Cometabolic bioremediation (open access)

Cometabolic bioremediation

Cometabolic bioremediation is probably the most under appreciated bioremediation strategy currently available. Cometabolism strategies stimulate only indigenous microbes with the ability to degrade the contaminant and cosubstrate e.g. methane, propane, toluene and others. This highly targeted stimulation insures that only those microbes that can degrade the contaminant are targeted, thus reducing amendment costs, well and formation plugging, etc. Cometabolic bioremediation has been used on some of the most recalcitrant contaminants, e.g. PCE, TCE, MTBE, TNT, dioxane, atrazine, etc. Methanotrophs have been demonstrated to produce methane monooxygense, an oxidase that can degrade over 300 compounds. Cometabolic bioremediation also has the advantage of being able to degrade contaminants to trace concentrations, since the biodegrader is not dependent on the contaminant for carbon or energy. Increasingly we are finding that in order to protect human health and the environment that we must remediate to lower and lower concentrations, especially for compounds like endocrine disrupters, thus cometabolism may be the best and maybe the only possibility that we have to bioremediate some contaminants.
Date: February 15, 2009
Creator: Hazen, Terry C.
System: The UNT Digital Library
Cometabolic bioremediation (open access)

Cometabolic bioremediation

This is a report on the comebiotic bioremediation which is the most under-appreciated strategy currently available.
Date: February 15, 2009
Creator: Hazen, Terry C.
System: The UNT Digital Library
FCC Record, Volume 24, No. 2, Pages 857 to 1611, January 19 - February 13, 2009 (open access)

FCC Record, Volume 24, No. 2, Pages 857 to 1611, January 19 - February 13, 2009

Biweekly, comprehensive compilation of decisions, reports, public notices, and other documents of the U.S. Federal Communications Commission.
Date: February 2009
Creator: United States. Federal Communications Commission.
System: The UNT Digital Library
FCC Record, Volume 24, No. 3, Pages 1612 to 2571, February 16 - February 26, 2009 (open access)

FCC Record, Volume 24, No. 3, Pages 1612 to 2571, February 16 - February 26, 2009

Biweekly, comprehensive compilation of decisions, reports, public notices, and other documents of the U.S. Federal Communications Commission.
Date: February 2009
Creator: United States. Federal Communications Commission.
System: The UNT Digital Library
In situ groundwater bioremediation (open access)

In situ groundwater bioremediation

In situ groundwater bioremediation of hydrocarbons has been used for more than 40 years. Most strategies involve biostimulation; however, recently bioaugmentation have been used for dehalorespiration. Aquifer and contaminant profiles are critical to determining the feasibility and strategy for in situ groundwater bioremediation. Hydraulic conductivity and redox conditions, including concentrations of terminal electron acceptors are critical to determine the feasibility and strategy for potential bioremediation applications. Conceptual models followed by characterization and subsequent numerical models are critical for efficient and cost effective bioremediation. Critical research needs in this area include better modeling and integration of remediation strategies with natural attenuation.
Date: February 1, 2009
Creator: Hazen, Terry C.
System: The UNT Digital Library
Mathematical models as tools for probing long-term safety of CO2 storage (open access)

Mathematical models as tools for probing long-term safety of CO2 storage

Subsurface reservoirs being considered for storing CO{sub 2} include saline aquifers, oil and gas reservoirs, and unmineable coal seams (Baines and Worden, 2004; IPCC, 2005). By far the greatest storage capacity is in saline aquifers (Dooley et al., 2004), and our discussion will focus primarily on CO{sub 2} storage in saline formations. Most issues for safety and security of CO{sub 2} storage arise from the fact that, at typical temperature and pressure conditions encountered in terrestrial crust, CO{sub 2} is less dense than aqueous fluids. Accordingly, CO{sub 2} will experience an upward buoyancy force in most subsurface environments, and will tend to migrate upwards whenever (sub-)vertical permeable pathways are available, such as fracture zones, faults, or improperly abandoned wells (Bachu, 2008; Pruess, 2008a, b; Tsang et al., 2008). CO{sub 2} injection will increase fluid pressures in the target formation, thereby altering effective stress distributions, and potentially triggering movement along fractures and faults that could increase their permeability and reduce the effectiveness of a caprock in containing CO{sub 2} (Rutqvist et al., 2008; Chiaramonte et al., 2008). Induced seismicity as a consequence of fluid injection is also a concern (Healy et al., 1968; Raleigh et al., 1976; Majer et al., 2007). …
Date: February 1, 2009
Creator: Pruess, Karsten; Birkholzer, Jens & Zhou, Quanlin
System: The UNT Digital Library
MOLECULAR SPECTROSCPY AND REACTIONS OF ACTINIDES IN THE GAS PHASE AND CRYOGENIC MATRICES (open access)

MOLECULAR SPECTROSCPY AND REACTIONS OF ACTINIDES IN THE GAS PHASE AND CRYOGENIC MATRICES

In this chapter we review the spectroscopic data for actinide molecules and the reaction dynamics for atomic and molecular actinides that have been examined in the gas phase or in inert cryogenic matrices. The motivation for this type of investigation is that physical properties and reactions can be studied in the absence of external perturbations (gas phase) or under minimally perturbing conditions (cryogenic matrices). This information can be compared directly with the results from high-level theoretical models. The interplay between experiment and theory is critically important for advancing our understanding of actinide chemistry. For example, elucidation of the role of the 5f electrons in bonding and reactivity can only be achieved through the application of experimentally verified theoretical models. Theoretical calculations for the actinides are challenging due the large numbers of electrons that must be treated explicitly and the presence of strong relativistic effects. This topic has been reviewed in depth in Chapter 17 of this series. One of the goals of the experimental work described in this chapter has been to provide benchmark data that can be used to evaluate both empirical and ab initio theoretical models. While gas-phase data are the most suitable for comparison with theoretical calculations, …
Date: February 1, 2009
Creator: Heaven, Michael C.; Gibson, John K. & Marcalo, Joaquim
System: The UNT Digital Library

The Sutton-taylor Feud: the Deadliest Blood Feud in Texas

Access: Use of this item is restricted to the UNT Community
The Sutton-Taylor Feud of DeWitt, Gonzales, Karnes, and surrounding counties began shortly after the Civil War ended. The blood feud continued into the 1890s when the final court case was settled with a governmental pardon. Of all the Texas feuds, the one between the Sutton and Taylor forces lasted longer and covered more ground than any other. William E. Sutton was the only Sutton involved, but he had many friends to wage warfare against the large Taylor family. The causes are still shrouded in mystery and legend, as both sides argued they were just and right. In April 1868 Charles Taylor and James Sharp were shot down in Bastrop County, alleged horse thieves attempting to escape. During this period many men were killed “while attempting to escape.” The killing on Christmas Eve 1868 of Buck Taylor and Dick Chisholm was perhaps the final spark that turned hard feelings into fighting with bullets and knives. William Sutton was involved in both killings. “Who sheds a Taylor's blood, by a Taylor's hand must fall” became a fact of life in South Texas. Violent acts between the two groups now followed. The military reacted against the killing of two of their soldiers in …
Date: February 15, 2009
Creator: Parsons, Chuck
System: The UNT Digital Library