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The development of precipitated iron catalysts with improved stability
The objective of this program is to identify the chemical principles governing the deactivation of precipitated iron catalysts during Fischer-Tropsch synthesis and to use these chemical principles in the design of catalysts suitable for slurry reactors. The performance targets are 88% CO+H{sub 2} conversion with less than 1% deactivation/day for 1 month and a methane and ethane selectivity of no more than 7% (based on hydrocarbons and oxygenates only) at a space velocity of at least 2 normal liters per hr per gram iron (NL/hr/gFe) using a synthesis gas with 0.5-1.0 H{sub 2}:CO ratio in a slurry reactor.
Date:
May 6, 1992
Creator:
Abrevaya, H.
System:
The UNT Digital Library
An update on passive correctors for the SSC dipole magnets
The concept of correction of the magnetization sextupole became a topic of discussion as soon as it was realized that superconductor magnetization could have a serious effect on the SSC beam during injection. Several methods of correction were proposed. These included (1) correction with active bore tube windings like those on the HERA machine which correct out magnetization sextupole and the sextupole due to iron saturation, (2) correction with persistent sextupole windings mounted on the bore tube (3) correction using passive superconductor (4) correction using ferromagnetic material, and (5) correction using oriented magnetized materials. This report deals with the use of passive superconductor to correct the magnetization sextupole. Two basic methods are explored in this report: (1) One can correct the magnetization sextupole by changing the diameter of the superconductor filaments in one or more blocks of the SSC dipole. (2) One can correct the magnetization sextupole and decapole by mounting passive superconducting wires on the inside of the SSC dipole coil bore. In addition, an assessment of the contribution of each conductor in the dipole to the magnetization sextupole and decapole is shown. 38 refs, 25 figs., 15 tabs.
Date:
May 1, 1991
Creator:
Green, Michael A.
System:
The UNT Digital Library
A Program of FRC Theory Research Annual Report
At the request of the Office of Fusion Energy, a group of experts was convened on February 6--8, 1990. This group met to assess the world data base on Reversed Field Pinch (RFP) physics, and, further, to assess the role of the ZTH experiment in providing reactor relevant physics understanding for that confinement geometry. This group met, analyzed some of the relevant literature, and heard extensive presentations on the physics of the RFP and the plans for the ZTH and RFX devices. The conclusions of this group of experts are contained in this report.
Date:
May 18, 1990
Creator:
Krall, Nicholas A.
System:
The UNT Digital Library
Site Specific Verification Guidelines.
The Bonneville Power Administration (BPA) and the Northwest region have moved from energy surplus to a time when demand for energy is likely to exceed available supplies. The Northwest Power Planning Council is calling for a major push to acquire new resources.'' To meet anticipated loads in the next decade, BPA and the region must more than double that rate at which we acquire conservation resources. BPA hopes to achieve some of this doubling by programs independently designed and implemented by utilities and other parties without intensive BPA involvement. BPA will accept proposals for programs using performance-based payments, in which BPA bases its reimbursement to the sponsor on measured energy savings rather than program costs. To receive payment for conservation projects developed under performance-based programs, utilities and other project developers must propose verification plans to measure the amount of energy savings. BPA has traditionally used analysis of billing histories, before and after measure installation, adjusted by a comparison group on non-participating customers to measure conservation savings. This approach does not work well for all conversation projects. For large or unusual facilities the comparison group approach is not reliable due to the absence of enough comparable non-participants to allow appropriate statistical …
Date:
May 1, 1992
Creator:
Harding, Steve; Gordon, Frederick M. & Kennedy, Mike
System:
The UNT Digital Library
Repair Welding of Fusion Reactor Components
Recent experimental investigations indicate that the repair welding of irradiated materials containing greater than 1 to 2.5 appm helium leads to catastrophic cracking in the heat affected zone of the weld. The high temperatures and cooling tensile stresses which occur during the welding process lead to enhanced helium bubble growth in the heat affected zone region, resulting in catastrophic cracking upon cooling. An investigation is proposed which seeks to determine the effect of stress state on the helium bubble growth process and develop engineering modifications to the welding process based upon this understanding in an attempt to alleviate or eliminate the weld cracking problem in type 316 stainless steel materials.
