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20-kW Solar Photovoltaic Flat-Panel Power System for an Uninterruptible Power-System Load in El Paso, Texas. Phase Ii. System Fabrication. Final Report October 1, 1979-May 31, 1981 (open access)

20-kW Solar Photovoltaic Flat-Panel Power System for an Uninterruptible Power-System Load in El Paso, Texas. Phase Ii. System Fabrication. Final Report October 1, 1979-May 31, 1981

The system plans, construction, integration and test, and performance evaluation are discussed for the photovoltaic power supply at the Newman Power Station in El Paso, Texas. The system consists of 64 parallel-connected panels, each panel containing nine series-connected photovoltaic modules. The system is connected, through power monitoring equipment, to an existing DC bus that supplies uninterruptible power to a computer that controls the power generating equipment. The site is described and possible environmental hazards are assessed. Site preparation and the installation of the photovoltaic panels, electrical cabling, and instrumentation subsystems are described. System testing includes initial system checkout, module performance test, control system test. A training program for operators and maintenance personnel is briefly described, including visual aids. Performance data collection and analysis are described, and actual data are compared with a computer simulation. System drawings are included. (LEW)
Date: December 1, 1981
Creator: Risser, V.V.
Object Type: Report
System: The UNT Digital Library
1978 Houston-Galveston and Texas Gulf Coast vertical-control surveys (open access)

1978 Houston-Galveston and Texas Gulf Coast vertical-control surveys

Comparisons between leveling surveys of different epochs are used to determine vertical displacement of permanent bench marks. Displacement of bench marks usually represents the movement of the surrounding area. In this report, the 1978 Houston-Galveston and Texas Gulf Coast releveling surveys are compared to the 1963, 1973, and 1976 releveling results. The changes in elevations of bench marks common to two or more epochs are tabulated and plotted in Appendix A. From these differences, contour maps were prepared for the 1963 to 1978 and 1973 to 1978 epochs in the 2/sup 0/ x 2/sup 0/ area of maximum subsidence. Annual subsidence rates computed for the 1973 to 1978 period are about 25% less in the maximum subsidence area than the rates computed for the 1963 to 1973 period.
Date: November 1, 1980
Creator: Balazs, E. I.
Object Type: Report
System: The UNT Digital Library
Active And Passive Seismic Studies of Geothermal Resources in New Mexico and Investigations of Earthquake Hazards to Geothermal Development (open access)

Active And Passive Seismic Studies of Geothermal Resources in New Mexico and Investigations of Earthquake Hazards to Geothermal Development

Seismic data were collected in southwestern New Mexico to investigate the sources of the geothermal anomalies and to investigate the potential earthquake hazards of geothermal development. No major crustal structure anomalies have been located related to known geothermal resources, and no areas of continual seismicity have been identified, which is interpreted to indicate a lack of active, or recently active crustal intrusions in southwestern New Mexico. Without a magnetic heat source, the geothermal potential of the known anomalies is probably limited to intermediate and low temperature applications (<180/sup 0/C). The lack of continual seismicity indicates low seismic hazard in the area directly related to geothermal development, although the historic and geologically recent tectonic activity should be taken into consideration during any development in the area. A model of forced groundwater convection is presented to explain the geothermal anomalies in southwestern New Mexico, which is consistent with all available geological and geophysical data from the area.
Date: January 1980
Creator: Morgan, Paul & Daggett, Paul H.
Object Type: Book
System: The UNT Digital Library
Airborne Gamma-Ray Spectrometer and Magnetometer Survey: Final Report, Volume 2B. Seattle Quadrangle (Washington) (open access)

Airborne Gamma-Ray Spectrometer and Magnetometer Survey: Final Report, Volume 2B. Seattle Quadrangle (Washington)

