Excellent separations of metal ions can be obtained very quickly by capillary electrophoresis provided a weak complexing reagent is incorporated into the electrolyte to alter the effective mobilities of the sample ions. Indirect photometric detection is possible by also adding a UV-sensitive ion to the electrolyte. Separations are described using phthalate, tartrate, lactate or hydroxyisobutyrate as the complexing reagent. A separation of twenty-seven metal ions was achieved in only 6 min using a lactate system. A mechanism for the separation of lanthanides is proposed for the hydroxyisobutyrate system.

Control of criticality in spent nuclear fuel is necessary during all phases of fuel management during storage, transportation, and permanent disposal. Work completed to date is described. Tasks in the original proposal include: seek coverage by an approved quality control program, review documents related to criticality, attend criticality meetings and workshops, and maintain an expertise in criticality. Current work is covered by Univ. of Nevada QA plan, however, coverage under a more thorough plan will be sought in order that the results can be used during NRC licensing.

The development of a three-dimensional spatially evolving compressible mixing layer is investigated numerically using a parallel implementation of Adaptive Mesh Refinement (AMR) on a Cray C-90. The parallel implementation allowed the flow to be highly resolved while significantly reducing the wall-clock runtime. A sustained computation rate of 5.3 Gigaflops including I/O was obtained for a typical production run on a 16 processor machine. A novel mixing layer configuration is investigated where a pressure mismatch is maintained between the two inlet streams. In addition, the sonic character of the two streams is sufficiently different so that the pressure relief wave is trapped in the high speed stream. The trapped wave forces the mixing layer to form a characteristic cellular pattern. The cellular structure introduces curvature into the mixing layer that excites centrifugal instabilities characterized by large-scale counter-rotating vortical pairs embedded within the mixing layer. These are the dominant feature of the flow. Visualizations of these structures in cross-section show the pumping action which lifts dense fluid up into light gas. This effect has a strong impact on mixing enhancement as monitored by a conserved scalar formulation. Once the large-scale structures axe well established in the flow and undergo intensification from favorable …

The Fernald Environmental Management Project (FEMP) is a federal facility located near Cincinnati, Ohio that is being remediated. Operable Unit 3 (OU3) of the FEMP consists of 232 buildings and other structures that formerly housed various uranium and thorium metallurgical and chemical processes. The buildings are constructed primarily of steel and concrete, with transite siding. The structures are being decontaminated and dismantled using an interim remedial action approach. The disposition of the debris and other waste materials generated by the interim action is being addressed by the final remedial action for the operable unit. The preferred alternative is disposal of most of the material in an engineered disposal cell located on the FEMP property. This is complicated by the fact that the FEMP is located in an environmentally sensitive area and by the complex nature of the materials. The principal aquifer located beneath the site, the Great Miami Aquifer, is designated as a sole-source aquifer under the Safe Drinking Water Act. Disposal of any wastes at the FEMP must be protective of the aquifer. Dismantlement of OU3 structures will result in a very heterogeneous waste stream, both in terms of types of materials and levels of contamination. Wastes to be …

Mo{sub 5}Si{sub 3} shows promise as a high temperature creep resistant material. The high temperature oxidation resistance of Mo{sub 5}Si{sub 3} has been found to be poor, however, limiting its use in oxidizing atmospheres. Undoped Mo{sub 5}Si{sub 3} exhibits mass loss in the temperature range 800{degrees}-1200{degrees}C due to volatilization of molybdenum oxide, indicating that the silica scale does not provide a passivating layer. The addition of boron results in protective scale formation and parabolic oxidation kinetics in the temperature range of 1050{degrees}-1300{degrees}C. The oxidation rate of Mo{sub 5}Si{sub 3} was decreased by 5 orders of magnitude at 1200{degrees}C by doping with less than two weight percent boron. Boron doping eliminates catastrophic {open_quote}pest{close_quote} oxidation at 800{degrees}C. The mechanism for improved oxidation resistance of boron doped Mo{sub 5}Si{sub 3} is due to scale modification by boron.

