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Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes. Final report
Assignment of the vibrational modes Of Os{sub 2}(CO){sub 8}(CHCH{sub 3}) and Os(CO){sub 4}(C{sub 2}H{sub 4)} has given fingerprint vibrational spectra for the following species when chemisorbed on metal catalyst surfaces: ethylidene and ethylene bound in a metallacyclopropane mode. The formation and fragmentation of diosmacyclobutanes have been shown to involve slippage of the outgoing olefin onto a single osmium, and associative exchange of the olefin from that site. The incorporation of vinylcyclopropane without rearrangement has confirmed the absence of a diradical intermediate. The anomalous stability of the diosmacyclobutane derived from trans-2-butene has proven due to greater destabilization (by the substituent methyls) of the slipped intermediate than of the ground state. Reaction of an osmacyclobutane with 1,3- or 1,2-dienes (allenes) gives 1,2 rather than 1,4 addition to the diosmium unit. Treatment of Os(CO){sub 4}(C{sub 2}H{sub 4}) with triflic acid results in the formation of Os(CO){sub 4}(C{sub 2}H{sub 5})OTf. The authors have found that the reaction of an aryl iodine(III) reagent with propargyl stannanes or silanes results in o-iodo propargyl arenes.
Date:
April 25, 1994
Creator:
Norton, J. R.
System:
The UNT Digital Library
Chemically modified electrodes and related solution studies. Final technical report, January 15, 1991--January 14, 1992
This report is divided into 5 sections: Ru{sub 4}/Fe complexes of tetra(4{prime}-methyl-2,2{prime}-bipyridine)porphyrin--catalytic epoxidation of olefins; water oxidation catalysis by doubly linked {mu}-oxo ruthenium complexes; polymer films formed by oxidation of transition metal electrodes into solutions of bisbipyridinealkane ligands; polymer films containing [CpMo({mu}-S)]{sub 2}S{sub 2}CHR dinuclear clusters;and conducting polymer films for catalyst incorporation.
Date:
April 1, 1993
Creator:
Elliott, C. M.
System:
The UNT Digital Library
Pegmatites of the Crystal Mountain District, Larimer County, Colorado
From introduction: The study of the Crystal Mountain district, Larimer County, Colo., is but one phase of this post-World War II pegmatite program, in part carried out by the Geological Survey on behalf of the Division of Raw Materials of the Atomic Energy Commission.
Date:
April 1952
Creator:
Thurston, William R.
System:
The UNT Digital Library
Pegmatites of the Crystal Mountain District, Larimer County, Colorado
Report discussing the geology of the pegmatites in the Crystal Mountain district in Larimer County, Colorado.
Date:
April 1952
Creator:
Thurston, William R.
System:
The UNT Digital Library
Chemically modified electrodes and related solution studies
This report is divided into 5 sections: Ru[sub 4]/Fe complexes of tetra(4[prime]-methyl-2,2[prime]-bipyridine)porphyrin--catalytic epoxidation of olefins; water oxidation catalysis by doubly linked [mu]-oxo ruthenium complexes; polymer films formed by oxidation of transition metal electrodes into solutions of bisbipyridinealkane ligands; polymer films containing [CpMo([mu]-S)][sub 2]S[sub 2]CHR dinuclear clusters;and conducting polymer films for catalyst incorporation.
Date:
April 1, 1993
Creator:
Elliott, C.M.
System:
The UNT Digital Library