1,3-Propanediol is one of two ingredients used in producing polytrimethylene terephthalate (PTT), a polymer which can be used in polyester and nylon applications. Researchers are developing a process to ferment biomass feedstock to malonic acid using filamentous fungi and then catalytically convert malonic acid to 1,3-propanediol.

We report preliminary results using the Lawrence Livermore National Laboratory (LLNL) Janus laser facility to generate high pressure laser-driven shocks in the 1-10 Mbar regime. These experiments address various issues, including shock steadiness, planarity, uniformity and low target preheat, important for making precision EOS measurements on a small (E < 250 J) laser facility. A brief description of the experimental techniques, target design and measurements will be given.

This paper describes electrical design criteria and first operational results a 140 kV, 1 MW average, 11 MW peak, zero-voltage-switching 20 kHz polyphase bridge, boost converter/modulator for klystron pulse application. The DC-DC converter derives the buss voltages from a standard 13.8 kV to 2300 Y substation cast-core transformer. Energy storage and filtering is provided by self-clearing metallized hazy polypropylene traction capacitors. Three ''H-Bridge'' Insulated Gate Bipolar Transistor (IGBT) switching networks are used to generate the polyphase 20 kHz transformer primary drive waveforms. The 20 kHz drive waveforms are chirped the appropriate duration to generate the desired klystron pulse width. PWM (pulse width modulation) of the individual 20 kHz pulses is utilized to provide regulated output waveforms with adaptive feedforward and feedback techniques. The boost transformer design utilizes amorphous nanocrystalline material that provides the required low core loss at design flux levels and switching frequencies. Resonant shunt-peaking is used on the transformer secondary to boost output voltage and resonate transformer leakage inductance. With the appropriate transformer leakage inductance and peaking capacitance, zero-voltage-switching of the IGBT's is attained, minimizing switching losses. A review of these design parameters and the first results of the performance characteristics will be presented.

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A vertically integrated dynamical drainage flow model is developed from conservation equations for momentum and mass in a terrain-following coordinate system. Wind fields from the dynamical model drive a Monte Carlo transport and diffusion model. The model needs only topographic data, an Eulerian or Lagrangian time scale and a surface drag coefficient for input data, and can be started with a motionless atmosphere. Model wind and diffusion predictions are compared to observations from the rugged Geysers CA area. Model winds generally agree with observed surface winds, and in some cases may give better estimates of area-averaged flow than point observations. Tracer gas concentration contours agree qualitatively with observed contours, and point predictions of maximum concentrations were correctly predicted to within factors of 2 to 10. Standard statistical tests of model skill showed that the accuracy of the predictions varied significantly from canyon to canyon in the Geysers are a. Model wind predictions are also compared to observations from the Savannah River Plant of SC which has gently rolling terrain. The model correctly simulated the slower development of drainage winds and slower deepening of the drainage layer in the Savannah River Valley, relative to the Geysers CA simulations. The SC simulations …

T*e, which is an elastic-plastic fracture parameter based on incremental theory of plasticity, was determined numerically and experimentally. The T*e integral of a tunneling crack in 2024-T3 aluminum, three point bend specimen was obtained through a hybrid analysis of moire interferometry and 3-D elastic-plastic finite element analysis. The results were verified by the good agreement between the experimentally and numerically determined T*e on the specimen surface.

The design of high power UV laser systems is limited to a large extent by the laser-initiated damage performance of transmissive fused silica optical components. The 3{omega} (i.e., the third harmonic of the primary laser frequency) damage growth mitigation LDRD effort focused on understanding and reducing the rapid growth of laser-initiated surface damage on fused silica optics. Laser-initiated damage can be discussed in terms of two key issues: damage initiated at some type of precursor and rapid damage growth of the damage due to subsequent laser pulses. The objective of the LDRD effort has been the elucidation of laser-induced damage processes in order to quantify and potentially reduce the risk of damage to fused silica surfaces. The emphasis of the first two years of this effort was the characterization and reduction of damage initiation. In spite of significant reductions in the density of damage sites on polished surfaces, statistically some amount of damage initiation should always be expected. The early effort therefore emphasized the development of testing techniques that quantified the statistical nature of damage initiation on optical surfaces. This work led to the development of an optics lifetime modeling strategy that has been adopted by the NIF project to …

This document defines the detailed NIF full system shot procedure to obtain 8% power balance as specified by the SDR002 3.2.1.04. Because the 48 quads of the NIF will be set up over a period of five years, obtaining power balance will naturally be accomplished in two steps. First, as each quad is brought online, the four laser beams within each quad will be tuned by setting the PABTS splitter ratios so that each beam will give the same laser power on target during low energy square pulse shots. During the quad activation period all of the technical tools and procedures will be developed that are needed for attaining full laser power balance. After the initial settings of the 48 PABTS, if no other tuning is done the overall NIF power balance is expected to be about <15%. In the second step, an iteration procedure with approximately 18 full laser system shots will be needed to obtain 8% power balance by tuning out the remaining systematic differences among the quads to an acceptable small difference of 2% rms (at 3{omega}). This rms difference is smaller than the expected variation of the injection energy or the amplifier gain, and is also …

