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1-D Van der Waals Foams Heated by Ion Beam Energy Deposition (open access)

1-D Van der Waals Foams Heated by Ion Beam Energy Deposition

One dimensional simulations of various initial average density aluminum foams (modeled as slabs of solid metal separated by low density regions) heated by volumetric energy deposition are conducted with a Lagrangian hydrodynamics code using a van der Waals equation of tate (EOS). The resulting behavior is studied to facilitate the design of future warm dense matter (WDM) experiments at LBNL. In the simulations the energy deposition ranges from 10 to 30 kJ/g and from 0.075 to 4.0 ns total pulse length, resulting in temperatures from approximately 1 o 4 eV. We study peak pressures and temperatures in the foams, expansion velocity, and the phase evolution. Five relevant time scales in the problem are identified. Additionally, we present a method for characterizing the level of inhomogeneity in a foam target as it is heated and the time it takes for a foam to homogenize.
Date: December 23, 2009
Creator: Zylstra, A. B.; Barnard, J. J. & More, R. M.
System: The UNT Digital Library
2009 Exploring Giant Planets on NIF: A New Generation of Condensed Matter Workshop (open access)

2009 Exploring Giant Planets on NIF: A New Generation of Condensed Matter Workshop

None
Date: December 18, 2009
Creator: Eggert, J. H.; Robey, H. F.; Spears, B. K.; Thomas, C. A.; Weber, S. V.; Wilson, D. C. et al.
System: The UNT Digital Library
2009 Pilot Scale Fluidized Bed Steam Reforming Testing Using the Thor (Thermal Organic Reduction) Process: Analytical Results for Tank 48h Organic Destruction - 10408 (open access)

2009 Pilot Scale Fluidized Bed Steam Reforming Testing Using the Thor (Thermal Organic Reduction) Process: Analytical Results for Tank 48h Organic Destruction - 10408

The Savannah River Site (SRS) must empty the contents of Tank 48H, a 1.3 million gallon Type IIIA HLW storage tank, to return this tank to service. The tank contains organic compounds, mainly potassium tetraphenylborate that cannot be processed downstream until the organic components are destroyed. The THOR{reg_sign} Treatment Technologies (TTT) Fluidized Bed Steam Reforming (FBSR) technology, herein after referred to as steam reforming, has been demonstrated to be a viable process to remove greater than 99.9% of the organics from Tank 48H during various bench scale and pilot scale tests. These demonstrations were supported by Savannah River Remediation (SRR) and the Department of Energy (DOE) has concurred with the SRR recommendation to proceed with the deployment of the FBSR technology to treat the contents of Tank 48H. The Savannah River National Laboratory (SRNL) developed and proved the concept with non-radioactive simulants for SRR beginning in 2003. By 2008, several pilot scale campaigns had been completed and extensive crucible testing and bench scale testing were performed in the SRNL Shielded Cells using Tank 48H radioactive sample. SRNL developed a Tank 48H non-radioactive simulant complete with organic compounds, salt, and metals characteristic of those measured in a sample of the radioactive …
Date: December 28, 2009
Creator: Williams, M. R.; Jantzen, Carol M.; Burket, P. R.; Crawford, C. L.; Daniel, W. E.; Aponte, C. et al.
System: The UNT Digital Library
Absolute Bunch Length Measurements by Incoherent Radiation Fluctuation Analysis (open access)

Absolute Bunch Length Measurements by Incoherent Radiation Fluctuation Analysis

By analyzing the pulse to pulse intensity fluctuations of the radiation emitted by a charge particle in the incoherent part of the spectrum, it is possible to extract information about the spatial distribution of the beam. At the Advanced Light Source (ALS) of the Lawrence Berkeley National Laboratory, we have developed and successfully tested a simple scheme based on this principle that allows for the absolute measurement of the rms bunch length. A description of the method and the experimental results are presented.
Date: December 9, 2009
Creator: Sannibale, F.; /LBL, Berkeley; Stupakov, G.V.; /SLAC; Zolotorev, M.S.; /LBL, Berkeley et al.
System: The UNT Digital Library
Advances and future needs in particle production and transport code developments (open access)

Advances and future needs in particle production and transport code developments

The next generation of accelerators and ever expanding needs of existing accelerators demand new developments and additions to Monte-Carlo codes, with an emphasis on enhanced modeling of elementary particle and heavy-ion interactions and transport. Challenges arise from extremely high beam energies and beam power, increasing complexity of accelerators and experimental setups, as well as design, engineering and performance constraints. All these put unprecedented requirements on the accuracy of particle production predictions, the capability and reliability of the codes used in planning new accelerator facilities and experiments, the design of machine, target and collimation systems, detectors and radiation shielding and minimization of their impact on environment. Recent advances in widely-used general-purpose all-particle codes are described for the most critical modules such as particle production event generators, elementary particle and heavy ion transport in an energy range which spans up to 17 decades, nuclide inventory and macroscopic impact on materials, and dealing with complex geometry of accelerator and detector structures. Future requirements for developing physics models and Monte-Carlo codes are discussed.
Date: December 1, 2009
Creator: Mokhov, N. V.
System: The UNT Digital Library
Analysis of micro-structural relaxation phenomena in laser-modified fused silica using confocal Raman microscopy (open access)

Analysis of micro-structural relaxation phenomena in laser-modified fused silica using confocal Raman microscopy

Fused silica micro-structural changes associated with localized 10.6 {micro}m CO{sub 2} laser heating are reported. Spatially-resolved shifts in the high-frequency asymmetric stretch transverse-optic (TO) phonon mode of SiO{sub 2} were measured using confocal Raman microscopy, allowing construction of axial fictive temperature (T{sub f}) maps for various laser heating conditions. A Fourier conduction-based finite element model was employed to compute on-axis temperature-time histories, and, in conjunction with a Tool-Narayanaswamy form for structural relaxation, used to fit T{sub f}(z) profiles to extract relaxation parameters. Good agreement between the calculated and measured T{sub f} was found, yielding reasonable values for relaxation time and activation enthalpy in the laser-modified silica.
Date: December 15, 2009
Creator: Matthews, M.; Vignes, R.; Cooke, J.; Yang, S. & Stolken, J.
System: The UNT Digital Library
B meson decays to charmless meson pairs containing eta or eta' (open access)

B meson decays to charmless meson pairs containing eta or eta'

The authors present updated measurements of the branching fractions for B{sup 0} meson decays to {eta}K{sup 0}, {eta}{eta}, {eta}{phi}, {eta}{omega}, {eta}{prime}K{sup 0}, {eta}{prime}{eta}{prime}, {eta}{prime}, {phi}, and {eta}{prime}{omega} and branching fractions and CP-violating charge asymmetries for B{sup +} decays to {eta}{pi}{sup +}, {eta}K{sup +}, {eta}{prime}{pi}{sup +}, and {eta}{prime} K{sup +}. The data represent the full dataset of 467 x 10{sup 6} B{bar B} pairs collected with the BABAR detector at the PEP-II asymmetric-energy e{sup +}e{sup -} collider at the SLAC National Accelerator Laboratory. Besides large signals for the four charged B decays modes and for B{sup 0} {yields} {eta}{prime}K{sup 0}, they find evidence for three B{sup 0} decays modes at greater than 3.0{sigma} significance. They find {Beta}(B{sup 0} {yields} {eta}K{sup 0}) = (1.15{sub -0.38}{sup +0.43} {+-} 0.09) x 10{sup -6}, {Beta}(B{sup 0} {yields} {eta}{omega}) = (0.94{sub -0.30}{sup +0.35} {+-} 0.09) x 10{sup -6}, and {Beta}(B{sup 0} {yields} {eta}{prime}{omega}) = (1.01{sub -0.38}{sup +0.46} {+-} 0.09) x 10{sup -6}, where the first (second) uncertainty is statistical (systematic). For the B{sup +} {yields} {eta}K{sup +} decay mode, they measure the charge asymmetry {Alpha}{sub ch} (B{sup +} {yields} {eta}K{sup +}) = -0.36 {+-} 0.11 {+-} 0.03.
Date: December 14, 2009
Creator: Aubert, B.
System: The UNT Digital Library
Beam Echo Effect for Generation of Short-Wavelength Radiation (open access)

