To form Cu interconnects, dual-damascene techniques like chemical mechanical planarization (CMP) and post-CMP became inevitable for removing the "overburden" Cu and for planarizing the wafer surface. During the CMP processing, Cu interconnects and barrier metal layers experience different electrochemical interactions depending on the slurry composition, pH, and ohmic contact with adjacent metal layers that would set corrosion process. Ruthenium as a replacement of existing diffusion barrier layer will require extensive investigation to eliminate or control the corrosion process during CMP and post CMP. Bimetallic corrosion process was investigated in the ammonium citrate (a complexing agent of Cu in CMP solutions) using micro test patterns and potentiodynamic measurements. The enhanced bimetallic corrosion of copper observed is due to noble behavior of the ruthenium metal. Cu formed Cu(II)-amine and Cu(II)-citrate complexes in alkaline and acidic solutions and a corrosion mechanism has been proposed. The currently used metallization process (PVD, CVD and ALD) require ultra-high vacuum and are expensive. A novel method of Si surface metallization process is discussed that can be achieved at room temperature and does not require ultra-high vacuum. Ruthenation of Si surface through strong Si-Ru covalent bond formation is demonstrated using different ruthenium carbonyl compounds. RBS analysis accounted for …

Relationships between the collective actors within interorganizational relationships are a growing area of research in management. Interorganizational networks continue to be a popular mechanism used by organizations to achieve greater performance. Organizations develop competencies to work with other organizations, but the confidence of these organizations to use these strengths for a competitive advantage has yet to be empirically examined. The purpose of this study is to examine organizational efficacy, how competencies may related to that efficacy, and the relationship of efficacy with performance. The goal of this study is to observe the relationship among trust, dependence, information quality, continuous quality improvement, and supplier flexibility with organizational efficacy. In addition, the relationship between organizational efficacy and performance is also observed. There are two primary research questions driving this study. First, what is the relationship between trust, dependence, information quality, continuous quality improvement, supplier flexibility and organizational efficacy? Second, what is the relationship between organizational efficacy and performance? The theories supporting the hypotheses generated from these questions include theories such as social cognitive theory, quality improvement, and path-goal theory. Data collected from the suppliers of a large university support the hypotheses. Regression analysis and structure coefficients were used to analyze the data. …

This dissertation is mainly based on the reading of three American novels to explore how female characters deal with their illegitimate pregnancies and how their solutions re-shape their futures and affect their inner growth. Chapter 1 discusses Dorinda Oakley's premarital pregnancy in Ellen Glasgow's Barren Ground and draws the circle of limits from Barbara Welter's "four cardinal virtues" (purity, submissiveness, domesticity, and piety) which connect to the analogous female roles (daughter, sister, wife, and mother). Dorinda's childless survival reconstructs a typical household from her domination and absence of maternity. Chapter 2 examines Ántonia Shimerda's struggles and endurance in My Ántonia by Willa Cather before and after Ántonia gives birth to a premarital daughter. Ántonia devotes herself to being a caring mother and to looking after a big family although her marriage is also friendship-centered. Chapter 3 adopts a different approach to analyze Charlotte Rittenmeyer's extramarital pregnancy in The Wild Palms by William Faulkner. As opposed to Dorinda and Ántonia who re-enter domesticity to survive, Charlotte runs out on her family and dies of a botched abortion. To help explain the aftermath of illicit pregnancies, I extend or shorten John Duvall's formula of female role mutations: "virgin>sexually active (called whore)>wife" to …

I start writing by conjuring up an image in my mind. Sometimes it will be something that I have thought about for a while, sometimes it will be something that I sit around attempting to create. Either way, it is simply the idea that I need in order to get started. People will say, "Just sit down and write" which I can do, but it does not mean I will end up anywhere worthwhile. In my writing I need a focus. I need an idea or just one image to get me writing and I can base an entire story off of that one image. I think the reason this works for me is because in my mind it is an illustration and always something that is vibrant and unique. I want the image to stand out and to mean something because I feel that it comes to me for a specific reason, I just have to piece it all together and let the characters and plot unfold for themselves. People often say this, that the characters end up running the story. I think this is true, but in my case my stories are not so driven by character or …

The emerging interests in spatial pattern mining leads to the demand for a flexible spatial pattern mining language, on which easy to use and understand visual pattern language could be built. It is worthwhile to define a pattern mining language called LCSPM to allow users to specify complex spatial patterns. I describe a proposed pattern mining language in this paper. A visual interface which allows users to specify the patterns visually is developed. Visual pattern queries are translated into the LCSPM language by a parser and data mining process can be triggered afterwards. The visual language is based on and goes beyond the visual language proposed in literature. I implemented a prototype system based on the open source JUMP framework.

