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Extending the cereus group genomics to putative food-borne pathogens of different toxicity (open access)

Extending the cereus group genomics to putative food-borne pathogens of different toxicity

The cereus group represents sporulating soil bacteriacontaining pathogenic strains which may cause diarrheic or emetic foodpoisoning outbreaks. Multiple locus sequence typing revealed a presencein natural samples of these bacteria of about thirty clonal complexes.Application of genomic methods to this group was however biased due tothe major interest for representatives closely related to B. anthracis.Albeit the most important food-borne pathogens were not yet defined,existing dataindicate that they are scattered all over the phylogenetictree. The preliminary analysis of the sequences of three genomesdiscussed in this paper narrows down the gaps in our knowledge of thecereus group. The strain NVH391-98 is a rare but particularly severefood-borne pathogen. Sequencing revealed that the strain must be arepresentative of a novel bacterial species, for which the name Bacilluscytotoxis is proposed. This strain has a reduced genome size compared toother cereus group strains. Genome analysis revealed absence of sigma Bfactor and the presence of genes encoding diarrheic Nhe toxin, notdetected earlier. The strain B. cereus F837/76 represents a clonalcomplex close to that of B. anthracis. Including F837/76, three such B.cereus strains had been sequenced. Alignment of genomes suggests that B.anthracis is their common ancestor. Since such strains often emerge fromclinical cases, they merit a special attention. The …
Date: August 24, 2006
Creator: Lapidus, Alla; Goltsman, Eugene; Auger, Sandrine; Galleron, Nathalie; Segurens, Beatrice; Dossat, Carole et al.
System: The UNT Digital Library
On the Virial Theorem for Interstellar Medium (open access)

On the Virial Theorem for Interstellar Medium

An attempt has been made to derive a version of the virial integral that would describe average properties of the interstellar medium (ISM). It is suggested to eliminate the (large) contribution of stellar matter by introducing 'exclusion zones' surrounding stars. Such an approach leads to the appearance of several types of additional surface integrals in the general expression. Their contribution depends on the rate of energy and matter exchange between the stars and ISM. If this exchange is weak, one can obtain a desired virial integral for ISM. However, the presence of intermittent large-scale energetic events significantly constrains the applicability of the virial theorem. If valid, the derived virial integral is dominated by cold molecular/atomic clouds, with only minor contribution of the global magnetic field and low-density warm part.
Date: September 24, 2007
Creator: Ryutov, D.
System: The UNT Digital Library
System-level modeling for geological storage of CO2 (open access)

System-level modeling for geological storage of CO2

One way to reduce the effects of anthropogenic greenhousegases on climate is to inject carbon dioxide (CO2) from industrialsources into deep geological formations such as brine formations ordepleted oil or gas reservoirs. Research has and is being conducted toimprove understanding of factors affecting particular aspects ofgeological CO2 storage, such as performance, capacity, and health, safetyand environmental (HSE) issues, as well as to lower the cost of CO2capture and related processes. However, there has been less emphasis todate on system-level analyses of geological CO2 storage that considergeological, economic, and environmental issues by linking detailedrepresentations of engineering components and associated economic models.The objective of this study is to develop a system-level model forgeological CO2 storage, including CO2 capture and separation,compression, pipeline transportation to the storage site, and CO2injection. Within our system model we are incorporating detailedreservoir simulations of CO2 injection and potential leakage withassociated HSE effects. The platform of the system-level modelingisGoldSim [GoldSim, 2006]. The application of the system model is focusedon evaluating the feasibility of carbon sequestration with enhanced gasrecovery (CSEGR) in the Rio Vista region of California. The reservoirsimulations are performed using a special module of the TOUGH2 simulator,EOS7C, for multicomponent gas mixtures of methane and CO2 or methane andnitrogen. …
Date: April 24, 2006
Creator: Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan & Bodvarsson, Gudmundur S.
System: The UNT Digital Library
Sigma: Web Retrieval Interface for Nuclear Reaction Data (open access)