Date:
May 20, 1992
Creator:
Chin, Bryan A.
System:
The UNT Digital Library
Investigation of joining techniques for advanced austenitic alloys
Modified Alloys 316 and 800H, designed for high temperature service, have been developed at Oak Ridge National Laboratory. Assessment of the weldability of the advanced austenitic alloys has been conducted at the University of Tennessee. Four aspects of weldability of the advanced austenitic alloys were included in the investigation.
Date:
May 1, 1991
Creator:
Lundin, C. D.; Qiao, C. Y. P.; Kikuchi, Y.; Shi, C. & Gill, T. P. S.
System:
The UNT Digital Library
Milliwatt Generator Project
This report covers progress on the Milliwatt Generator Project from April 1986 through March 1988. Activities included fuel processing and characterization, production of heat sources, fabrication of pressure-burst test units, compatibility studies, impact testing, and examination of surveillance units. The major task of the Los Alamos Milliwatt Generator Project is to fabricate MC2893A heat sources (4.0 W) for MC2730A radioisotope thermoelectric generators (RTGS) and MC3599 heat sources (4.5 W) for MC3500 RTGs. The MWG Project interfaces with the following contractors: Sandia National Laboratories, Albuquerque (designer); E.I. du Pont de Nemours and Co. (Inc.), Savannah River Plant (fuel); Monsanto Research Corporation, Mound Facility (metal hardware); and General Electric Company, Neutron Devices Department (RTGs). In addition to MWG fabrication activities, Los Alamos is involved in (1) fabrication of pressure-burst test units, (2) compatibility testing and evaluation, (3) examination of surveillance units, and (4) impact testing and subsequent examination of compatibility and surveillance units.
Date:
May 1, 1992
Creator:
Latimer, T.W. & Rinehart, G.H.
System:
The UNT Digital Library
Effects of catalytic mineral matter on CO/CO sub 2 , temperature and burning time for char combustion
The temperature of a char particle burning in an oxygen containing atmosphere is the product of a strongly coupled balance between particle size and physical properties, heat transfer from the particle, surface reactivity, CO/CO{sub 2} ratio and gas phase diffusion in the surrounding boundary layer and within the particle. CO{sub 2}/CO ratios can be strongly influenced by catalytic material in the carbon and by the char temperature. In this program we are measuring the CO{sub 2}/CO ratio for both catalyzed and uncatalyzed chars over a wide range of temperature. These results will then be used to develop predictive models for char temperature and burning rates. The electrodynamic balance has been successfully used to make such measurements for single 200{mu}m spherocarb particles. A few theoretical approaches to model a single particle oxidation have been made, but most of them assumed the infinitely thin reaction zone at the particle surface. This approach can not explain pore diffusion limitation, structural change, or reaction at low temperatures inside the particle. Too simplifying solid phase reaction may leads to wrong predictions. In this report, progress on constructing models including both solid and gas phase reaction are reported.
Date:
May 4, 1992
Creator:
Longwell, J. P.; Sarofim, A. F.; Lee, Chun-Hyuk & Modestino, A. J.
System:
The UNT Digital Library
Manufactured Homes Acquisition Program : Heat Loss Assumptions and Calculations, Heat Loss Coefficient Tables.
This manual is intended to assist builders of manufactured homes in assessing the thermal performance of structural components used in the Manufactured Housing Acquisition Program (MAP) sponsored by the Bonneville Power Administration (BPA). U-factors for these components are calculated using the ASHRAE (1989) parallel heat loss method, with adaptations made for the construction practices found in the Pacific Northwest manufactured home industry. This report is divided into two parts. The first part describes the general assumptions and calculation procedures used to develop U-factors and R-values for specific materials used in the construction industry, overall U-factors for component sections, and the impact of complex framing and thermal configurations on various components' heat loss rates. The individual components of manufactured homes are reviewed in terms of overall thermal conductivity. The second part contains tables showing the results of heat loss calculations expressed as U-factors for various configurations of the major building components: floor systems, ceiling systems, wall systems, windows, doors and skylights. These values can be used to establish compliance with the MAP specifications and thermal performance criteria or to compare manufactured homes built to different standards.
