Many government and private industry sites that were once contaminated with radioactive and chemical wastes cannot be cleaned up enough to permit unrestricted human access. The sites will require long term management, in some cases indefinitely, leaving site owners with the challenge of protecting human health and environmental quality at these "legacy" sites. Long-term monitoring of groundwater contamination is one of the largest projected costs in the life cycle of environmental management at the Savannah River Site, the larger DOE complex, and many large federal and private sites. There is a need to optimize the performance and manage the cost of long term surveillance and monitoring at their sites. Currently, SRNL is initiating a pilot field test using alternative protocols for long term monitoring of metals and radionuclides. A key component of the approach is that monitoring efforts are focused on measurement of low cost metrics related to hydrologic and chemical conditions that control contaminant migration. The strategy combines careful monitoring of hydrologic boundary conditions with measurement of master variables such as chemical surrogates along with a smaller number of standard well analyses. In plumes contaminated with metals, master variables control the chemistry of the groundwater system, and include redox …

The aim of the work reported is to study Shewanella population genomics, and to understand the evolution, ecophysiology, and speciation of Shewanella. The tasks supporting this aim are: to study genetic and ecophysiological bases defining the core and diversification of Shewanella species; to determine gene content patterns along redox gradients; and to Investigate the evolutionary processes, patterns and mechanisms of Shewanella.

Computational models of particle dynamics often exchange solution data with discretized continuum-fields using interpolation functions. These particle methods require a series expansion of the interpolation function for two purposes: numerical analyses used to establish the models consistency and accuracy, and logical-coordinate evaluation used to locate particles within a grid. This report presents a new method of developing discrete-expansions for interpolation; they are similar to multi-variable expansions but, unlike a Taylor's series, discrete-expansions are valid throughout a discretized domain. Discrete-expansions are developed herein by parametrically integrating the interpolation function's total-differential between two particles located within separate, non-contiguous cells. Discrete-expansions are valid for numerical analyses since they acknowledge the functional dependence of interpolation and account for mapping discontinuities across cell boundaries. The use of discrete-expansions for logical-coordinate evaluation provides an algorithmically robust and computationally efficient particle localization method. Verification of this new method is demonstrated herein on a simple test problem.

Strong shock waves produced by illumination of a CH target by laser produced x-rays were driven through a copper sphere. The motion and deformation of the sphere were measured using radiographs generated by backlighting the sphere with a large area backlighter. The sphere became non-spherical after the passage of the shock, having a complicated down-stream structure. This was an instability-induced structure that was predicted by calculations. The experiment is a convenient laboratory model of the complicated interactions occurring in much larger systems such as in astrophysics in the interaction of shocks formed in the interstellar medium with various types of clouds. In particular, the experiment is a useful tool for checking the computational ability of the new generation ASCI computers, as it requires three-dimensional modeling. This experiment has shown that three dimensional calculations seem to be necessary to describe major features observed in the experiment. Any attempt to explain hydrodynamic behavior with similar instabilities must take into account these three dimensional effects.

Unidirectional solidification experiments have been carried out in organic crystals with the aim of improving our knowledge on the effects of constraints on the interface morphology and to increase our understanding of the growth of anisotropic materials. The experimental information shows that lateral constraints such as a sharp change in the cross-sectional area in the solid liquid interface path, can produce important changes in the microstructure if the interface morphology is planar, cellular or dendritic. The study of anisotropic materials cover several topics. It is first shown that slight anisotropy does not influence the dendrite tip selection criterion. This conclusion is obtained from the analysis of the relationship between tip radius and velocity for dendrites growing under the steady state condition for two different materials, CBr{sub 4} and C{sub 2}Cl{sub 6}, which have different surface energy anisotropy values. The values of the dendrite operating parameters {sigma}* are compared with the predictions of the solvability theory and the morphological stability theory. The experiments show better agreement with the latter theory. Critical experiments have been designed and carried out to find the response functions which determine the composition and temperature of the interface as a function of velocity in faceted materials. The …

These lectures are an attempt to a pedagogical introduction into the elementary concepts of chiral symmetry in nuclear physics. Effective chiral models such as the linear and nonlinear sigma model will be discussed as well as the essential ideas of chiral perturbation theory. Some applications to the physics of ultrarelativistic heavy ion collisions will be presented.