Sigma: Web Retrieval Interface for Nuclear Reaction Data

The authors present Sigma, a Web-rich application which provides user-friendly access in processing and plotting of the evaluated and experimental nuclear reaction data stored in the ENDF-6 and EXFOR formats. The main interface includes browsing using a periodic table and a directory tree, basic and advanced search capabilities, interactive plots of cross sections, angular distributions and spectra, comparisons between evaluated and experimental data, computations between different cross section sets. Interactive energy-angle, neutron cross section uncertainties plots and visualization of covariance matrices are under development. Sigma is publicly available at the National Nuclear Data Center website at www.nndc.bnl.gov/sigma.
Date: June 24, 2008
Creator: Pritychenko,B. & Sonzogni, A.A.
System: The UNT Digital Library
Long-range and head-on beam-beam compensation studies in RHIC with lessons for the LHC (open access)

Long-range and head-on beam-beam compensation studies in RHIC with lessons for the LHC

Long-range as well as head-on beam-beam effects are expected to limit the LHC performance with design parameters. They are also important consideration for the LHC upgrades. To mitigate long-range effects current carrying wires parallel to the beam were proposed. Two such wires are installed in RHIC where they allow studying the effect of strong long-range beam-beam effects, as well as the compensation of a single long-range interaction. The tests provide benchmark data for simulations and analytical treatments. To reduce the head-on beam-beam effect electron lenses were proposed for both RIDC and the LHC. We present the experimental long-range beam-beam program at RHIC and report on head-on compensations studies based on simulations.
Date: November 24, 2008
Creator: Fischer, W.; Luo, Y.; Abreu, N.; Calaga, R.; Montag, C.; Robert-Demolaize, G. et al.
System: The UNT Digital Library
Entropy of near-extremal black holes in AdS5 (open access)

Entropy of near-extremal black holes in AdS5

We construct the microstates of near-extremal black holes in AdS_5 x S5 as gases of defects distributed in heavy BPS operators in the dual SU(N) Yang-Mills theory. These defects describe open strings on spherical D3-branes in the S5, and we show that they dominate the entropy by directly enumerating them and comparing the results with a partition sum calculation. We display new decoupling limits in which the field theory of the lightest open strings on the D-branes becomes dual to a near-horizon region of the black hole geometry. In the single-charge black hole we find evidence for an infrared duality between SU(N) Yang-Mills theories that exchanges the rank of the gauge group with an R-charge. In the two-charge case (where pairs of branes intersect on a line), the decoupled geometry includes an AdS_3 factor with a two-dimensional CFT dual. The degeneracy in this CFT accounts for the black hole entropy. In the three-charge case (where triples of branes intersect at a point), the decoupled geometry contains an AdS_2 factor. Below a certain critical mass, the two-charge system displays solutions with naked timelike singularities even though they do not violate a BPS bound. We suggest a string theoretic resolution of these …
Date: July 24, 2007
Creator: Simon, Joan; Balasubramanian, Vijay; de Boer, Jan; Jejjala, Vishnu & Simon, Joan
System: The UNT Digital Library
Deinococcus geothermalis: The Pool of Extreme Radiation Resistance Genes Shrinks (open access)