Date:
May 1, 1992
Creator:
Davis, Bob & Baylon, David
System:
The UNT Digital Library
Surfaces and Thin Films Studied by Picosecond Ultrasonics
This research is the study of thin films and interfaces via the use of the picosecond ultrasonic technique. In these experiments ultrasonic waves are excited in a structure by means of a picosecond light pulse ( pump pulse''). The propagation of these waves is detected through the use of a probe light pulse that is time-delayed relative to the pump. This probe pulse measures the change {Delta}R(t) in the optical reflectivity of the structure that occurs because the ultrasonic wave changes the optical properties of the structure. This technique make possible the study of the attenuation and velocity of ultrasonic waves up to much higher frequencies than was previously possible (up to least 500 GHz). In addition, the excellent time-resolution of the method makes it possible to study nanostructures of linear dimensions down to 100 {Angstrom} or less by ultrasonic pulse-echo techniques. 25 refs.
Date:
May 1, 1992
Creator:
Maris, J. H. & Tauc, J.
System:
The UNT Digital Library
Comparative mutagenesis of human cells in vivo and in vitro
This report discusses measuring methods of point mutations; high density cell cultures for low dose studies; measurement and sequence determination of mutations in DNA; the mutational spectra of styrene oxide and ethlyene oxide in TK-6 cells; mutational spectrum of Cr in human lymphoblast cells; mutational spectra of radon in TK-6 cells; and the mutational spectra of smokeless tobacco. (CBS)
Date:
May 1, 1992
Creator:
Thilly, W.G.
System:
The UNT Digital Library
Fundamental spectroscopic studies of carbenes and hydrocarbon radicals
This document details activities during this reporting period topics discussed are: The first spectroscopic identification of the HCCCO and DCCCO radicals; detection of new vibrationally excited states of the carbon chain radicals CCH and CCD and the three-membered carbene ring, cyclopropenylidene; determination of an accurate structure of the cumulene carbene H{sub 2}CCC; analysis the hyperfine structure in the SiC radical; and the undertaking of a systematic search for new sulfur bearing radicals.
Date:
May 1, 1992
Creator:
Thaddeus, P. & Gottlieb, C.
System:
The UNT Digital Library
Wolf Point Substation, Roosevelt County, Montana
The Western Area Power Administration (Western), an agency of the United States Department of Energy, is proposing to construct the 115-kV Wolf Point Substation near Wolf Point in Roosevelt County, Montana (Figure 1). As part of the construction project, Western's existing Wolf Point Substation would be taken out of service. The existing 115-kV Wolf Point Substation is located approximately 3 miles west of Wolf Point, Montana (Figure 2). The substation was constructed in 1949. The existing Wolf Point Substation serves as a Switching Station'' for the 115-kV transmission in the region. The need for substation improvements is based on operational and reliability issues. For this environmental assessment (EA), the environmental review of the proposed project took into account the removal of the old Wolf Point Substation, rerouting of the five Western lines and four lines from the Cooperatives and Montana-Dakota Utilities Company, and the new road into the proposed substation. Reference to the new proposed Wolf Point Substation in the EA includes these facilities as well as the old substation site. The environmental review looked at the impacts to all resource areas in the Wolf Point area. 7 refs., 6 figs.
Date:
May 1, 1991
Creator:
unknown
System:
The UNT Digital Library
International research into chlorofluorocarbon (CFC) alternatives
Selected researchers from 21 countries were queried through questionnaires about their current and planned research activities. The results of the survey show that the majority of research being conducted by the respondents is devoted to investigating the hydrogenated fluorocarbon HFC-134a as a replacement for CFC-12 in refrigeration applications. The main issue with this alternative is identifying compatible lubricants that do not reduce its effectiveness.
Date:
May 1, 1992
Creator:
Marseille, T. J.; Shankle, D. L. & Thurman, A. G.
