Creation of 20-year data set of surface infrared fluxes from satellite measurements. A reliable estimate of the surface downwelling longwave radiation flux (DLF) is a glaring void in available forcing data sets for models of Arctic sea ice and ocean circulation. We have developed a new method to estimate the DLF from a combination of satellite sounder retrievals and brightness temperatures from the TIROS Operational Vertical Sounder (TOVS), which has flown on NOAA polar-orbiting satellites continuously since late 1979. The overarching goal of this project was to generate a 20-year data set of surface downwelling longwave flux measurements from TOVS data over the Arctic Ocean. Daily gridded fields of DLF were produced with a spatial resolution of (100 km){sup 2} north of 60{sup o}N for 22.5 years rather than only 20. Surface measurements from the field station at Barrow, AK--part of the Atmospheric Radiation Measurement (ARM) Program --and from the Surface Heat Budget of the Arctic (SHEBA) were used to validate the satellite-derived fluxes and develop algorithm improvements for conditions that had resulted in systematic errors in early versions of the algorithm. The resulting data set has already been sent to two other investigators for incorporation into their research, and …

This report discusses the historical and current political stability of Afghanistan. Detailed in the report is a description of the limited operations of Al Qaeda within Afghanistan. The report also describes that the primary goal of the U.S. military within the region is to create stability.

Photocopy of an Alternate to Delegate Elevation Form and fax to Charles McGarry from Al Daniels on June 15, 2004, including a message: "Alternate Delegate Elevation Form."

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This report covers a one-year, no-cost extension that was requested and received in 2003; the extension runs through September 14, 2004. The extension has been used to continue data analysis and prepare additional manuscripts for submission to refereed journals. The primary research focus of the original three-year period of funding was to develop and demonstrate an automated method of conducting two-dimensional (2D) shallow-seismic surveys with the goal of saving time, effort, and money. Tests involving the second generation of the hydraulic geophone-planting device dubbed the ''Autojuggie'' showed that large numbers of geophones can be placed quickly and automatically and can acquire high-quality data, although not under all conditions (please see the Status and Results of Experiments sections for details). In some easy-access environments, this device could make shallow seismic surveying considerably more efficient and less expensive. The most recent research analyzed the difference in seismic response of the geophones with variable geophone spike length and geophones attached to various steel media. Experiments investigated the azimuthal dependence of the quality of data relative to the orientation of the rigidly attached geophones. Other experiments designed to test the hypothesis that the data are being amplified in much the same way that an …

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Approximately 10 percent of all radioactive wastes produced in the U. S. are mixed with hazardous or toxic chemicals and therefore can not be placed in secure land disposal facilities. Mixed wastes containing hazardous organic chemicals are often incinerated, but volatile radioactive elements are released directly into the biosphere. Some mixed wastes do not currently have any identified disposal option and are stored locally awaiting new developments. Biological treatment has been proposed as a potentially safer alternative to incineration for the treatment of hazardous organic mixed wastes, since biological treatment would not release volatile radioisotopes and the residual low-level radioactive waste would no longer be restricted from land disposal. Prior studies have shown that toxicity associated with acetonitrile is a significant limiting factor for the application of biotreatment to mixed wastes and excessive dilution was required to avoid inhibition of biological treatment. In this study, we demonstrate that a novel reactor configuration, where the concentrated toxic waste is drip-fed into a complete-mix bioreactor containing a pre-concentrated active microbial population, can be used to treat a surrogate acetonitrile mixed waste stream without excessive dilution. Using a drip-feed bioreactor, we were able to treat a 90,000 mg/L acetonitrile solution to less than …

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This report provides an overview of Legal Analysis of Houses of Worship Free Speech Restoration Act related to Campaign Activity by Churches.

Organic ligands that exhibit a high degree of metal ion recognition are essential precursors for developing separation processes and sensors for metal ions. Since the beginning of the nuclear era, much research has focused on discovering ligands that target specific radionuclides. Members of the Group 1A and 2A cations (e.g., Cs, Sr, Ra) and the f-block metals (actinides and lanthanides) are of primary concern to DOE. Although there has been some success in identifying ligand architectures that exhibit a degree of metal ion recognition, the ability to control binding affinity and selectivity remains a significant challenge. The traditional approach for discovering such ligands has involved lengthy programs of organic synthesis and testing that, in the absence of reliable methods for screening compounds before synthesis, have resulted in much wasted research effort. This project seeks to enhance and strengthen the traditional approach through computer-aided design of new and improved host molecules. Accurate electronic structure calculations are coupled with experimental data to provide fundamental information about ligand structure and the nature of metal-donor group interactions (design criteria). This fundamental information then is used in a molecular mechanics model (MM) that helps us rapidly screen proposed ligand architectures and select the best members …

Testimony issued by the General Accounting Office with an abstract that begins "The General Accounting Office (GAO) discussed some of the work the it is undertaking to address various operations and rebuilding efforts in Iraq. Specifically, GAO has a body of ongoing work looking at a range of issues involving Iraq, including Iraq's transitional administrative law, efforts to restore essential services to the Iraqi people, and the effectiveness of logistics activities during Operation Iraqi Freedom, among others. Importantly, given the challenging security environment in Iraq and the various other accountability organizations involved in the oversight process, it is attempting to coordinate its engagement planning and execution with other organizations as appropriate. In this testimony it discussed (1) its report (GAO-04-605) that was released yesterday on the contract award procedures for contracts awarded in fiscal year 2003 to help rebuild Iraq and (2) its preliminary findings on the military's use of global logistics support contracts. These support contracts have emerged as important tools in providing deployed military services with a wide range of logistics services."

