Analysis of Mixtures of Alcohols by Acylation (open access)

Analysis of Mixtures of Alcohols by Acylation

From abstract: "Recently a general chemical method for the analysis of mixtures of alcohols appeared, using pyridine catalyzed acetylation and second order kinetics to determine the amount of the faster reacting component. The use of 0.25M isobutyric anhydride in pyridine containing 0.0025M perchloric acid as catalyst promotes the rate of the reaction and diminishes the time necessary to perform an analysis. A mathematical treatment of the data and kinetic plot reduces the number of kinetic points to only four or five. The mixtures are primarily composed of isomers."
Date: November 1961
Creator: Fellows, William Dean & Fritz, James S. (James Sherwood), 1924-
System: The UNT Digital Library