Using the general expression for the ponderomotive Hamiltonian, the quasi-static quasi-neutral density change caused by the ponderomotive force of a cold magnetoplasma wave of arbitrary frequency and polarization is obtained. This formula agrees with and extends previous results for unmagnetized and magnetized plasma.

An experimental arrangement consisting of an ultrahigh vacuum bell jar equipped with an internal sample isolation cell was used to investigate the hydrogenation of CO over Fe and Rh surfaces. This apparatus permitted both UHV surface characterization (Auger electron spectroscopy, low-energy electron diffraction) and high pressure (1-20 atm) catalytic reactions to be carried out. Small surface area (approximately 1 cm/sup 2/) metal samples, both single crystals and polycrystalline foils, were used to catalyze the H/sub 2//CO reaction at high pressures (1-6 atm). Reaction products were monitored with a gas chromatograph equipped with a flame ionization detector. The surface compositions of the metal samples were determined before and after the reaction and the results correlated with the observed product distributions and reaction rates. In addition, the influence of various surface additives (carbon, oxygen, potassium) was also investigated. Iron was the more reactive of the two metals studied and was found to produce C/sub 1/-C/sub 5/ straight chain hydrocarbons but it poisoned rapidly. The catalytically active surface of both metals was covered with a carbonaceous monolayer. The carbonaceous monolayer was stable on the rhodium surface and produced C/sub 1/-C/sub 4/ hydrocarbons at a steady rate even after several hours of reaction. The …

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