On-farm conversion of poultry litter into energy is a unique market connected opportunity for commercialization of small modular bioenergy systems. The United States Department of Energy recognized the need in the poultry industry for alternative litter management as an opportunity for bioenergy. The DOE created a relevant topic in the December 2000 release of the small business innovative research (SBIR) grant solicitation. Community Power Corporation responded to this solicitation by proposing the development of a small modular gasification and gas cleanup system to produce separate value streams of clean producer gas and mineral rich solids. This phase II report describes our progress in the development of an on-farm litter to energy system.

The scale-up of deposition in next-step devices such as ITER will pose new diagnostic challenges. Codeposition of hydrogen with carbon needs to be characterized and understood in the initial hydrogen phase in order to mitigate tritium retention and qualify carbon plasma facing components for DT operations. Plasma facing diagnostic mirrors will experience deposition that is expected to rapidly degrade their reflectivity, posing a new challenge to diagnostic design. Some eroded particles will collect as dust on interior surfaces and the quantity of dust will be strictly regulated for safety reasons - however diagnostics of in-vessel dust are lacking. We report results from two diagnostics that relate to these issues. Measurements of deposition on NSTX with 4 Hz time resolution have been made using a quartz microbalance in a configuration that mimics that of a typical diagnostic mirror. Often deposition was observed immediately following the discharge suggesting that diagnostic shutters should be closed as soon as possible after the time period of interest. Material loss was observed following a few discharges. A novel diagnostic to detect surface particles on remote surfaces was commissioned on NSTX.

This report describes the design issues that are associated with a superconducting focusing solenoid that goes around a liquid hydrogen absorber for the Muon Ionization Cooling Experiment (MICE) proposed for the Rutherford Appleton Laboratory. The solenoid consists of two superconducting coils that may operated at the same polarity or at opposite polarities. As a result, the coils and their support structure must be designed to carry a 360-ton inter-coil force that is forcing the coils apart along their axis. The basic design parameters for the focusing magnet are discussed. The magnet and its cryostat are designed so that the absorber can be assembled and tested before installation into the pre-tested focusing solenoid. Safety requirements for MICE dictate that the insulating vacuum for the superconducting magnet be separated from the insulating vacuum for the absorber and that both vacuum be separated from the experiment vacuum and the vacuum within adjacent RF cavities. The safety issues associated with the arrangement of the various vacuums in the MICE focusing modules are presented. The effect of magnet operation and magnet quench on the liquid hydrogen absorber is also discussed.

Various forms of general and localized corrosion represent principal threats to the integrity of DOE liquid waste storage tanks. These tanks, which are of a single wall or double wall design, depending upon their age, are fabricated from welded carbon steel and contain a complex waste-form comprising NaOH and NaNO3, among other chemicals. Because waste leakage can have a profound environmental impact, considerable interest exists in predicting the accumulation of corrosion damage, so as to more effectively schedule maintenance and repair.

NSTX High Harmonic Fast Wave (HHFW) current drive discharges will require density control for acceptable efficiency. We have compared boronization on hot and cold surfaces, varying helium glow discharge conditioning (HeGDC) durations, and brief morning boronization with between discharge boronization for improving density control. Access to Ohmic H-modes was enabled by boronization on hot surfaces, however, the duration of the effectiveness of hot and cold boronization was comparable. A 15 min HeGDC between discharges was needed for reproducible L-H transitions. Brief morning boronization followed by a comparable duration of applied HeGDC restored and enhanced good conditions. Additional short boronizations between discharges did not improve plasma performance (reduced recycling, reduced impurity luminosities, earlier L-H transitions, longer plasma current flattops, higher stored energies) if conditions were already good. Between discharge boronization requires increases in the duty cycle due to the need for additional HeGDC to remove co-deposited D{sub 2}.

This CRADA project involved the cooperative research of investigators in ORNL's Center for Engineering Science Advanced Research (CESAR) with researchers at Caterpillar, Inc. The subject of the research was the development of cooperative control strategies for autonomous vehicles performing applications of interest to Caterpillar customers. The project involved three Phases of research, conducted over the time period of November 1998 through December 2001. This project led to the successful development of several technologies and demonstrations in realistic simulation that illustrated the effectiveness of the control approaches for distributed planning and cooperation in multi-robot teams.

