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Oxygen Transport Ceramic Membranes (open access)

Oxygen Transport Ceramic Membranes

Ti doping on La{sub 1-x}Sr{sub x}FeO{sub 3-{delta}} (LSF) tends to increase the oxygen equilibration kinetics of LSF in lower oxygen activity environment because of the high valence state of Ti. However, the addition of Ti decreases the total conductivity because the acceptor ([Sr{prime}{sub La}]) is compensated by the donor ([Ti{sub Fe}{sup {sm_bullet}}]) which decreases the carrier concentration. The properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 1-x}Ti{sub x}O{sub 3-{delta}} (LSFT, x = 0.45) have been experimentally and theoretically investigated to elucidate (1) the dependence of oxygen occupancy and electrochemical properties on temperature and oxygen activity by thermogravimetric analysis (TGA) and (2) the electrical conductivity and carrier concentration by Seebeck coefficient and electrical measurements. In the present study, dual phase (La{sub 0.2}Sr{sub 0.8}Fe{sub 0.6}Ti{sub 0.4}O{sub 3-{delta}}/Ce{sub 0.9}Gd{sub 0.1}O{sub 2-{delta}}) membranes have been evaluated for structural properties such as hardness, fracture toughness and flexural strength. The effect of high temperature and slightly reducing atmosphere on the structural properties of the membranes was studied. The flexural strength of the membrane decreases upon exposure to slightly reducing conditions at 1000 C. The as-received and post-fractured membranes were characterized using XRD, SEM and TG-DTA to understand the fracture mechanisms. Changes in structural properties of the composite were sought …
Date: December 31, 2006
Creator: Bandopadhyay, S. & Nithyanantham, T.
Object Type: Report
System: The UNT Digital Library
The Panola Watchman (Carthage, Tex.), Vol. 134, No. 103, Ed. 1 Sunday, December 31, 2006 (open access)

The Panola Watchman (Carthage, Tex.), Vol. 134, No. 103, Ed. 1 Sunday, December 31, 2006

Semiweekly newspaper from Carthage, Texas that includes local, state, and national news along with advertising.
Date: December 31, 2006
Creator: unknown
Object Type: Newspaper
System: The Portal to Texas History
Phase II Calderon Process to Produce Direct Reduced Iron Research and Development Project (open access)

Phase II Calderon Process to Produce Direct Reduced Iron Research and Development Project

None
Date: December 31, 2006
Creator: Calderon, Albert
Object Type: Report
System: The UNT Digital Library
Polk County Enterprise (Livingston, Tex.), Vol. 124, No. 105, Ed. 1 Sunday, December 31, 2006 (open access)

Polk County Enterprise (Livingston, Tex.), Vol. 124, No. 105, Ed. 1 Sunday, December 31, 2006

Semi-weekly newspaper from Livingston, Texas that includes local, state and national news along with advertising.
Date: December 31, 2006
Creator: White, Barbara
Object Type: Newspaper
System: The Portal to Texas History
Quantum Well Thermoelectrics for Converting Waste Heat to Electricity (open access)

Quantum Well Thermoelectrics for Converting Waste Heat to Electricity

None
Date: December 31, 2006
Creator: Ghamaty, Saeid
Object Type: Report
System: The UNT Digital Library
Radkowsky Thorium Fuel Project (open access)

Radkowsky Thorium Fuel Project

In the early/mid 1990’s Prof. Alvin Radkowsky, former chief scientist of the U.S. Naval Reactors program, proposed an alternate fuel concept employing thorium-based fuel for use in existing/next generation pressurized water reactors (PWRs). The concept was based on the use of a 'seed-blanket-unit' (SBU) that was a one-for-one replacement for a standard PWR assembly with a uranium-based central 'driver' zone, surrounded by a 'blanket' zone containing uranium and thorium. Therefore, the SBU could be retrofit without significant modifications into existing/next generation PWRs. The objective was to improve the proliferation and waste characteristics of the current once-through fuel cycle. The objective of a series of projects funded by the Initiatives for Proliferation Prevention program of the U.S. Department of Energy (DOE-IPP) - BNL-T2-0074,a,b-RU 'Radkowsky Thorium Fuel (RTF) Concept' - was to explore the characteristics and potential of this concept. The work was performed under several BNL CRADAs (BNL-C-96-02 and BNL-C-98-15) with the Radkowsky Thorium Power Corp./Thorium Power Inc. and utilized the technical and experimental capabilities in the Former Soviet Union (FSU) to explore the potential of this concept for implementation in Russian pressurized water reactors (VVERs), and where possible, also generate data that could be used for design and licensing of …
Date: December 31, 2006
Creator: Todosow, Michael
Object Type: Report
System: The UNT Digital Library
Reducing Ultra-Clean Transportation Fuel Costs with HyMelt Hydrogen (open access)

Reducing Ultra-Clean Transportation Fuel Costs with HyMelt Hydrogen

None
Date: December 31, 2006
Creator: Malone, Donald P. & Renner, William R.
Object Type: Report
System: The UNT Digital Library
Reliable, Economic, Efficient CO2 Heat Pump Water Heater for North America (open access)

