Adolf von Henselt (1814–1889) was one of the most renowned German pianists and composers of his day. The majority of his compositions are for the piano, one of his most successful being the set of Piano Études, Op. 2. It consists of twelve etudes, each of which is designed for developing a particular technique. Henselt's etudes are as demanding as Chopin's and Liszt's, so this pedagogical guide is designed for advanced-level students. Henselt uses many finger extensions and stretches larger than an octave, which may be difficult for smaller hands to play, but proper flexibility and relaxation should enable all students to play them. This dissertation describes the specific technique for six selected etudes and provides exercises to help students learn each technique effectively. The selected etudes—Nos. 1, 2, 3, 6, 9, and 11—were chosen to cover all three technical levels of less-advanced, advanced, and very advanced as well as a variety of musical styles and technical challenges.

The Abraham solvation model (ABSM) is an experimentally derived predictive model used to help predict various solute properties. This work covers various uses for the ABSM including predicting molar enthalpies of vaporization, predicting solvent coefficients for two new solvents (2,2,5,5-tetramethyloxolane and diethyl carbonate), predicting values for multiple new ionic liquids (ILs). This work also introduces a novel method for updating IL ABSM parameters by updating cation- and anion-specific values using linear algebra and binary matrices.

This dissertation is an examination of Divertimento for Solo Trombone and Wind Band by renowned wind band composer and conductor Jack Stamp. The result of this study is the illumination of a 21st-century composition for solo trombone and band that is made accessible for future performers, accomplished by constructing original musical exercises that are influenced by current trombone pedagogical materials that have either been edited, annotated or created by current performers and pedagogues such as Joseph Alessi, Brad Edwards and Michael Mulcahy. The piece also incorporates 20th -century American wind band influences. The careful selection of pedagogical materials serves the purpose of making this challenging solo accessible for the advanced academic trombonist and can serve as a template for surveying advanced literature of the present and future. Additionally, the pedagogical materials selected for use in this dissertation were considered based on their value in the present academic trombone repertory. Thus, this performance guide reflects on the validity of the modern trombone pedagogical literature to guide a performer's study, interpretation, and performance of a 21st-century work for solo trombone.

Children with disabilities are three to four times more likely to be abused than their non-disabled peers due to the impact of challenges related to behavior, cognition, language, social skills, and communication skills. In September of 2018, the Council for Exceptional Children (CEC) specifically noted the need to establish maltreatment prevention and response curricula and promote research and advocacy surrounding maltreatment of children with disabilities. One common curriculum recommended is Kidpower®. While Kidpower® shows promise in increasing people safety skills and offers some basic accommodations for use with disabled populations, a complete accommodation plan for deaf or hard of hearing students has not been developed. The purpose of this study was to explore how Kidpower® curriculum could be accommodated to meet the unique needs of deaf and hard of hearing students from the perspective of the deaf education community, including deaf adults, deaf education teachers, deaf education teacher preparation faculty, and parents with deaf or hard of hearing children. A combination of focus groups and interviews were utilized to review lessons and homework from the Kidpower® curriculum. Participants gave feedback on obstacles and ideas for accommodations and modifications that would mediate the challenges. Data were inductively coded and analyzed for …

A series of acene-fused porphyrins and 1,10-phenanthroline-fused porphyrins were synthesized and characterized via NMR spectroscopy and mass spectrometry. The acene-fused porphyrins exhibit unique optoelectronic properties, most notably they exhibit highly red-shifted absorption bands. The 1,10-phenanthroline-fused porphyrins are of interest for their ability to bond to as variety of metals to form chelation complexes.

This study examined the direct and indirect associations of the perceived coach-created motivational climate, athletes' implicit theory, and athletes' achievement goal orientation in relation to their levels of grit. Five hundred twenty-three Division I and II collegiate student-athletes (male = 246, female = 277) from five institutions across the south-central and southeast areas of the United States completed self-report measures assessing the previously described constructs. The measurement model fit the data well (SRMR = .055; CFI = .938; RMSEA = .067) and demonstrated invariance across the male and female athletes. The structural model demonstrated adequate fit (SRMR = .088; CFI = .918; RMSEA = .068). All direct and indirect paths in the model were significant in the expected direction, with the exception of the direct path from entity theory to ego goal orientation and the indirect path from ego-involving climate to ego goal orientation through entity theory, which were both non-significant. The mastery-incremental constructs accounted for 65% of the variance in grit. Results indicate that achievement motivation theory is an appropriate framework through which to examine grit, and achievement motivation constructs may be significant antecedents of grit's development. Limitations and future directions are discussed.