Recent studies reveal that a considerable number of U.S. community college leaders will be retiring in the next several years. The concern is that with the large turnover, history, culture, and important lessons of leadership will be lost. The current research on the lives of presidents, their career paths, and experiences in community college leadership centers on approaches to the study of leadership at the macro level. Limited research exists in the published literature that reports and analyzes the development of individuals as community college leaders at the micro level. This results in a gap regarding understanding leadership development and strategies to prepare leaders. This study addresses this gap by providing a critical description of the leadership development of one individual who became a community college chancellor and who the literature on the community context indicates contributed to the local and national context for community colleges. Biography is gaining prominence as a legitimate and viable tool in the study of leadership. Few biographical studies currently exist which focus on leadership development in context at the micro level. This dissertation is a biographical, qualitative study of the leadership path and legacy of R. Jan LeCroy, a community college leader. The study …

This work examines particular attributes of the purgatorial phenomena from pre-Christian history of the Indo-European world to the Early Modern Period of England. An attempt has been made to identify and concentrate attention upon examples which provide the most significant and penetrating look into this evolution. For example, a portion of this paper attempts to determine just how widespread purgatorial customs were throughout England and the various types of community that supported these beliefs pre and post Reformation. By comparing life before and after the reigns of Henry and Edward a conclusion is reached that reveals the Protestant Reformation in England stripped the laity of a fundamental instrument they needed to support their religiosity and custom. This becomes evident in further years as some of those same customs and rituals that had been considered anathema by Protestants, slowly crept back into the liturgy of the new religion. Strong evidence of this is provided, with a strong emphasis placed upon late seventeenth and early eighteenth century death eulogies, with a section of this paper being devoted to the phenomena of the Sin-Eater.

John Thomas Biggers (1924–2001) was a major African American artist who inspired countless others through his teaching, murals, paintings, and drawings. After receiving conventional art training at Hampton Institute and Pennsylvania State, he had his personal and artistic breakthrough in 1957 when he spent six months in the newly independent country of Ghana. From this time forward, he integrated African abstract elements with his rural Southern images to create a personal iconography. His new approach made him famous, as his personal discovery of African heritage fit in well with the growing U.S. civil rights movement. He is best known for his murals at Hampton University, Winston-Salem University, and Texas Southern, but the drawings and lithographs that lie behind the murals have received scant attention—until now. Theisen interviewed Dr. Biggers during the last thirteen years of his life, and was welcomed into his studio innumerable times. Together, they selected representative works for this volume, some of which have not been previously published for a general audience. After his death in 2001, his widow continued to work closely with Theisen, resulting in a book that is intimate and informative for both the scholar and the student.

Johann Sebastian Bach's chorale preludes are varied and artistic not only in the treatment of chorale melodies, but also in the accompaniments of those chorale melodies. This study examines the accompaniments of Bach's long chorale preludes, focusing on identifying the various types and the characteristics that make them unique. This study investigates the two broad categories of accompaniments depending on whether the motives are chorale-derived or independent of the chorale. While the chorale prelude accompaniments in the first large group are closely related, the accompaniments of the chorale preludes in the second group stand independently and illustrate the vast range of Bach's compositional skill. Both groups demonstrate Bach's interest in expanding his predecessors' models, a trait that can be traced throughout all of Bach's compositional history.