Deinococcus geothermalis: The Pool of Extreme Radiation Resistance Genes Shrinks

Bacteria of the genus Deinococcus are extremely resistant to ionizing radiation (IR), ultraviolet light (UV) and desiccation. The mesophile Deinococcus radiodurans was the first member of this group whose genome was completely sequenced. Analysis of the genome sequence of D. radiodurans, however, failed to identify unique DNA repair systems. To further delineate the genes underlying the resistance phenotypes, we report the whole-genome sequence of a second Deinococcus species, the thermophile Deinococcus geothermalis, which at itsoptimal growth temperature is as resistant to IR, UV and desiccation as D. radiodurans, and a comparative analysis of the two Deinococcus genomes. Many D. radiodurans genes previously implicated in resistance, but for which no sensitive phenotype was observed upon disruption, are absent in D. geothermalis. In contrast, most D. radiodurans genes whose mutants displayed a radiation-sensitive phenotype in D. radiodurans are conserved in D. geothermalis. Supporting the existence of a Deinococcus radiation response regulon, a common palindromic DNA motif was identified in a conserved set of genes associated with resistance, and a dedicated transcriptional regulator was predicted. We present the case that these two species evolved essentially the same diverse set of gene families, and that the extreme stress-resistance phenotypes of the Deinococcus lineage emerged …
Date: July 24, 2007
Creator: Makarova, Kira S.; Omelchenko, Marina V.; Gaidamakova, Elena K.; Matrosova, Vera Y.; Vasilenko, Alexander; Zhai, Min et al.
System: The UNT Digital Library
Quantifying the Diffusion of a Fluid through Membranes by RemoteDetection MRI (open access)

Quantifying the Diffusion of a Fluid through Membranes by RemoteDetection MRI

We present a method to measure self-diffusion acrossmembranes without the need for concentration or pressure gradients.Hyperpolarized xenon in combination with remote detection of NMR allowsthe measurement of membrane permeation, even in the gas phase. Theresulting images allow quantification of the amount of fluid diffusedthrough the membrane, and represent an alternative, potentially moreprecise way of measuring a membrane diffusion coefficient. The use ofremote detection of NMR allows for non-invasive signal encoding coupledto sensitive detection, making this approach ideal for the study ofdiffusion in intact devices such as fuel cells or separationsystems.
Date: October 24, 2006
Creator: Telkki, Ville-Veikko; Hilty, Christian; Garcia, Sandra; Harel,Elad & Pines, Alexander
System: The UNT Digital Library
Where Water is Oxidized to Dioxygen: Structure of the Photosynthetic Mn4Ca Cluster from X-ray Spectroscopy (open access)

Where Water is Oxidized to Dioxygen: Structure of the Photosynthetic Mn4Ca Cluster from X-ray Spectroscopy

Light-driven oxidation of water to dioxygen in plants, algae and cyanobacteria iscatalyzed within photosystem II (PS II) by a Mn4Ca cluster. Although the cluster has been studied by many different methods, the structure and the mechanism have remained elusive. X-ray absorption and emission spectroscopy and EXAFS studies have been particularly useful in probing the electronic and geometric structure, and the mechanism of the water oxidation reaction. Recent progress, reviewed here, includes polarized X-ray absorption spectroscopy measurements of PS II single crystals. Analysis of those results has constrained the Mn4Ca cluster geometry to a setof three similar high-resolution structures. The structure of the cluster from the present study is unlike either the 3.0 or 3.5 Angstrom-resolution X-ray structures or other previously proposed models. The differences between the models derived from X-rayspectroscopy and crystallography are predominantly because of damage to the Mn4Ca cluster by X-rays under the conditions used for structure determination by X-ray crystallography. X-ray spectroscopy studies are also used for studying the changes in the structure of the Mn4Ca catalytic center as it cycles through the five intermediate states known as the Si-states (i=0-4). The electronic structure of the Mn4Ca cluster has been studied more recently using resonant inelastic X-ray …
Date: October 24, 2007
Creator: Yano, Junko; Yano, Junko & Yachandra, Vittal K.
System: The UNT Digital Library
Emittance and Current of Electrons Trapped in a Plasma Wakefield Accelerator (open access)

Emittance and Current of Electrons Trapped in a Plasma Wakefield Accelerator

In recent experiments plasma electrons became trapped in a plasma wakefield accelerator (PWFA). The transverse size of these trapped electrons on a downstream diagnostic yields an upper limit measurement of transverse normalized emittance divided by peak current, {var_epsilon}{sub N,x}/I. The lowest upper limit for {var_epsilon}{sub N,x}/I measured in the experiment is 1.3 {center_dot} 10{sup -10} m/A.
Date: September 24, 2008
Creator: Kirby, N.; Blumenfeld, I.; Clayton, C. E.; Decker, F. J.; Hogan, M. J.; Huang, C. et al.
System: The UNT Digital Library
A High Repetition Rate VUV-Soft X-Ray FEL Concept (open access)

