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Development of Continuous Solvent Extraction Processes for Coal Derived Carbon Products Quarterly Report
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Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems Quarterly Report
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Proceedings of RIKEN BNL Research Center Workshop
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Analysis of Devonian Black Shales in Kentucky for Potential Carbon Dioxide Sequestration and Enhanced Natural Gas Production Quarterly Report
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2.1 Pan-WCRP Monsoon Modelling Workshop Summary
Ken Sperber led a discussion of the outcome of the Pan-WCRP Monsoon Modelling Workshop that was held at the University of California at Irvine from 15-17 June 2005. At the workshop presentations from key CLIVAR and GEWEX panels were presented to highlight the outstanding problems in modelling the Earth's monsoons. Additionally, presentations from invited experts were given to highlight important aspects of monsoon phenomena and processes, such as low-level jets, air-sea interaction, predictability, observational networks/studies, and model test beds etc. Since all persons attending the CLIVAR AAMP meeting were present for all, or most, of the monsoon workshop, a detailed description of the workshop presentations was not given. Rather, the discussion was focused on the recommendations of the workshop breakout groups and their relevance to CLIVAR AAMP. CLIVAR AAMP endorsed the near-term workshop recommendation of investigating the diurnal cycle using a hierarchy of models a key way forward for promoting CLIVAR/GEWEX interactions. In GCM studies CLIVAR researchers have identified the diurnal cycle as a forced ''mode'' of variability that is poorly represented in terms of amplitude and phase, especially in the case of precipitation. Typical phase errors of 6-12 hours are noted over both land and ocean in GCMs. CLIVAR …
Date:
June 28, 2005
Creator:
Sperber, K R
Object Type:
Report
System:
The UNT Digital Library
2-D Modeling of Energy-z Beam Dynamics Using the LiTrack Matlab Program
Short bunches and the bunch length distribution have important consequences for both the LCLS project at SLAC and the proposed ILC project. For both these projects, it is important to simulate what bunch length distributions are expected and then to perform actual measurements. The goal of the research is to determine the sensitivity of the bunch length distribution to accelerator phase and voltage. This then indicates the level of control and stability that is needed. In this project I simulated beamlines to find the rms bunch length in three different beam lines at SLAC, which are the test beam to End Station A (ILC-ESA) for the ILC studies, Linac Coherent Light Source (LCLS) and LCLS-ESA. To simulate the beamlines, I used the LiTrack program, which does a 2-dimensional tracking of an electron bunch's longitudinal (z) and the energy spread beam (E) parameters. In order to reduce the time of processing the information, I developed a small program to loop over adjustable machine parameters. LiTrack is a Matlab script and Matlab is also used for plotting and saving and loading files. The results show that the LCLS in Linac-A is the most sensitive when looking at the ratio of change in …
Date:
December 15, 2005
Creator:
Cauley, S .K. & Woods, M.
Object Type:
Report
System:
The UNT Digital Library
2-D or not 2-D, that is the question: A Northern California test
Reliable estimates of the seismic source spectrum are necessary for accurate magnitude, yield, and energy estimation. In particular, how seismic radiated energy scales with increasing earthquake size has been the focus of recent debate within the community and has direct implications on earthquake source physics studies as well as hazard mitigation. The 1-D coda methodology of Mayeda et al. has provided the lowest variance estimate of the source spectrum when compared against traditional approaches that use direct S-waves, thus making it ideal for networks that have sparse station distribution. The 1-D coda methodology has been mostly confined to regions of approximately uniform complexity. For larger, more geophysically complicated regions, 2-D path corrections may be required. The complicated tectonics of the northern California region coupled with high quality broadband seismic data provides for an ideal ''apples-to-apples'' test of 1-D and 2-D path assumptions on direct waves and their coda. Using the same station and event distribution, we compared 1-D and 2-D path corrections and observed the following results: (1) 1-D coda results reduced the amplitude variance relative to direct S-waves by roughly a factor of 8 (800%); (2) Applying a 2-D correction to the coda resulted in up to 40% variance …
Date:
June 6, 2005
Creator:
Mayeda, K; Malagnini, L; Phillips, W S; Walter, W R & Dreger, D
Object Type:
Article
System:
The UNT Digital Library
2-D Path Corrections for Local and Regional Coda Waves: A Test of Transportability