The purpose of this study was to determine the effectiveness of and the subjects' overall satisfaction with the implementation of an internally created performance appraisal system. The system was implemented at a major technology consulting firm in the US. The subjects of this study were manager level employees of the firm. An employee survey conducted annually at the firm included questions relating to the implementation of the performance appraisal system. Eight years of managers' responses to six key questions in the Career Development category were analyzed. Managers' perceptions of their contribution to the firm, their understanding of what career paths are available to them, their understanding of the requirements for promotion, as well as their overall satisfaction with the implementation of the performance appraisal system were captured by this survey. Trend analysis indicates that managers at the firm perceived their career path knowledge improved and their understanding of promotion criteria improved as a result of the implementation. Overall satisfaction with the implementation did not improve enough to site confidence in managers' perceptions for the period immediately after the implementation; managers' responses to the actual implementation were disagreeable to neutral. Managers did not feel their impact on the organization improved as …

Post-Reconstruction Texas in the mid-1870s was still relatively primitive, with communities isolated from each other in a largely open-range environment. Cattlemen owned herds of cattle in numerous counties while brand laws remained local. Friction arose when the nonresident stockmen attempted to gather their cattle, and mavericking was common. Law enforcement at the local level could cope with handling local drunks, collecting taxes, and attending the courts when in session, but when an outrageous crime occurred, or depredations in a community were at a level that severely taxed or overwhelmed the local sheriff, there was seldom any other recourse except a vigilante movement. With such a fragile hold on civilization in these communities, it is not difficult to understand how a “blood feud” could occur. During 1874 the Hoo Doo War erupted in the Texas Hill Country of Mason County, and for the remainder of the century violence and fear ruled the region in a rising tide of hatred and revenge. It is widely considered the most bitter feud in Texas history. Traditionally the feud is said to have begun with the intention of protecting the families, property and livelihood of the largely agrarian settlers in Mason and Llano counties. The …

Ruthenium and ruthenium dioxide thin films have shown great promise in various applications, such as thick film resistors, buffer layers for yttrium barium copper oxide (YBCO) superconducting thin films, and as electrodes in ferroelectric memories. Other potential applications in Si based complementary metal oxide semiconductor (CMOS) devices are currently being studied. The search for alternative metal-based gate electrodes as a replacement of poly-Si gates has intensified during the last few years. Metal gates are required to maintain scaling and performance of future CMOS devices. Ru based materials have many desirable properties and are good gate electrode candidates for future metal-oxide-semiconductor (MOS) device applications. Moreover, Ru and RuO2 are promising candidates as diffusion barriers for copper interconnects. In this thesis, the thermal stability and interfacial diffusion and reaction of both Ru and RuO2 thin films on HfO2 gate dielectrics were investigated using Rutherford backscattering spectrometry (RBS), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). An overview of Ru and RuO2/HfO2 interface integrity issues will be presented. In addition, the effects of C ion modification of RuO2 thin films on the physico-chemical and electrical properties are evaluated.

Although a change of religious landscape in America in recent years has been suggested and widely accepted in the social sciences, most studies tend to focus on measures of religiosity and how it is changing. The subject of spirituality and its correlates seem to be mostly ignored. This study utilizes nationally representative data generated for the first time in General Social Survey (GSS) on the subject of spirituality to measure Americans' spirituality and daily spiritual experiences and their most significant correlates. In this study, most Americans (89%) showed to have some degree of spirituality and daily spiritual experiences. Moreover, variables of gender, race/ethnicity, marital status, religious origin, and residence in conservative region when growing up shown to be significant predictors of spirituality.

Death, as a subject, has been treated extensively throughout history, both in literature as well as in music. The focus of Memento mori is to portray the inevitability of death through music. The first part of the document is an essay exploring the topic of death, its inevitability, unpredictability and the fragility of life. This section also includes a number of examples of composer's whose works have influenced the composition of the piece. The title of the work is meant to reflect that death catches up with all of us and that humans no matter how invincible they feel at certain stages of life will, eventually, succumb to death. The second part of the document is the notated orchestral score. The work is for full orchestra and solo violoncello. It is in three acts that loosely resemble three stages of life; Youth followed by life in adulthood and finally death. The work is not programmatic and the piece's formal structure varies from a traditional concerto, for although comprised of three distinct acts, there are no pauses between them. The entire work is meant to be dark and morbid and the specter of death looms throughout the piece.