This document examines current practices and opportunities in the music performance field related to artistic citizenship, community engagement, and the field of teaching artistry. The relationship of musicians to their audiences and communities has shifted significantly in the twenty-first century, and there is an increasing need to redefine the essential skills of the professional musician. Derived from the field of teaching artistry, the concept of "activating artistry" suggests that our greatest strength and power as artists lies in drawing out individual artistic expression in other people, and it is with this power that artists as a workforce can create meaningful change in society. This intention could be manifested in many different contexts during the course of a given music career, however, developing the tool kit necessary for engaging in such work is not widely emphasized in the training of musicians. What tools can be provided for students and professionals to help them navigate both traditional and evolving career paths in music? How are bassoonists doing as a field in addressing the imperative of community engagement and artistic citizenship? How might we explore more collaborative ways to engage with our diverse communities – ways that value their perspectives? These questions guide …

The first study project is based on modeling Earth abundant 3d transition-metal methoxide complexes with potentially redox-noninnocent ligands for methane C–H bond activation to form methanol (LnM-OMe + CH4 → LnM–Me + CH3OH). Three types of complex consisting of tridentate pincer terpyridine-like ligands, and different first-row transition metals (M = Ti, V, Cr, Mn, Fe, Co, Ni, and Cu) were modeled to elucidate the reaction mechanism as well as the effect of the metal identity on the thermodynamics and kinetics of a methane activation reaction. The calculations showed that the d electron count of the metal is a more significant factor than the metal's formal charge in controlling the thermodynamics and kinetics of C–H activation. These researches suggest that late 3d-metal methoxide complexes that favor σ-bond metathesis pathways for methane activation will yield lower barriers for C–H activation, and are more profitable catalyst for future studies. Second, subsequently, on the basis of the first project, density functional theory is used to analyze methane C−H activation by neutral and cationic nickel-methoxide complexes. This study identifies strategies to further lower the barriers for methane C−H activation through evaluation of supporting ligand modifications, solvent polarity, overall charge of complex, metal identity and counterion …

We investigated the modifying effects of ultraviolet (UV) light and chemical dispersant (Corexit 9500A) on crude oil toxicity in juvenile mysids (≤ 24 h) (Americamysis bahia) and larval red drum (24-72 hpf) (Sciaenops ocellatus). These results demonstrate that crude oil toxicity significantly increases with co-exposure to environmentally relevant UV levels in both species, indicating photo-induced toxicity. This toxicity was further exacerbated by the application of chemical dispersants which increased the dissolution and concentration of oil-derived polycyclic aromatic hydrocarbons (PAHs) in test solutions. To better understand the mechanisms and initiating events of this observed photo-induced toxicity, the incidence of apoptotic cell death and global transcriptomic changes were assessed in larval red drum (24-72 hpf) following co-exposure to crude oil and UV. These results showed that co-exposure to UV and low concentrations of crude oil (<1 µg/L ∑PAH50) induced apoptotic cell death in skin and eye tissue and altered transcriptomic pathways related to visual processing and dermatological disease. To link these cellular and molecular impacts of photo-induced toxicity to apical endpoints of ecological performance, sublethal impacts to growth, metabolic rate, and visually mediated behaviors were explored in larval red drum at 2 developmental stages. These results suggested that earlier life stages may …

Oil spills are well-known adverse anthropogenic events, as they can induce severe impacts on the environment and negative economic consequences. Still, much remains to be learned regarding the effects of crude oil exposure to aquatic organisms. The objectives of this dissertation were to fill some of those knowledge gaps by examining the effects of Deepwater Horizon (DWH) crude oil exposure on teleost kidney development and function. To this end, I analyzed how these effects translate into potential osmoregulatory impairments and investigated the interactive effects of ubiquitous natural factors, such as dissolved organic carbon (DOC) and ultraviolet (UV) light, on acute crude oil toxicity. Results demonstrated that acute early life stage (ELS) crude oil exposure induces developmental defects to the primordial kidney in teleost fish (i.e., the pronephros) as evident by alterations in: (1) transcriptional responses of key genes involved in pronephros development and function and (2) alterations in pronephros morphology. Crude oil-exposed zebrafish (Danio rerio) larvae presented defective pronephric function characterized by reduced renal clearance capacity and altered filtration selectivity, factors that likely contributed to the formation of edema. Latent osmoregulatory implications of crude oil exposure during ELS were observed in red drum (Sciaenops ocellatus) larvae, which manifested reduced survival …