Reliable, Economic, Efficient CO2 Heat Pump Water Heater for North America

Adoption of heat pump water heating technology for commercial hot water could save up to 0.4 quads of energy and 5 million metric tons of CO2 production annually in North America, but industry perception is that this technology does not offer adequate performance or reliability and comes at too high of a cost. Development and demonstration of a CO2 heat pump water heater is proposed to reduce these barriers to adoption. Three major themes are addressed: market analysis to understand barriers to adoption, use of advanced reliability models to design optimum qualification test plans, and field testing of two phases of water heater prototypes. Market experts claim that beyond good performance, market adoption requires 'drop and forget' system reliability and a six month payback of first costs. Performance, reliability and cost targets are determined and reliability models are developed to evaluate the minimum testing required to meet reliability targets. Three phase 1 prototypes are designed and installed in the field. Based on results from these trials a product specification is developed and a second phase of five field trial units are built and installed. These eight units accumulate 11 unit-years of service including 15,650 hours and 25,242 cycles of compressor …
Date: December 31, 2006
Creator: Radcliff, Thomas D; Sienel, Tobias; Huff, Hans-Joachim; Thompson, Adrian; Sadegh, Payman; Olsommer, Benoit et al.
Object Type: Report
System: The UNT Digital Library
Sapulpa Daily Herald (Sapulpa, Okla.), Vol. 92, No. 43, Ed. 1 Sunday, December 31, 2006 (open access)

Sapulpa Daily Herald (Sapulpa, Okla.), Vol. 92, No. 43, Ed. 1 Sunday, December 31, 2006

Daily newspaper from Sapulpa, Oklahoma that includes local, state, and national news along with advertising.
Date: December 31, 2006
Creator: Mattox, Jami
Object Type: Newspaper
System: The Gateway to Oklahoma History
Selective NOx Recirculation for Stationary Lean-Burn Natural Gas Engines (open access)

Selective NOx Recirculation for Stationary Lean-Burn Natural Gas Engines

Nitric oxide (NO) and nitrogen dioxide (NO2) generated by internal combustion (IC) engines are implicated in adverse environmental and health effects. Even though lean-burn natural gas engines have traditionally emitted lower oxides of nitrogen (NOx) emissions compared to their diesel counterparts, natural gas engines are being further challenged to reduce NOx emissions to 0.1 g/bhp-hr. The Selective NOx Recirculation (SNR) approach for NOx reduction involves cooling the engine exhaust gas and then adsorbing the NOx from the exhaust stream, followed by the periodic desorption of NOx. By sending the desorbed NOx back into the intake and through the engine, a percentage of the NOx can be decomposed during the combustion process. SNR technology has the support of the Department of Energy (DOE), under the Advanced Reciprocating Engine Systems (ARES) program to reduce NOx emissions to under 0.1 g/bhp-hr from stationary natural gas engines by 2010. The NO decomposition phenomenon was studied using two Cummins L10G natural gas fueled spark-ignited (SI) engines in three experimental campaigns. It was observed that the air/fuel ratio ({lambda}), injected NO quantity, added exhaust gas recirculation (EGR) percentage, and engine operating points affected NOx decomposition rates within the engine. Chemical kinetic model predictions using the software …
Date: December 31, 2006
Creator: Clark, Nigel N.
Object Type: Report
System: The UNT Digital Library
Seminole Sentinel (Seminole, Tex.), Vol. 98, No. 24, Ed. 1 Sunday, December 31, 2006 (open access)

Seminole Sentinel (Seminole, Tex.), Vol. 98, No. 24, Ed. 1 Sunday, December 31, 2006

Semiweekly newspaper from Seminole, Texas that includes local, state, and national news along with extensive advertising.
Date: December 31, 2006
Creator: Wright, Dustin
Object Type: Newspaper
System: The Portal to Texas History
Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles (open access)

Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles

A fundamental filtration study was started to investigate the separation of Fischer-Tropsch Synthesis (FTS) liquids from iron-based catalyst particles. Slurry-phase FTS in slurry bubble column reactor systems is the preferred mode of operation since the reaction is highly exothermic. Consequently, heavy wax products in one approach may be separated from catalyst particles before being removed from the reactor system. Achieving an efficient wax product separation from iron-based catalysts is one of the most challenging technical problems associated with slurry-phase iron-based FTS and is a key factor for optimizing operating costs. The separation problem is further compounded by attrition of iron catalyst particles and the formation of ultra-fine particles.
Date: December 31, 2006
Creator: Sarkar, Amitava; Neathery, James K. & Davis, Burtron H.
Object Type: Report
System: The UNT Digital Library
Solid State Energy Conversion Alliance Delphi SOFC (open access)