Did you know that Pre-Columbian Mexican cuisine was low in fat and high in fiber and vitamins? Based on corn, squash, tomatoes, beans, and lean meats, the everyday diet of the first Americans was remarkably close to the recommendations for healthy eating we hear about every day. Now for the first time, cooks can use the secrets of the Aztecs in today’s kitchen, thanks to Kris Rudolph’s thoroughly researched cookbook. And because cooks from both sides of the border will be eager to try these recipes, Rudolph presents the recipes and text in Spanish on facing pages. The book opens with a short introduction outlining the history of Mexican cooking, followed by an overview of healthy eating habits, a description of the most common ingredients, and a useful guide to planning for parties. The fifty recipes cover everything from appetizers to after-dinner refreshers and each includes the number of calories, amounts of total fat and saturated fat, grams of carbohydrates, and amount of fiber. Rudolph suggests low-fat and low-carbohydrate alternatives, as well as ways to vary the spiciness.

The major sources of power dissipation in a nanometer CMOS circuit are capacitive switching, short-circuit current, static leakage and gate oxide tunneling. However, with the aggressive scaling of technology the gate oxide direct tunneling current (gate leakage) is emerging as a prominent component of power dissipation. For sub-65 nm CMOS technology where the gate oxide (SiO2) thickness is very low, the direct tunneling current is the major form of tunneling. There are two contribution parts in this thesis: analytical modeling of behavioral level components for direct tunneling current and propagation delay, and the reduction of tunneling current during behavioral synthesis. Gate oxides of multiple thicknesses are useful in reducing the gate leakage dissipation. Analytical models from first principles to calculate the tunneling current and the propagation delay of behavioral level components is presented, which are backed by BSIM4/5 models and SPICE simulations. These components are characterized for 45 nm technology and an algorithm is provided for scheduling of datapath operations such that the overall tunneling current dissipation of a datapath circuit under design is minimal. It is observed that the oxide thickness that is being considered is very low it may not remain constant during the course of fabrication. Hence …

This dissertation is a study of morale in the western Confederacy from early 1864 until the Civil War's end in spring 1865. It examines when and why Confederate morale, military and civilian, changed in three important western states, Mississippi, Alabama, and Tennessee. Focusing on that time frame allows a thorough examination of the sources, increases the opportunity to produce representative results, and permits an assessment of the lingering question of when and why most Confederates recognized, or admitted, defeat. Most western Confederate men and women struggled for their ultimate goal of southern independence until Federal armies crushed those aspirations on the battlefield. Until the destruction of the Army of Tennessee at Franklin and Nashville, most western Confederates still hoped for victory and believed it at least possible. Until the end they drew inspiration from battlefield developments, but also from their families, communities, comrades in arms, the sacrifices already endured, simple hatred for northerners, and frequently from anxiety for what a Federal victory might mean to their lives. Wartime diaries and letters of western Confederates serve as the principal sources. The dissertation relies on what those men and women wrote about during the war - military, political, social, or otherwise - …

The ductus arteriosi (DA) are two blood vessels connecting the pulmonary arteries to the descending aorta in the avian embryo. Following hatching, the DA closes, separation of the systemic and pulmonary circulation. I present the morphological changes that occur in the chicken DA during prepipping, internal pipping, external pipping, and hatching. The avian DA consists of two distinct tissue types, a proximal and a distal portion. Histological examination shows developmental differences between the proximal and distal portions of the DA with regard to lumen occlusion, endothelial cells, smooth muscle and elastin. Endothelial cell proliferation begins to occur as early as external pipping, with the lumen almost completely occluded by the 3rd day of post-hatching life. Expression of vascular endothelial growth factor (VEGF) increases in avian endothelial cells during hatching. I provide a morphological timeline of changes in the DA as the chicken develops from embryo to hatchling.

The classifier discussed in this thesis considers the path traversed by an email (instead of its content) and reputation of the relays, features inaccessible to spammers. Groups of spammers and individual behaviors of a spammer in a given domain were analyzed to yield association patterns, which were then used to identify similar spammers. Unsolicited and phishing emails were successfully isolated from legitimate emails, using analysis results. Spammers and phishers are also categorized into serial spammers/phishers, recent spammers/phishers, prospective spammers/phishers, and suspects. Legitimate emails and trusted domains are classified into socially close (family members, friends), socially distinct (strangers etc), and opt-outs (resolved false positives and false negatives). Overall this classifier resulted in far less false positives when compared to current filters like SpamAssassin, achieving a 98.65% precision, which is well comparable to the precisions achieved by SPF, DNSRBL blacklists.