This is the first annual report describing the activities performed under Contract No. DE-AC21-94MC31160. Task I of this contract is concerned with the analyses of HGCU ashes and descriptions of filter performance and is designed to address the problems with filter operation that are apparently linked to the characteristics of the collected ash. Task 2 of this contract includes characterization of new and used filter elements. Some of the problems observed at the Tidd and Karhula PFBC facilities include excessive filtering pressure drop, the formation of large, tenacious ash deposits within the filter vessel, and bent or broken candle filter elements. In addition to these problems related to the characteristics of PFBC ashes and the ceramic materials used to construct candle filters, our previous laboratory characterizations of gasifier and carbonizer ashes have shown that these ashes also have characteristics that might negatively affect filtration.

A sodium-layer laser guide star adaptive optics system has been developed at Lawrence Livermore National Laboratory (LLNL) for use on the 3-meter Shane telescope at Lick Observatory. The system is based on a 127-actuator continuous-surface deformable mirror, a Hartmann wavefront sensor equipped with a fast-framing low-noise CCD camera, and a pulsed solid-state-pumped dye laser tuned to the atomic sodium resonance line at 589 nm. The adaptive optics system has been tested on the Shane telescope using natural reference stars yielding up to a factor of 12 increase in image peak intensity and a factor of 6.5 reduction in image full width at half maximum (FWHM). The results are consistent with theoretical expectations. The laser guide star system has been installed and operated on the Shane telescope yielding a beam with 22 W average power at 589 nm. Based on experimental data, this laser should generate an 8th magnitude guide star at this site, and the integrated laser guide star adaptive optics system should produce images with Strehl ratios of 0.4 at 2.2 {mu}m in median seeing and 0.7 at 2.2 {mu}m in good seeing.

Performance measurement and analysis of the Advanced Photon Source (APS) beam position monitor (BPM) electronics are reported. The results indicate a BPM resolution of 0.16 {mu}m{center_dot}mA/{radical}Hz in terms of the single-bunch current and BPM bandwidth. For the miniature insertion device (ID) BPM, the result was 0.1 {mu}m{center_dot}mA/{radical}Hz. The improvement is due to the 3.6 times higher position sensitivity (in the vertical plane), which is partially canceled by the lower button signal by a factor of 2.3. The minimum single-bunch current required was roughly 0.03 mA. The long-term drift of the BPM electronics independent of the actual beam motion was measured at 2 {mu}m/hr, which settled after approximately 1.5 hours. This drift can be attributed mainly to the temperature effect. Implications of the BPM resolution limit on the global and local orbit feedback systems for the APS storage ring will also be discussed.

We present initial performance studies for Beamlet, a single-beam prototype for megajoule-class neodymium-glass laser fusion drivers using a multipass main amplifier, adaptive optics, and efficient, high-fluence conversion to the third harmonic. The Beamlet final amplifier uses Brewsters-angle glass slabs with a square 39 {times} 39 cm{sup 2} aperture and a full-aperture plasma-electrode Pockels cell switch. The laser has been tested at the fundamental wavelength over a range of pulselengths from 1-10 ns up to energies of 5.8 kJ at 10 ns and 17.3 kJ at 10 ns at a beam area of 35 {times} 35 cm{sup 2}. A 39-actuator deformable mirror system corrects the beam to a Strehl ratio of 0.4.

The PHENIX [Photon Electron New Heavy Ion Experiment] Detector is one of two large detectors presently under construction for RHIC (Relativistic Heavy Ion Collider) located at Brookhaven National Laboratory. Its primary goal is to detect a new phase of matter; the quark-gluon plasma. In order to achieve this objective, the PHENIX Detector utilizes a complex magnet subsystem which is comprised of two large magnets identified as the Central Magnet (CM) and the Muon Magnet (MM). Muon Identifier steel is also included as part of this package. The entire magnet subsystem stands over 10 meters tall and weighs in excess of 1900 tons (see Fig. 1). Magnet size alone provided many technical challenges throughout the design and fabrication of the project. In addition, interaction with foreign collaborators provided the authors with new areas to address and problems to solve. Russian collaborators would fabricate a large fraction of the steel required and Japanese collaborators would supply the first coil. This paper will describe the overall design of the PHENIX magnet subsystem and discuss its present fabrication status.