In December 1998, LBNL Director Charles Shank and LLNL Director Bruce Tarter signed a Memorandum of Agreement to create the Heavy-Ion Fusion Virtual National Laboratory (HIF-VNL) with the purpose of improving the efficiency and productivity of heavy ion research through coordination of the two laboratories' efforts under one technical director. In 1999, PPPL Director Robert Goldston signed the VNL MOA for PPPL's heavy-ion fusion group to join the VNL. LBNL and LLNL each contribute about 45% of the $10.6 M/yr trilab VNL effort, and PPPL contributes currently about 10% of the VNL effort. The three labs carry out collaborative experiments, theory and simulations of a variety of intense beam scientific issues described below. The tri-lab HIF VNL program is part of the DOE Office of Fusion Energy Sciences (OFES) fusion program. A short description of the four major tasks areas of HIF-VNL research is given in the next section. The task areas are: High Current Experiment, Final Focus/Chamber Transport, Source/Injector/Low Energy Beam Transport (LEBT), and Theory/Simulation. As a result of the internal review, more detailed reviews of the designs, costs and schedules for some of the tasks have been completed, which will provide more precision in the scheduled completion dates …

Pinhole-assisted point-projection backlighting with 10{micro}m and 5 {micro}m pinholes placed a small distance of order 1 mm away from the backlighter produces images with large field of view and high resolution. Pinholes placed closely to high-power backlighter sources can vaporize and close due to x-ray driven ablation, thereby limiting the usefulness of this method. A study of streaked 1-D backlit imaging of 25 {micro}m W wires using the OMEGA laser is presented. The pinhole closure timescale for 10 {micro}m pinholes placed 0.45 mm and 1 mm distant from the backlighter is 1.3 ns and 2.2 ns, respectively. Similar timescales for 5 {micro}m pinholes is also presented. Successful wire imaging prior to pinhole closure is clearly demonstrated.

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This document reports the results of the 25 Can Verification Run. The 25 Can Verification Run was performed as outlined in Section 1.d of SRS Acceptance Criteria (Reference 1). The run was performed over the period of February 16 to the 28, 2001. Each of these cans was welded with a dummy Inner Can containing about 5 kg of surrogate material. The cans were then analyzed using radiography and metallography of samples taken at four locations of the weld. The radiographs were examined for porosity. The micrographs of the metallurgical samples were examined for porosity, cracks, and lack of fusion. The results were reviewed by Derrill Rikard (a level 3 inspector at LLNL) and by Ken Durland (a level 3 inspector from WSRC). These reviews did not find anything of concern. Therefore we are submitting these results to SRS for concurrence.

Thirty years ago, July 1, 1971, significant enhancement of negative ion emission from a gas discharge following an admixture of cesium was observed for the first time. This observation became the basis for the development of Surface Plasma Sources (SPS) for efficient production of negative ions from the interaction of plasma particles with electrodes on which adsorbed cesium reduced the surface work-function. The emission current density of negative ions increased rapidly from j {approximately} 10 mA/cm{sup 2} to 3.7 A/cm{sup 2} with a flat cathode and up to 8 A/cm{sup 2} with an optimized geometrical focusing in the long pulse SPS, and to 0.3 A/cm{sup 2} for DC SPS, recently increased up to 0.7 A/cm{sup 2}. Discovery of charge-exchange cooling helped decrease the negative ion temperature T below 1 eV, and increase brightness by many orders to a level compatible with the best proton sources, B = j/T> 1 A/cm{sup 2} eV. The combination of the SPS with charge-exchange injection improved large accelerators operation and has permitted beam accumulation up to space-charge limit and overcome this limit several times. The early SPS for accelerators have been in operation without modification for {approximately} 25 years. Advanced version of the SPS for …

A 60 TeV center of mass hadron collider is proposed, which has capability of using Superbunch beam. With Superbunch beam, the luminosity is expected to be increased by a factor of 20, compared with conventional acceleration using RF cavities. This hadron collider will be built in two stages with a low field magnet ring first and a high field magnet ring later in the same tunnel. The low field magnet rig will be built with Pipetron scheme, with 7 TeV and 7 TeV proton beams, making a 14 TeV center of mass energy high luminosity collider, using Superbunch beams. In the second stage 10 Tesla high field magnets with twin beams, will be installed. It also utilizes Superbunch beams, realizing high luminosity collider. To accelerate Superbunch beams, the barrier bucket and acceleration induction cells will be used, which are made of induction cells, utilizing FINEMET material. The core loss of the FINEMET is estimated for the whole collider is estimated. The synchrotron radiation of the collider is also estimated. Merits of Superbunch beams over RF bunched beams for the high energy experiments is described.