The Internet and networks in general have become essential tools for disseminating in-formation. Search engines have become the predominant means of finding information on the Web and all other data repositories, including local resources. Domain scientists regularly acquire and analyze images generated by equipment such as microscopes and cameras, resulting in complex image files that need to be managed in a convenient manner. This type of integrated environment has been recently termed a netcentric sci-entific research repository. I developed a number of data manipulation tools that allow researchers to manage their information more effectively in a netcentric environment. The specific contributions are: (1) A unique interface for management of data including files and relational databases. A wrapper for relational databases was developed so that the data can be indexed and searched using traditional search engines. This approach allows data in databases to be searched with the same interface as other data. Fur-thermore, this approach makes it easier for scientists to work with their data if they are not familiar with SQL. (2) A Web services based architecture for integrating analysis op-erations into a repository. This technique allows the system to leverage the large num-ber of existing tools by wrapping them …

Individuals diagnosed with schizotypal personality disorder (SPD) exhibit patterns of cognitive deficits, neuromotor disturbances, and behavior problems similar to individuals with schizophrenia, and thus SPD is thought to represent one point on the continuum of schizophrenia spectrum disorders (SSDs). Deficits in behavior, cognition, and motor functioning have been implicated as childhood precursors of SSDs and appear to also vary as a function of gender and family history of psychopathology. As such, studies of youth may help in further identification of individuals at risk for SSDs. The current study examined the prospective associations between problem behaviors, neuromotor and neurocognitive functioning, as well as SSD symptoms, at baseline and 2-year follow-up in youth meeting criteria for SPD, other personality disorders, or healthy controls. The neuromotor and neurocognitive measures were able to significantly predict SSD symptoms and behavior problems above and beyond baseline predictors. Overall, the findings provide further support for the role of subcortical motor centers operating together with prefrontal cortical areas in the regulation of higher-order cognitive functioning and in producing the psychiatric features of SSDs. Significant correlations between gender, family history of schizophrenia, and history of head injury with symptoms, behavior, cognition, and motor functioning were also found and highlight …

This is the first known study to explore the image retrieval preferences of news photographers and news photo editors in work contexts. Survey participants (n=102) provided opinions regarding 11 photograph searching methods. The quantitative survey data were analyzed using descriptive statistics, while content analysis was used to evaluate the qualitative survey data. In addition, news photographers and news photo editors (n=11) participated in interviews. Data from the interviews were analyzed with phenomenography. The survey data demonstrated that most participants prefer searching by events taking place in the photograph, objects that exist in the photograph, photographer-provided keywords, and relevant metadata, such as the date the picture was taken. They also prefer browsing. Respondents had mixed opinions about searching by emotions elicited in a photograph, as well as the environmental conditions represented in a photograph. Participants' lowest-rated methods included color and light, lines and shapes, and depth, shadow, or perspective. They also expressed little interest in technical information about a photograph, such as shutter speed and aperture. Interview participants' opinions about the search methods reflected the survey respondents' views. They discussed other aspects of news photography as well, including the stories told by the pictures, technical concerns about digital photography, and digital …

From book jacket: “Mr. Guitar” Chet Atkins called Lenny Breau (1941-1984) “the greatest guitarist who ever walked the face of the earth.” Breau began playing the instrument at age seven, and went on to master many styles, especially jazz. Between 1968 and 1983 he made a series of recordings that are among the most influential guitar albums of the century. Breau’s astonishing virtuosity influenced countless performers, but unfortunately it came at the expense of his personal relationships. Despite Breau’s fascinating life story and his musical importance, no full-length biography has been published until now. Forbes-Roberts has interviewed more than 175 people and closely analyzed Breau’s recordings to reveal an enormously gifted man and the inner workings of his music. “Lenny Breau was, and will always be, a great treasure. We need him today more than ever.” —Mundell Lowe

Interview with Abe C. Cooper, African-American alumnus of North Texas State University. The interview includes Cooper's personal experiences about childhood and early adulthood in Dallas, Texas, attending all-black schools, and enrolling at North Texas State College in 1958. Cooper speaks about the adjustments required for attending school in an integrated setting, boarding with African-American families in the "Shack Town" neighborhood of Denton, and the comparative experiences with students and faculty in the Schools of Engineering and Education.