A theoretical discussion of the formation and steady state kinetic behavior of metal complexes is provided.

This quarterly progress report describes four programs namely (1) The Metabolic Properties of Plutonium and Allied Materials (2) Biological studies of radiation effects, (3) Biological effects of radiation from external and internal sources, and (4) Health Physics and Chemistry. Progress for each program has been separately indexed and abstracted for the database.

Included herein is a historical record of the AAF sponsored NEPA Project during the period of October 1945, to the present time, and covers in narrative form the nature of planning leading to the implementation of the project, the establishment of the operating group and its relationship to the Manhattan District (later to become the Atomic Energy Commission) and the approach to applicable technological problems bearing on both nuclear science and aeronautical propulsion engineering aspects.

Determinations of the density and coefficient of thermal expansions of postum (Polonium 210) were attempted on 20 curies of polonium as obtained from production foils.

There is definitely a technical possibility that atomic power may gradually develop into one of the principal sources of useful power. If this expectation will prove correct, great advantages can be expected to come from the fact that the weight of the fuel is almost negligible. This feature may be particularly valuable for making power available to regions of difficult access and far from deposits of coal. It also may prove a great asset in mobile power units for example in a power plant for ship propulsion. On the negative side there are some technical limitations to be applicability of atomic power of which perhaps the most serious is the impossibility of constructing light power units; also there will be some peculiar difficulties in operating atomic plants, as for example the necessity of handling highly radioactive substances which will necessitate, at least for some considerable period, the use of specially skilled personnel for the operation. But the chief obstacle in the way of developing atomic power will be the difficulty of organizing a large scale industrial development in an internationally safe way. This presents actually problems much more difficult to solve than any of the technical developments that are necessary, …

This brief report provides recommendations on handling of radioactive materials in the laboratory

This is the University of California, Radiation Laboratory monthly progress report for May 1948. It discusses the following: (1) 184-inch Cyclotron Program; (2) 60-inch Cyclotron Program; (3) Synchrotron Program; (4) Linear Accelerator Program; (5) Experimental Physics; (6) Theoretical Physics, (7) Isotope Separation Program; (8) Chemistry Departments; (9) Medical Physics; and (10) Health Physics and Chemistry.

This report gives a short summary of each of the following programs: (1) 184-inch Cyclotron Program; (2) 60-inch Cyclotron Program; (3) Synchrotron Program; (4) Linear Accelerator Program; (5) Experimental Physics; (6) Theoretical Physics; (7) Chemistry; (8) Medical Physics; and (9) Health Physics and Chemistry.

The radioactive amino acid's synthesized from C{sup 14}O{sub 2} by green algae both in the light and in the dark after CO{sub 2}-free preillumination have been separated and identified using paper chromatography and radioautography. The radioactive amino acids identified were aspartic acid, alanine and smaller amounts of 3- and 4-carbon amino acids. This finding as well as the total absence of radioactive glutamic acid substantiates the mechanism for reduction of CO{sub 2} previously postulated by members of this laboratory.

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The quartz-fiber microbalances used in the Mound Laboratory operations are of the conventional Kirk-Craig type, but are housed in vacuum-tight cases which permit foil weighing by remote control.

Production of tetrafluoride for the month of April was 49,400. New equipment installed late in March operated smoothly and the production was slightly over the rated capacity of the plant. Nickel ends were welded on to the steel reactor tubes to prevent corrosion at the cover joint and possible contamination of the product with iron. The nickel ends will also save considerable repair work on the tube ends. The magnesium trays for some of the reactors are beginning to crack at the sides from frequent straightening. The trays are bent out of shape by the expansion of the product and are reshaped by hammering over a die. Some of the cracks have been repaired by welding but this is not very satisfactory because the welded trays are harder to straighten and often crack again.

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Physical and inorganic Chemistry. Studies are reported on: volatile complexes of ZrCl/sub 4/ and HfCl/sub 4/ with POCl/sub 3/; reaction of UCl/sub 4/ with LiAlH/sub 4/; preparation and properties of metal uranates and polyuranates; heats of solution of UO/sub 2/(NO/sub 3/)/sub 2/ hydrates; absorption spectra of Np in HClO/sub 4/, and separation of Np and Pu chlorides by a flow method. Process Chemistry. Extraction of Th from Mailiackrodt U raffinate was studied. Nuclear Chemistry aad Radiochemistry. Invesigations were carried out on: organic tritium; exchange reactions of U ions in solution; exchange reactions of Fe in aqueous solutions: Tc recovery from old Hanford slugs; (a,2n) cross section of Pa/sup 231/; and spontaneous fission counting U/sup 236/ and Pu/sup 238. (T.R.H) l822 Nuclear Chemistry and Radiochemistry. Measurements of the half- lives of Ac/sup 227/ and RaD(Pb/sup 210/) were continued. The effective pile neutron capture cross sections for U/sup 236/ were determined by measuring the activity of the resultant U/sup 237/ with an end window geiger counter. A study of ion chambers for tritium analysis is presented. Procedures were developed for the determination of tritium and C/sup 14/ in onganic compounds. Physical and Inorganic Chemistry. An investigation of the electrochemistry of Np in …

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The primary purpose of the corrosion work was to find a tuballoy alloy which would be sufficiently corrosion resistant to be useful for canned slugs even if some of the can were to leak. The secondary purpose was to obtain general corrosion data on tuballoy alloys.

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