This is a summary report of various technical projects relating to uranium.

The following report summarizes an investigation made to determine the extent to which zirconium and zirconium alloys exhibit delayed failure as caused by a combination of absorbed hydrogen and applied stress during the period September 15, 1961, to September 14, 1962.

The following report is the first semi-annual report of a literature survey designed to investigate the uses and technology of radioisotopes in the countries of the world from 1955 to the present. This survey includes two phases: 1) involves the direct comparison of radioisotopic work in all fields in various countries as demonstrated at international conferences. 2) involves a more detailed examination and evaluation of the individual fields of interest selected previously (Phase II is also expected to comprise the bulk of the remainder of this investigation).

Quarterly report describing progress on a project to develop and evaluate high-temperature tungsten alloys. This report discusses experimentation with fabrication to improve thermal stability of tested combinations by further alloying.

Abstract: "Theoretical equations have been derived for calculating heat transfer coefficients for fluids flowing through concentric annuli for the following two cases: (A) constant and equal heat fluxes from both walls, and (B) constant, but unequal, heat fluxes from the walls, with equal wall temperatures at a given axial position along annular channel. In the derivations, the conditions of fully-established flow, and independence of physical properties with temperature variation across the flow channel, were assumed. The only geometrical parameter in this general case is the radius ratio r2/r1, and in the study it was varied from 1.0 to 10.0."

From introduction: This report discusses AEC-sponsored nuclear superheat meetings whose primary purpose is to keep the AEC contractors engaged in nuclear superheat projects abreast of the overall AEC superheat program and to provide a means for the exchange of current technical information.

Abstract. Fourteen commercial enamel frits from five different manufacturers were tested to determine their abilities to protect Nb-1% Zr during the forging cycle in the temperature range of 1800 to 2300 deg F. One frit was found to afford good coverage and protection at 2200 deg F at times up to 5 hours of exposure. Adherence was excellent during upset forging of a coated Nb--1% Zr sample heated 45 minutes at 2200 deg F. Another frit afforded good protection and coverage at 1700 deg F. (auth)

Summary: The following narrative interspersed with figures and attached reference exhibits is designed to acquaint the reader with the scheduling procedure developed at ORGDP, trial results and evaluation, subsequent improvement, further application, and use in conjunction with our IBM 7090 Computer.

From abstract: The objective of the contract is the design, development, fabrication, installation initial testing and operation of a prepackaged, air transportable nuclear power plant, the PM-1.

From introduction in Volume I: Volume II describes those programs established by the operator to assure the safe operation of the reactor.

From introduction: Volume I of the summary report contains a detailed plant description and the results of analysis of credible accidents and the associated hazards.

From introduction: "The over-all objective of the present study was to determine the nature and extent of the present study was to determine the nature and extent of the corrosion of these materials under a variety of such storage conditions and to determine the ability of several potential protective coatings to retard this corrosion."

From abstract: Project Dugout was a chemical explosive row charge cratering experiment in hard rock conducted at the AEC Nevada Test Site as part of the Plowshare Program for development of nuclear excavation technology.

This report summarizes progress on investigation into improving the technological limits of boiling water reactors, Vallecitos Boiling Water Reactor and other facilities.

Abstract: "Geodimeter surveys were made on four traverses near the east scarp of Rainier Mesa between October 27, 1967 and April 26, 1968. These measurements were made in order to determine if an changes in distance between survey stations had resulted from downslope creep of the rocks behind the scarp, or if any displacements had resulted from nuclear explosions beneath the mesa and in adjacent areas. A persistent small but possibly significant, slopeward displacement was measured along one traverse and may represent detachment of a large block; monitoring for an additional period of time is recommended."

Writing the VARI-II Program was motivated by the need for a method of analyzing the results for the Absorber Burn-Up Experiment in progress at the Vallecitos Atomic Laboratory.

