The adsorption of acetic and oleic acids on the surface of thoria was studied by means of infrared spectroscopy. An infrared analysis of the adsorbates before and after adsorption using differential double bean methods indicated that the adsorption of organic acids on thoria surfaces occurs by an esterification reaction between the organic acid and the hydroxylated thoria surface. Ammonia vapor will not adsorb on thoria, indicated the basic character of the hydroxylated surface.

This technical report constitutes a brief review of the work undertaken, entirely or in part, under the Contract AT(30-1)-1772 with eh United States Atomic Energy Commission. The work published during 1959 is listed at the end of this report and copies of the reprints or reports are attached where available. These investigations have been concerned with the examination of defect production and behavior as it may be observed by high frequency ultrasonic attenuation and velocity (modulus) changes in such materials as quartz, silicon, germanium, alkali halides (especially NaCl and XCl), high purity aluminum, and glass containing boron. The irradiations used are cobalt 60 gamma-ray irradiation and the reactor irradiation obtained in the Brookhaven National Laboratory graphite reactor.

Attempts to secure a high degree of synchronization of cell division of the Krebs mouse ascites carcinoma, by combined use of aminopterin and citrovorum factor, and by use of colchicine and N-acetyl colchinol, were unsuccessful. In the course of the work, a new method for securing smears of ascites tumor cells was out, which we believe will be found useful

The concentration gradients of uranyl ion in aqueous and organic solutions were analyzed by taking a macro photograph of the desired gradient by monochromatic (436 m mu ) light transmitted by the solution normal to the gradient in an appropriate diffusion cell. Two Druhm runs were terminated due to malfunction of the sodium metering system and the third run was terminated when the UF/sub 6/ nozzle ruptured. Calculations of particle temperature versus time relations for the flame denitration-calcination method of preparing metallic oxide from nitrate solutions indicate that the times required for heat transfer are controlled by the rate of radiant heat transfer to particle surfaces instead of by conductive heat transfer within the particles. A completed experimental study indicated that electrolysis in a cell with a mercury cathode and a platinum anode is a practical process for removing nickel from HRT fuel solution. The apparent diffusion coefficient of uranium loading on Dowex 21K was shown to be directly related to the resin size. An explosion of sufficient violence to blow apart the Pyrex pipe dissolver occurred during the fifth Darex dissolution of simulated SRE fuel probably from a rapid gas phase reaction between hydrogen and oxidizing gases such as …

This report describes the design, construction and operation of a sub-critical nuclear reactor, intended for college teaching of reactor physics and of nuclear phenomena.

None

The objective of this test is to demonstrate the feasibility of projection fuel elements for use In existing process tubing and to determine the reduction in rupture rates or hot-spot incidence so achieved. This test is to authorize, (a) charging 20 columns of bumper type fuel elements and 20 columns of control elements per reactor into B, D, DR, F, and R Reactors for irradiation up to 1200 MWD/T exposure, and (b) irradiation of four columns each of enriched (0.947%) bumper and enriched (0.947%) normal type fuel elements until two ruptures are sustained in each (or until one group shows a significant improvement).

Experimentally determine the overall isothermal temperature coefficient of the SER up to the design operating temperatures.

This document provides details of activities of the Hanford Operations Office during the month of September 1959. (FI)

Routine monitoring procedures are summarized. Based on samples collected by continuous air monitors, the wcekly average value for air contamiration in the laboratory area was 1.98 x 10/sup -12/ mu c/cc. Radioactive fall-out was determined by measuring the total activity and total number of particles collected on gum paper fall-out trays. Two peak periods of activity in July and September were concluded to be the result of weapons tests. Meteorological data are tabulated. Data are included from a survey of natural radioactive elements in TVA lake waters, activity levels in samples of river and lake waters in the laboratory drainage area, rain water, and laundry decontamination measuremcnts. The combination film dosimeter-personnel identification badge was redesigned. A drawing of the badge and its component parts is included. Design modifications are described which wcre made in an automatic air sampler rized from radiation surveys. (C.H.)

The diffusion process in uranium and its alloys was studied from 550 to 1075 deg C with diffusion couples of U with Zr, Mo, Ti, and Nb and with the alloys U--Nb and U--Mo. A brief description is given of the experimental methods. Results relative to the concentration-penetration curves are presented, and the coefficients of diffusion are calculated. The equilibrium diagram was established for the U--Zr system. The results obtained by micrographic examination, microhardness measurements, and autoradiography are compared with each other. The mechanisms of diffusion are investigated by studying the Kirkendall effect and calculating the Darken intrinsic coeffi cients in the U--Zr and U--UMo diffusion couples. (J.S.R.)

Design and construction are proceeding satisfactorily. Fuel capsule irradiation studies are progressing, and preparation of specifications for fuel elements and assemblies is almost complete. Other design, development, and construction progress is reported. Instrumentation developments are described. Reactor physics studies are reported. (For preceding period see AECU-4013.) (T.R.H.)

An alternate design of the Elk River Reactor was completed during the quarter. