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1,2-HOIQO--A highly versatile 1,2-HOPO analog (open access)

1,2-HOIQO--A highly versatile 1,2-HOPO analog

A cyclic, bidentate hydroxamic acid binding unit based on an isoquinoline scaffold has been utilized for the synthesis of a hexadentate tripodal ligand based on the TREN backbone. This prototype for a new class of multidentate chelators forms mononuclear iron(III) complexes and one-dimensional coordination polymers with lanthanide(III) cations. The latter has been determined by single crystal X-ray analysis of the cerium species. The solid state structure in the monoclinic space group P2{sub 1}/c (C{sub 36}H{sub 34}CeN{sub 7}O{sub 11}, a = 12.341(2){angstrom}, b = 26.649(4){angstrom}, c = 10.621(2){angstrom}, {alpha} = {gamma} = 90{sup o}, {beta} = 96.753(3){sup o}, V = 3468.6(9) {angstrom}{sup 3}, Z = 4) exhibits a trigonal-dodecahedral environment around the cerium cation. The proof of concept for the versatility of the new scaffold has been shown by the modification of the crucial precursor 3-carboxyiso-coumarin through electrophilic aromatic substitutions to yield the corresponding chlorosulfonated and nitrated analogs.
Date: August 7, 2006
Creator: Seitz, Michael; Pluth, Michael D. & Raymond, Kenneth N.
Object Type: Article
System: The UNT Digital Library
3-D Hydrodynamic Modeling in a Geospatial Framework (open access)

3-D Hydrodynamic Modeling in a Geospatial Framework

3-D hydrodynamic models are used by the Savannah River National Laboratory (SRNL) to simulate the transport of thermal and radionuclide discharges in coastal estuary systems. Development of such models requires accurate bathymetry, coastline, and boundary condition data in conjunction with the ability to rapidly discretize model domains and interpolate the required geospatial data onto the domain. To facilitate rapid and accurate hydrodynamic model development, SRNL has developed a pre- and post-processor application in a geospatial framework to automate the creation of models using existing data. This automated capability allows development of very detailed models to maximize exploitation of available surface water radionuclide sample data and thermal imagery.
Date: August 24, 2006
Creator: Bollinger, J.; Alfred Garrett, A.; Larry Koffman, L. & David Hayes, D
Object Type: Article
System: The UNT Digital Library
4-D High-Resolution Seismic Reflection Monitoring of Miscible CO2 Injected into a Carbonate Reservoir (open access)

4-D High-Resolution Seismic Reflection Monitoring of Miscible CO2 Injected into a Carbonate Reservoir

The objective of this research project is to acquire, process, and interpret multiple high-resolution 3-D compressional wave and 2-D, 2-C shear wave seismic data in an attempt to observe changes in fluid characteristics in an oil field before, during, and after the miscible carbon dioxide (CO{sub 2}) flood that began around December 1, 2003, as part of the DOE-sponsored Class Revisit Project (DOE DE-AC26-00BC15124). Unique and key to this imaging activity is the high-resolution nature of the seismic data, minimal deployment design, and the temporal sampling throughout the flood. The 900-m-deep test reservoir is located in central Kansas oomoldic limestones of the Lansing-Kansas City Group, deposited on a shallow marine shelf in Pennsylvanian time. After 30 months of seismic monitoring, one baseline and eight monitor surveys clearly detected changes that appear consistent with movement of CO{sub 2} as modeled with fluid simulators and observed in production data.
Date: August 31, 2006
Creator: Miller, Richard D.; Raef, Abdelmoneam E.; Byrnes, Alan P. & Harrison, William E.
Object Type: Report
System: The UNT Digital Library
300 AREA PACIFIC NORTHWEST NATIONAL LABORATORY FACILITY RADIONUCLIDE EMISSION POINTS AND SAMPLING SYSTEMS (open access)

300 AREA PACIFIC NORTHWEST NATIONAL LABORATORY FACILITY RADIONUCLIDE EMISSION POINTS AND SAMPLING SYSTEMS

Radionuclide emission points for 300 Area and Battelle Private facilities are presented herein. The sampling systems and associated emission specifics are detailed.
Date: August 28, 2006
Creator: Barfuss, Brad C.; Barnett, J. M. & Harbinson, L Jill
Object Type: Report
System: The UNT Digital Library
15th Street News (Midwest City, Okla.), Vol. 36, No. 1, Ed. 1 Friday, August 25, 2006 (open access)