Reliable estimates of the seismic source spectrum are necessary for accurate magnitude, yield, and energy estimation. In particular, how seismic radiated energy scales with increasing earthquake size has been the focus of recent debate within the community and has direct implications on earthquake source physics studies as well as hazard mitigation. The 1-D coda methodology of Mayeda et al. [2003] has provided the lowest variance estimate of the source spectrum when compared against traditional approaches that use direct S-waves, thus making it ideal for networks that have sparse station distribution. The 1-D coda methodology has been mostly confined to regions of approximately uniform complexity. For larger, more geophysically complicated regions, 2-D path corrections may be required. We will compare performance of 1-D versus 2-D path corrections in a variety of regions. First, the complicated tectonics of the northern California region coupled with high quality broadband seismic data provides for an ideal ''apples-to-apples'' test of 1-D and 2-D path assumptions on direct waves and their coda. Next, we will compare results for the Italian Alps using high frequency data from the University of Genoa. For Northern California, we used the same station and event distribution and compared 1-D and 2-D path …
Date:
July 13, 2005
Creator:
Mayeda, K M; Malagnini, L; Phillips, W S; Walter, W R; Dreger, D S & Morasca, P
Object Type:
Article
System:
The UNT Digital Library
2-D Reflectometer Modeling for Optimizing the ITER Low-field Side Reflectometer System
The response of a low-field side reflectometer system for ITER is simulated with a 2?D reflectometer code using a realistic plasma equilibrium. It is found that the reflected beam will often miss its launch point by as much as 40 cm and that a vertical array of receiving antennas is essential in order to observe a reflection on the low-field side of ITER.
Date:
September 2, 2005
Creator:
Kramer, G. J.; Nazikian, R.; Valeo, E. J.; Budny, R. V.; Kessel, C. & Johnson, D.
Object Type:
Report
System:
The UNT Digital Library
2-Page Summary for Neptunium solubility in the Near-field Environment of A Proposed Yucca Mountain Repository
The total system performance assessment (TSPA) for the proposed repository at Yucca Mountain, NV, includes a wide variety of processes to evaluate the potential release of radionuclides from the Engineered Barrier System into the unsaturated zone of the geosphere. The principal processes controlling radionuclide release and mobilization from the waste forms are captured in the model to assess the dissolved concentrations of radionuclides in the source-term. The TSPA model of the source-term incorporates the far-from-equilibrium dissolution of, for example, spent nuclear fuel (SNF) to capture bounding rates of radionuclide availability as the SNF degrades. In addition, for individual radionuclides, the source-term model evaluates solubility constraints that are more indicative of longer-term, equilibrium processes that can limit the potential mass transport from the source term in those cases. These solubility limits represent phase saturation and precipitation processes that can occur either at the waste form as it alters, or at other locations in the near-field environment (e.g., within the invert) if chemical conditions are different. Identification and selection of applicable constraints for solubility-limited radionuclide concentrations is a primary focus in formulating the source-term model for the TSPA. Neptunium is a long-lived radionuclide that becomes a larger fraction of the potential dose …
Date:
March 29, 2005
Creator:
Sassani, D.; van Luik, A. & Summerson, J.
Object Type:
Report
System:
The UNT Digital Library
A 3-D Model of Signaling and Transport Pathways in Epithelial Cells
A 3-dimensional computer model was developed to simulate the spatial and chemical evolution of calcium ions inside an array of human epithelial kidney cells. This is a prototype model, intended to develop a methodology to incorporate much more complex interactions of metabolic and other processes within many types of cells and lead to increased ability to predict cellular responses to disease as well as to chemical and biological warfare situations. Preliminary tests of the model are described.
Date:
April 1, 2005
Creator:
Quong, Andrew A. & Westbrook, Charles K.
Object Type:
Report
System:
The UNT Digital Library
3-D Seismic Experimentation and Advanced Processing/Inversion Development for Investigations of the Shallow Subsurface
Gian Fradelizio, a Rice Ph.D. student has completed reprocessing the 3D seismic reflection data acquired at Hill AFB through post-stack depth migration for comparison to the traveltime and waveform tomography results. Zelt, Levander, Fradelizio, and 5 others spent a week at Hill AFB in September 2005, acquiring an elastic wave data set along 2 profiles. We used 60 3-component Galperin mounted 40 Hz geophones recorded by 3 GEOMETRICS Stratavision systems. The seismic source employed was a sledgehammer used to generate transverse, and radial, and vertical point source data. Data processing has begun at Rice to generate S-wave reflection and refraction images. We also acquired surface wave and ground penetrating rada data to complement the elastic wave dataset.
