We consider the steady state operation of wall-cooled, fixed-bed tubular reactors. In these reactors the temperature rise ..delta..T must normally be limited to small fractions of the adiabatic temperature rise ..delta..T/sub ad/, both to avoid runaway and maintain product selectivity. Yet ..delta..T/..delta..T/sub ad/ << 1 can only occur if eta = t/sub dif//t/sub reac/ << 1, where t/sub dif/ is the timescale on which heat escapes the reactor by ''diffusing'' to the cooled walls, and t/sub reac/ is the timescale over which the reaction occurs. So here we use asymptotic methods based on eta << 1 to analyze the 2-d reactor equations, and find the radial concentration and temperature profiles to leading order in eta. We then obtain a 1-d model of the reactor by substituting these asymptotically correct profiles into the reactor equations and averaging over r. This model, the ..cap alpha..-model, is identical to the standard (Beek and Singer) 1-d model, except that the reactor's overall heat transfer coefficient U is a decreasing function of the temperature rise ..delta..T. This occurs because as ..delta..T increases, the reaction becomes increasingly concentrated near r = 0, causing a decreased heat transfer efficiency through the reactor's walls. By comparing it with …

The results from QN3D are presented. QN3D is a 3-dimensional hybrid particle-in-cell code designed to run efficiently on the Cray-2 Multiprocessor. The chief application has been to the tilt mode instability in FRCs. QN3D accepts as input, the magnetic field, the ion particle density and the ion temperature on a two-dimensional r-z grid. These quantities are interpolated to the rest of the cartesian grid under the assumption of azimuthal symmetry. The particles are initialized with random numbers chosen according to the particle distributions input from the equilibrium code. The runs done here used equilibria computed by EQV, a kinetic equilibrium code.

The title electron donors, unsymmetrical analogs of Bis(ethylenedithio)tetrathiafulvalene, are synthesized. The utility of /sup 252/Cf Plasma Desorption Mass Spectrometry in the characterization and purity determinations is also reported.

None

A conference sponsored by the United States Department of Energy (DOE), was held on waste management. Topics included waste management, site remediation, waste minimization, economic and social aspects of waste management, and waste management training. Several case studies of US DOE facilities are included. Individual projects are processed separately for the data bases. (CBS)

See the abstract for Volume I for general information on the conference. Topics discussed in Volume II include data management techiques for environmental protection efforts, the use of models in environmental auditing, in emergency plans, chemical accident emergency response, risk assessment, monitoring of waste sites, air and water monitoring of waste sites, and in training programs. (TEM)

A conference sponsored by the United States Department of Energy (DOE) was held on Waste Mangement. Topics discussed were waste stabilization technologies regulations and standards, innovative treatment technology, waste stabilization projects. Individual projects are processed separately for the data bases. (CBS)

A conference sponsored by the United States Department of Energy (DOE), was held on waste management. Topics of discussion were transuranic waste management, chemical and physical treatment technologies, waste minimization, land disposal technology and characterization and analysis. Individual projects are processed separately for the data bases. (CBS)

We are developing a 20mK temperature sensor made of neutron transmutation doped (NTD) germanium for use as a phonon detector in a dark matter search. We find that NTD germanium thermistors around 20mK have resistances which are a strong function of temperature, and have sufficient sensitivity to eventually reach a base line rms energy fluctuation of 6eV at 25mK. Further work is needed to understand the extreme sensitivity of the thermistors to bias power. 13 refs., 18 figs.

A new approach for surface studies using the density functional formalism for structural determination and a first principles many-body theory for the quasiparticle surface state energies is discussed. The many-body calculation involves the evaluation of the electron self-energy operator including both local fields and dynamical screening effects. Results for the Ge(111):As and Si(111):As surface are in excellent agreement with recent angle-resolved photoemission data and show a substantially larger gap between the empty and occupied surface states in comparison to local density functional calculations.