15th Street News (Midwest City, Okla.), Vol. 36, No. 1, Ed. 1 Friday, August 25, 2006

Newspaper from Rose State College in Midwest City, Oklahoma that includes national, local, and campus news along with advertising.
Date: August 25, 2006
Creator: Ray, Johnna
Object Type: Newspaper
System: The Gateway to Oklahoma History
16th Workshop on Crystalline Silicon Solar Cells and Modules: Materials and Processes; Program, Extended Abstracts, and Papers (open access)

16th Workshop on Crystalline Silicon Solar Cells and Modules: Materials and Processes; Program, Extended Abstracts, and Papers

The National Center for Photovoltaics sponsored the 16th Workshop on Crystalline Silicon Solar Cells and Modules: Materials and Processes held August 6-9, 2006 in Denver, Colorado. The workshop addressed the fundamental properties of PV-Si, new solar cell designs, and advanced solar cell processing techniques. It provided a forum for an informal exchange of technical and scientific information between international researchers in the photovoltaic and relevant non-photovoltaic fields. The Workshop Theme was: "Getting more (Watts) for Less ($i)". A combination of oral presentations by invited speakers, poster sessions, and discussion sessions reviewed recent advances in crystal growth, new cell structures, new processes and process characterization techniques, and cell fabrication approaches suitable for future manufacturing demands. The special sessions included: Feedstock Issues: Si Refining and Purification; Metal-impurity Engineering; Thin Film Si; and Diagnostic Techniques.
Date: August 1, 2006
Creator: Sopori, B. L.
Object Type: Article
System: The UNT Digital Library
2005 SITE ENVIRONMENTAL REPORT (open access)

2005 SITE ENVIRONMENTAL REPORT

Each year, Brookhaven National Laboratory (BNL) prepares an annual Site Environmental Report (SER) in accordance with DOE Order 231.1A, Environment, Safety and Health Reporting of the U.S. Department of Energy (DOE). The report is written to inform the public, regulators, employees, and other stakeholders of BNL's environmental performance during the calendar year in review. The SER summarizes environmental data; environmental management performance; compliance with applicable DOE, federal, state, and local regulations; and compliance, restoration, and surveillance monitoring program performance. BNL has prepared annual SERs since 1971 and has documented nearly all of its environmental history since the Laboratory's inception in 1947. The report is available in print and as a downloadable file on the BNL web page at http://www.bnl.gov/ewms/ser/. A summary of the SER is also prepared each year to provide a general overview of the report, and is distributed with a CD of the full report.
Date: August 29, 2006
Creator: Brookhaven National Laboratory
Object Type: Report
System: The UNT Digital Library
21st Century Locomotive Technology: Quarterly Technical Status Report 14 DOE/AL68284-TSR14 (open access)

21st Century Locomotive Technology: Quarterly Technical Status Report 14 DOE/AL68284-TSR14

Baseline single cylinder engine testing with unit fuel pump system has been completed. This will support subsequent development of high pressure common rail fuel injection. The hybrid battery vendor is preparing an instrumented battery with improved vibration design.
Date: August 21, 2006
Creator: Salasoo, Lembit & Topinka, Jennifer
Object Type: Report
System: The UNT Digital Library
Abandoned Mine Reclamation Fee on Coal (open access)

Abandoned Mine Reclamation Fee on Coal

This report summarizes the problems that surround the Abandoned Mine Reclamation Fund or Abandoned Mine Land (AML) Fund. This report also includes information on the history of the fund and fees, such as congress extending the fees it imposes six times. Nevertheless, one of the central problems in the report is extending the fees further.
Date: August 31, 2006
Creator: Bamberger, Robert L.
Object Type: Report
System: The UNT Digital Library
Academic Competitiveness Grants: Background, Description, and Selected Issues (open access)

Academic Competitiveness Grants: Background, Description, and Selected Issues

From Summary: "This report describes the AC grant program, including the eligibility criteria and the various ways of satisfying the rigorous secondary school requirement. It also includes a discussion of the funding levels for the program. Finally, the report concludes with a discussion of selected policy issues related to the AC program.
Date: August 18, 2006
Creator: Mercer, Charmaine
Object Type: Report
System: The UNT Digital Library
Academic excellence and instructional expenditures in Texas. (open access)

Academic excellence and instructional expenditures in Texas.