Date:
June 1, 2005
Creator:
Levander, Alan R.
Object Type:
Report
System:
The UNT Digital Library
3-D Simulations of Plasma Wakefield Acceleration with Non-Idealized Plasmas and Beams
3-D Particle-in-cell OSIRIS simulations of the current E-162 Plasma Wakefield Accelerator Experiment are presented in which a number of non-ideal conditions are modeled simultaneously. These include tilts on the beam in both planes, asymmetric beam emittance, beam energy spread and plasma inhomogeneities both longitudinally and transverse to the beam axis. The relative importance of the non-ideal conditions is discussed and a worst case estimate of the effect of these on energy gain is obtained. The simulation output is then propagated through the downstream optics, drift spaces and apertures leading to the experimental diagnostics to provide insight into the differences between actual beam conditions and what is measured. The work represents a milestone in the level of detail of simulation comparisons to plasma experiments.
Date:
September 27, 2005
Creator:
Deng, S.; Katsouleas, T.; Lee, S.; Muggli, P.; Mori, W. B.; Hemker, R. et al.
Object Type:
Article
System:
The UNT Digital Library
3-Nitropropionic Acid is a Suicide Inhibitor of MitochondrialRespiration that, Upon Oxidation by Complex II, Forms a Covalent AdductWith a Catalytic Base Arginine in the Active Site of the Enzyme
We report three new structures of mitochondrial respiratory Complex II (succinate ubiquinone oxidoreductase, E.C. 1.3.5.1) at up to 2.1 {angstrom} resolution, with various inhibitors. The structures define the conformation of the bound inhibitors and suggest the residues involved in substrate binding and catalysis at the dicarboxylate site. In particular they support the role of Arg297 as a general base catalyst accepting a proton in the dehydrogenation of succinate. The dicarboxylate ligand in oxaloacetate-containing crystals appears to be the same as that reported for Shewanella flavocytochrome c treated with fumarate. The plant and fungal toxin 3-nitropropionic acid, an irreversible inactivator of succinate dehydrogenase, forms a covalent adduct with the side chain of Arg297. The modification eliminates a trypsin cleavage site in the flavoprotein, and tandem mass spectroscopic analysis of the new fragment shows the mass of Arg 297 to be increased by 83 Da and to have potential of losing 44 Da, consistent with decarboxylation, during fragmentation.
Date:
December 1, 2005
Creator:
Huang, Li-shar; Sun, Gang; Cobessi, David; Wang, Andy C.; Shen,John T.; Tung, Eric Y. et al.
Object Type:
Article
System:
The UNT Digital Library
4-D High-Resolution Seismic Reflection Monitoring of Miscible CO2 Injected into a Carbonate Reservoir
The objective of this research project is to acquire, process, and interpret multiple high-resolution 3-D compressional wave and 2-D, 2-C shear wave seismic data to observe changes in fluid characteristics in an oil field before, during, and after the miscible carbon dioxide (CO{sub 2}) flood that began around December 1, 2003, as part of the DOE-sponsored Class Revisit Project (DOE DE-AC26-00BC15124). Unique and key to this imaging activity is the high-resolution nature of the seismic data, minimal deployment design, and the temporal sampling throughout the flood. The 900-m-deep test reservoir is located in central Kansas oomoldic limestones of the Lansing-Kansas City Group, deposited on a shallow marine shelf in Pennsylvanian time. After 18 months of seismic monitoring, one baseline and six monitor surveys clearly imaged changes that appear consistent with movement of CO{sub 2} as modeled with fluid simulators.
Date:
September 1, 2005
Creator:
Miller, Richard D.; Raef, Abdelmoneam E.; Byrnes, Alan P. & Harrison, William E.
Object Type:
Report
System:
The UNT Digital Library
An 8-Element Fast-Neutron Double-Scatter Directional Detector.