Identity is a powerful concept that influences behavior and health. For over thirty years, researchers in sport psychology have been using the Athletic Identity Measurement Scale (AIMS) as a research instrument providing insights into the relationships between athletic identity and health variables. While musician identity is recognized as an important factor to be investigated in relation to occupational health, there are no known robust instruments like the AIMS in music psychology research. The current study aimed to adapt and validate the athletic identity measurement scale for use with musicians. The AIMS history includes episodes of modifications for performance enhancement of the instrument that resulted in five different models. The validation process includes evaluating the psychometrical properties across all five models. The sample included student musicians and non-student musicians (N = 1040). The traditional confirmatory factor analysis (CFA) and the maximum likelihood (ML) estimation method were used. The exploratory structural equation modeling (ESEM) and robust weighted least squares (WLS) was utilized to explore a new method of estimation that was known to resolve issues consistent with the CFA and ML method. The goodness-of-fit indices of CFA and ESEM were compared. The results showed that the MIMS is a reliable and valid …

This study investigates how different guitarists introduced saxophone-like phrasing into the improvisatory and compositional vocabulary of jazz guitar through their collaborations with saxophonists. This research presents a comparative analysis of phrasing, articulation, and melodic design in solo improvisations. The mixed approach to this study includes analysis of motives, voice leading, articulation, length of phrases, melodic contour, and the execution of bebop vocabulary on the guitar. The findings are based on original transcriptions from significant recordings by guitar-saxophone pairs. These highlight the similarities between and adaptations of musical devices from saxophonists Stan Getz, Jimmy Giuffre, and Joe Lovano into the jazz guitar styles of Jimmy Raney, Jim Hall, and John Scofield. This study supports the argument that the evolution of modern jazz guitar playing is directly connected to the adaptation of saxophone-like phrasing at an improvisatory and compositional level. It also shows that the concept of style in jazz flows between different instruments' lineages. Understanding these findings provides a more complex and accurate concept of the development of style in jazz.

In light of incidents and concerns regarding the vulnerability of the global positioning system (GPS), the main purpose of the thesis is to look at alternative systems for radio guidance and to put up a serious study on such alternatives with receive and transmit antenna. There is also the need to design such antennas with multiple frequencies to offer robustness in the unlikely event that such adversarial attacks on the GPS happen. The basis on which such alternative antennas are designed is a slotted microstrip. The characteristics of the slot or slots on the microstrip are analyzed by mapping their exact locations on the patch and then noting the resultant center frequencies, the return losses, and the bandwidth. The activities associated with this also focus on the design, fabrication, validation, and characterization of one or more slotted antennas prototypes. The measurement of the antenna prototypes does confirm several frequencies that coexist to see applications, in aeronautical radionavigation, fixed-mobile radionavigation, and radiolocation. The antennas could also feature in a wide-area augmentation system (WAAS), satellite ground link system (SGLS) as well as in surveillance and precision approach radars. Some variations of the antenna are deployed in the areas of law enforcement, surveillance, …

During the Great Depression, for the first time in its history, the federal government provided relief to the unemployed and destitute through myriad New Deal agencies. This dissertation examines how "general relief" (direct or "make-work") from federal programs—primarily the Emergency Relief and Construction Act (ERCA) and Federal Emergency Relief Administration (FERA)—was acquired and administered by the government of Texas through state administrative agencies. These agencies included the Chambers of Commerce (1932-1933), Unofficial Texas Relief Commission (1933), Texas Rehabilitation and Relief Commission (1933), Official Texas Relief Commission (1933-1934), Texas Relief Commission Division of the State Board of Control (1934), and the Department of Public Welfare (1939). Overall, the effective administration of general relief in the Lone Star State was undermined by a political ideology that persisted from, and was embodied by, the "Redeemer" Constitution of 1876.

The purpose of this study was to explore adolescent self-views of singing ability through both implicit theories and self-concept meaning systems. A secondary purpose of this study was to examine these self-views specifically in the context of a choral hierarchy. Using a researcher-designed survey instrument, I gathered data from middle- and high-school students currently enrolled in a choir program organized in a hierarchical structure. I analyzed descriptive statistics of survey responses to items designed to measure implicit theories of singing ability, singing self-concept, and goal orientation. I also examined differences among participants by ensemble placement in implicit theory and self-concept scores, correlation between implicit theory and self-concept, and whether implicit theory, self-concept, goal orientation, or current enrollment could predict future enrollment decisions. In addition to these quantitative measures, I coded open-ended responses to two failure scenarios and examined participant responses by ensemble and gender. Both implicit theory and self-concept scores were higher for participants at the top of the choral hierarchy than at the bottom. Open-ended responses, however, did not align with the implicit theory scale and a number of students presented a false growth mindset. Open-ended responses also indicated that failure scenarios were likely to result in an altered …