A High Repetition Rate VUV-Soft X-Ray FEL Concept

We report on design studies for a seeded FEL light source that is responsive to the scientific needs of the future. The FEL process increases radiation flux by several orders of magnitude above existing incoherent sources, and offers the additional enhancements attainable by optical manipulations of the electron beam: control of the temporal duration and bandwidth of the coherent output, reduced gain length in the FEL, utilization of harmonics to attain shorter wavelengths, and precise synchronization of the x-ray pulse with seed laser systems. We describe an FEL facility concept based on a high repetition rate RF photocathode gun, that would allow simultaneous operation of multiple independent FEL's, each producing high average brightness, tunable over the VUV-soft x-ray range, and each with individual performance characteristics determined by the configuration of the FEL. SASE, enhanced-SASE (ESASE), seeded, harmonic generation, and other configurations making use of optical manipulations of the electron beam may be employed, providing a wide range of photon beam properties to meet varied user demands.
Date: June 24, 2007
Creator: Corlett, J.; Byrd, J.; Fawley, W. M.; Gullans, M.; Li, D.; Lidia, S. M. et al.
System: The UNT Digital Library
Does complex absorption behavior leading to conditioning and damage in KDP/DKDP reflect the electronic structure of initiators? (open access)

Does complex absorption behavior leading to conditioning and damage in KDP/DKDP reflect the electronic structure of initiators?

Currently, most of our thinking about the defects responsible for initiating laser damage considers them as featureless absorbers. However, an increasing body of evidence, particularly involving multi-wavelength irradiation, suggests electronic structure of damage initiators is important in determining both initiation and conditioning behaviors in KDP. The effective absorption coefficient of energy under multi-wavelength irradiation cannot be accounted for by a structureless absorber, but is consistent with an initiator with a multi-level structure. We outline the evidence and assess the ability of such a simple multi-level model to explain these and other experimentally observed behaviors.
Date: October 24, 2007
Creator: Feit, M D; DeMange, P P; Negres, R A; Rubenchik, A M & Demos, S G
System: The UNT Digital Library
Measurement of the tau- to eta pi-pi+pi-nu tau Branching Fraction and a Search for a Second-Class Current in the tau- to eta'(958)pi-nu tau Decay (open access)

Measurement of the tau- to eta pi-pi+pi-nu tau Branching Fraction and a Search for a Second-Class Current in the tau- to eta'(958)pi-nu tau Decay

The {tau}{sup -} {yields} {eta}{pi}{sup -}{pi}{sup +}{pi}{sup -}{nu}{sub {tau}} decay with the {eta} {yields} {gamma}{gamma} mode is studied using 384 fb{sup -1} of data collected by the BABAR detector. The branching fraction is measured to be (1.60 {+-} 0.05 {+-} 0.11) x 10{sup -4}. It is found that {tau}{sup -} {yields} f{sub 1}(1285){pi}{sup -} {nu}{sub {tau}} {yields} {eta}{pi}{sup -}{pi}{sup +}{pi}{sup -}{nu}{sub {tau}} is the dominant decay mode with a branching fraction of (1.11 {+-} 0.06 {+-} 0.05) x 10{sup -4}. The first error on the branching fractions is statistical and the second systematic. In addition, a 90% confidence level upper limit on the branching fraction of the {tau}{sup -} {yields} {eta}{prime}(958){pi}{sup -}{nu}{sub {tau}} decay is measured to be 7.2 x 10{sup -6}. This last decay proceeds through a second-class current and is expected to be forbidden in the limit of isospin symmetry.
Date: March 24, 2008
Creator: Aubert, B.; Bona, M.; Boutigny, D.; Karyotakis, Y.; Lees, J. P.; Poireau, V. et al.
System: The UNT Digital Library
The impact of retail rate structures on the economics of commercial photovoltaic systems in California (open access)