We have constructed a fast-neutron double-scatter spectrometer that efficiently measures the neutron spectrum and direction of a spontaneous fission source. The device consists of two planes of organic scintillators, each having an area of 125 cm{sup 2}, efficiently coupled to photomultipliers. The four scintillators in the front plane are 2 cm thick, giving almost 25% probability of detecting an incident fission-spectrum neutron at 2 MeV by proton recoil and subsequent ionization. The back plane contains four 5-cm-thick scintillators which give a 40% probability of detecting a scattered fast neutron. A recordable double-scatter event occurs when a neutron is detected in both a front plane detector and a back plane detector within an interval of 500 nanoseconds. Each double-scatter event is analyzed to determine the energy deposited in the front plane, the time of flight between detectors, and the energy deposited in the back plane. The scattering angle of each incident neutron is calculated from the ratio of the energy deposited in the first detector to the kinetic energy of the scattered neutron.
Date:
July 31, 2005
Creator:
Vanier, P. E. & Forman, L.
Object Type:
Article
System:
The UNT Digital Library
8 GeV H- ions: Transport and injection
Fermilab is working on the design of an 8 GeV superconducting RF H{sup -} linac called the Proton Driver. The energy of H{sup -} beam will be an order of magnitude higher than the existing ones. This brings up a number of technical challenges to transport and injection of H{sup -} ions. This paper will focus on the subjects of stripping losses (including stripping by blackbody radiation, field and residual gas) and carbon foil stripping efficiency, along with a brief discussion on other issues such as Stark states lifetime of hydrogen atoms, single and multiple Coulomb scattering, foil heating and stress, radiation activation, collimation and jitter correction, etc.
Date:
May 1, 2005
Creator:
Chou, W.; Bryant, H.; Drozhdin, A.; Hill, C.; Kostin, M.; Macek, R. et al.
Object Type:
Article
System:
The UNT Digital Library
10 MMBt/Hr AFBC Commercial Demonstration Cedar Lane Farms
The objective of this project was to demonstrate and promote the commercialization of coal-fired atmospheric fluidized bed combustion (AFBC) systems, with limestone addition for SO2 emissions control and a baghouse for particulate emissions control. This AFBC system was targeted for small scale industrial-commercial-institutional space and process heat applications in the 4-40 MMBtu/hr size range. A cost effective and environmentally acceptable AFBC technology in this size range could displace a considerable amount of heating gas and oil with coal, while resulting in significant total cost savings to the owner/operators.
Date:
October 31, 2005
Creator:
Keener, Harold M.; Wicks, Mary H.; Machamer, Tom; Hoecke, Dave; Bonk, Don & Brown, Bob
Object Type:
Report
System:
The UNT Digital Library
17.5% p-Type Silicon Heterojunction Solar Cells with HWCVD a-Si:H as the Emitter and Back Contact
Thin hydrogenated amorphous silicon (a-Si:H) layers deposited by hot-wire chemical vapor deposition (HWCVD) are used as both emitters and back contacts in silicon heterojunction solar cells. Low interface recombination velocity and high open-circuit voltage are achieved by a low substrate temperature (<150 deg C) intrinsic a-Si:H deposition which ensures immediate amorphous silicon deposition. This is followed by deposition of doped a-Si:H at a higher temperature (>200 deg C) which appears to improve dopant activation. With an i/n a-Si:H emitter, we obtain a confirmed efficiency of 17.1% on textured p-type float-zone (FZ) silicon with a screen-printed aluminum back-surface-field (Al-BSF) contact. Employing a-Si:H as both the front emitter and the back contact, we achieve a confirmed efficiency of 17.5%, the highest reported efficiency for a p-type c-Si based heterojunction solar cell.
Date:
November 1, 2005
Creator:
Wang, T. H.; Page, M. R.; Iwaniczko, E.; Wang, Q.; Xu,Y.; Yan, Y. et al.
Object Type:
Article
System:
The UNT Digital Library
19-electron intermediates in the Ligand Substitution of CpW(CO)3with a Lewis Base
Odd electron species are important intermediates in organometallic chemistry, participating in a variety of catalytic and electron-transfer reactions which produce stable even-electron products. While electron deficient 17-electron (17e) radicals have been well characterized, the possible existence of short-lived 19-electron (19e) radicals has been a subject of continuing investigation. 19e radicals have been postulated as intermediates in the photochemical ligand substitution and disproportionation reactions of organometallic dimers containing a single metal-metal bond, yet the reactions of these intermediates on diffusion-limited time scales (ns-{micro}s) have never been directly observed. This study resolves the 19e dynamics in the ligand substitution of 17e radicals CpW(CO){sub 3}{sup {sm_bullet}} (Cp = C{sub 5}H{sub 5}) with the Lewis base P(OMe){sub 3}, providing the first complete description 19e reactivity.