Beam Echo Effect for Generation of Short-Wavelength Radiation

The Echo-Enabled Harmonic Generation (EEHG) FEL uses two modulators in combination with two dispersion sections to generate a high-harmonic density modulation starting with a relatively small initial energy modulation of the beam. After presenting the concept of the EEHG, we address several practically important issues, such as the effect of coherent and incoherent synchrotron radiation in the dispersion sections. Using a representative realistic set of beam parameters, we show how the EEHG scheme enhances the FEL performance and allows one to generate a fully (both longitudinally and transversely) coherent radiation. We then discuss application of the echo modulation for generation of attosecond pulses of radiation, and also using echo for generation of terahertz radiation. We present main parameters of a proof-of-principle experiment currently being planned at SLAC for demonstration of the echo modulation mechanism.
Date: December 9, 2009
Creator: Stupakov, G.
System: The UNT Digital Library
Biofuel alternatives to ethanol: pumping the microbial well (open access)

Biofuel alternatives to ethanol: pumping the microbial well

Engineered microorganisms are currently used for the production of food products, pharmaceuticals, ethanol fuel and more. Even so, the enormous potential of this technology has yet to be fully exploited. The need for sustainable sources of transportation fuels has gener-ated a tremendous interest in technologies that enable biofuel production. Decades of work have produced a considerable knowledge-base for the physiology and pathway engineering of microbes, making microbial engineering an ideal strategy for producing biofuel. Although ethanol currently dominates the biofuel mar-ket, some of its inherent physical properties make it a less than ideal product. To highlight additional options, we review advances in microbial engineering for the production of other potential fuel molecules, using a variety of biosynthetic pathways.
Date: December 2, 2009
Creator: Fortman, J. L.; Chhabra, Swapnil; Mukhopadhyay, Aindrila; Chou, Howard; Lee, Taek Soon; Steen, Eric et al.
System: The UNT Digital Library
Calculation of Coherent Synchrotron Radiation Impedance Using the Mode Expansion Method (open access)

Calculation of Coherent Synchrotron Radiation Impedance Using the Mode Expansion Method

We study an impedance due to coherent synchrotron radiation (CSR) generated by a short bunch of charged particles passing through a dipole magnet of finite length in a vacuum chamber of a given cross section. In our method we decompose the electromagnetic field of the beam over the eigenmodes of the toroidal chamber and derive a system of equations for the expansion coefficients in the series. The general method is further specialized for a toroidal vacuum chamber of a rectangular cross section where the eigenmodes can be computed analytically. We also develop a computer code that calculates the CSR impedance for a toroid of rectangular cross section. Numerical results obtained with the code are presented in the paper.
Date: December 9, 2009
Creator: Stupakov, G. V. & Kotelnikov, I. A.
System: The UNT Digital Library
Chemical pressure and hidden one-dimensional behavior in rare earth tri-telluride (open access)

Chemical pressure and hidden one-dimensional behavior in rare earth tri-telluride

We report on the first optical measurements of the rare-earth tri-telluride charge-density-wave systems. Our data, collected over an extremely broad spectral range, allow us to observe both the Drude component and the single-particle peak, ascribed to the contributions due to the free charge carriers and to the charge-density-wave gap excitation, respectively. The data analysis displays a diminishing impact of the charge-density-wave condensate on the electronic properties with decreasing lattice constant across the rare-earth series. We propose a possible mechanism describing this behavior and we suggest the presence of a one-dimensional character in these two-dimensional compounds. We also envisage that interactions and umklapp processes might play a relevant role in the formation of the charge-density-wave state in these compounds.
Date: December 14, 2009
Creator: Sacchetti, A.; Degiorgi, L.; Giamarchi, T.; Ru, N. & Fisher, I. R.
System: The UNT Digital Library
Collimation of dense plasma jets created by low energy laser pulses (open access)

