Transmission Electron Microscopy developed from an imagingtool into a quantitative electron beam characterization tool that locallyaccesses structure, chemistry, and bonding in materials with sub Angstromresolution. Experiments utilize coherently and incoherently scatteredelectrons. In this contribution, the interface between gallium nitrideand sapphire as well as thin silicon gate oxides are studied tounderstand underlying physical processes and the strength of thedifferent microscopy techniques. An investigation of the GaN/sapphireinterface benefits largely from the application of phase contrastmicroscopy that makes it possible to visualize dislocation corestructures and single columns of oxygen and nitrogen at a closest spacingof 85 pm. In contrast, it is adequate to investigate Si/SiOxNy/poly-Siinterfaces with incoherently scattered electrons and electronspectroscopy because amorphous and poly crystalline materials areinvolved. Here, it is demonstrated that the SiOxNy/poly-Si interface isrougher than the Si/SiOx interface, that desirable nitrogen diffusiongradients can be introduced into the gate oxide, and that a nitridationcoupled with annealing increases its physical width while reducing theequivalent electrical oxide thickness to values approaching 1.2 nm.Therefore, an amorphous SiNxOy gate dielectric seems to be a suitablesubstitute for traditional gate oxides to further increase device speedby reducing dimensions in Si technology.

Predictions of airflows around buildings and the associated thermal and dispersion phenomena continue to be challenging because of the presence of extremely heterogeneous surface structures within urban areas. Atmospheric conditions can induce local winds to flow around structures rather than over them. Thus pollutants that are released at or near the ground tend to persist at relatively low levels with only minimal ventilation of the airborne material away from the ground surface. While flow and dispersion phenomena can be studied within wind tunnel settings, recent advances in numerical modeling have enabled computational fluid dynamics (CFD) to evolve into an important tool in the simulation of building scale flows. They are developing numerical models to simulate the flow and dispersion of releases around multi-building complexes. These models will be used to assess the transport and fate of releases of hazardous agents within urban areas and to support emergency response activities. There are already a number of models that have been developed to simulate flow and dispersion around urban settings. A recent collection of these papers can be found in the Proceedings of the International Workshop on CFD for Wind Climate in Cities. Most of the simulation studies presented in the literature …

This document is a collection of the contributions made to the March IIT workshop on an e{sup +}e{sup -} collider in the VLHC tunnel. This machine, which is based on a relatively conservative extrapolation of LEP technology, has a baseline luminosity of 10{sup 33}/cm{sup 2}/s at a CM energy of 370 GeV. The overall parameters and general description of such a machine is described in T. Sen and J. Norem, ''A Very Large Lepton Collider in the VLHC Tunnel'', to be published. A preprint of this paper is included as Appendix 2 of this report. The intention of the workshop was to define the parameters of such a collider and make them available to the community for use in further physics studies. It is clear that the machine cannot compete with a full scale linear collider. Its main interest would be if a VLHC were built and if a linear collider did not already exist. In this case, it could provide a limited and perhaps crucial view of low mass Higgs states. Although the study is incomplete, it does define rather well the parameters of the machine, as well as the challenges that the design faces. The study benefited greatly …

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An integrating solid state detector with segmentation has been developed that addresses the needs in scanning transmission x-ray microscopy below 1 keV photon energy. The detector is not cooled and can be operated without an entrance window which leads to a total photon detection efficiency close to 100%. The chosen segmentation with 8 independent segments is matched to the geometry of the STXM to maximize image mode flexibility. In the bright field configuration for 1 ms integration time and 520 eV x-rays the rms noise is 8 photons per integration.

The promise of inertial fusion energy driven by heavy ion beams requires the development of accelerators that produce ion currents (approx 100's Amperes/beam) and ion energies ({approx} 1 - 10 GeV) that have not been achieved simultaneously in any existing accelerator. The high currents imply high generalized perveances, large tun depressions, and high space charge potentials of the beam center relative to the beam pipe. Many of the scientific issues associated with ion beams of high perveance and large tune depression have been addressed over the last two decades on scaled experiments at Lawrence Berkeley and Lawrence Livermore National Laboratories, the University of Maryland, and elsewhere. The additional requirement of high space charge potential (or equivalently high line charge density) gives rise to effects (particularly the role of electrons in beam transport) which must be understood before proceeding to a large scale accelerator. The first phase of a new series of experiments in the Heavy Ion Fusion Virtual National Laboratory (HIF VNL), the High Current Experiments (HCX), is now beginning at LBNL. The mission of the HCX is to transport beams with driver line charge density so as to investigate the physics of this regime, including constraints on the maximum …

A model-based detector is developed to process shallow water ocean acoustic data. The function of the detector is to adaptively monitor the environment and decide whether or not a change from normal has occurred. Here we develop a processor incorporating both a normal-mode ocean acoustic model and a vertical hydrophone array. The detector is applied to data acquired from the Hudson Canyon experiments at various ranges and its performance is evaluated.