Date:
December 14, 2005
Creator:
Cahoon, James F.; Kling, Matthias F.; Sawyer, Karma R.; Frei,Heinz & Harris, Charles B.
Object Type:
Article
System:
The UNT Digital Library
21-kW Thin-Film PV Technology Validation -- An NREL/Solar Energy Centre of India MOU Cooperative Project
This paper summarizes findings during a one-week (27-31 October 2003) site visit to the Thin-Film Technology Test Bed at India's Solar Energy Centre (SEC) near New Delhi. The U.S. and Indian governments signed a Memorandum of Understanding in March 2000 to undertake a 50-50 cost-shared 21-kW thin-film PV technology validation project to evaluate the performance of thin-film photovoltaic (PV) modules under Indian climatic conditions. This project benefits Indian researchers by giving them experience with cost-effective PV materials, and it benefits the United States because data will be sent to the appropriate U.S. thin-film PV manufacturers for evaluation and analysis. During the visit, NREL personnel engaged in technical discussions regarding thin-film PV technologies with Ministry of Non-Conventional Energy Sources engineers and scientists. Issues included inspecting the newly constructed arrays, discussing better methods of electrically loading the PV arrays, taking I-V traces, and gathering baseline I-V data.
Date:
January 1, 2005
Creator:
McNutt, P. F. & Ullal, H. S.
Object Type:
Article
System:
The UNT Digital Library
21-PWR Waste Package Side and End Impacts
The objective of this calculation is to determine the structural response of a 21-Pressurized Water Reactor (PWR) spent nuclear fuel waste package impacting an unyielding surface. A range of initial velocities and initial angles between the waste package and the unyielding surface is studied. The scope of this calculation is limited to estimating the area of the outer shell (OS) where the residual stress exceeds a given limit (hereafter ''damaged area''). The stress limit is defined as a fraction of the yield strength of the OS material, Alloy 22 (SB-575 N06022), at the appropriate temperature. The design of the 21-PWR waste package used in this calculation is that defined in Reference 8. However, a value of 4 mm was used for the gap between the inner shell and the OS, and the thickness of the OS was reduced by 2 mm. The sketch in Attachment I provides additional information not included in Reference 8. All obtained results are valid for this design only. This calculation is associated with the waste package design and was performed by the Specialty Analyses and Waste Package Design Section. The waste package (i.e. uncanistered spent nuclear fuel disposal container) is classified as Quality Level 1.
Date:
August 29, 2005
Creator:
Schmitt, T.
Object Type:
Report
System:
The UNT Digital Library
53 MHz beam loading compensation for slip stacking in the Fermilab Main Injector
Recently In-Phase and Quadrature (I&Q) was added to both the 53 MHz Feedback and Feedforward Beam Loading Compensation for Slip Stacking in the Fermilab Main Injector. With 53 MHz Feedback, we can now turn the 18 Radio Frequency (RF) Stations off down to below 100 V. In using I&Q on Feedforward, beam loading compensation to the beam on both the upper and lower frequencies of Slip Stacking can be applied as we slip the beam. I&Q theory will be discussed.
Date:
May 1, 2005
Creator:
Dey, J. & Kourbanis, I.
Object Type:
Article
System:
The UNT Digital Library
A 90-GHz Photoinjector
Photocathode rf guns depend on mode locked laser systems to produce an electron beam at a given phase of the rf. In general, the laser pulse is less than {sigma}{sub z} = 10{sup o} of rf phase in length and the required stability is on the order of {Delta}{phi} = 1{sup o}. At 90 GHz (W-band), these requirements correspond to {sigma}{sub z} = 333 fsec and {Delta}{phi} = 33 fsec. Laser system with pulse lengths in the fsec regime are commercially available, the timing stability is a major concern. We propose a multi-cell W-band photoinjector that does not require a mode locked laser system. Thereby eliminating the stability requirements at W-band. The laser pulse is allowed to be many rf periods long. In principle, the photoinjector can now be considered as a thermionic rf gun. Instead of using an alpha magnet to compress the electron bunch, which would have a detrimental effect on the transverse phase space quality due to longitudinal phase space mixing, we propose to use long pulse laser system and a pair of undulators to produce a low emittance, high current, ultra-short electron bunch for beam dynamics experiments in the 90 GHz regime.