A research and development program aimed at devising processes for the economical recovery of the potentially valuable long-lived fission products from Purex waste has been under wat at Hanford for several years. When this work has begun, the concentrated waste was primarily a nitric acid solution (6 to 10 M HNO3) containing the fission products and relatively small concentrations of iron, sulfate, and other corrosion products. Flowsheets based on classical separation schemes and rather similar to processes used by the Isotopes Division at the AEC's Oak Ridge operation served to separate the desired fission products from one another and from the corrosion products (1,2,3).These separation schemes employed careful step-wise pH adjustment to precipitate first the iron and then to separate the desired fission products from one another. The flowsheets were demonstrated on a pilot-plant scale with full-level plant waste. However, since the earlier work was complete, plant operations have been modified....

Thermal oxidation of graphite in flowing CO2 is being studied at 650 to 850 C, in a single-pass gas system at atmospheric pressure, by observing weight loss rates. The method is used to provide comparative data for candidate reactor graphites. The effects on oxidation rates of graphite purity, structure, coke type, graphitization temperatures and other manufacturing variables are determined. In addition, the effects of gas flow rates and graphite surface to volume ratios are observed.

Four capsules containing Al-1.65 w/o Pu and Al-12 w/o Si-1.65 w/o Pu were charged into the MTR. These capsules will be irradiated to a burnup of 80-100% of the plutonium atoms to determine the stability of the material at high exposures. An additional sixteen capsules containing 5 to 20 w/o Pu in Al and Al-Si have been prepared. Eight are awaiting reactor space and should be charged soon. The remaining eight are being recanned to increase the end gap between the core and the can. Also four capsules containing high density UO2-PuO2 pellets canned in Zircaloy are awaiting assignment of reactor space.

Technical report. From Abstract : "Paramagnetic susceptibilities of samarium structure alloys in the systems La-Gd, Nd-Y, Nd-Tm, and Ce-Y were measured from 4.2 - 300°K to determine what effect the formation of this structure has on the magnetic properties of the alloys. Susceptibility maxima were observed in the Nd-Y and Nd-Tm alloys, at 34.5 and 28.5°K, respectively. Slope changes were observed in the curve of 1/x versus T for the La-Gd alloy at 155 and 130°K, and the susceptibility of this alloy remained temperature-independent from 130-7°K. A rather poorly defined region of constant susceptibility was also observed or the Ce-Y alloy, from 26-37°K. Above these transition temperatures, the alloys obeyed the Curie-Weiss law, the susceptibilities of the La-Gd and Ce-Y samples indicating the possibility of electron transfer occurring in these cases."

Technical report. From Abstract : "The stoichiometric formula of the lower chloride in the BiCl3-Bi system has been established as Bi12Cl14 (BiCl1.167) through a dingle crystal, X-ray determination of its structure. ... Previous studies of the Bi-Cl3-Bi system are re-examined in the light of the structural results."

Technical report. Form Abstract : "Perchlorate is extracted from aqueous solution by n-butyronitrile as ferrous 1,10-phenanthroline perchlorate. The amount of perchlorate is calculated from spectrophotometric measurement of the absorbance of the extract. Moderate to large amounts of chloride, sulfate, or nitrate cause little or no interference. Chlorate is slightly extracted but the interference can be corrected."

Technical report. From Abstract : "A system has been developed to program a digital computer in much the same manner as an analog computer is programmed. Properties of a general purpose analog computer and a digital differential analyzer are combined to yield a program which employs, as input, standard data cards prepared from a diagram analogous to an analog computer diagram. The capacity of the system is much greater than that of most analog computers, making it applicable to large simulation problems. No scaling is required. The system is compatible with the Fortran symbolic language and may be used as part of a larger digital computer program. It may be applied to the more general types of boundary value problems arising in process simulation in addition to the initial value problems ordinarily solved on analog computers. It is particularly well adapted to non-linear problems and to control problems involving large transport delays. The program operates in basic machine language and, when used by itself, requires no compilation time."

From Introduction: "This paper consists essentially of a) a bibliography, b) an author index, and c) an index of the subject matter of the bibliography. While the primary objective is to focus on vacuum measurement, it was believed essential to include in the bibliography articles on vacuum technology in some measure accessory or essential to vacuum measurement. For maximum usefulness, an index of the subject matter of the references has been prepared. The abstract publications listed in the previous paragraph have been freely drawn upon in preparing the bibliography."