Collimation of dense plasma jets created by low energy laser pulses

None
Date: December 1, 2009
Creator: Purvis, M. A.; Grava, J.; Filevich, J.; Ryan, D. P.; Moon, S. J.; Dunn, J. et al.
System: The UNT Digital Library
Combustion Synthesis of Nanoparticulate LiMgxMn1-xPO4 (x=0, 0.1, 0.2) Carbon Composites (open access)

Combustion Synthesis of Nanoparticulate LiMgxMn1-xPO4 (x=0, 0.1, 0.2) Carbon Composites

A combustion synthesis technique was used to prepare nanoparticulate LiMgxMn1-xPO4 (x=0, 0.1,0.2)/carbon composites. Powders consisted of carbon-coated particles about 30 nm in diameter, which were partly agglomerated into larger secondary particles. The utilization of the active materials in lithium cells depended most strongly upon the post-treatment and the Mg content, and was not influenced by the amount of carbon. Best results were achieved with a hydrothermally treated LiMg0.2Mn0.8PO4/C composite, which exhibited close to 50percent utilization of the theoretical capacity at a C/2 discharge rate.
Date: December 14, 2009
Creator: Doeff, Marca M; Chen, Jiajun; Conry, Thomas E.; Wang, Ruigang; Wilcox, James & Aumentado, Albert
System: The UNT Digital Library
Comment on "Modification of graphene properties due to electron-beam irradiation" (open access)

Comment on "Modification of graphene properties due to electron-beam irradiation"

This article gives comment to a previous article entitled 'Modification of graphene properties due to electron-beam irradiation'. These articles discuss the modification of graphene properties due to electron-beam irradiation.
Date: December 17, 2009
Creator: Jones, Jason D.; Ecton, Philip A.; Mo, Yudong & Pérez, José M.
System: The UNT Digital Library
COMMENTS ON "A NEW LOOK AT LOW-ENERGY NUCLEAR REACTION RESEARCH" (open access)

COMMENTS ON "A NEW LOOK AT LOW-ENERGY NUCLEAR REACTION RESEARCH"

Cold fusion researchers have accumulated a large body of anomalous results over the last 20 years that they claim proves a new, mysterious nuclear reaction is active in systems they study. Krivit and Marwan give a brief and wholly positive view of this body of research. Unfortunately, cold fusion researchers routinely ignore conventional explanations of their observations, and claim much greater than real accuracy and precision for their techniques. This paper attempts to equally briefly address those aspects of the field with the intent of providing a balanced view of the field, and to establish some criteria for subsequent publications in this arena.
Date: December 30, 2009
Creator: Shanahan, K.
System: The UNT Digital Library
Comparison of IUPAC k0 Values and Neutron Cross Sections to Determine a Self-consistent Set of Data for Neutron Activation Analysis (open access)

Comparison of IUPAC k0 Values and Neutron Cross Sections to Determine a Self-consistent Set of Data for Neutron Activation Analysis

Independent databases of nuclear constants for Neutron Activation Analysis (NAA) have been independently maintained by the physics and chemistry communities for many year. They contain thermal neturon cross sections s0, standardization values k0, and transition probabilities Pg. Chemistry databases tend to rely upon direct measurements of the nuclear constants k0 and Pg which are often published in chemistry journals while the physics databases typically include evaluated s0 and Pg data from a variety of experiments published mainly in physics journals. The IAEA/LBNL Evaluated Gamma-ray Activation File (EGAF) also contains prompt and delayed g-ray cross sections sg from Prompt Gamma-ray Activation Analysis (PGAA) measurements that can also be used to determine k0 and s0 values. As a result several independent databases of fundamental constants for NAA have evolved containing slightly different and sometimes discrepant results. An IAEA CRP for a Reference Database for Neutron Activation Analysis was established to compare these databases and investigate the possibilitiy of producing a self-consistent set of s0, k0, sg, and Pg values for NAA and other applications. Preliminary results of this IAEA CRP comparison are given in this paper.
Date: December 1, 2009
Creator: Firestone, Richard B & Revay, Zsolt
System: The UNT Digital Library
Comparison of laser-based mitigation of fused silica surface damage using mid- versus far-infrared lasers (open access)