One uranium anomaly meets the minimum statistical requirements as defined. This anomaly is over the potassium (%K) contact area between undifferentiated Tertiary rocks and Pleistocene glacial deposits. Equivalent uranium (ppM eU), equivalent thorium (ppM eT), eU/eT, eU/eK, eT,K, and magnetic pseudo-contour maps are presented in Appendix E. Stacked profiles showing geologic strip maps along each flight-line, together with sensor data, and ancillary data are presented in Appendix F. All maps and profiles were prepared on a scale of 1:250,000, but have been reduced to 1:500,000 for presentation in this report.
Date: 1981
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Analysis of temperature-time data from 3 m drillholes at Crystal Hot Springs, Utah (open access)

Analysis of temperature-time data from 3 m drillholes at Crystal Hot Springs, Utah

A method for determining the background geothermal gradient values through the analysis of temperature measurements at multiple depths to 3 m and recorded over a time span of several days is presented. The analysis is based on the amplitude decay and phase shift of temperature waves with depth. Diurnal and other high frequency temperature variations are used to compute thermal diffusivities which in turn are used to model and remove the effect of the annual temperature wave. The analysis considers both a homogeneous half space and a two layer medium consisting of an overburden of finite thickness overlying a semi-infinite substratum. The method was tested in three holes in the Crystal Hot Springs geothermal field. Temperatures in each hole were recorded once a minute over a period of three days with a probe containing thermistors at eight different depths. Five of the thermistors were positioned at shallow depths (less than or equal to 0.5 m) to monitor diurnal and other high frequency waves and three at greater depths (greater than or equal to 1 m) to measure lower frequency variations. Since measurements were recorded at only three sites, the accuracy and reliability of the method is not fully evaluated. Potential …
Date: January 1, 1986
Creator: Howell, Jack & Chapman, David S.
Object Type: Report
System: The UNT Digital Library
Approximation of continuity of lenticular Mesaverde Group sandstone lenses utilizing close-well correlations, Piceance Basin, NW Colorado. SPE 11610 (open access)

Approximation of continuity of lenticular Mesaverde Group sandstone lenses utilizing close-well correlations, Piceance Basin, NW Colorado. SPE 11610

Mesaverde Group sandstone units in 13 closely-spaced wells in the central and southern Piceance Basin of Colorado were correlated utilizing wireline log response quantitatively and qualitatively. Based on these correlations, the environmental subdivisions of the Mesaverde Group were characterized as follows: (1) paralic (upper mixed-marine) zone, occurring in the uppermost Mesaverde Group, includes thick sandstone units which are interpreted to be regionally continuous, (2) fluvial zone, containing point-bars 20 to 30+ ft thick, is interpreted to be correlatable to a maximum of 6800 ft, and (3) paludal zone has insufficient data to adequately characterize the sand units. However, 63 percent of the units are correlatable across at least 139 ft. An approximation of the dimensional characteristics of Mesaverde sandstone units has potential applications in designing hydraulic fracturing treatments and estimating gas reserves more accurately. 15 figures, 2 tables.
Date: January 1, 1982
Creator: Peterson, Richard E. & Kohout, Julie B.
Object Type: Report
System: The UNT Digital Library
Arizona geothermal institutional handbook: Arizona geothermal commercialization planning team, January 1-December 31, 1979 (open access)

Arizona geothermal institutional handbook: Arizona geothermal commercialization planning team, January 1-December 31, 1979

The purpose of this handbook is to assist in understanding the various procedures and requirements necessary for the development of geothermal energy in the State of Arizona. It contains the names of key persons and agencies who are directly or indirectly involved in the institutional process. A detailed assessment of all agencies and the role they play in geothermal energy development is provided. The handbook is divided into four sections: State and Local rules and regulations, the Federal rules and regulations, references, and a technical bibliography. (MHR)
Date: May 1, 1980
Creator: Malysa, L.
Object Type: Report
System: The UNT Digital Library
Assessment of advanced coal-gasification processes. [AVCO high throughput gasification in process; Bell High Mass Flux process; CS-R process; and Exxon Gasification process] (open access)

Assessment of advanced coal-gasification processes. [AVCO high throughput gasification in process; Bell High Mass Flux process; CS-R process; and Exxon Gasification process]

This report represents a technical assessment of the following advanced coal gasification processes: AVCO High Throughput Gasification (HTG) Process, Bell Single - Stage High Mass Flux (HMF) Process, Cities Service/Rockwell (CS/R) Hydrogasification Process, and the Exxon Catalytic Coal Gasification (CCG) Process. Each process is evaluated for its potential to produce SNG from a bituminous coal. In addition to identifying the new technology these processes represent, key similarities/differences, strengths/weaknesses, and potential improvements to each process are identified. The AVCO HTG and the Bell HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging and syngas as the initial raw product gas. The CS/R Hydrogasifier is also SRT but is non-slagging and produces a raw gas high in methane content. The Exxon CCG gasifier is a long residence time, catalytic fluidbed reactor producing all of the raw product methane in the gasifier.
Date: June 1, 1981
Creator: McCarthy, J.; Ferrall, J.; Charng, T. & Houseman, J.
Object Type: Report
System: The UNT Digital Library
Basic data for thermal springs and wells as recorded in GEOTHERM: Arizona (open access)

Basic data for thermal springs and wells as recorded in GEOTHERM: Arizona

GEOTHERM sample file contains 314 records for Arizona. Three computer-generated indexes are found in appendices A, B, and C of this report. The indexes give one line summaries of each GEOTHERM record describing the chemistry of geothermal springs and wells in the sample file for Arizona. Each index is sorted by different variables to assist the user in locating geothermal records describing specific sites. Appendix A is sorted by the county name and the name of the source. Also given are latitude, longitude (both use decimal minutes), township, range, section, GEOTHERM record identifier, and temperature (/sup 0/C). Appendix B is sorted by county, township, range, and section. Also given are name of source, GEOTHERM record identifier, and temperature (/sup 0/C). Appendix C is first sorted into one-degree blocks by latitude, and longitude, and then by name of source. Adjacent one-degree blocks which are published as a 1:250,000 map are combined under the appropriate map name. Also given are GEOTHERM record identifier, and temperature (/sup 0/C). A bibliography is given in Appendix D.
Date: May 1, 1983
Creator: Bliss, J. D.
Object Type: Report
System: The UNT Digital Library
Basic data for thermal springs and wells as recorded in GEOTHERM: New Mexico (open access)

Basic data for thermal springs and wells as recorded in GEOTHERM: New Mexico

GEOTHERM sample file contains 251 records for New Mexico. Three computer-generated indexes are found in appendices A, B, and C of this report. The indexes give one line summaries of each GEOTHERM record describing the chemistry of geothermal springs and wells in the sample file for New Mexico. Each index is sorted by different variables to assist the user in locating geothermal records describing specific sites. Appendix A is sorted by the county name and the name of the source. Also given are latitude, longitude (both use decimal minutes), township, range, section, GEOTHERM record identifier, and temperature (/sup 0/C). Appendix B is sorted by county, township, range, and section. Also given are name of source, GEOTHERM record identifier, and temperature (/sup 0/C). Appendix C is first sorted into one-degree blocks by latitude, and longitude, and then by name of source. Adjacent one-degree blocks which are published as a 1:250,000 map are combined under the appropriate map name. Also given are GEOTHERM record identifier, and temperature (/sup 0/C). A bibliography is given in Appendix D.
Date: July 1, 1983
Creator: Bliss, J. D.
Object Type: Report
System: The UNT Digital Library
Basic data for thermal springs and wells as recorded in GEOTHERM: Wyoming (open access)