Public school per pupil costs and demands for better performance have increased over the past several decades. While the overall per pupil expenditures have increased, the percent of the educational dollar directed toward instructional activities has remained at approximately 60%. A grass-roots movement known as the "65% Solution" caught national attention by claiming that schools are not efficiently allocating resources into areas that have the greatest link to student achievement, such as instruction. Proponents of the 65% Solution claim that per pupil expenditures can be increased by shifting funds from areas considered non-instructional to areas that directly impact student instruction, such as teachers and instructional materials. The purpose of this study was to determine the relationship between district Panel Recommended and Commended Performance TAKS Reading/ELA and Math results and three measurements of instructional expenditures, Instructional Staff Percent; TEA Instructional Expenditure Ratio; and the NCES Instructional Expenditure Ratio (65% Solution), in Texas public schools. Data was collected from the 2003-2004 AEIS report. Multiple regression was used to conduct the analyses. In most instances, there was little, if any, relationship between TAKS Reading/ELA and TAKS Math, and the Instructional Staff Percent (ISP), TEA Instructional Expenditure Ratio (TIER), and NCES Instructional Expenditure Ratio …
Date: August 2006
Creator: Helvey, Jearl Kenton
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Access to Broadband Networks (open access)

Access to Broadband Networks

From Summary: "This report analyzes these three components to identify the parameters that network providers have within their control (such as their choices about network architecture, overall bandwidth capacity, bandwidth reserved for their own use, traffic prioritization, the terms and rates for access to their networks and for their own use, traffic prioritization, the terms and rates for access to their networks and for their retail services) that can affect how end users and independent applications providers can access their networks, how those parameters might be used strategically to harm competition for, and consumers of, voice over internet protocol (VOIP), video, and other applications that ride over broadband networks."
Date: August 31, 2006
Creator: Goldfarb, Charles B.
Object Type: Report
System: The UNT Digital Library
Accurate iterative analytic solution of theKapchinskij-Vladimirskij equations for the case of a matched beam (open access)

Accurate iterative analytic solution of theKapchinskij-Vladimirskij equations for the case of a matched beam

The well-known Kapchinskij-Vladimirskij (KV) equations are difficult to solve in general, but the problem is simplified for the matched-beam case with sufficient symmetry. They show that the interdependence of the two KV equations is eliminated, so that only one needs to be solved--a great simplification. They present an iterative method of solution which can potentially yield any desired level of accuracy. The lowest level, the well-known smooth approximation, yields simple, explicit results with good accuracy for weak or moderate focusing fields. The next level improves the accuracy for high fields; they previously showed how to maintain a simple explicit format for the results. That paper used expansion in a small parameter to obtain the second level. The present paper, using straightforward iteration, obtains equations of first, second, and third levels of accuracy. For a periodic lattice with beam matched to lattice, they use the lattice and beam parameters as input and solve for phase advances and envelope waveforms. They find excellent agreement with numerical solutions over a wide range of beam emittances and intensities.
Date: August 6, 2006
Creator: Anderson, Oscar A.
Object Type: Report
System: The UNT Digital Library
Accurate labeling of the light-actinide O4,5 ionization edges (open access)

Accurate labeling of the light-actinide O4,5 ionization edges

In this short article the accurate labeling of the O4,5 edges of the light actinides is addressed. The O4 and O5 edges are both contained in what is termed the ''giant resonance'' and the smaller ''pre-peak'' that is observed is a consequence of first-order perturbation by the 5d spin-orbit interaction. Thus, the small prepeak in the actinide 5d {yields} 5f transition should not be labeled the O5 peak, but rather the {Delta}S=1 peak.
Date: August 23, 2006
Creator: Moore, K & der Laan, G v
Object Type: Article
System: The UNT Digital Library
ACRF Instrumentation Status: New, Current, and Future August 2006 (open access)