The impact of retail rate structures on the economics of commercial photovoltaic systems in California

This article examines the impact of retail electricity rate design on the economic value of grid-connected photovoltaic (PV) systems, focusing on commercial customers in California. Using 15-min interval building load and PV production data from a sample of 24 actual commercial PV installations, we compare the value of the bill savings across 20 commercial-customer retail electricity rates currently offered in the state. Across all combinations of customers and rates, we find that the annual bill savings from PV, per kWh generated, ranges from $0.05 to $0.24/kWh. This sizable range in rate-reduction value reflects differences in rate structures, revenue requirements, the size of the PV system relative to building load, and customer load shape. The most significant rate design issue for the value of commercial PV is found to be the percentage of total utility bills recovered through demand charges, though a variety of other factors are also found to be of importance. The value of net metering is found to be substantial, but only when energy from commercial PV systems represents a sizable portion of annual customer load. Though the analysis presented here is specific to California, our general results demonstrate the fundamental importance of retail rate design for the …
Date: June 24, 2008
Creator: Mills, Andrew D.; Wiser, Ryan; Barbose, Galen & Golove, William
System: The UNT Digital Library
Can cross sections be accurately known for priori? (open access)

Can cross sections be accurately known for priori?

Distinct maxima and minima in the neutron total cross section uncertainties were observed in our large scale covariance calculations using a spherical optical potential. In this contribution we investigate the physical origin of this oscillating structure. Specifically, we analyze the case of neutron reactions on {sup 56}Fe, for which total cross section uncertainties are characterized by the presence of five distinct minima at 0.1, 1.1, 5, 25, and 70 MeV. To investigate their origin, we calculated total cross sections by perturbing the real volume depth V{sub v} by its expected uncertainty {+-}{Delta}V{sub v}. Inspecting the effect of this perturbation on the partial wave cross sections we found that the first minimum (at 0.1 MeV) is exclusively due to the contribution of the s-wave. On the other hand, the same analysis at 1.1 MeV showed that the minimum is the result of the interplay between s-, p-, and d-waves; namely the change in the s-wave happens to be counterbalanced by changes in the p- and d-waves. Similar considerations can be extended for the third minimum, although it can be also explained in terms of the Ramsauer effect as well as the other ones (at 25 and 70 MeV). We discuss the …
Date: June 24, 2008
Creator: Pigni, M. T.; Dietrich, F. S.; Herman, M. & Oblozinsky, P.
System: The UNT Digital Library
Depth-resolved soft x-ray photoelectron emission microscopy in nanostructures via standing-wave excited photoemission (open access)

Depth-resolved soft x-ray photoelectron emission microscopy in nanostructures via standing-wave excited photoemission

We present an extension of conventional laterally resolved soft x-ray photoelectron emission microscopy. A depth resolution along the surface normal down to a few {angstrom} can be achieved by setting up standing x-ray wave fields in a multilayer substrate. The sample is an Ag/Co/Au trilayer, whose first layer has a wedge profile, grown on a Si/MoSi2 multilayer mirror. Tuning the incident x-ray to the mirror Bragg angle we set up standing x-ray wave fields. We demonstrate the resulting depth resolution by imaging the standing wave fields as they move through the trilayer wedge structure.
Date: November 24, 2008
Creator: Kronast, F.; Ovsyannikov, R.; Kaiser, A.; Wiemann, C.; Yang, S. -H.; Locatelli, A. et al.
System: The UNT Digital Library
Energy dependence of jet transport parameter and parton saturationin quark-gluon plasma (open access)

Energy dependence of jet transport parameter and parton saturationin quark-gluon plasma