Seminaries in the United States have for more than two centuries sought to equip ministerial leaders for service within the community of faith. And yet these institutions have traditionally been the focus of very little quantitative research. This lack of data is particularly noteworthy given the existential crises many seminaries currently face, especially regarding their flagship Master of Divinity (MDiv) programs. Among seminary leadership, a common response to declining MDiv enrollment has been to decrease the length of the program, which historically required at least 90 credit hours. The purpose of this quantitative study was to explore change at the Association of Theological Schools member institutions (AMIs) between 2000–2019 through the lens of these credit-hour reductions. Longitudinal data from 113 AMIs were analyzed to examine the relationship between a variety of financial, enrollment, and institutional characteristics and the likelihood that an AMI would reduce its required MDiv credit hours. Results from an event history analysis revealed that, all else being equal, experiencing an increase in total revenues reduced an AMI's likelihood of making a reduction, while being a middle-age institution (founded 1870–1959) and having a higher percentage of peer institutions that made a change increased the likelihood of making a …

This research study examined the implementation of an extended reality (XR) lab on a community college campus to facilitate student and faculty access to immersive learning resources. The study, conducted during one skills day, involved 46 students and was designed to understand if integrating immersive VR into emergency medical technician (EMT) education could enhance learner confidence and motivation, develop problem-solving and analytical thinking skills, and thus connecting the classroom learning with real-world application. The majority of participants reported increased motivation and engagement, alongside improvements in learning outcomes like knowledge retention and skill development. Applying the unified theory of acceptance and use of technology (UTAUT) model revealed performance expectancy, effort expectancy, social influence, and facilitating conditions as key determinants of VR adoption in EMT education. While no significant overall performance enhancement was observed, VR training showed potential to boost motivation, confidence, and specific performance aspects. Furthermore, student perceptions towards VR in EMT education were largely positive, thereby suggesting its utility in immersive scenario training, skill acquisition in a risk-free environment, enhancing learner engagement, and real-world situational preparedness. VR demonstrated promise as a transformative tool in EMT education, necessitating further research to fully exploit its potential in diverse learning environments.

This dissertation is organized in a traditional format while including three essays that address specific research questions. Essay 1 examined the relationship between physical activity and community engagement and their effect on mental well-being among older men and women. Data from National Health and Aging Trends Study (NHATS) from 2018 to 2020 were explored and the posited relationships were tested. This essay provides empirical support that older adults who are reasonably active and involved in the community have greater mental well-being than those who isolate themselves. Essay 2 provides insight into older adults' motivation to improve their physical activity through the use of a fitness tracker. The key finding from this study is that wearables, especially fitness trackers, can significantly facilitate increased physical activity. Essay 3 is a mixed-methods study to understand older adults' perception of the usefulness of fitness trackers and interaction with such devices. Findings suggest that to increase the adoption of fitness trackers among older adults, makers could improve the esthetics and quality of the wristband in addition to the battery life of the tracker.

A systematic development of 2D alloy catalyst with synergistic performance of high lithium polysulfide (LiPS) binding energy and efficient Li+ ion/electron conduction is presented. The first section of work found that Li+ ions can flow through the percolated ion transport pathway in polycrystalline MoS2, while Na+ and K+ ions can easily flow through the percolated 1D ion channel near the grain boundaries. An unusually high ionic conductivity of extrinsic Li+, Na+, and K+ ions in 2D MoS2 film exceeding 1 S/cm was measured that is more than two orders of magnitude higher than those of conventional solid ionic materials, including 2D ionic materials. The second section of this dissertation focus on catalyzing the transformation of LiPSs to prevent the shuttle effect during the battery cycling by synthesizing 2H (semiconducting) – 1T (metallic) mixed phase 2D Mo0.5W0.5S2 alloy on CNF paper, using two step sputtering and sulfurization method. The lithium sulfur (Li-S) battery cell assembled with the 2D Mo0.5W0.5S2/CNF/S cathode shows a high specific capacity of 1228 mAh g-1 at 0.1C and much higher cyclic stability over 4 times as compared to the pristine cathodes. The high LiPSs binding energy of catalyst efficiently prevents the shuttling effect and corrosion of Li …

Networked multi-agent systems have attracted lots of researchers to develop algorithms, techniques, and applications.A multi-agent networked system consists of more than one subsystem (agent) to cooperately solve a global problem with only local computations and communications in a fully distributed manner. These networked systems have been investigated in various different areas including signal processing, control system, and machine learning. We can see massive applications using networked systems in reality, for example, persistent surveillance, healthcare, factory manufacturing, data mining, machine learning, power system, transportation system, and many other areas. Considering the nature of those mentioned applications, traditional centralized control and optimization algorithms which require both higher communication and computational capacities are not suitable. Additionally, compared to distributed control and optimization approaches, centralized control, and optimization algorithms cannot be scaled into systems with a large number of agents, or guarantee performance and security. All of the limitations of centralized control and optimization algorithms motivate us to investigate and develop new distributed control and optimization algorithms in networked systems. Moreover, convergence rate and analysis are crucial in control and optimization literature, which motivates us to investigate how to analyze and accerlate the convergence of distributed optimization algorithms.