ACRF Instrumentation Status: New, Current, and Future August 2006

The purpose of this report is to provide a concise but comprehensive overview of Atmospheric Radiation Measurement Program Climate Research Facility instrumentation status. The report is divided into four sections: (1) new instrumentation in the process of being acquired and deployed, (2) existing instrumentation and progress on improvements or upgrades, (3) proposed future instrumentation, and (4) Small Business Innovation Research instrument development. New information is highlighted in blue text.
Date: August 1, 2006
Creator: Liljegren, J. C.
Object Type: Report
System: The UNT Digital Library
Active Detection of Small Quantities of Shielded Highly-Enriched Uranium Using Low-Dose 60-keV Neutron Interrogation (open access)

Active Detection of Small Quantities of Shielded Highly-Enriched Uranium Using Low-Dose 60-keV Neutron Interrogation

Active interrogation with low-energy neutrons provides a search technique for shielded highly-enriched uranium. We describe the technique and show initial results using a low-dose 60 keV neutron beam. This technique produces a clear induced fission signal in the presence of small quantities of {sup 235}U. The technique has been validated with low-Z and high-Z shielding materials. The technique uses a forward-directed beam of 60 keV neutrons to induce fission in {sup 235}U. The induced fission produces fast neutrons which are then detected as the signature for {sup 235}U. The beam of neutrons is generated with a 1.93 MeV proton beam impinging on a natural lithium target. The proton beam is produced by a radio-frequency quadrupole (RFQ) LINAC. The 60 keV neutron beam is forward directed because the {sup 7}Li(p,n) reaction is just at threshold for the proton energy of 1.93 MeV.
Date: August 16, 2006
Creator: Kerr, P.; Rowland, M.; Dietrich, D.; Stoeffl, W.; Wheeler, B.; Nakae, L. et al.
Object Type: Article
System: The UNT Digital Library
N-Acylethanolamine (NAE) Profiles Change During Arabidopsis Thaliana Seed Germination and Seedling Growth (open access)

N-Acylethanolamine (NAE) Profiles Change During Arabidopsis Thaliana Seed Germination and Seedling Growth

An understanding of the potential roles as lipid mediators of a family of bioactive metabolites called N-acylethanolamines (NAEs) depends on their accurate identification and quantification. The levels of 18C unsaturated NAEs (e.g. NAE18:2, NAE 18:3, etc.) in wild-type seeds (about 2000 ng/g fw) generally decreased by about 80% during germination and post-germinative growth. In addition, results suggest NAE-degradative fatty acid amide hydrolase (FAAH) expression does not play a major role in normal NAE metabolism as previously thought. Seedlings germinated and grown in the presence of abscisic acid (ABA), an endogenous plant hormone, exhibited growth arrest and secondary dormancy, similar to the treatment of seedlings with exogenous N­lauroylethanolamine (NAE12:0). ABA-mediated growth arrest was associated with higher levels of unsaturated NAEs. Overall, these results are consistent with the concept that NAE metabolism is activated during seed germination and suggest that the reduction in unsaturated NAE levels is under strict temporal control and may be a requirement for normal seed germination and post-germinative growth.
Date: August 2006
Creator: Wiant, William C.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Adequate Yearly Progress (AYP): Implementation of the No Child Left Behind Act (open access)

Adequate Yearly Progress (AYP): Implementation of the No Child Left Behind Act

This report is intended to provide an overview of the Adequate Yearly Process (AYP) concept and several related issues, a description of the AYP provisions of the No Child Left Behind Act, and an analysis of the implementation of these provisions by the U.S. Department of Education (ED) and the states. It will be updated when major administrative actions are taken by ED, or substantial new data on state implementation become available.
Date: August 31, 2006
Creator: Riddle, Wayne C.
Object Type: Report
System: The UNT Digital Library
Advanced Gasification By-Product Utilization (open access)