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In applications where jets propagate through energetic materials, they have been observed to become sufficiently perturbed to reduce their ability to effectively penetrate subsequent material. Analytical calculations of the jet Bernoulli flow provides an estimate of the onset and extent of such perturbations. Although two-dimensional calculations show the back-flow interaction pressure pulses, the symmetry dictates that the flow remains axial. In three dimensions the same pressure impulses can be asymmetrical if the jet is asymmetrical. The 3D calculations thus show parts of the jet having a significant component of radial velocity. On the average the downstream effects of this radial flow can be estimated and calculated by a 2D code by applying a symmetrical radial component to the jet at the appropriate position as the jet propagates through the energetic material. We have calculated the 3D propagation of a radio graphed TOW2 jet with measured variations in straightness and diameter. The resultant three-dimensional perturbations on the jet result in radial flow, which eventually tears apart the coherent jet flow. This calculated jet is compared with jet radiographs after passage through the energetic material for various material thickness and plate thicknesses. We noted that confinement due to a bounding metal plate …

The construction of the first high-pressure liquid-phase flow microreactor has been completed, and kinetic studies of reaction of dibenzothiophene have been started. Understanding of catalytic hydrodesulfurization and catalyst decay has been advanced by examination of the reaction rate of thiophene, tetrahydrothiophene, and butanethiol on Harshaw 0402T catalyst. Two batch autoclave reactors have been completely assembled behind appropriate safety barricades; satisfactory operation has been demonstrated; and quinoline hydrodenitrogenation studies are underway to demonstrate operating procedures providing quantitative, reproducible data. Quinoline rapidly hydrogenates to tetrahydroquinoline; the two compounds appear to be in thermodynamic equilibrium. The tetrahydroquinoline apparently undergoes slow hydrogenolysis of the nitrogen-containing ring giving n-propylaniline as an identified long-lived product. The reaction engineering of the pulsed microreactor system has been developed and compared to some laboratory data. The moments of the inlet and exit pulses show substantial effects from product adsorption.

Since the submission of our last Semi-annual Report, dated September 2006, the research objectives of this Co-operative Agreement shifted toward geologic sequestration of carbon dioxide. In the period September 2006-February 2007, experiments were conducted in a High-Pressure Batch Reactor (HPBR) for creating emulsions of liquid carbon dioxide (/CO{sub 2})-in-water stabilized by fine particles for geologic sequestration of CO{sub 2}. Also, emulsions were created in water of a binary mixture of liquid carbon dioxide and liquid hydrogen sulfide (/H{sub 2}S), called Acid Gas (AG). This leads to the possibility of safe disposal of AG in deep geologic formations, such as saline aquifers. The stabilizing particles included pulverized limestone (CaCO{sub 3}), unprocessed flyash, collected by an electrostatic precipitator at a local coal-fired power plant, and pulverized siderite (FeCO{sub 3}). Particle size ranged from submicron to a few micrometers. The first important finding is that /CO{sub 2} and /H{sub 2}S freely mix as a binary liquid without phase separation. The next finding is that the mixture of /CO{sub 2} and /H{sub 2}S can be emulsified in water using fine particles as emulsifying agents. Such emulsions are stable over prolonged periods, so it should not be a problem to inject an emulsion into subterranean …