Solid State Energy Conversion Alliance Delphi SOFC

The following report details the results under the DOE SECA program for the period July 2006 through December 2006. Developments pertain to the development of a 3 to 5 kW Solid Oxide Fuel Cell power system for a range of fuels and applications. This report details technical results of the work performed under the following tasks for the SOFC Power System: Task 1 SOFC System Development; Task 2 Solid Oxide Fuel Cell Stack Developments; Task 3 Reformer Developments; Task 4 Development of Balance of Plant Components; Task 5 Project Management; and Task 6 System Modeling & Cell Evaluation for High Efficiency Coal-Based Solid Oxide Fuel Cell Gas Turbine Hybrid System.
Date: December 31, 2006
Creator: Shaffer, Steven; Blake, Gary; Kelly, Sean; Mukerjee, Subhasish; Haltiner, Karl; Chick, Larry et al.
Object Type: Report
System: The UNT Digital Library
Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas (open access)

Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas

This project Final Report is submitted to the U.S. Department of Energy (DOE) as part of Cooperative Agreement DE-FC26-03NT41987, 'Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas.' Sorbent injection technology is targeted as the primary mercury control process on plants burning low/medium sulfur bituminous coals equipped with ESP and ESP/FGD systems. About 70% of the ESPs used in the utility industry have SCAs less than 300 ft2/1000 acfm. Prior to this test program, previous sorbent injection tests had focused on large-SCA ESPs. This DOE-NETL program was designed to generate data to evaluate the performance and economic feasibility of sorbent injection for mercury control at power plants that fire bituminous coal and are configured with small-sized electrostatic precipitators and/or an ESP-flue gas desulfurization (FGD) configuration. EPRI and Southern Company were co-funders for the test program. Southern Company and Reliant Energy provided host sites for testing and technical input to the project. URS Group was the prime contractor to NETL. ADA-ES and Apogee Scientific Inc. were sub-contractors to URS and was responsible for all aspects of the sorbent injection systems design, installation and operation at the different host sites. Full-scale sorbent injection for mercury control …
Date: December 31, 2006
Creator: Richardson, Carl; Dombrowski, Katherine & Orr, Douglas
Object Type: Report
System: The UNT Digital Library
“Structural Transformations in Ceramics: Perovskite-like Oxides and Group III, IV, and V Nitrides” (open access)

“Structural Transformations in Ceramics: Perovskite-like Oxides and Group III, IV, and V Nitrides”

1 Overview of Results and their Significance Ceramic perovskite-like oxides with the general formula (A. A0. ...)(B. B0. ...)O3and titanium-based oxides are of great technological interest because of their large piezoelectric and dielectric response characteristics.[1] In doped and nanoengineered forms, titantium dioxide finds increasing application as an organic and hydrolytic photocatalyst. The binary main-group-metal nitride compounds have undergone recent advancements of in-situ heating technology in diamond anvil cells leading to a burst of experimental and theoretical interest. In our DOE proposal, we discussed our unique theoretical approach which applies ab initio electronic calculations in conjunction with systematic group-theoretical analysis of lattice distortions to study two representative phase transitions in ceramic materials: (1) displacive phase transitions in primarily titanium-based perovskite-like oxide ceramics, and (2) reconstructive phase transitions in main-group nitride ceramics. A sub area which we have explored in depth is doped titanium dioxide electrical/optical properties.
Date: December 31, 2006
Creator: James P. Lewis (PI, former Co-PI), Dorian M. Hatch (Co-PI, former PI), and Harold T. Stokes (Co-PI)
Object Type: Report
System: The UNT Digital Library
Subtask 1.17 - Measurement of Hydrocarbon Evolution from Coal and Petroleum Reservoirs Under Carbon Dioxide Floods (open access)

Subtask 1.17 - Measurement of Hydrocarbon Evolution from Coal and Petroleum Reservoirs Under Carbon Dioxide Floods

The project developed, built, and tested three apparatuses for studying different interactions of carbon dioxide with geologic materials. In Year 1, an online instrument was constructed by coupling a high-pressure carbon dioxide extraction system with a flame ionization detector that can yield a real-time profile and quantitative measurements of hydrocarbons removed from materials such as coal and petroleum reservoir rock. In Years 2 and 3, one instrument was built to measure the excess sorption of carbon dioxide in geologic materials such as coal and showed that measurable uptake of carbon dioxide into the coal matrix is rapid. The final apparatus was built to expose geologic materials to carbon dioxide for long periods of time (weeks to months) under the range of pressures and temperatures relevant to carbon dioxide sequestration. The apparatus allows as many as twenty gram-sized samples of geologic materials to be exposed simultaneously and can also include exposures with geologic brines. The system was used to demonstrate complete conversion of magnesium silicate to magnesium carbonate in less than 4 weeks when exposed to clean water or brine, compared to no measurable conversion of dry magnesium carbonate.
Date: December 31, 2006
Creator: Hawthorne, Steven B.
Object Type: Report
System: The UNT Digital Library
Surface Area, Volume, Mass, and Density Distributions for Sized Biomass Particles (open access)

Surface Area, Volume, Mass, and Density Distributions for Sized Biomass Particles

None
Date: December 31, 2006
Creator: Sampath, Ramanathan
Object Type: Report
System: The UNT Digital Library