Properties of rock materials under quasistatic conditions are well characterized in laboratory experiments. Unfortunately, quasistatic data alone are not sufficient to calibrate models for use to describe inelastic wave propagation associated with conventional and nuclear explosions, or with impact. First, rock properties are size-dependent. properties measured using laboratory samples on the order of a few centimeters in size need to be modified to adequately describe wave propagation in a problem on the order of a few hundred meters in size. Second, there is lack of data about the damage (softening) behavior of rock because most laboratory tests focus on the pre-peak hardening region with very little emphasis on the post-peak softening region. This paper presents a model for granite that accounts for both the hardening and softening of geologic materials, and also provides a simple description of rubblized rock. The model is shown to reproduce results of quasistatic triaxial experiments as well as peak velocity and peak displacement attenuation from a compendium of dynamic wave propagation experiments that includes US and French nuclear tests in granite.

The large strain deformation response of 6061-T6 and Ti-6Al-4V has been evaluated over a range in strain rates from 10{sup -4} s{sup -1} to over 10{sup 4} s{sup -1}. The results have been used to critically evaluate the strength and damage components of the Johnson-Cook (JC) material model. A new model that addresses the shortcomings of the JC model was then developed and evaluated. The model is derived from the rate equations that represent deformation mechanisms active during moderate and high rate loading. Another model that accounts for the influence of void formation on yield and flow behavior of a ductile metal (the Gurson model) was also evaluated. The characteristics and predictive capabilities of these models are reviewed.

Recent work in classification indicates that significant improvements in accuracy can be obtained by growing an ensemble of classifiers and having them vote for the most popular class. This paper focuses on ensembles of decision trees that are created with a randomized procedure based on sampling. Randomization can be introduced by using random samples of the training data (as in bagging or boosting) and running a conventional tree-building algorithm, or by randomizing the induction algorithm itself. The objective of this paper is to describe the first experiences with a novel randomized tree induction method that uses a sub-sample of instances at a node to determine the split. The empirical results show that ensembles generated using this approach yield results that are competitive in accuracy and superior in computational cost to boosting and bagging.

The form of the most general orbifold breaking of gauge, global and supersymmetries with a single extra dimension is given. In certain theories the Higgs boson mass is ultraviolet finite due to an unbroken local supersymmetry, which is explicitly exhibited. We construct: a 1 parameter SU(3) \times SU(2) \times U(1) theory with 1 bulk Higgs hypermultiplet, a 2 parameter SU(3) \times SU(2) \times U(1) theory with 2 bulk Higgs hypermultiplets, and a 2 parameter SU(5) \to SU(3) \times SU(2) \times U(1) theory with 2 bulk Higgs hypermultiplets, and demonstrate that these theories are unique. We compute the Higgs mass and compactification scale in the SU(3) \times SU(2) \times U(1) theory with 1 bulk Higgs hypermultiplet.

The National Spent Nuclear Fuel Program, operating from the Idaho National Engineering and Environmental Laboratory (INEEL), developed the standardized Department of Energy (DOE) spent nuclear fuel (SNF) canister. During the development of this canister, more than twenty drop tests were completed, evaluating high strain behavior, puncture resistance, maintenance of containment, and other canister responses. Computer analyses of these drop-test specimens/canisters employed the ABAQUS/Explicit software. A pre-drop analysis was performed for each test specimen to predict the deformed shape and resulting material straining. Typically, a postdrop analysis was also performed to better match actual test specifics (actual impact angle, test specimen material properties, etc.). The purpose for this analysis effort was to determine the capability of current analysis techniques to accurately predict the deformed shape of a standardized DOE SNF canister subjected to a defined drop event, without actually having to perform a drop test for every drop event of interest. Those analytical efforts yielded very accurate predictions for nearly all of the drop tests. However, it was noted, during one small-scale test, that the calculated deformed shape of the test specimen depended on the modeled frictional behavior as it impacted the essentially unyielding flat surface. In order to calculate the …