Large-eddy simulation of passive scalar mixing by a fully three-dimensional round incompressible turbulent jet is evaluated using the Inertial LES methodology with multifractal subgrid-scale modeling. The Inertial LES approach involves the direct calculation of the inertial term {ovr u{sub i} u{sub j}} in the filtered incompressible Navier-Stokes equation and the scalar flux term {ovr u{sub j} {phi}} in the filtered advection-diffusion equation, using models for the subgrid velocity field u{sup sgs} and the subgrid scalar-concentration field {phi}{sup sgs}. In this work, the models are based on the multifractal structure of the subgrid enstrophy 2Q{sup sgs}(x,t) {triple_bond} {omega}{sup sgs} {center_dot} {omega}{sup sgs} and scalar-dissipation {chi}{sup sgs} (x,t) {triple_bond} D{del}{phi}{sup sgs} {center_dot} {del}{phi}{sup sgs} fields, respectively. No artificial viscosity or diffusivity constructs are applied and no explicit dealiasing is performed. Numerical errors are controlled by the application of an adaptive backscatter limiter. The present work summarizes the initial evaluation of the Inertial LES approach in the context of the round turbulent jet, including examinations of jet self-similarity and the scale-to-scale distribution of kinetic and scalar energy in the jet far field. These inquiries confirm that the Inertial LES method accurately recovers the large scale structure of this complex turbulent shear flow.

Experimental spectroscopy data of fission products have been obtained using highly automated and rapid chemical separations followed by automated spectroscopy studies of isolated fission products. These data have established the presence of only a single level with spin-parity of 1/sup +/ below 1500 keV of excitation in Z = 51 /sup 132/Sb/sub 81/. This is in contrast to the results of our studies of /sup 130/Sb and /sup 134/I. For /sup 134/I, the N = 81 isotone with Z = 53, we can characterize three 1/sup +/ levels below 1200 keV. For /sup 130/Sb/sub 79/ that has a neutron pair less than /sup 132/Sb, we can identify two 1/sup +/ levels below 1100 keV. We can account for the additional levels using the LLNL shell-model code which is based on the Lanczos tridiagonalization algorithm using an uncoupled m-scheme basis and vector manipulations. The 1g/sub 7/2/, 2d/sub 5/2/, 2d/sub 3/2/, 1h/sub 11/2/, and 3s/sub 1/2/ orbitals are available to the valence protons and the 2d/sub 5/2/, 2d/sub 3/2/, 1h/sub 11/2/, and 3s/sub 1/2/ orbitals are available to the valence neutron holes. Analysis of the wavefunctions show the dominant role of three nucleon cluster configurations in producing the increased number of states …

Identifying the symmetry of the superconducting order parameter in the recently-discovered ferrooxypnictide family of superconductors, RFeAsO{sub 1-x}F{sub y}, where R is a rare earth, is a high priority. Many of the proposed order parameters have internal {pi} phase shifts, like the d-wave order found in the cuprates, which would result in direction-dependent phase shifts in tunneling. In dense polycrystalline samples, these phase shifts in turn would result in spontaneous orbital currents and magnetization in the superconducting state. We perform scanning SQUID microscopy on a dense polycrystalline sample of NdFeAsO{sub 0.94}F{sub 0.06} with T{sub c} = 48K and find no such spontaneous currents, ruling out many of the proposed order parameters.

Some recent work has been done to look at improvements of transporting beam from the Lithium Lens to the Debuncher. This work has been done using the beamline modeling tools developed by Dave McGinnis. These tools, console application P143 and optimization code running MAD repeatedly on the Beam Physics UNIX system, were first used to match the Twiss and dispersion parameters at the end of AP2 to the Debuncher. Imaginary trims were then added to AP2 to study where additional trims could be used to help with beam control in small aperture areas.

A new version of a Constricted Plasma Source is described,characterized by all metal-ceramic construction, a linear slit exit of180 mm length, and cw-operation (typically 50 kHz) at an average power of1.5 kW. The plasma source is here operated with oxygen gas, producingstreaming plasma that contains mainly positive molecular and atomic ions,and to a much lesser degree, negative ions. The maximum total ion currentobtained was about 0.5 A. The fraction of atomic ions reached more than10 percent of all ions when the flow rate was less then 10 sccm O2,corresponding to a chamber pressure of about 0.5 Pa for the selectedpumping speed. The energy distribution functions of the different ionspecies were measured with a combinedmass spectrometer and energyanalyzer. The time-averaged distribution functions were broad and rangedfrom about 30eV to 90 eV at 200 kHz and higher frequencies, while theywere only several eV broad at 50 kHz and lower frequencies, with themaximum located at about 40 eV for the grounded anode case. This maximumwas shifted down to about 7 eV when the anode was floating, indicatingthe important role of the plasma potential for the ion energy for a givensubstrate potential. The source could be scaled to greater length and maybe useful for …