Date:
September 12, 2005
Creator:
Palmer, D. T.; Hogan, M. J.; Ferrario, M. & Serafini, L.
Object Type:
Article
System:
The UNT Digital Library
The 100,000 amp dc power supply for a staged hadron collider super ferric magnet
A 1.5 volt 100,000 amp DC switcher power supply was developed for testing a superferric magnet string at FNAL. This supply was used during testing as both the ramping supply and holding supply powering a single magnet load with a total load resistance of 0.7{micro} Ohms. The supply consists of ten paralleled switcher cells, powered by a 400 volt/600 Amp DC power supply. Each cell consists of an IGBT H-bridge driving a step-down transformer at a switching frequency of 2 kHz. The transformer has an effective turns ratio of 224:1. The secondary consists of 32 parallel single-turn full wave rectifier windings. The rectification is done with 64 Shottky diodes. Each cell is rated at 1.5 volts/10,000 amps. During this test each cell was operated as a constant power source without load current or field feedback. This paper will describe the design of the switcher cell and control system used during testing. We will also describe the next level of improvements to the current feedback system to improve the ramp control.
Date:
September 1, 2005
Creator:
Hays, Steven L.; Claypool, Bradley & Foster, G. William
Object Type:
Article
System:
The UNT Digital Library
100/300 Area Aquifer Tube Task: Annual Sampling for Fiscal Year 2006, Hanford Site, Washington
This letter report has been prepared to provide the U.S. Department of Energy, U.S. Environmental Protection Agency, Washington State Department of Ecology, and Hanford Site contractors with logistical information pertaining to the use of certain environmental monitoring sites. Although the distribution is not limited, It is not intended for general distribution beyond that audience.
Date:
November 1, 2005
Creator:
Peterson, Robert E.; Hartman, Mary J.; Raidl, Robert F. & Borghese, Jane V.
Object Type:
Report
System:
The UNT Digital Library
The 100 kA current leads for a superconducting transmission line magnet
A pair of current leads to power a transmission line magnet cooled at liquid helium temperature has been designed and developed at Fermilab. The leads designed to carry 100 kA dc current. Each lead consists of a warm end, heat exchange section and a cold end. The warm end is a half moon plate and cylinder brazed together. The heat exchange section is made of 202 copper rods arranged in a staggered pattern. Each rod is 6.35 mm in diameter and 1650 mm in length. The rods were soft-soldered into 12.7 mm deep holes at both warm and cold ends. The helium gas flow, guided by anodized aluminum baffles along the lead length, allows for a relatively high heat transfer coefficient between the current carrying rods and cooling helium gas. As a result the current leads were successfully tested with a ramping current of up to 104 kA. The current lead design, assembly work and the test results are presented.
Date:
September 1, 2005
Creator:
Huang, Yuenian; Foster, William; Kim, Seog-Whan; Mazur, Peter; Oleck, Andrew; Piekarz, Henryk et al.
Object Type:
Article
System:
The UNT Digital Library
120 MW, 800 MHz Magnicon for a Future Muon Collider
Development of a pulsed magnicon at 800 MHz was carried out for the muon collider application, based on experience with similar amplifiers in the frequency range between 915 MHz and 34.3 GHz. Numerical simulations using proven computer codes were employed for the conceptual design, while established design technologies were incorporated into the engineering design. A cohesive design for the 800 MHz magnicon amplifier was carried out, including design of a 200 MW diode electron gun, design of the magnet system, optimization of beam dynamics including space charge effects in the transient and steady-state regimes, design of the drive, gain, and output cavities including an rf choke in the beam exit aperture, analysis of parasitic oscillations and design means to eliminate them, and design of the beam collector capable of 20 kW average power operation.
Date:
December 15, 2005
Creator:
Hirshfield, Jay L.
Object Type:
Report
System:
The UNT Digital Library