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Studies in Hot Atom and Radiation Chemistry Progress Report: September 1972
None
Date:
September 1, 1973
Creator:
unknown
System:
The UNT Digital Library
Studies in Hot Atom and Radiation Chemistry Progress Report: September 1974
None
Date:
September 1, 1974
Creator:
unknown
System:
The UNT Digital Library
Studies in Hot Atom and Radiation Chemistry Progress Report: September 1975
None
Date:
January 1, 1975
Creator:
unknown
System:
The UNT Digital Library
Studies in Hot Atom and Radiation Chemistry Progress Report: September 1977
The reactive scattering of the reaction of the first excited state of C/sup +/ (/sup 4/P) with molecular hydrogen was studied over an energy range of 0.5 to 9.0 eV. The measurements indicate that the reaction proceeded by a direct mechanism and the final product was in the a/sup 3/pi state. The reaction of ground-state C/sup +/(/sup 2/P) with D/sub 2/ and H/sub 2/ was examined over the energy range of 2.5 eV to 28 eV. Over this energy range unambiguous identification of CD/sup +/ in the X/sup 1/sigma, a/sup 3/..pi.. and A/sup 1/..pi.. states was demonstrated. In addition the vibrational structure in the energy spectrum of CH/sup +/ and CD/sup +/ was resolved for the first time; the v = 0, 1, 2, and 3 product vibrational states were populated in the relative ratios 1.0:0.52:0.21:0.04. The vibrational band shapes permitted a determination of the rotational level distribution in the product. Careful measurements of the limiting value of the translational exoergicity (Q/sub MIN/) showed that the product state in the reaction F/sup +/(H/sub 2/,H)FH/sup +/ is /sup 2/..pi.. and that no FH/sup +/ in the /sup 2/sigma/sup +/ is formed although energetically feasible. Furthermore, it was shown that Q/sub MIN/ …
Date:
January 1, 1977
Creator:
Koski, W. S.
System:
The UNT Digital Library