Over the past few years, our group has gained expertise at developing low-temperature solution-based synthetic pathways to complex nanoscale solids, with particular emphasis on nanocrystalline intermetallic compounds. Our synthetic capabilities are providing tools to reproducibly generate intermetallic nanostructures with simultaneous control over crystal structure, composition, and morphology. This DOE-funded project aims to expand these capabilities to intermetallic superconductors. This could represent an important addition to the tools that are available for the synthesis and processing of intermetallic superconductors, which traditionally utilize high-temperature, high-pressure, thin film, or gas-phase vacuum deposition methods. Our current knowledge of intermetallic superconductors suggests that significant enhancements could result from the inherent benefits of low-temperature solution synthesis, e.g. metastable phase formation, control over nanoscale morphology to facilitate size-dependent property studies, robust and inexpensive processability, low-temperature annealing and consolidation, and impurity incorporation (for doping, stoichiometry control, flux pinning, and improving the critical fields). Our focus is on understanding the superconducting properties as a function of synthetic route, crystal structure, crystallite size, and morphology, and developing the synthetic tools necessary to accomplish this. This research program can currently be divided into two classes of superconducting materials: intermetallics (transition metal/post transition metal) and metal carbides/borides. Both involve the development and …

Fifty nanosecond pulses of visible light have been used to produce hard, hydrogen-free diamond-like-carbon (DLC) films at irradiances between 5 x 10{sup 8} and 5 x 10{sup 10} W/cm{sup 2} The films were characterized by a number of techniques including: Raman spectroscopy, Electron Energy Loss Spectroscopy (EELS), atomic force microscopy, and spectroscopic ellipsometry. The cost for manufacturing DLC with high average power, high-pulse repetition frequency, visible light is low enough to compete with other diamond thin film production methods.

A novel prototype fission meter is being designed at National Security Technologies, LLC, using a thin uniform coating (only 1 micron thick) of {sup 10}B as a neutron converter inside a large array of thin (4 mm diameter) copper tubes. The copper tubes are only 2 mils thick, and each holds the stretched anode wire under tension and high voltage. The tubes are filled with proportional counter gas (a mixture of 90%/10% of Ar/CO{sub 2}). The tubes operate in proportional counter mode and attract mobile charged particles ({alpha}'s) created in the nuclear interaction {sup 10}B(n, {sup 4}He){sup 7}Li. However, a single tube has about 1/7th the sensitivity of a {sup 3}He tube. Modeling is required to determine if enough such tubes could be placed in a neutron detection assembly of the current size to give comparable sensitivity to {sup 3}He. Detectors lined with {sup 10}B lie between {sup 3}He and {sup 10}BF{sub 3} proportional counters and fission chambers in terms of neutron detection efficiency and gamma ray insensitivity. The mean free path of thermal neutrons in {sup 10}B is about 18 {micro}m. It takes about 60 {micro}m of {sup 10}B layer to completely stop thermal neutrons, but the energetic {alpha}-particles …

The authors present a measurement of D{sup 0}-{bar D}{sup 0} mixing parameters using the ratios of lifetimes extracted from a sample of D{sup 0} mesons produced through the process D*{sup +} {yields} D{sup 0}{pi}{sup +}, that decay to K{sup -}{pi}{sup +}, I{sup -}K{sup +}, or {pi}{sup -}{pi}{sup +}. the Cabibbo-suppressed modes K{sup -}K{sup +} and {pi}{sup -}{pi}{sup +} are compared to the Cabibbo-favored mode K{sup -}{pi}{sup +} to obtain a measurement of ycp, which in the limit of CP conservation corresponds to the mixing parameter y. The analysis is based on a data sample of 384 fb{sup -1} collected by the BABAR detector at the PEP-II asymmetric-energy e{sup +}e{sup -} collider. They obtain ycp = [1.24 {+-} 0.39(stat) {+-} 0.13(syst)]%, which is evidence of D{sup 0}-{bar D}{sup 0} mixing at the 3{sigma} level, and {Delta}Y = [-0.26 {+-} 0.36(stat) {+-} 0.08(syst)]%, where {Delta}Y constrains possible CP violation. Combining this result with a previous BABAR measurement of ycp obtained from a separate sample of D{sup 0} {yields} K{sup -}K{sup +} events, they obtain ycp = [1.03 {+-} 0.33(stat) {+-} 0.19(syst)]%.