We study the evolution and saturation of the gluondistribution function in the quark-gluon plasma as probed by apropagating parton and its effect on the computation of jet quenching ortransport parameter $\hat q $. For thermal partons, the saturation scale$Q2_s$ is found to be proportional to the Debye screening mass $\mu_D2$.For hard probes, evolution at small $x=Q2_s/6ET$ leads to jet energydependence of hat q. We study this dependence for both a conformal gaugetheory in weak and strong coupling limit and for (pure gluon) QCD. Theenergy dependence can be used to extract the shear viscosity $\eta$ ofthe medium since $\eta$ can be related to the transport parameter forthermal partons in a transport description. We also derive upper boundson the transport parameter for both energetic and thermal partons. Thelater leads to a lower bound on shear viscosity-to-entropy density ratiowhich is consistent with the conjectured lower bound $\eta/s\geq 1/4\pi$.Implications on the study of jet quenching at RHIC and LHC and the bulkproperties of the dense matter are discussed.
Date: June 24, 2007
Creator: Casalderrey-Solana, Jorge & Wang, Xin-Nian
System: The UNT Digital Library
Measurement of electron clouds in large accelerators by microwave dispersion (open access)

Measurement of electron clouds in large accelerators by microwave dispersion

Clouds of low energy electrons in the vacuum beam pipes of accelerators of positively charged particle beams present a serious limitation for operation at high currents. Furthermore, it is difficult to probe their density over substantial lengths of the beam pipe. We have developed a novel technique to directly measure the electron cloud density via the phase shift induced in a TE wave transmitted over a section of the accelerator and used it to measure the average electron cloud density over a 50 m section in the positron ring of the PEP-II collider at the Stanford Linear Accelerator Center.
Date: January 24, 2008
Creator: Desantis, Stefano; De Santis, Stefano; Byrd, John M.; Sonnad, Kiran G.; Pivi, Mauro T.F.; Krasnykh, Anatoly et al.
System: The UNT Digital Library
Analyses of Oxyanion Materials by Prompt Gamma Activation Analysis (open access)

Analyses of Oxyanion Materials by Prompt Gamma Activation Analysis

Prompt gamma activation analysis (PGAA) has been used to analyze metal ion oxyanion materials that have multiple applications, including medicine, materials, catalysts, and electronics. The significance for the need for accurate, highly sensitive analyses for the materials is discussed in the context of quality control of end products containing the parent element in each material. Applications of the analytical data for input to models and theoretical calculations related to the electronic and other properties of the materials are discussed.
Date: March 24, 2008
Creator: Firestone, Richard B.; Perry, D. L.; English, G. A.; Firestone, R. B.; Leung, K. N.; Garabedian, G. et al.
System: The UNT Digital Library
Experimental Tests of Cooling: Expectations and Additional Needs (open access)

Experimental Tests of Cooling: Expectations and Additional Needs

Cooling is a critical aspect for a high-performance Neutrino Factory or a MuonCollider. For this reason, considerable effort is being put toward theexperimental verification of this technique. The international Muon IonizationCooling Experiment, MICE, was approved to operate at Rutherford AppletonLaboratory (RAL) in the UK and beam line commissioning commenced in March, 2008. The MICE collaboration comprises about 130 scientists and engineers from Asia, Europe, and the U.S. In this paper we present the motivation and goals for thisexperiment and describe its present status. MICE is scheduled for completion in2011. We will also indicate the prospects for a future 6D muon coolingexperiment and discuss its possible time schedule.
Date: September 24, 2008
Creator: Zisman, Michael S
System: The UNT Digital Library
Development of a Multi Megawatt Circulator for X Band (open access)