System:
The UNT Digital Library
Research on elementary particle physics: Task P, Studies in theory and phenomenology of elementary particles
Over the last year, work has focused on two areas: the phenomenology of quark-gluon differentiation in jets, and theoretical studies involving Dirac-like equations for various systems. Substantive progress has been made in both areas. A paper comparing details of the Lund and Herwig simulations for quark and gluon jets has been written and accepted by Physical Review D. A paper describing a new type of Dirac equation for the relativistic harmonic oscillator, and finding solutions thereof, has been written and submitted for publication.
Date:
May 1, 1992
Creator:
unknown
System:
The UNT Digital Library
Modeling of Integrated Environmental Control Systems for Coal-Fired Power Plants Quarterly Report: Final Report
The Integrated Environmental Control Model (IECM) was designed to permit the systematic evaluation of environmental control options for pulverized coal-fired (PC) power plants. Of special interest was the ability to compare the performance and cost of advanced pollution control systems to conventional'' technologies for the control of particulate, SO{sub 2} and NO{sub x}. Of importance also was the ability to consider pre-combustion, combustion and post-combustion control methods employed alone or in combination to meet tough air pollution emission standards. Finally, the ability to conduct probabilistic analyses is a unique capability of the IECM. Key results are characterized as distribution functions rather than as single deterministic values. (VC)
Date:
May 1, 1991
Creator:
Rubin, E. S.; Salmento, J. S.; Frey, H. C.; Abu-Baker, A. & Berkenpas, M.
System:
The UNT Digital Library
Demonstration of innovative applicatiions of technology for cost reductions to the CT-121 FGD process
The objective of this project is to demonstrate on a commercial scale several innovative applications of cost-reducing technology to the Chiyoda Thoroughbred-121 (CT-121) process. CT-121 is a second generation flue gas desulfurization (FGD) process which is considered by the Electric Power Research Institute (EPRI) and Southern Company Services (SCS) to be one of the most reliable and lowest cost FGD options for high-sulfur coal-fired utility boiler applications. Demonstrations of the innovative design approaches will further reduce the cost and provide a clear advantage to CT121 relative to competing technology.
Date:
May 15, 1991
Creator:
unknown
System:
The UNT Digital Library
Electrostatic turbulence and transport in the RFP edge
This thesis details measurements of electrostatic turbulence and transport in the Madison Symmetric Torus reversed field pinch. The electrostatic fluctuation levels are found to be large, with {tilde n}{sub e}/n{sub e} {approximately} 30%--55% and {tilde T}{sub e}/T{sub e} {approximately} 15%--40%. The frequency and wavenumber spectra are broad, with {Delta}n {approximately} 70--150 and {Delta}m {approximately} 3--6, and differ from measured magnetic fluctuation spectra. The transport inferred from coherence measurements indicates that electrostatic fluctuations can account for most of the observed particle losses, but contribute only {approximately}20% to the observed electron energy loss.
Date:
May 1, 1992
Creator:
Spragins, C.W.
System:
The UNT Digital Library
The structure of perturbative quantum gravity on a de Sitter background
Classical gravitation on de Sitter space suffers from a linearization instability. One consequence is that the response to a spatially localized distribution of positive energy cannot be globally regular. We use this fact to show that no causal Green's function can give the correct linearized response to certain bilocalized distributions, even though these distributions obey the constraints of linearization stability. We avoid the problem by working on the open submanifold spanned by conformal coordinates. The retarded Green's function is first computed in a simple gauge, then the rest of the propagator is inferred by analyticity -- up to the usual ambiguity about real, analytic and homogeneous terms. We show that the latter can be chosen so as to give a propagator which does not grow in any direction. The ghost propagator is also given and the interaction vertices are worked out.
Date:
May 1, 1992
Creator:
Tsamis, N. C. & Woodward, R. P.