The authors report a measurement of the branching fractions for {bar B} {yields} D{sup (*)}{pi}{ell}{sup -}{bar {nu}}{sub {ell}} decays based on 341.1 fb{sup -1} of data collected at the {Upsilon}(4S) resonance with the BABAR detector at the PEP-II e{sup +}e{sup -} storage rings. Events are tagged by fully reconstructing one of the B mesons in a hadronic decay mode. The obtain {Beta}(B{sup -} {yields} D{sup 0}{ell}{sup -}{bar {nu}}{sub {ell}}) = (2.33 {+-} 0.09{sub stat.} {+-} 0.09{sub syst.})%, {Beta}(B{sup -} {yields} D*{sup 0}{ell}{sup -}{bar {nu}}{sub {ell}}) = 5.83 {+-} 0.15{sub stat.} {+-} 0.30{sub syst.}%, {Beta}({bar B}{sup 0} {yields} D{sup +}{ell}{sup -}{bar {nu}}{sub {ell}}) = (2.21 {+-} 0.11{sub stat.} {+-} 0.12{sub syst.})% {Beta}({bar B}{sup 0} {yields} D*{sup +}{ell}{sup -}{bar {nu}}{sub {ell}}) = 5.49 {+-} 0.16{sub stat.} {+-} 0.25{sub syst.}%, {Beta}(B{sup -} {yields} D{sup +}{pi}{sup -}{ell}{sup -}{bar {nu}}{sub {ell}}) = (0.42 {+-} 0.06{sub stat.} {+-} 0.03{sub syst.})%, {Beta}(B{sup -} {yields} D*{sup +} {pi}{sup -}{ell}{sup -}{bar {nu}}{sub {ell}}) = (0.59 {+-} 0.05{sub stat.} {+-} 0.04{sub syst.})%, {Beta}({bar B}{sup 0} {yields} D{sup 0}{pi}{sup +}{ell}{sup -}{bar {nu}}{sub {ell}}) = (0.43 {+-} 0.08{sub stat.} {+-} 0.03{sub syst.})% and {Beta}({bar B}{sup 0} {yields} D*{sup 0} {pi}{sup +}{ell}{sup -}{bar {nu}}{sub {ell}}) = (0.48 {+-} 0.08{sub stat.} {+-} 0.04{sub syst.})%.

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We propose a scenario for dynamical supersymmetry breaking in string compactifications based on geometric engineering of quiver gauge theories. In particular we show that the runaway behavior of fractional branes at del Pezzo singularities can be stabilized by a flux superpotential in compact models. Our construction relies on homological mirror symmetry for orientifolds.

The Optic Assembly Building (OAB) is a facility where large optical mirror units are assembled and installed into Line Replaceable Units (LRUs) for deployment into the National Ignition Facility (NIF) laser system. The New Optics Insertion Device (NOID) is a powered jib crane specially designed to handle large optical assemblies. The NOID arm has three degrees of freedom. it can rotate about the vertical boom, travel up and down the boom, and extend away from and retract in towards the boom. The NOID is used to assist in the assembly of five types of Laser Mirror (LM) LRUs. These five LMs have been creatively named, LM4, LM5, LM6, LM7, and LM8. The LM4 and LM5 LRUs each contain four Mirror Sub-Assemblies (MSAs). The LM6, LM7, and LM8 LRUs each contain 2 MSAs. The MSAs are assembled apart from the LRU and are then installed in the LRU at the LM4-8 workstations. An MSA NOID End-Effector is required to interface with the MSAs and install them into the LRUs. The End-Effector must attach to the robo-hand on the end of the NOID arm. At the time the MSA NOID End-Effector was being designed the NOID, the LM4-5 workstation, and the LM6-8 …