Comparison of laser-based mitigation of fused silica surface damage using mid- versus far-infrared lasers

Laser induced growth of optical damage can limit component lifetime and therefore operating costs of large-aperture fusion-class laser systems. While far-infrared (IR) lasers have been used previously to treat laser damage on fused silica optics and render it benign, little is known about the effectiveness of less-absorbing mid-IR lasers for this purpose. In this study, they quantitatively compare the effectiveness and efficiency of mid-IR (4.6 {micro}m) versus far-IR (10.6 {micro}m) lasers in mitigating damage growth on fused silica surfaces. The non-linear volumetric heating due to mid-IR laser absorption is analyzed by solving the heat equation numerically, taking into account the temperature-dependent absorption coefficient {alpha}(T) at {lambda} = 4.6 {micro}m, while far-IR laser heating is well-described by a linear analytic approximation to the laser-driven temperature rise. In both cases, the predicted results agree well with surface temperature measurements based on infrared radiometry, as well as sub-surface fictive temperature measurements based on confocal Raman microscopy. Damage mitigation efficiency is assessed using a figure of merit (FOM) relating the crack healing depth to laser power required, under minimally-ablative conditions. Based on their FOM, they show that for cracks up to at least 500 {micro}m in depth, mitigation with a 4.6 {micro}m mid-IR laser …
Date: December 16, 2009
Creator: Yang, S T; Matthews, M J; Elhadj, S; Cooke, D; Guss, G M; Draggoo, V G et al.
System: The UNT Digital Library
Connecting the molecular scale to the continuum scale for diffusion processes in smectite-rich porous media (open access)

Connecting the molecular scale to the continuum scale for diffusion processes in smectite-rich porous media

In this paper, we address the manner in which the continuum-scale diffusive properties of smectite-rich porous media arise from their molecular- and pore-scale features. Our starting point is a successful model of the continuum-scale apparent diffusion coefficient for water tracers and cations which decomposes it as a sum of pore-scale terms describing diffusion in macropore and interlayer 'compartments.' We then apply molecular dynamics (MD) simulations to determine molecular-scale diffusion coefficients D{sub interlayer} of water tracers and representative cations (Na{sup +}, Cs{sup +}, Sr{sup 2+}) in Na-smectite interlayers. We find that a remarkably simple expression relates D{sub interlayer} to the pore-scale parameter {delta}{sub nanopore} {<=} 1, a constrictivity factor that accounts for the lower mobility in interlayers as compared to macropores: {delta}{sub nanopore} = D{sub interlayer}/D{sub 0}, where D{sub 0} is the diffusion coefficient in bulk liquid water. Using this scaling expression, we can accurately predict the apparent diffusion coefficients of tracer H{sub 2}O, Na{sup +}, Sr{sup 2+} and Cs{sup +}+ in compacted Na-smectite-rich materials.
Date: December 1, 2009
Creator: Bourg, I.C. & Sposito, G.
System: The UNT Digital Library
Construction of Large Period Symplectic Maps by Interpolative Methods (open access)

Construction of Large Period Symplectic Maps by Interpolative Methods

The goal is to construct a symplectic evolution map for a large section of an accelerator, say a full turn of a large ring or a long wiggler. We start with an accurate tracking algorithm for single particles, which is allowed to be slightly non-symplectic. By tracking many particles for a distance S one acquires sufficient data to construct the mixed-variable generator of a symplectic map for evolution over S, given in terms of interpolatory functions. Two ways to find the generator are considered: (1) Find its gradient from tracking data, then the generator itself as a line integral. (2) Compute the action integral on many orbits. A test of method (1) has been made in a difficult example: a full turn map for an electron ring with strong nonlinearity near the dynamic aperture. The method succeeds at fairly large amplitudes, but there are technical difficulties near the dynamic aperture due to oddly shaped interpolation domains. For a generally applicable algorithm we propose method (2), realized with meshless interpolation methods.
Date: December 17, 2009
Creator: Warnock, Robert; Cai, Yunhai & Ellison, James A.
System: The UNT Digital Library
Continuity and Performance in Composite Electrodes (open access)

