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CHEMICAL TRAPPING OF A PRIMARY QUANTUM CONVERSION PRODUCT INPHOTOSYNTHESIS (open access)

CHEMICAL TRAPPING OF A PRIMARY QUANTUM CONVERSION PRODUCT INPHOTOSYNTHESIS

The capacity of photosynthetic organisms to exhibit photo-induced electron paramagnetic resonance (EPR) signals has been known for over ten years. Subcellular units of photosynthetic materials, the quantasomes and the chromatophores, are capable of Hill Reaction activity, and also of exhibiting the light-induced EPR signals. This, coupled with the rapid rise and decay kinetics of these signals, suggests but does not prove that the unpaired electrons are involved in the initial electron transfer processes in the primary quantum conversion act. The identification of the species giving rise to these signals and their connection with processes of primary quantum conversion remains elusive even though such varied approaches as mutant strains, special growth conditions, extreme physical conditions, special metabolic inhibitors, etc. have been applied to this problem. In this communication the authors wish to report another method being used in an attempt to identify the species responsible for the unpaired electrons. Hoffman prepared a water soluble, stable free radical, di-tertiary-butylnitroxide (hereafter called DTBN), which is a 'vigorous free radical scavenger'. It shows a sharp, well resolved, symmetrical, three-line paramagnetic resonance spectrum that is relatively insensitive to the molecular environment. The chemistry of di-tertiary butylnitroxide has not been studied extensively. However, four distinct types …
Date: September 9, 1966
Creator: Corker, Gerald A.; Klein, Melvin P. & Calvin, Melvin.
System: The UNT Digital Library
EXPERIMENTAL PROBLEMS IN THE USE OF A POLARIZED PROTONTARGET (open access)

EXPERIMENTAL PROBLEMS IN THE USE OF A POLARIZED PROTONTARGET

I have understood my assignment as a review of some of the work done in high-energy physics with polarized proton targets and a description of some of the special problems connected with polarized targets. Most of my report will be based on the polarized target that I am most familiar with--that constructed by Jeffries, Schultz, Shapiro, and myself. This target is no longer unique; in fact, it is now somewhat old-fashioned in some respects. Other polarized proton targets are in operation at CERN, Saclay, the Rutherford Laboratory, Argonne National Laboratory, the Soviet Union, and there is a target newly in operation at the Brookhaven Laboratory. Other targets are in operation or are in the process of design or construction at a number of other places. Unfortunately, none of these targets consists of pure hydrogen. The target material most often used is made of lanthanum magnesium nitrate, LMN. About a quarter of the weight of this crystal is water; it is the protons within the water molecules that are polarized. Hydrogen constitutes only 3 percent of the weight of the crystal. This means that scattering processes on hydrogen must be distinguished kinematically from scattering processes involving the heavy elements of the …
Date: September 9, 1966
Creator: Chamberlain, Owen
System: The UNT Digital Library
Positron Scanner for Brain Tumors (open access)

Positron Scanner for Brain Tumors

It was thought that if a multi-detector device could be developed, the scanning time would be greatly shortened, with such consequent advantages as being able to work with lower dose of radiation, to obtain serial determinations, and to work with shorter-lived isotopes.
Date: October 9, 1964
Creator: Robertson, J. S. & Bozzo, S. R.
System: The UNT Digital Library
In-reactor corrosion: A paper presented at the 9th annual AEC Corrosion Symposium, Boston, Massachusetts, May 10--12, 1960 (open access)

In-reactor corrosion: A paper presented at the 9th annual AEC Corrosion Symposium, Boston, Massachusetts, May 10--12, 1960

Object of this paper is to present preliminary results of experiments in Hanford in-reactor loops to determine if exposure to neutrons will increase corrosion rates of Al alloys, Zy-2, and 304 stainless steel. Results were negligible or no corrosion.
Date: May 9, 1960
Creator: Larrick, A. P.
System: The UNT Digital Library