Energy efficiency standards for appliances mandate that appliance manufacturers not manufacture or import models that have a test energy efficiency below a specified level after the standard effective date. Thus, appliance standards set a floor for energy efficiency. But do they also induce more significant changes in the efficiencies that manufacturers offer after the standard becomes effective? To address this question, we undertook an examination of before-standard and after-standard efficiency of models on the market for three products: (1) Refrigerators (1990, 1993, and 2001 standards); (2) Room air conditioners (1990 and 2000 standards); and (3) Gas furnaces (1992 standard).

We examine the efficiency with which supernova-enriched gas may be ejected from dwarf disk galaxies, using a methodology previously employed to study the self-enrichment efficiency of dwarf spheroidal systems. Unlike previous studies that focused on highly concentrated starbursts, in the current work we consider discrete supernova events spread throughout various fractions of the disk. We model disk systems having gas masses of 10{sup 8} and 10{sup 9} M{sub {circle_dot}} with supernova rates of 30, 300, and 3000 Myr{sup -1}. The supernova events are confined to the midplane of the disk, but distributed over radii of 0, 30, and 80% of the disk radius, consistent with expectations for Type II supernovae. In agreement with earlier studies, we find that the enriched material from supernovae is largely lost when the supernovae are concentrated near the nucleus, as expected for a starburst event. In contrast, we find the loss of enriched material to be much less efficient (as low as 21%) when the supernovae occur over even a relatively small fraction of the disk. The difference is due to the ability of the system to relax following supernova events that occur over more extended regions. Larger physical separations also reduce the likelihood of …

During the epoch of large galaxy formation, thermal instability leads to the formation of a population of cool fragments which are embedded within a background of tenuous hot gas. The hot gas attains a quasi hydrostatic equilibrium. Although the cool clouds are pressure confined by the hot gas, they fall into the galactic potential, subject to drag from the hot gas. The release of gravitational energy due to the infall of the cool clouds is first converted into their kinetic energy which is subsequently dissipated as heat. The cool clouds therefore represent a potentially significant energy source for the background hot gas, depending upon the ratio of thermal energy deposited within the clouds versus the hot gas. In this paper, we show that most of dissipated energy is deposited in to the tenuous hot halo gas, which provides a source of internal energy to replenish its loss in the hot gas through Bremsstrahlung cooling and conduction into the cool clouds. Through this process, the multi-phase structure of the interstellar medium is maintained.

Radionuclide and metal contaminants are present in the vadose zone and groundwater throughout the U.S. Department of Energy (DOE) weapons complex. In situ containment and stabilization of these contaminants in vadose zones or groundwater is a cost-effective treatment strategy. Our facilitated approach relies upon the hydrolysis of introduced urea to cause the acceleration of calcium carbonate precipitation (and trace metal coprecipitation) by increasing groundwater pH and alkalinity (Fujita et al., 2000; Warren et al., 2001). Subsurface urea hydrolysis is catalyzed by the urease enzyme, which may be either introduced with the urea or produced in situ by ubiquitous subsurface urea hydrolyzing microorganisms. Because the precipitation processes are irreversible and many western aquifers are saturated with respect to calcite, the co-precipitated metals and radionuclides will be effectively removed from groundwater. The rate at which trace metals are incorporated into calcite is a function of calcite precipitation kinetics, adsorption interactions between the calcite surface and the trace metal in solution (Zachara et al., 1991), solid solution properties of the trace metal in calcite (Tesoriero and Pankow, 1996), and also the surfaces upon which the calcite is precipitating. A fundamental understanding of the coupling of calcite precipitation and trace metal partitioning, and how …

Radionuclide and metal contaminants are present in the vadose zone and groundwater throughout the U.S. Department of Energy (DOE) weapons complex. In situ containment and stabilization of these contaminants in vadose zones or groundwater is a cost-effective treatment strategy. Our facilitated approach relies upon the hydrolysis of introduced urea to cause the acceleration of calcium carbonate precipitation (and trace metal coprecipitation) by increasing groundwater pH and alkalinity (Fujita et al., 2000; Warren et al., 2001). Subsurface urea hydrolysis is catalyzed by the urease enzyme, which may be either introduced with the urea or produced in situ by ubiquitous subsurface urea hydrolyzing microorganisms. Because the precipitation processes are irreversible and many western aquifers are saturated with respect to calcite, the co-precipitated metals and radionuclides will be effectively removed from groundwater. The rate at which trace metals are incorporated into calcite is a function of calcite precipitation kinetics, adsorption interactions between the calcite surface and the trace metal in solution (Zachara et al., 1991), solid solution properties of the trace metal in calcite (Tesoriero and Pankow, 1996), and also the surfaces upon which the calcite is precipitating. A fundamental understanding of the coupling of calcite precipitation and trace metal partitioning, and how …

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