Basic data for thermal springs and wells as recorded in GEOTHERM: Wyoming

GEOTHERM sample file contains 356 records for Wyoming. Three computer-generated indexes are found in appendices A, B, and C of this report. The indexes give one line summaries of each GEOTHERM record describing the chemistry of geothermal springs and wells in the sample file for Wyoming. Each index is sorted by different variables to assist the user in locating geothermal records describing specific sites. Appendix A is sorted by the county name and the name of the source. Also given are latitude, longitude (both use decimal minutes), township, range, section, GEOTHERM record identifier, and temperature (/sup 0/C). Appendix B is sorted by county, township, range, and section. Also given are name of source, GEOTHERM record identifier, and temperature (/sup 0/C). Appendix C is first sorted into one-degree blocks by latitude, and longitude, and then by name of source. Adjacent one-degree blocks which are published as a 1:250,000 map are combined under the appropriate map name. Also given are GEOTHERM record identifier, and temperature (/sup 0/C). A bibliography is given in Appendix D.
Date: May 1, 1983
Creator: Bliss, J. D.
Object Type: Report
System: The UNT Digital Library
Calderas and mineralization: volcanic geology and mineralization in the Chinati caldera complex, Trans-Pecos Texas (open access)

Calderas and mineralization: volcanic geology and mineralization in the Chinati caldera complex, Trans-Pecos Texas

This report describes preliminary results of an ongoing study of the volcanic stratigraphy, caldera activity, and known and potential mineralization of the Chinati Mountains area of Trans-Pecos Texas. Many ore deposits are spatially associated with calderas and other volcanic centers. A genetic relationship between calderas and base and precious metal mineralization has been proposed by some and denied by others. Steven and others have demonstrated that calderas provide an important setting for mineralization in the San Juan volcanic field of Colorado. Mineralization is not found in all calderas but is apparently restricted to calderas that had complex, postsubsidence igneous activity. A comparison of volcanic setting, volcanic history, caldera evolution, and evidence of mineralization in Trans-Pecos to those of the San Juan volcanic field, a major mineral producer, indicates that Trans-Pecos Texas also could be an important mineralized region. The Chianti caldera complex in Trans-Pecos Texas contains at least two calderas that have had considerable postsubsidence activity and that display large areas of hydrothermal alteration and mineralization. Abundant prospects in Trans-Pecos and numerous producing mines immediately south of the Trans-Pecos volcanic field in Mexico are additional evidence that ore-grade deposits could occur in Texas.
Date: January 1, 1981
Creator: Duex, T. W. & Henry, C. D.
Object Type: Report
System: The UNT Digital Library
California: basic data for thermal springs and wells as recorded in GEOTHERM. Part A (open access)

California: basic data for thermal springs and wells as recorded in GEOTHERM. Part A

This GEOTHERM sample file contains 1535 records for California. Three computer-generated indexes give one line summaries of each GEOTHERM record. Each index is sorted by different variables to assist in locating geothermal records describing specific sites. 7 refs. (ACR)
Date: July 1, 1983
Creator: Bliss, J. D.
Object Type: Report
System: The UNT Digital Library
Central and eastern United States: basic data for thermal springs and wells as recorded in GEOTHERM (open access)

Central and eastern United States: basic data for thermal springs and wells as recorded in GEOTHERM

The GEOTHERM sample file contains 119 records for the central and eastern United States. The records contain data on location, sample description, analysis type, collection condition, flow rates, and the chemical and physical properties of the fluid. Stable and radioisotopic data are occasionally available. 7 refs. (ACR)
Date: June 1, 1983
Creator: Bliss, J. D.
Object Type: Report
System: The UNT Digital Library
Civilian and military missions SP-100 preliminary user requirements (open access)

Civilian and military missions SP-100 preliminary user requirements

This document defines the top level requirements of potential users of a space based nuclear electric power supply. This provides the SP-100 Project and information required to design the modular (10-1000 KWe) space power systems to meet the needs of most potential users.
Date: June 29, 1987
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Clay mineralogy and depositional history of the Frio Formation in two geopressured wells, Brazoria County, Texas (open access)

Clay mineralogy and depositional history of the Frio Formation in two geopressured wells, Brazoria County, Texas