For the past several years, researchers at the Idaho National Engineering and Environmental Laboratory, under the sponsorship of the U.S. Nuclear Regulatory Commission, have been investigating the ability of motor-operated valves (MOVs) used in Nuclear Power Plants to close or open when subjected to design basis flow and pressure loads. Part of this research addresses the response of a dcpowered motor-operated gate valve to assess whether it will achieve flow isolation and to evaluate whether it will slow down excessively under design-basis conditions and thus fail to achieve the required stroke time. As part of this research, we have developed a model of a dc motor operating under load and a model of actuator efficiency under load based on a first principle evaluation of the equipment. These models include the effect that reduced voltage at the Motor Control Center and elevated containment temperatures have on the performance of a dc powered MOV. The model also accounts for motor torque and speed changes that result from the heatup of the motor during the stroke. These models are part of the Motor- Operated Valve In Site Test Assessment (MISTA) software which is capable of independently evaluating the ability of dc-powered motoroperated gate …

Disciplined science and technology roadmapping provides a framework to coordinate research and development activities with project objectives. This case-history paper describes initial project technology needs identification, assessment and R&D ranking activities supporting characterization of 781 waste tanks requiring a 'hazardous waste determination' or 'verification of empty' decision to meet an Idaho state Voluntary Consent Order.

The INEEL has developed a photorefractive ultrasonic imaging technology that records both phase and amplitude of ultrasonic waves on the surface of solids. Phase locked dynamic holography provides full field images of these waves scattered from subsurface defects in solids, and these data are compared with theoretical predictions. Laser light reflected by a vibrating surface is imaged into a photorefractive material where it is mixed in a heterodyne technique with a reference wave. This demodulates the data and provides an image of the ultrasonic waves in either 2 wave or 4 wave mixing mode. These data images are recorded at video frame rates and show phase locked traveling or resonant acoustic waves. This technique can be used over a broad range of ultrasonic frequencies. Acoustic frequencies from 2 kHz to 10 MHz have been imaged, and a point measuring (non-imaging) version of the system has measured picometer amplitudes at 1 GHz.

This paper documents the results of recent tests sponsored by the U. S. Nuclear Regulatory Commission (NRC) and performed by the Idaho National Engineering and Environmental Laboratory (INEEL). These tests address the effectiveness of the lubricant used on the threaded portion of the valve stem, where the stem nut turns on the stem. Recent testing indicates that an elevated temperature environment can lead to significant increases in the friction coefficient at the stem/stem-nut interface. Most valve actuator qualification tests are performed at room temperature. Similarly, in-service tests are run at ambient plant temperatures, usually 70 to 100°F. Since design conditions can lead to valve operating temperatures in the 200 to 300°F range, it is important to know whether a temperature-induced increase in friction at the stem/stem-nut interface will prevent the required operation of critical valves. Lubricant aging is another phenomenon that might have deleterious effects on the thrust output of a valve actuator. Laboratory experience and field experience both indicate that after long periods in elevated temperature environments, the lubricants may lose their lubrication qualities. The scope of the current test program includes testing of five different lubricants on four different valve stems. Pending completion of the testing, results of …

We describe the use of machine learning methods in the analysis of spatial soil fertility, soil physical characteristics, and yield data, with a particular objective of determining local (field- to farm-scale) crop response patterns. For effective prescriptive use, the output of these tools is augmented with economic data and operational constraints, and recast as a rulebased decision support tool to maximize economic return in variable rate fertilization systems. We describe some of the practical issues addressed in development of one such system, including data preparation, adaptation of regression tree output for use in a rule-based expert system, and incorporation of real-world limits on system recommendations. Results from various field trials of this system are summarized.

We have conducted low energy X-ray spectroscopy of ion/surface interactions with superconducting tunnel junction (STJ) detectors. The STJ detectors (Nb-Al-AlOx-Al-Nb) developed at the Lawrence Livermore National Laboratory have a high energy resolution and a high count-rate capability. The detectors are operated in an adiabatic demagnetization refrigerator with 60 mK base temperature at the end of a 40 cm long cold finger, which can be inserted into a UHV sample chamber connected to an ion source. We have studied the interaction of Ar{sup 9+}, O{sup 7+}, N{sup 6+} and C{sup 5+} with various targets (Au, SiH and SiO{sub 2}) at a kinetic energy of 10 keV/q. The resolution of 12-15 eV below 1 keV allows the different satellite lines emitted by these ions to be separated.

