Recital presented at the UNT College of Music Concert Hall in partial fulfillment of the Doctor of Musical Arts (DMA) degree.

Concert presented at the UNT College of Music Concert Hall.

In recent years, roof-spraying and rooftop lawns has proved effective on roofs with poor thermal insulation. However, roofs of most buildings have insulating material to provide thermal insulation during the winter. The effects of such a practice have not previously been quantified. In this study, the authors conducted measurements of an insulated building to quantify the thermal effects of roof-spraying and rooftop lawns. Roof-spraying did not significantly reduce cooling loads, and required significant amounts of water. The conclusion is that roof spraying is not suitable for buildings with well-insulated roofs. Rooftop lawns, however, significantly stabilized the indoor temperature while additionally helping to mitigate the heat island phenomenon.

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The Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) operated a grain storage facility at Barnes, Kansas, during most of the interval 1949-1974. Carbon tetrachloride contamination was initially detected in 1986 in the town's public water supply wells. In 2006-2007, the CCC/USDA conducted a comprehensive targeted investigation at and near its former property in Barnes to characterize this contamination. Those results were reported previously (Argonne 2008a). In November 2007, the CCC/USDA began quarterly groundwater monitoring at Barnes. The monitoring is being conducted on behalf of the CCC/USDA by Argonne National Laboratory, in accord with the recommendations made in the report for the 2006-2007 targeted investigation (Argonne 2008a). The objective is to monitor the carbon tetrachloride contamination identified in the groundwater at Barnes. The sampling is presently conducted in a network of 28 individual monitoring wells (at 19 distinct locations), 2 public water supply wells, and 1 private well (Figure 1.1). The results of the 2006-2007 targeted investigation and the subsequent monitoring events in November 2007 (Argonne 2008b) and March 2008 (Argonne 2008c) demonstrated the presence of carbon tetrachloride contamination in groundwater at levels slightly exceeding the Kansas Department of Health and Environment (KDHE) Tier 2 risk-based screening level …

Part I: Electrochemical and X-ray Characterization of Solid-Oxide Electrolysis Cell Oxygen Electrodes on Electrolyte Substrates--The governing reaction mechanisms, and the electrode and electrolyte material compositions and structures, that controls the efficiency and durability of the solid oxide electrolysis cells (SOEC) need to be identified and well-understood for a significant improvement in nuclear hydrogen production using high temperature steam electrolysis. ANL conducted experimental analysis of SOEC electrolyte and electrodes to progress in this objective. Our study on the oxygen electrode focused on specifically the effect of electrode crystal structure on its electrochemical performance, and the evolution of the electronic and structural properties of the electrodes while under electrochemical conditions and high temperature. We found through electrochemical impedance spectroscopy experiments that, while different crystal orientations in La{sub 0.8}Sr{sub 0.2}MnO{sub 3+d} (LSM) show different initial performance and different electrochemical activation under SOEC conditions, a good mixed ionic electronic conductor La{sub 0.8}Sr{sub 0.2}CoO{sub 3+d} (LSC) does not seem to exhibit similar variations. Our in-situ x-ray and electrochemical measurements at the Advanced Photon Source of ANL have identified the chemical states of the A-site elements of the doped lanthanum manganite electrodes. We found that the changes in the concentration and in the electronic state of …