This review concentrates on the recent advances in treating the electronic aspect of the electron-molecule interaction and leaves to other articles the description of the rotational and vibrational motions. Those methods which give the most complete treatment of the direct, exchange, and correlation effects are focused on. Such full treatments are generally necessary at energies below a few Rydbergs (approx. = 60 eV). This choice unfortunately necessitates omission of those active and vital areas devoted to the development of model potentials and approximate scattering formulations. The ab initio and model approaches complement each other and are both extremely important to the full explication of the electron-scattering process. Due to the rapid developments of recent years, the approaches that provide the fullest treatment are concentrated on. 81 refs.

Due to rapid improvements in high-power laser performance, two-photon absorption processes have become a very useful tool for studying the molecular structures of various gases, liquids and solids. However, measurements of absolute two-photon absorption cross sections were more or less ignored previously because of their small size. In this work, we obtained not only the two-photon absorption spectra, but also measurements of their absolute cross sections for various gases, liquids, and solids. 8 refs., 1 fig., 1 tab.

When deprived of nutrients, spore forming bacilli produce endospores which are remarkably resistant to chemical sterilization. Little is known about the morphology and response fo these spores following exposure to sporocidal agents. Light microscopy does not provide sufficient resolution for studying the rupture of the spore coat and fate of intracellular material. Transmission and scanning electron microscopy offer superior resolution but require specimen preparation methods that induce physiologic as well as morphologic changes in the spores, thereby making accurate interpretation of micrographs difficult. To eliminate the possible artifacts induced by chemical fixation, dehydration, embeddment, staining and sectioning, treated and non-sporocide-treated endospores of B. thuringiensis and B. subtilis were imaged by x-ray contact microscopy using monochromatic x-rays. 6 refs., 2 figs.

Seventy-eight summaries of presentations are included. (DLC)

In this paper an analysis of the depolarization expected during acceleration from 0.8 to 45.0 GeV kinetic energy in the Advanced Hadron Facility (AHF) accelerators is performed.

Experiments have begun at Los Alamos to assess the potential of using spheromaks to transfer energy from large, slow moving metal walls to much smaller, faster moving less massive walls so as to achieve hypervelocities in the 20 to 60 km/s range. A large plate transfers energy to the spheromak during a slow compression. The spheromak then releases this energy in a much shorter time to the small plate, accelerating it to much higher velocity. It has been estimated that velocity gains in excess of 4 (V/sub final/ ..-->.. 20 km/s) can be achieved in a practical single stage experiment.

Cold positron beams produced using solid state moderators have been used profitably for condensed matter and positronium research. The low emittance and energy spread of these beams make the technique attractive as a potential positron source for future linear colliders, reducing or eliminating the need for damping rings. However, the intensities attained so far fall short of the requirements of a high energy linear collider. (approx.10/sup 11/ positrons/pulse at 10 kHz was taken as the positron flux necessary for a linear collider-B anti B factory). This report briefly reviews the state of the art in accelerator produced coal positron beams and indicates some areas in which yields might be improved. The discussion here is limited to electroproduced positrons.

An approximate method is described to evaluate the maximum acceptable residual magnetic field in the background of a neutral beam. 5 refs., 8 figs.

EPA standards set forth limitations regarding releases to the accessible environment adjacent to a geologic repository. The NRC criteria pertaining to waste form and engineered barrier performance place certain restrictions on the physical and chemical nature of the waste form and require substantially complete confinement of radioactivity until the high-heat-production period is past. After this period, the annual release of radionuclides from the waste package is normally limited to 1 part in 100,000 of the amounts calculated to be present at 1000-y decay. The regulation permits deviation from these criteria in exceptional circumstances. One such circumstance might be the absence of a significant perturbation in temperature around the stored waste. The lack of significant heat release will eliminate the hydrologic driving force for dispersal of radionuclides. Exceptional circumstances which potentially could justify a less stringent long-term release criterion are: small quantity of radioactivity, the nature of the radioactive species, and the nature of the geology in which the waste is to be emplaced. Because the MW after a suitable decay period have low heat release rates per unit volume, they apparently could be so emplaced in a repository that there would be no compelling need, according to the reasoning presented …