The scheme of a 62-TeV center of mass p-p collider with superbunch beams at Fermilab is proposed as a practical and realistically achievable future project. It will be built in two stages, using the same tunnel, first with a 2 Tesla low field magnet collider ring and later with a 10 Tesla high field magnet collider ring. Both low and high field magnets have twin bore aperture and will be installed in the tunnel with the circumference of 87.25 km. In each bore a proton beam is accelerated, using induction cavities to increase luminosity. In the first stage they install a 7 TeV accelerator ring with operating field of 2 Tesla, based on the superferric transmission-line design. This ring will be operated at a 14-TeV center of mass collider. This will have the same energy as the LHC, but it will have 15 times higher luminosity, namely 1.5 x 10{sup 35}/cm{sup 2}/sec. The estimated synchrotron radiation is negligible with this machine. The existing Fermilab accelerator system, including the 150 GeV main injector, will be used as the injector system. Its rough cost estimation and schedule for this first stage are presented. In the second stage proton beams are accelerated, also …

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The US economy is linked to efficient heavy vehicle transportation and diesel remains the fuel of choice for mass transportation of goods and services. Diesel engines remain the most reliable and cost effective system for commerce. Recent deleterious effects of diesel exhaust on health and environment have led to an urgent need for cost effective technologies that would bring about reduction in NOx and PM. CARB estimates on-road diesel mobile source will contribute almost 50% NOx and 78% PM emissions by 2010. As a result recent Federal and State mandates have been adopted to reduce emissions from diesel exhaust to 1 Gm/bhp.-Hr of NOx and 0.05 Gm/bhp-hr of PM by the year 2007. The 2007 standard is to be achieved in a stepwise manner starting with the standards for 2002 namely 2 Gm/bhp-hr NOx and 0.1 Gm/bhp-hr of PM. 2002 standards are likely to be met by most engine manufacturer by some modified form of exhaust gas recirculation (EGR) system or by employing a sophisticated engine control system. Importance of cost effective technology requirement is further exaggerated by the fact that in recent years diesel engine production have increased dramatically see figure 1 and has out stripped the gasoline engine …

The overall objective of this work is to develop preliminary operating data including expected concentration endpoints using a C waste envelope simulant. The data is to be used for the preliminary Hanford RPP flow sheet development and LAW Melter Feed Evaporator design.

The objectives of this program were: (a) to develop and demonstrate a new polymer electrolyte membrane fuel cell (PEMFC) system that operates up to 160 C temperatures and at ambient pressures for stationary power applications, and (b) to determine if the GTI-molded composite graphite bipolar separator plate could provide long term operational stability at 160 C or higher. There are many reasons that fuel cell research has been receiving much attention. Fuel cells represent environmentally friendly and efficient sources of electrical power generation that could use a variety of fuel sources. The Gas Technology Institute (GTI), formerly Institute of Gas Technology (IGT), is focused on distributed energy stationary power generation systems. Currently the preferred method for hydrogen production for stationary power systems is conversion of natural gas, which has a vast distribution system in place. However, in the conversion of natural gas into a hydrogen-rich fuel, traces of carbon monoxide are produced. Carbon monoxide present in the fuel gas will in time cumulatively poison, or passivate the active platinum catalysts used in the anodes of PEMFC's operating at temperatures of 60 to 80 C. Various fuel processors have incorporated systems to reduce the carbon monoxide to levels below 10 ppm, …

Various strategies were developed for the purpose of mitigating respirable dust experienced at facilities in the southwest corner of the 200 West Area. These strategies focused on treatment of that portion of the dust source located within the 200 West Expansion Area. Strategies included direct shielding of the facilities via establishment of a poplar windbreak and installation of an artificial windscreen; soil stabilization via seeding of herbaceous plants, soil fixatives, straw crimping, straw blankets, gravel mulches, drift fences, baled straw, and living fences; and various irrigation systems that would function both to water seeded herbs and to suppress dust.

This document is a proposed groundwater monitoring plan for the 300 Area process trenches to comply with RCRA final status, corrective action groundwater monitoring.

This document is a proposed groundwater monitoring plan for the 300 Area process trenches to comply with RCRA final status, corrective action groundwater monitoring.

The 11th Workshop will provide a forum for an informal exchange of technical and scientific information between international researchers in the photovoltaic and non-photovoltaic fields. Discussions will include the various aspects of impurities and defects in silicon--their properties, the dynamics during device processing, and their application for developing low-cost processes for manufacturing high-efficiency silicon solar cells. Sessions and panel discussions will review impurities and defects in crystalline-silicon PV, advanced cell structures, new processes and process characterization techniques, and future manufacturing demands. The workshop will emphasize some of the promising new technologies in Si solar cell fabrication that can lower PV energy costs and meet the throughput demands of the future. The three-day workshop will consist of presentations by invited speakers, followed by discussion sessions. Topics to be discussed are: Si Mechanical properties and Wafer Handling, Advanced Topics in PV Fundamentals, Gettering and Passivation, Impurities and Defects, Advanced Emitters, Crystalline Silicon Growth, and Solar Cell Processing. The workshop will also include presentations by NREL subcontractors who will review the highlights of their research during the current subcontract period. In addition, there will be two poster sessions presenting the latest research and development results. Some presentations will address recent technologies in the …

This report is on 12th International Workshop on Plant Membrane Biology