Twenty-three shale samples ranging in depth from 5194 ft to 13,246 ft from Gulf Oil Corporation No. 2 Texas State Lease 53034 well and 33 shale samples ranging in depth from 2185 ft to 15,592 ft from General Crude Oil Company/Department of Energy No. 1 Pleasant Bayou well were examined by x-ray techniques to determine the mineralogy of the geopressured zone in the Brazoria Fairway. Both wells have similar weight-percent trends with depth for a portion of the mineralogy. Calcite decreases, and plagioclase, quartz and total clay increase slightly. Within the clays, illite in mixed-layer illite/smectite (I/S) increases and smectite in mixed-layer I/S decreases. Four minerals have distinctly different trends with depth for each well. In the No. 2 Texas State Lease 53034 well, potassium feldspar and mixed-layer I/S decrease, kaolinite increases, and discrete illite is constant. In the No. 1 Pleasant Bayou well, potassium feldspar and kaolinite are constant, mixed-layer I/S increases, and discrete illite decreases.
Date: January 1, 1982
Creator: Freed, R.L.
Object Type: Article
System: The UNT Digital Library
Colorado: basic data for thermal springs and wells as recorded in GEOTHERM (open access)

Colorado: basic data for thermal springs and wells as recorded in GEOTHERM

GEOTHERM sample file contains 225 records for Colorado. Three computer-generated indexes are found in appendices A, B, and C of this report. The indexes give one line summaries of each GEOTHERM record describing the chemistry of geothermal springs and wells in the sample file for Colorado. Each index is sorted by different variables to assist the user in locating geothermal records describing specific sites. Appendix A is sorted by the county name and the name of the source. Also given are latitude, longitude (both use decimal minutes), township, range, section, GEOTHERM record identifier, and temperature (/sup 0/C). Appendix B is sorted by county, township, range, and section. Also given are name of source, GEOTHERM record identifier, and temperature (/sup 0/C). Appendix C is first sorted into one-degree blocks by latitude, and longitude, and then by name of source. Adjacent one-degree blocks which are published as a 1:250,000 map are combined under the appropriate map name. Also given are GEOTHERM record identifier, and temperature (/sup 0/C). A bibliography is given in Appendix D.
Date: May 1, 1983
Creator: Bliss, J. D.
Object Type: Report
System: The UNT Digital Library
The comet Giacobini-Zinner magnetotail: Axial stresses and inferred near-nucleus properties (open access)

The comet Giacobini-Zinner magnetotail: Axial stresses and inferred near-nucleus properties

Utilizing the electron and magnetic field data from the ICE tail traversal of Comet Giacobini-Zinner along with the MHD equations, we have developed a steady state, stress balance model of the cometary magnetotail. With it we infer many important but unmeasured ion properties within the G-Z magnetotail both at ICE and upstream at the average point along each streamline where cometary ions are picked-up. The derived tailward ion flow speed at ICE is quite constant at approx.-20 to -30 km/sec across the entire tail. The flow velocity, ion temperature, density, and ion source rates upstream from the lobes (current sheet) at the average pickup locations are approx.-75 km/sec (approx.-12), approx.4 x 10/sup 6/ K (approx.1 x 10/sup 5/), approx.20 /cm/sup 3/ (approx.400), and approx..15 /cm/sup 3//sec (approx.3.6). Gradients in the plasma properties between these two regions are quire strong. Implications of our inferred plasma properties for the near-nucleus region and for cometary magnetotail formation are examined. 9 refs., 1 fig.
Date: October 1, 1986
Creator: McComas, D. J.; Gosling, J. T.; Bame, S. J.; Slavin, J. A.; Smith, E. J. & Steinberg, J. L.
Object Type: Article
System: The UNT Digital Library
Comparison of the Response of a Nai Scintillation Crystal With a Pressurized Ionization Chamber as a Function of Altitude, Radiation Level and RA-226 Concentration (open access)

Comparison of the Response of a Nai Scintillation Crystal With a Pressurized Ionization Chamber as a Function of Altitude, Radiation Level and RA-226 Concentration