Changes in the US NRC Accident Sequence Precursor program methods since the initial program evaluations of 1969-81 operational events are described, along with insights from the review of 1984-85 events. For 1984-85, the number of significant precursors was consistent with the number observed in 1980-81, dominant sequences associated with significant events were reasonably consistent with PRA estimates for BWRs, but lacked the contribution due to small-break LOCAs previously observed and predicted in PWRs, and the frequency of initiating events and non-recoverable system failures exhibited some reduction compared to 1980-81. Operational events which provide information concerning additional PRA modeling needs are also described.

The ACP Branchbus, a high speed differential bus for data movement in multiprocessing and data acquisition environments, is described. This bus was designed as the central bus in the ACP multiprocessing system. In its full implementation with 16 branches and a bus switch, it will handle data rates of 160 MByte/sec and allow reliable data transmission over inter rack distances. We also summarize applications of the ACP system in experimental data acquisition, triggering and monitoring, with special attention paid to FASTBUS environments.

During the past year, a dedicated triple-axis powder diffractometer has been in routine operation at the Brookhaven National Synchrotron Light Source as a user-oriented facility. The diffractometer is designed to allow easy interchange between energy-dispersive and monochromatic beam experiments. In the latter mode of operation, high resolution data have been collected for a variety of samples with the use of the crystal-analyzer technique, and in several cases these data sets have been used successfully for structure solution and Rietveld refinement. Several aspects of data acquisition at a synchrotron beam-line are described, and some of the different types of scattering geometry which have been used are discussed. Simple expressions are given for the instrumental resolution function expressed as the angular variation of peak widths for each of these. The peak shapes observed for a reference sample of Si on the present triple-axis instrument are well-described by the convolution of Gaussian and Lorentzian functions, and the angular dependence of the Gaussian component is in excellent agreement with the corresponding calculated instrumental function. One of the most important considerations for each type of experiment is the necessary compromise between intensity and resolution over a wide range of scattering angles, and some of the …

The actinide series of elements begins with f-shell electrons forming energy bands, contributing to the bonding, and possessing no magnetic moments. At americium the series switches over to localized f electrons with magnetic moments. In metallic compounds this crossover of behavior can be modified and studied. In this continuum of behavior a few compounds on the very edge of localized f-electron behavior exhibit enormous electronic heat capacities at low temperatures. This is associated with an enhanced thermal mass of the conduction electrons, which is well over a hundred times the free electron mass, and is what led to the label heavy fermion for such compounds. A few of these become superconducting at even lower temperatures. The excitement in this field comes from attempting to understand how this heaviness arises and from the likelihood that the superconductivity is different from that of previously known superconductors. The effects of thorium impurities in UBe/sub 13/ were studied as a representative system for studying the nature of the superconductivity.

Since 1981 three wells have been drilled to depths of between 2.0 and 2.6 km in the Carnmenellis granite, Cornwall, England in order to create a HDR geothermal system. These wells are separated by between 150 and 300 m and have been hydraulically connected by massive injections of both water and viscous gel (50 cpoise). Passive microseismic monitoring of the hydraulic stimulation and circulation experiments has been used since 1982 to determine the size and structure of the reservoir, and monitor its growth. The active seismic survey techniques of cross-hole seismics and vertical seismic profiling (VSP) have been introduced to complement the passive microseismic monitoring in characterizing the reservoir. The cross-hole seismic surveys indicate that the microseismicity defines the area of joint dilation. The attenuation of high frequencies in the region of microseismicity suggests that the reservoir is composed of a complex zone of cracks rather than a single large fracture. VSP surveys also show a good agreement between the microseismically defined reservoir and seismic signal attenuation. Recent improvements in hardware, computer processing and interpretation indicate that active seismics will play an increasingly important part in mapping and understanding geothermal reservoirs. 11 figs., 10 refs.