Unnatural analogs of sialic acid can be delivered to mammalian cell surfaces through the metabolic transformation of unnatural N-acetylmannosamine (ManNAc) derivatives. In previous studies, mannosamine analogs bearing simple N-acyl groups up to five carbon atoms in length were recognized as substrates by the biosynthetic machinery and transformed into cell-surface sialoglycoconjugates [Keppler, O. T., et al. (2001) Glycobiology 11, 11R-18R]. Such structural alterations to cell surface glycans can be used to probe carbohydrate-dependent phenomena. This report describes our investigation into the extent of tolerance of the pathway toward additional structural alterations of the N-acyl substituent of ManNAc. A panel of analogs with ketone-containing N-acyl groups that varied in the lengthor steric bulk was chemically synthesized and tested for metabolic conversion to cell-surface glycans. We found that extension of the N-acyl chain to six, seven, or eight carbon atoms dramatically reduced utilization by the biosynthetic machinery. Likewise, branching from the linear chain reduced metabolic conversion. Quantitation of metabolic intermediates suggested that cellular metabolism is limited by the phosphorylation of the N-acylmannosamines by ManNAc 6-kinase in the first step of the pathway. This was confirmed by enzymatic assay of the partially purified enzyme with unnatural substrates. Identification of ManNAc 6-kinase as a bottleneck …

In-situ studies of CO adsorption by surface x-ray scattering (SXS) and Fourier transform infrared (FTIR) spectroscopy techniques are used to create the link between the macroscopic kinetic rates of CO oxidation and the microscopic level of understanding the structure/site occupancy of CO on Pt(111). A remarkable difference in activity was observed between alkaline and acid solutions. In alkaline solution the oxidation of CO proceeds at low overpotential (<0.2 V) by the surface reaction between the adsorbed CO and OH, the latter forming selectively in the hydrogen underpotential potential region at defect sites. In acid solution these sites are blocked by specific adsorption of anions, and consequently in a solution containing Br{sup -} the ignition potential is shifted positively by 0.6 V. Anions of supporting electrolytes also have dramatic effects on both the potential range of stability and the domain size of the p(2x2)-3CO structure which is formed at 0.05 V. The stability/domain size of this structure increases from KOH (ca. 30 {angstrom} between 0.05 < E < 0.3V), to HClO{sub 4} (ca. 140 {angstrom} between 0.05 < E < 0.6V) to HClO{sub 4} + Br{sup -} (ca 350 {angstrom} between 0.05 < E < 0.8V). The larger the ordered domains …

The first phylogenetic hypothesis for the Sri Lankan agamid lizard genus Ceratophora is presented based on 1670 aligned base positions (472 parsimony informative) of mitochondrial DNA sequences, representing coding regions for eight tRNAs, ND2, and portions of ND1 and COI. Phylogenetic analysis reveals multiple origins and possibly losses of rostral horns in the evolutionary history of Ceratophora. Our data suggest a middle Miocene origin of Ceratophora with the most recent branching of recognized species occurring at the Pliocene/Pleistocene boundary. Haplotype divergence suggests that an outgroup species, Lyriocephalus scutatus, dates at least to the Pliocene. These phylogenetic results provide a framework for comparative studies of the behavioral ecological importance of horn evolution in this group.

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The properties of currently available NbTi superconductor and carbon-fiber structural materials enable the possibility of constructing a magnetically levitated space elevator from the earth's surface up to an altitude of {approx} 200 km. The magnetic part of the elevator consists of a long loop of current-carrying NbTi, composed of one length that is attached to the earth's surface in an east-west direction and a levitated-arch portion. The critical current density of NbTi is sufficiently high that these conductors will stably levitate in the earth's magnetic field. The magnetic self-field from the loop increases the levitational force and for some geometries assists levitational stability. The 200-km maximum height of the levitated arch is limited by the allowable stresses of the structural material. The loop is cryogenically cooled with helium, and the system utilizes intermediate pumping and cooling stations along both the ground and the levitated portion of the loop, similar to other large terrestrial cryogenic systems. Mechanically suspended from the basic loop is an elevator structure, upon which mass can be moved between the earth's surface and the top of the loop by a linear electric motor or other mechanical or electrical means. At the top of the loop, vehicles may …

Developing an understanding of the processes that control the H-mode transport barrier is motivated by the significant impact this small region (typically <2% of the minor radius) can have on overall plasma performance. Conditions at the inner edge of the H-mode transport barrier can strongly influence the overall energy confinement, and the maximum density, and therefore fusion power, that can be achieved with the typically flat H-mode density profiles [1,2]. The ELM instability, which usually regulates the pressure gradient in the H-mode edge, can result in large power loads to, and erosion of, the divertor targets in a reactor scale device [3]. The goal of H-mode pedestal research at DIII-D is to: (1) develop a physics based model that would allow prediction of the conditions at the top of the H-mode pedestal, (2) develop an understanding of processes which control Type I ELM effects in the core and divertor, and (3) explore alternatives to the Type I ELM regime.