Located 35 miles West of Idaho Falls, Idaho, Argonne National Laboratory-West operates a number of nuclear facilities for the Department of Energy (DOE) through the University of Chicago. Part of the present mission of Argonne National Laboratory-West includes shutdown of the EBR-II Reactor. In order to accomplish this task the Engineering-Drafting Department is exploring cost effective methods of providing as-building services. A new technology of integrating photographic images and AUTOCAD drawing files is considered one of those methods that shows promise.

The W-259 project will provide upgrades to the 2706-T/TA Facility to comply with Federal and State of Washington environmental regulations for secondary containment and leak detection. The project provides decontamination activities supporting the environmental restoration mission and waste management operations on the Hanford Site.

An essential component to hybrid electric and electric vehicles is energy storage. A power assist device could also be important to many vehicle applications. This discussion focuses on the use of compressed gas as a system for energy storage and power in vehicle systems. Three possible vehicular applications for which these system could be used are discussed in this paper. These applications are pneumatically driven vehicles, series hybrid electric vehicles, and power boost for electric and conventional vehicles. One option for a compressed gas system is as a long duration power output device for purely pneumatic and hybrid cars. This system must provide enough power and energy to drive under normal conditions for a specified time or distance. The energy storage system for this use has the requirement that it will be highly efficient, compact, and have low mass. Use of a compressed gas energy storage as a short duration, high power output system for conventional motor vehicles could reduce engine size or reduce transient emissions. For electric vehicles this kind of system could lengthen battery life by providing battery load leveling during accelerations. The system requirements for this application are that it be compact and have low mass. The …

New nuclear safety rules are being implemented at Department of Energy sites. This paper examines the impacts of these rules as each site decides where rules will be implemented, whether implementation activities will be centralized, and how the site management and staff will be introduced to the new rules.

This project will reactivate ARCO`s idle Pru Fee lease in the Midway-Sunset field, California and conduct a continuous steamflood enhanced oil recovery demonstration aided by an integration of modern reservoir characterization and simulation methods. Cyclic steaming will be used to reestablish baseline production within the reservoir characterization phase of the project. During the demonstration phase, a continuous steamflood enhanced oil recover will be initiated to test the incremental value of this method as an alternative to cyclic steaming. Other economically marginal Class 3 reservoirs having similar producibility problems will benefit from insight gained in this project. The objectives of the project are: (1) to return the shut-in portion of the reservoir to commercial production; (2) to accurately describe the reservoir and recovery process; and (3) to convey the details of this activity to the domestic petroleum industry, especially to other producers in California, through an aggressive technology transfer program. A summary of technical progress discusses the literature compilation, assembly of digitized log suites, development of a stratigraphic framework, installation of lease production facilities, return wells to production, drill producer and observation wells, and reservoir characterization.

The US Department of Energy (DOE) is preparing to request the US Environmental Protection Agency to certify compliance with the radioactive waste disposal standards found in 40 CFR Part 191 for the Waste Isolation Pilot Plant (WIPP). The DOE will also need to demonstrate compliance with a number of other State and Federal standards and, in particular, the Land Disposal Restrictions of the Resource Conservation and Recovery Act (RCRA), 40 CFR Part 268. Demonstrating compliance with these regulations requires an assessment of the long-term performance of the WIPP disposal system. Re-evaluation and extension of past scenario development for the WIPP forms an integral part of the ongoing performance assessment (PA) process.

Mo/Si multilayers, were removed from superpolished zerodur and fused silica substrates with a dry etching process that, under suitable processing conditions, produces negligible change in either the substrate surface figure or surface roughness. Full recovery of the initial normal incidence extreme ultra-violet (EUV) reflectance response has been demonstrated on reprocessed substrates.

