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Kinetics and Mechanisms of Ligand Exchange Reactions of Chelate Complexes
Certain ligand substitution reactions proceed to a complete displacement of the chelate ligand. Certain reactions proceed through a mechanism involving an initial fission of the tungsten-sulfur bond to afford a coordinatively-unsaturated intermediate which is rapidly attacked by chlorobenzene. The resulting solvated intermediate establishes an equilibrium which involves desolvation-solvation. Although main group organometallic chemistry has received a great deal of attention, this discussion will be centered in organotransition metal chemistry, in particular, metal carbonyls.
Date:
May 1989
Creator:
Cortés, José E. (José Enrique)
System:
The UNT Digital Library