Continuity and Performance in Composite Electrodes

It is shown that the rate performance of a lithium battery composite electrode may be compromised by poor internal connectivity due to defects and inhomogeneities introduced during electrode fabrication or subsequent handling. Application of a thin conductive coating to the top surface of the electrode or to the separator surface in contact with the electrode improves the performance by providing alternative current paths to partially isolated particles of electroactive material. Mechanistic implications are discussed and strategies for improvement in electrode design and fabrication are presented.
Date: December 23, 2009
Creator: Chen, Guoying & Richardson, Thomas J.
System: The UNT Digital Library
Control Banding and Nanotechnology Synergist (open access)

Control Banding and Nanotechnology Synergist

The average Industrial Hygienist (IH) loves a challenge, right? Okay, well here is one with more than a few twists. We start by going through the basics of a risk assessment. You have some chemical agents, a few workers, and the makings of your basic exposure characterization. However, you have no occupational exposure limit (OEL), essentially no toxicological basis, and no epidemiology. Now the real handicap is that you cannot use sampling pumps, cassettes, tubes, or any of the media in your toolbox, and the whole concept of mass-to-dose is out the window, even at high exposure levels. Of course, by the title, you knew we were talking about nanomaterials (NM). However, we wonder how many IHs know that this topic takes everything you know about your profession and turns it upside down. It takes the very foundations that you worked so hard in college and in the field to master and pulls it out from underneath you. It even takes the gold standard of our profession, the quantitative science of exposure assessment, and makes it look pretty darn rusty. Now with NM there is the potential to get some aspect of quantitative measurements, but the instruments are generally very …
Date: December 15, 2009
Creator: Zalk, D & Paik, S
System: The UNT Digital Library
A Coordinated Approach to Communicating Pediatric-Related Information on Pandemic Influenza at the Community Level (open access)

A Coordinated Approach to Communicating Pediatric-Related Information on Pandemic Influenza at the Community Level

The purpose of this document is to provide a suggested approach, based on input from pediatric stakeholders, to communicating pediatric-related information on pandemic influenza at the community level in a step-by-step manner.
Date: December 16, 2009
Creator: CHE, HCTT
System: The UNT Digital Library
Corner rounding in EUV photoresist: tuning through molecular weight, PAG size, and development time (open access)

Corner rounding in EUV photoresist: tuning through molecular weight, PAG size, and development time

In this paper, the corner rounding bias of a commercially available extreme ultraviolet photoresist is monitored as molecular weight, photoacid generator (PAG) size, and development time are varied. These experiments show that PAG size influences corner biasing while molecular weight and development time do not. Large PAGs are shown to exhibit less corner biasing, and in some cases, lower corner rounding, than small PAGs. In addition, heavier resist polymers are shown to exhibit less corner rounding than lighter ones.
Date: December 31, 2009
Creator: Anderson, Christopher; Daggett, Joe & Naulleau, Patrick
System: The UNT Digital Library
Curvature of the Lanthanide Contraction: An Explanation (open access)

Curvature of the Lanthanide Contraction: An Explanation

A number of studies have shown that for isostructural series of the lanthanides (elements La through Lu), a plot of equivalent metal-ligand bond lengths versus atomic number differs significantly from linearity and can be better fit as a quadratic equation. However, for hydrogen type wave functions, it is the inverse of the average distance of the electron from the nucleus (an estimate of size) that varies linearly with effective nuclear charge. This generates an apparent quadratic dependence of radius with atomic number. Plotting the inverse of lanthanide ion radii (the observed distance minus the ligand size) as a function of effective nuclear charge gives very good linear fits for a variety of lanthanide complexes and materials. Parameters obtained from this fit are in excellent agreement with the calculated Slater shielding constant, k.
Date: December 21, 2009
Creator: Raymond, Kenneth; Wellman, Daniel; Sgarlata, Carmelo & Hill, Aru
System: The UNT Digital Library