The Grand Junction Uranium Mill Tailings Remedial Action-Radiological Survey Activities Group (UMTRA-RASA) program employs a screening method in which external exposure rates are used to determine if a property contaminated with uranium mill tailings is eligible for remedial action. Portable NaI detectors are used by survey technicians to locate contaminated areas and determine exposure rates. The exposure rate is calculated using a regression equation derived from paired measurements made with a pressurized ionization chamber (PIC) and a NaI detector. During July of 1985 extensive measurements were taken using a PIC and a NaI scintillator with both analogue and digital readout for a wide range of exposure rates and at a variety of elevations. The surface soil was sampled at most of these locations and analyzed for /sup 226/Ra. The response of the NaI detectors was shown to be highly correlated to radiation level but not to /sup 226/Ra concentration or elevation.
Date: January 1, 1986
Creator: Provencher, R.; Smith, G.; Borak, T.B. & Kearney, P.
Object Type: Article
System: The UNT Digital Library
Consultation draft: Site characterization plan overview, Deaf Smith County Site, Texas: Nuclear Waste Policy Act (Section 113) (open access)

Consultation draft: Site characterization plan overview, Deaf Smith County Site, Texas: Nuclear Waste Policy Act (Section 113)

The Department of Energy (DOE) is preparing a site characterization plan for the candidate site in Deaf Smith County, Texas. The DOE has provided, for information and review, a consultation draft of the plan to the State of Texas and the US Nuclear Regulatory Commission. The site characterization plan is a lengthy document that describes in considerable detail the program that will be conducted to characterize the geologic, hydrologic, and other conditions relevant to the suitability of the site for a repository. The overview presented here consists of brief summaries of important topics covered in the consultation draft of the site characterization plan; it is not a substitute for the site characterization plan. The arrangement of the overview is similar to that of the plan itself, with brief descriptions of the repository system - the site, the repository, and the waste package - preceding the discussion of the characterization program to be carried out at the Deaf Smith County site. It is intended primarily for the management staff of organizations involved in the DOE&#x27;s repository program or other persons who might wish to understand the general scope of the site-characterization program, the activities to be conducted, and the facilities to …
Date: January 1, 1988
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Cross-Spectral Study of the Spatial Relationships in the North Pacific Sea-Surface Temperature Anomaly Field. Report No. 23 (open access)

Cross-Spectral Study of the Spatial Relationships in the North Pacific Sea-Surface Temperature Anomaly Field. Report No. 23

Cross-spectral analysis is used to examine the dependence of the temporal covariation of sea-surface temperature (SST) anomalies at pairs of spatially separated points in the North Pacific on (1) the time scale of the variations, (2) the relative displacement of the points and (3) their location within the North Pacific basin. Spatial scales considered here range from 1000 kilometers up to the width of the basin. The study focuses on cross-spectral estimates for the interannual frequency band, 0.125-0.75 yr/sup -1/ although estimates for three other bands spanning higher frequencies are also examined.
Date: March 1, 1980
Creator: Middleton, John W.
Object Type: Report
System: The UNT Digital Library
Developing a Predation Index and Evaluating Ways to Reduce Salmonid Losses to Predation in the Columbia River Basin, Annual Progress Report August 1988-September 1989. (open access)

Developing a Predation Index and Evaluating Ways to Reduce Salmonid Losses to Predation in the Columbia River Basin, Annual Progress Report August 1988-September 1989.

We are reporting progress on the predator-prey study for the period August 28, 1988 to September 1, 1989. The purpose of this research is to evaluate the feasibility of an index for assessment of predation in various reservoirs throughout the Columbia River basin, to describe the relationships among predator-caused mortality of smolts and physical and biological variables; to examine the feasibility of developing bounty, commercial or recreational fisheries on northern squawfish (Ptychocheilus oregonesis); and to develop a plan to evaluate the efficacy of predator control fisheries. Literature searches on predator abundance indexing and factors regulating fish population dynamics have been conducted; selected references have been summarized, and compiled in a key-word bibliography format. The feasibility of various types of predator abundance indices is being assessed; existing data relevant to mark-recapture, catch per unit effort (CPUE), physical and chemical variables, and reservoir morphology have been compiled, reviewed, and summarized. In cases where sufficient data exist, preliminary implementation of predator abundance indices has been demonstrated. Field sampling in John Day Reservoir was conducted during May to August, 1989 -- to continue time series data bases on northern squawfish CPUE and growth, and to evaluate the possibility of year class strength determinations of …
Date: December 1989
Creator: Nigro, Anthony A.
Object Type: Report
System: The UNT Digital Library
Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes (open access)

Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes

We have obtained a neutron diffraction data set for Os{sub 2}(CO){sub 8}({mu}-C{sub 2}H{sub 4}). While the structure is still being solved, it is already clear that the hybridization at both of the ethylene carbons is sp{sup 3}. Our first interpretation of our liquid crystal NMR results had suggested a very acute H-C-H angle. We have also obtained {sup 13}C liquid crystal data for Os{sub 2}(CO){sub 8}({mu}-C{sub 2}H{sub 4}). Liquid crystal NMR ({sup 13}C as well as {sup 1}H) spectra have been obtained for Os(CO){sub 4}(C{sub 2}H{sub 4}) and its solution structure determined, in order to test our methodology on a molecule with a rigid structure. The normal modes of Os(CO){sub 4}({mu}-C{sub 2}H{sub 4}) and its deuterated and {sup 13}C-labelled isotopomers have been completely assigned. A partial vibrational analysis of Os{sub 2}(CO){sub 8}({mu}-propene), Os{sub 2}(CO){sub 8}(trans-2-butene), and Os{sub 2}(CO){sub 8}(1-butene) has been completed. We have prepared Os(CO){sub 4}({mu}-CH{sub 2}CH{sub 2}CH{sub 2}) and its 3,3-dideuterio analog. In the course of this work the reaction of Na{sub 2}Os(CO){sub 4} with a number of 1,3-propanediol derivatives has been examined. 1,3-Propanediol ditosylate afforded much better yields of the osmacycle than did either the ditriflate or diiodide. 2,2-Dideutero-1,3-propanediol ditosylate was used to prepare the deuterium-labelled osmacyclobutane.
Date: January 1, 1989
Creator: Norton, J.R.
Object Type: Report
System: The UNT Digital Library
Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes. Progress report, April 1, 1988--March 31, 1989 (open access)

Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes. Progress report, April 1, 1988--March 31, 1989

We have obtained a neutron diffraction data set for Os{sub 2}(CO){sub 8}({mu}-C{sub 2}H{sub 4}). While the structure is still being solved, it is already clear that the hybridization at both of the ethylene carbons is sp{sup 3}. Our first interpretation of our liquid crystal NMR results had suggested a very acute H-C-H angle. We have also obtained {sup 13}C liquid crystal data for Os{sub 2}(CO){sub 8}({mu}-C{sub 2}H{sub 4}). Liquid crystal NMR ({sup 13}C as well as {sup 1}H) spectra have been obtained for Os(CO){sub 4}(C{sub 2}H{sub 4}) and its solution structure determined, in order to test our methodology on a molecule with a rigid structure. The normal modes of Os(CO){sub 4}({mu}-C{sub 2}H{sub 4}) and its deuterated and {sup 13}C-labelled isotopomers have been completely assigned. A partial vibrational analysis of Os{sub 2}(CO){sub 8}({mu}-propene), Os{sub 2}(CO){sub 8}(trans-2-butene), and Os{sub 2}(CO){sub 8}(1-butene) has been completed. We have prepared Os(CO){sub 4}({mu}-CH{sub 2}CH{sub 2}CH{sub 2}) and its 3,3-dideuterio analog. In the course of this work the reaction of Na{sub 2}Os(CO){sub 4} with a number of 1,3-propanediol derivatives has been examined. 1,3-Propanediol ditosylate afforded much better yields of the osmacycle than did either the ditriflate or diiodide. 2,2-Dideutero-1,3-propanediol ditosylate was used to prepare the deuterium-labelled osmacyclobutane.
Date: January 1, 1989
Creator: Norton, J. R.
Object Type: Report
System: The UNT Digital Library