992
Creator: Ding, Luying & Marshall, Paul
System: The UNT Digital Library
An ab Initio Study of Sulfinic Acid and Related Species (open access)

An ab Initio Study of Sulfinic Acid and Related Species

Article on an ab initio study of sulfinic acid and related species.
Date: March 1, 1992
Creator: Laakso, Dianna & Marshall, Paul
System: The UNT Digital Library
Kinetic Studies of the Reactions of Atomic Chlorine and Bromine with Silane (open access)

Kinetic Studies of the Reactions of Atomic Chlorine and Bromine with Silane

Article on kinetic studies of the reactions of atomic chlorine and bromine with silane.
Date: March 1, 1992
Creator: Ding, Luying & Marshall, Paul
System: The UNT Digital Library
[Newspaper Article: Railroad Museum Plans 'Harvey Girls' Luncheon] (open access)

[Newspaper Article: Railroad Museum Plans 'Harvey Girls' Luncheon]

Newspaper article about an upcoming Harvey Girls luncheon put on by the Temple, Texas Railroad and Pioneer Museum. The article was sent by Joe W. Zvolanek to Rosa Walston Latimer.
Date: February 1992
Creator: Ray, Randy
System: The Portal to Texas History
[Newspaper Article: B'wood Harvey Girl in 'Texas Highways'] (open access)

[Newspaper Article: B'wood Harvey Girl in 'Texas Highways']

Newspaper article about Lillian Preas, a resident of Brownwood, Texas and former Harvey Girl whose story was used in the magazine Texas Highways.
Date: January 26, 1992
Creator: Graves, Harriette
System: The Portal to Texas History
Thermodynamic Properties of Organic Compounds. 2. Combustion and Sublimation Enthalpies of 2,4,6-Trimethylbenzonitrile N-Oxide (open access)

Thermodynamic Properties of Organic Compounds. 2. Combustion and Sublimation Enthalpies of 2,4,6-Trimethylbenzonitrile N-Oxide

Article discussing thermodynamic properties of organic compounds and combustion and sublimation enthalpies of 2,4,6-trimethylbenzonitrile N-oxide.
Date: January 1992
Creator: Acree, William E. (William Eugene); Simirsky, Vladimir V.; Kozyro, Alexander A.; Krasulin, Alexander P.; Kabo, Gennady J. & Frenkel, Michael L.
System: The UNT Digital Library
Spectroscopic Investigation of Fluorescence Quenching Agents: Effect of Nitromethane on the Fluorescence Emission Behavior of Select Cyclopenta-PAH, Aceanthrylene, and Fluorene Derivatives (open access)

Spectroscopic Investigation of Fluorescence Quenching Agents: Effect of Nitromethane on the Fluorescence Emission Behavior of Select Cyclopenta-PAH, Aceanthrylene, and Fluorene Derivatives

Article on a spectroscopic investigation of fluorescence quenching agents and the effect of nitromethane on the fluorescence emission behavior of select cyclopenta-PAH, aceanthrylene, and fluorene derivatives.
Date: July 1, 1992
Creator: Amszi, Vicki L.; Cordero, Yvonne; Smith, Bradley; Tucker, Sheryl A. (Sheryl Ann); Acree, William E. (William Eugene); Yang, Chengxi et al.
System: The UNT Digital Library
Spectroscopic Properties of Polycyclic Aromatic Compounds: Examination of Nitromethane as a Selective Fluorescence Quenching Agent for Alternant Polycyclic Aromatic Nitrogen Hetero-Atom Derivatives (open access)

Spectroscopic Properties of Polycyclic Aromatic Compounds: Examination of Nitromethane as a Selective Fluorescence Quenching Agent for Alternant Polycyclic Aromatic Nitrogen Hetero-Atom Derivatives

Article on the spectroscopic properties of polycyclic aromatic compounds and an examination of nitromethane as a selective fluorescence quenching agent for alternant polycyclic aromatic nitrogen hetero-atom derivatives.
Date: February 1, 1992
Creator: Tucker, Sheryl A. (Sheryl Ann); Acree, William E. (William Eugene); Tanga, Mary J.; Tokita, Sumio; Hiruta, Kimihiro & Langhals, Heinz
System: The UNT Digital Library
Utilization of Cyanide as a Nitrogenous Substrate by Pseudomonas fluorescens NCIMB 11764: Evidence for Multiple Pathways of Metabolic Conversion (open access)

Utilization of Cyanide as a Nitrogenous Substrate by Pseudomonas fluorescens NCIMB 11764: Evidence for Multiple Pathways of Metabolic Conversion

Article on the utilization of cyanide as a nitrogenous substrate by Pseudomonas fluorescens NCIMB 11764 and evidence for multiple pathways of metabolic conversion.
Date: June 1, 1992
Creator: Kunz, Daniel A.; Nagappan, Olagappan; Silva-Avalos, Juan & Delong, George T.
System: The UNT Digital Library
Phonon Softening and High-Pressure Low-Symmetry Phases of Cesium Iodide (open access)

Phonon Softening and High-Pressure Low-Symmetry Phases of Cesium Iodide

Article on phonon softening and high-pressure low-symmetry phases of cesium iodide.
Date: August 17, 1992
Creator: Buongiorno Nardelli, Marco; Baroni, Stefano & Giannozzi, Paolo
System: The UNT Digital Library
Semiclassical chaos, the uncertainty principle, and quantum dissipation (open access)

Semiclassical chaos, the uncertainty principle, and quantum dissipation

Article on semiclassical chaos, the uncertainty principle, and quantum dissipation.
Date: June 15, 1992
Creator: Bonci, Luca; Roncaglia, Roberto; West, Bruce J. & Grigolini, Paolo
System: The UNT Digital Library
Methane Activation by Group IVB Imido Complexes (open access)

Methane Activation by Group IVB Imido Complexes

Article discussing an ab initio study of methane activation by group IVB imido complexes.
Date: December 1992
Creator: Cundari, Thomas R., 1964-
System: The UNT Digital Library
Transition Metal Imido Complexes (open access)

Transition Metal Imido Complexes

Article discussing a wide range of transition metal imido (TMI) complexes using ab initio molecular orbital (MO) calculations.
Date: September 1, 1992
Creator: Cundari, Thomas R., 1964-
System: The UNT Digital Library
High-Valent Transition-Metal Alkylidene Complexes: Effect of Ligand and Substituent Modification (open access)

High-Valent Transition-Metal Alkylidene Complexes: Effect of Ligand and Substituent Modification

Article on high-valent transition-metal alkylidene complexes and the effect of ligand and substituent modification.
Date: 1992
Creator: Cundari, Thomas R., 1964- & Gordon, Mark S.
System: The UNT Digital Library
Direct evidence for the amorphous silicon phase in visible photoluminescent porous silicon (open access)

Direct evidence for the amorphous silicon phase in visible photoluminescent porous silicon

Article on direct evidence for the amorphous silicon phase in visible photoluminescent porous silicon.
Date: June 1, 1992
Creator: Pérez, José M.; Villalobos, J.; McNeill, P.; Prasad, J.; Cheek, R.; Kelber, Jeffry A. et al.
System: The UNT Digital Library
Artificial Intelligence, Libraries, and Information Retrieval (open access)

Artificial Intelligence, Libraries, and Information Retrieval

Article discussing artificial intelligence, libraries, and information retrieval.
Date: 1992
Creator: Halbert, Martin
System: The UNT Digital Library