A 3D remote metrology system (RMS) is needed to map the interior plasma-facing components of the International Thermonuclear Experimental Reactor (ITER). The performance and survival of these components within the reactor vessel are strongly dependent on their precise alignment and positioning with respect to the plasma edge. Without proper positioning and alignment, plasma-facing surfaces will erode rapidly. A RMS design involving Coleman Research Corporation (CRC) fiber optic coherent laser radar (CLR) technology is examined in this study. The fiber optic CLR approach was selected because its high precision should be able to meet the ITER 0.1 mm accuracy requirement and because the CLR`s fiber optic implementation allows a 3D scanner to operate remotely from the RMS system`s vulnerable components. This design study has largely verified that a fiber optic CLR based RMS can survive the ITER environment and map the ITER interior at the required accuracy at a one measurement/cm{sup 2} density with a total measurement time of less than one hour from each of six or more vertically deployed measurement probes. The design approach employs a sealed and pressurized measurement probe which is attached with an umbilical spiral bellows conduit. This conduit bears fiber optic and electronic links plus …

Goal of the research was to develop and test effective, robust algorithms for general nonlinear programming (NLP) problems, particularly large or otherwise expensive NLP problems. We discuss the research conducted over the 3-year period Jan. 1990-Dec. 1992. We also describe current and future directions of our research.

Tanks 103-SY; 101-AW; 103-, 104-, and 105-AN are on the Flammable Gas Watch List. Recently, standard hydrogen monitoring system (SHMS) cabinets have been installed in the vent header of each of these tanks. Grab samples have been taken once per week, and a gas chromatograph was installed on tank 104-AN as a field test. The data that have been collected since gas monitoring began on these tanks are summarized in this document.

The results of a search for W boson pair production in p{bar p} collisions at {radical}s = 1.8 TeV with subsequent decay to dilepton (e{mu}, ee, and {mu}{mu}) channels are presented. One event is observed with an expected background of 0.56 {plus_minus} 0.13 events with an integrated luminosity of approximately 14 pb{sup {minus}1}. Assuming equal strengths for the WWZ and WW{gamma} gauge boson coupling parameters {kappa} and {lambda}, limits on the CP-conserving anomalous coupling constants are {minus}2.6 < {delta}{kappa} < 2.8 and {minus}2.1 {lambda} < 2.1 at the 95% confidence level.

The shock sensitivity of the pressed solid explosive 1,3,3-trinitroazetidine (TNAZ) was determined using the embedded manganin pressure gauge technique. At an initial pressure of 1.3 GPa, pressure buildup (exothermic reaction) was observed after ten {mu}s. At 2 GPa, TNAZ reacted rapidly and transitioned to detonation in approximately 13 mm. At 3.6 GPa, detonation occurred in less than 6 mm of shock propagation. Thus, pure TNAZ is more shock sensitive than HMX-based explosives but less shock sensitive than PETN-based explosives. The shocked TNAZ exhibited little reaction directly behind the shock front, followed by an extremely rapid reaction. This reaction caused both a detonation wave and a retonation wave in the partially decomposed TNAZ. An Ignition and Growth reactive model for TNAZ was developed to help understand this complex initiation phenomenon.

The shock sensitivity of the pressed solid explosive 2,4-dinitroimidazole (2,4-DNI) was determined using the embedded manganin pressure gauge technique. At an initial shock pressure of 2 GPa, several microseconds were required before any exothermic reaction was observed. At 4 GPa, 2,4-DNI reacted more rapidly but did not transition to detonation at the 12 mm deep gauge position. At 6 GPa, detonation occurred in less than 6 mm of shock propagation. Thus, 2,4-DNI is more shock sensitive than TATB-based explosives but is considerably less shock sensitive than HMX-based explosives. An Ignition and Growth reactive flow model for 2,4-DNI based on these gauge records showed that 2,4-DNI exhibits shock initiation characteristics similar to TATB but reacts faster. The chemical structure of 2,4-DNI suggests that it may exhibit thermal decomposition reactions similar to nitroguanine and explosives with similar ring structures, such as ANTA and NTO.

The shock sensitivity of a pressed solid explosive formulation, LX-19, containing 95.2% by weight epsilon phase 2,4,6,8,10,12-hexanitrohexaazaisowurtzitane (HNIW) and 4.8% Estane binder, was determined using the wedge test and embedded manganin pressure gauge techniques. This formulation was shown to be slightly more sensitive than LX-14, which contains 95.5% HMX and 4.5% Estane binder. The measured pressure histories for LX-19 were very similar to those obtained using several HMX-inert binder formulations. An Ignition and Growth reactive model for LX-19 was developed which differed from those for HMX-inert binder formulations only by a 25% higher hot spot growth rate.