Compressed sensing has been proposed as a computationally efficient method to estimate the finite-dimensional signals. The idea is to develop an undersampling operator that can sample the large but finite-dimensional sparse signals with a rate much below the required Nyquist rate. In other words, considering the sparsity level of the signal, the compressed sensing samples the signal with a rate proportional to the amount of information hidden in the signal. In this dissertation, first, we employ compressed sensing for physical layer signal processing of directional millimeter-wave communication. Second, we go through the theoretical aspect of compressed sensing by running a comprehensive theoretical analysis of compressed sensing to address two main unsolved problems, (1) continuous-extension compressed sensing in locally convex space and (2) computing the optimum subspace and its dimension using the idea of equivalent topologies using Köthe sequence. In the first part of this thesis, we employ compressed sensing to address various problems in directional millimeter-wave communication. In particular, we are focusing on stochastic characteristics of the underlying channel to characterize, detect, estimate, and track angular parameters of doubly directional millimeter-wave communication. For this purpose, we employ compressed sensing in combination with other stochastic methods such as Correlation Matrix Distance …

This research adds to the literature and provides insight to practice via three essays that increase understanding about the applications and consequences of the two new approaches to the after-sales service governance: warranty contract and performance-based contracts. First, we attempted to enhance our knowledge of the modeling of the after-sales service process. In the first essay, the research papers with analytical models of after-sales services to present current trends, issues, and future research directions in the literature are classified. In the second essay, the effect of the warranty contract on the supplier's product quality improvement efforts in the context of capital goods is examined. Three sets of optimization models reveal that the existence of a warranty improves product quality. In the third essay, the performance-based contract is examined in the context of the warranty contract. The numerical experimentations conducted demonstrate that the performance-based contract is superior to the warranty contract in terms of the supplier's product quality efforts and the customer's total cost of after-sales services. The alignment of incentives based on the product performance tackles the issues presented in the traditional after-sales service contracting. Collectively, the three studies presented in this research expand our understanding of after-sales service contracts. …

This educational biography is a study of Alexander Campbell's (1788-1866) educational activities and educational thinking. These activities included the following: his creation of Buffalo Seminary; advocacy for common schools at the Virginia State Constitutional Convention of 1829-1830; participation in the Western Literary Institute and College of Professional Teachers of Cincinnati, Ohio (an organization for educators); speeches on education and common schools; founding Bethany College in present-day Bethany, West Virginia; and his discussion of educational issues in his journal, the Millennial Harbinger. The study explores how Campbell's unique early-life affected his future educational life. His early-life included intensive study under his highly educated father, home-training in Christian piety, and studying for a time at the University of Glasgow. The study focuses especially upon Campbell's involvement in the College of Teachers, his founding of Bethany College, and his major educational ideas. Some of Campbell's major educational emphases include: the need for public education; human knowledge as a national resource; moral education; lifelong learning; female education; student interest; a broad and holistic conception of education; a focus on early childhood education; utilitarian education; and the power of education. This study concludes that the overarching theme of education as power pervades Campbell's educational thinking.

This thesis targets at providing an algebraic method to indicate network behaviors. Furthermore, for a signed-average consensus problem of the system behaviors, event-triggering signed-average algorithms are designed to reduce the communication overheads. In Chapter 1, the background is introduced, and the problem is formulated. In Chapter 2, notations and basics of graph theory are presented. It is known that the terminal value of the system state is determined by the initial state, left eigenvector and right eigenvector associated with zero eigenvalue of the Laplacian matrix. Since there is no mathematical expression of right eigenvector, in Chapter 3, mathematical expression of right eigenvector is given. In Chapter 4, algebraic trait for structurally balanced property of a node is proposed. In Chapter 5, a method for characterization of collective behaviors under directed signed networks is developed. In Chapter 6, dynamic event-triggering signed-average algorithms are proposed and proved for the purpose of relieving the communication burden between agents. Chapter 7 summarizes the thesis and gives future directions.