Advanced Gasification By-Product Utilization

With the passing of legislation designed to permanently cap and reduce mercury emissions from coal-fired utilities, it is more important than ever to develop and improve upon methods of controlling mercury emissions. One promising technique is carbon sorbent injection into the flue gas of the coal-fired power plant. Currently, this technology is very expensive as costly commercially activated carbons are used as sorbents. There is also a significant lack of understanding of the interaction between mercury vapor and the carbon sorbent, which adds to the difficulty of predicting the amount of sorbent needed for specific plant configurations. Due to its inherent porosity and adsorption properties as well as on-site availability, carbons derived from gasifiers are potential mercury sorbent candidates. Furthermore, because of the increasing restricted use of landfilling, the coal industry is very interested in finding uses for these materials as an alternative to the current disposal practice. The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported. This contract was with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part …
Date: August 31, 2006
Creator: Andrews, Rodney; Rubel, Aurora; Groppo, Jack; Marrs, Brock; Geertsema, Ari; Huggins, Frank et al.
Object Type: Report
System: The UNT Digital Library
Afghanistan: Elections, Constitution, and Government (open access)

Afghanistan: Elections, Constitution, and Government

This report discusses the political situation in Afghanistan, more specifically it discusses the recent elections, newly formed constitution and the elected government.
Date: August 8, 2006
Creator: Katzman, Kenneth
Object Type: Report
System: The UNT Digital Library
Afghanistan: Post-War Governance, Security, and U.S. Policy (open access)

Afghanistan: Post-War Governance, Security, and U.S. Policy

Afghanistan's political transition was completed with the convening of a parliament in December 2005, but since then insurgent threats to Afghanistan's government have escalated to the point that some experts are questioning the future of U.S. stabilization efforts. Afghan citizens are enjoying new personal freedoms that were forbidden under the Taliban. Women are participating in economic and political life. U.S. stabilization measures focus on strengthening the central government and its security forces and on promoting reconstructing while combating the renewed insurgent challenge.
Date: August 23, 2006
Creator: Katzman, Kenneth
Object Type: Report
System: The UNT Digital Library
Afghanistan: Post-War Governance, Security, and U.S. Policy (open access)

Afghanistan: Post-War Governance, Security, and U.S. Policy

The United States and its allies are helping Afghanistan emerging from more than 22 years of warfare, although substantial risk to Afghan stability remains. Before the U.S. military campaign against the orthodox Islamist Taliban movement began on October 7, 2001, Afghanistan had been mired in conflict since the Soviet invasion of Afghanistan in 1979. The defeat of the Taliban has enabled the United States and its coalition partners to send forces throughout Afghanistan to search for Taliban and Al Qaeda fighters and leaders that remain at large, including Osama bin Laden. As the war against remaining Al Qaeda and Taliban elements winds down, the United States is shifting its military focus toward stabilizing the interim government, including training a new Afghan national army, and supporting the international security force (ISAF) that is helping the new government provide security.
Date: August 23, 2006
Creator: Katzman, Kenneth
Object Type: Report
System: The UNT Digital Library
Afghanistan: Post-War Governance, Security, and U.S. Policy (open access)

Afghanistan: Post-War Governance, Security, and U.S. Policy

The United States and its allies are helping Afghanistan emerging from more than 22 years of warfare, although substantial risk to Afghan stability remains. Before the U.S. military campaign against the orthodox Islamist Taliban movement began on October 7, 2001, Afghanistan had been mired in conflict since the Soviet invasion of Afghanistan in 1979. The defeat of the Taliban has enabled the United States and its coalition partners to send forces throughout Afghanistan to search for Taliban and Al Qaeda fighters and leaders that remain at large, including Osama bin Laden. As the war against remaining Al Qaeda and Taliban elements winds down, the United States is shifting its military focus toward stabilizing the interim government, including training a new Afghan national army, and supporting the international security force (ISAF) that is helping the new government provide security.
Date: August 23, 2006
Creator: Katzman, Kenneth
Object Type: Report
System: The UNT Digital Library
[After a Fashion, August 17, 2005] (open access)

[After a Fashion, August 17, 2005]

Article about do-it-yourself fashion, the closing of Roy's taxi company, Austin Circle of Theaters, and several events happening around Austin, Texas.
Date: August 17, 2006
Creator: Moser, Stephen MacMillan
Object Type: Article
System: The UNT Digital Library