Development of a Multi Megawatt Circulator for X Band

Research is in progress on a TeV-scale linear collider that will operate at 5-10 times the energy of present-generation accelerators. This will require development of high power RF sources generating of 50-100 MW per source. Transmission of power at this level requires overmoded waveguide to avoid breakdown. In particular, the TE{sub 01} circular waveguide mode is currently the mode of choice for waveguide transmission at Stanford Linear Accelerator Center (SLAC) in the Multimode Delay Line Distribution System (MDLDS). A common device for protecting an RF source from reflected power is the waveguide circulator. A circulator is typically a three-port device that allows low loss power transmission from the source to the load, but diverts power coming from the load (reflected power) to a third terminated port. To achieve a low loss, matched, three port junction requires nonreciprocal behavior. This is achieved using ferrites in a static magnetic field which introduces a propagation constant dependent on RF field direction relative to the static magnetic field. Circulators are currently available at X-Band for power levels up to 1 MW in fundamental rectangular waveguide; however, the next generation of RF sources for TeV-level accelerators will require circulators in the 50-100 MW range. Clearly, …
Date: March 24, 2008
Creator: Neilson, J.; Ives, L. & Tantawi, S. G.
System: The UNT Digital Library
Testing Large CICC in Short Sample Configuration and Predicting Their Performance in Large Magnets (open access)

Testing Large CICC in Short Sample Configuration and Predicting Their Performance in Large Magnets

It is well known that large Nb3Sn Cable-in-Conduit Conductors (CICC) do not always completely utilize current carrying capacity of the strands they are made of. The modern state of theory is not accurate enough to eliminate CICC full scale testing. Measuring properties of large CICC is not a simple task due to variety of parameters that need to be controlled, like temperature, exposure of all the strands to the peak magnetic field, mass flow and particular nonuniform current distribution. The paper presents some measurement issues of CICC testing in a short sample test facility, particularly, conditions for uniform current distribution and effect of twist pitches on the critical current.
Date: August 24, 2007
Creator: Martovetsky, N. N.
System: The UNT Digital Library
The dihadron fragmentation function and its evolution (open access)

The dihadron fragmentation function and its evolution

Dihadron fragmentation functions and their evolution arestudied in the process of e+e- annihilation. Under the collinearfactorization approximation and facilitated by the cut-vertex technique,the two hadron inclusive cross section at leading order (LO) is shown tofactorize into a short distance parton cross section and a long distancedihadron fragmentation function. We provide the definition of such adihadron fragmentation function in terms of parton matrix elements andderive its DGLAP evolution equation at leading log. The evolutionequation for the non-singlet quark fragmentation function is solvednumerically with a simple ansatz for the initial condition and resultsare presented for cases of physical interest.
Date: February 24, 2004
Creator: Majumder, Abhijit & Wang, Xin-Nian
System: The UNT Digital Library
Vacuum-Ultraviolet (VUV) Photoionization of Small Methanol and Methanol-Water Clusters (open access)

Vacuum-Ultraviolet (VUV) Photoionization of Small Methanol and Methanol-Water Clusters

In this work, we report on the vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters. Clusters of methanol with water are generated via co-expansion of the gas phase constituents in a continuous supersonic jet expansion of methanol and water seeded in Ar. The resulting clusters are investigated by single photon ionization with tunable vacuum-ultraviolet synchrotron radiation and mass analyzed using reflectron mass spectrometry. Protonated methanol clusters of the form (CH3OH)nH+(n = 1-12) dominate the mass spectrum below the ionization energy of the methanol monomer. With an increase in water concentration, small amounts of mixed clusters of the form (CH3OH n(H2O)H+ (n = 2-11) are detected. The only unprotonated species observed in this work are the methanol monomer and dimer. Appearance energies are obtained from the photoionization efficiency (PIE) curves for CH3OH+, (CH3OH)2+, (CH3OH)nH+ (n = 1-9), and (CH3OH)n(H2O)H+ (n = 2-9) as a function of photon energy. With an increasein the water content in the molecular beam, there is an enhancement of photoionization intensity for the methanol dimer and protonated methanol monomer at threshold. These results are compared and contrasted to previous experimental observations.
Date: April 24, 2008
Creator: Kostko, Oleg; Belau, Leonid; Wilson, Kevin R. & Ahmed, Musahid
System: The UNT Digital Library