System:
The UNT Digital Library
Theoretical Studies in Nuclear Reactions and Nuclear Structure
Research in the Maryland Nuclear Theory Group focusses on problems in four basic areas of current relevance. Hadrons in nuclear matter; the structure of hadrons; relativistic nuclear physics and heavy ion dynamics and related processes. The section on hadrons in nuclear matter groups together research items which are aimed at exploring ways in which the properties of nucleons and the mesons which play a role in the nuclear force are modified in the nuclear medium. A very interesting result has been the finding that QCD sum rules supply a new insight into the decrease of the nucleon's mass in the nuclear medium. The quark condensate, which characterizes spontaneous chiral symmetry breaking of the late QCD vacuum, decreases in nuclear matter and this is responsible for the decrease of the nucleon's mass. The section on the structure of hadrons contains progress reports on our research aimed at understanding the structure of the nucleon. Widely different approaches are being studied, e.g., lattice gauge calculations, QCD sum rules, quark-meson models with confinement and other hedgehog models. A major goal of this type of research is to develop appropriate links between nuclear physics and QCD. The section on relativistic nuclear physics represents our continuing …
Date:
May 1, 1992
Creator:
unknown
System:
The UNT Digital Library
Weld Penetration and Defect Control
Highly engineered designs increasingly require the use of improved materials and sophisticated manufacturing techniques. To obtain optimal performance from these engineered products, improved weld properties and joint reliability are a necessarily. This requirement for improved weld performance and reliability has led to the development of high-performance welding systems in which pre-programmed parameters are specified before any welding takes place. These automated systems however lack the ability to compensate for perturbations which arise during the welding process. Hence the need for systems which monitor and control the in-process status of the welding process. This report discusses work carried out on weld penetration indicators and the feasibility of using these indicators for on-line penetration control.
Date:
May 15, 1992
Creator:
Chin, Bryan A.
System:
The UNT Digital Library
Two dimensional NMR and NMR relaxation studies of coal structure
This report covers the progress made on the title project for the project period. Four major areas of inquiry are being pursued. Advanced solid state NMR methods are being developed to assay the distribution of the various important functional groups that determine the reactivity of coals. Special attention is being paid to methods that are compatible with the very high magic angle sample spinning rates needed for operation at the high magnetic field strengths available today. Polarization inversion methods utilizing the difference in heat capacities of small groups of spins are particularly promising. Methods combining proton-proton spin diffusion with {sup 13}C CPMAS readout are being developed to determine the connectivity of functional groups in coals in a high sensitivity relay type of experiment. Additional work is aimed a delineating the role of methyl group rotation in the proton NMR relaxation behavior of coals.
Date:
May 27, 1992
Creator:
Zilm, K.W.
System:
The UNT Digital Library
Vortices associated with toroidal ion temperature gradient driven fluctuations
The three nonlinear hydrodynamic equations for potential, parallel ion velocity and ion pressure used in simulations of the toroidal ion temperature gradient driven fluctuations and transport in a shear magnetic field are analyzed for coherent vortex structures. Two types of vortex structures are found: one type for weak shear that is a generalization of the usual modon vortex construction and the second type of solution for strong magnetic shear where the convective nonlinearity in the parallel velocity field generates a cubic trapping nonlinearity in the vorticity equation. These vortex structures show the possibility of explaining the saturated states observed in the numerical simulations as self-organized nonlinear states in contrast to wave turbulence.
Date:
May 1, 1992
Creator:
Horton, W. (Texas Univ., Austin, TX (United States). Inst. for Fusion Studies); Jovanovic, D. (Belgrade Univ. (Yugoslavia). Inst. za Fiziku) & Rasmussen, J.J. (Association Euratom-Risoe National Lab., Roskilde (Denmark))
System:
The UNT Digital Library
Augmented Fish Health Monitoring; Volume 1. Completion Report.
The Bonneville Power Administration (BPA) initiated the Augmented Fish Health Monitoring project in 1986. This project was a five year interagency project involving fish rearing agencies in the Columbia Basin. Historically, all agencies involved with fish health in the Columbia Basin were conducting various levels of fish health monitoring, pathogen screening and collection. The goals of this project were; to identify, develop and implement a standardized level of fish health methodologies, develop a common data collection and reporting format in the area of artificial production, evaluate and monitor water quality, improve communications between agencies and provide annual evaluation of fish health information for production of healthier smolts. This completion report will contain a project evaluation, review of the goals of the project, evaluation of the specific fish health analyses, an overview of highlights of the project and concluding remarks. 8 refs., 1 fig., 4 tabs.
Date:
May 1, 1991
Creator:
Michak, Patty
System:
The UNT Digital Library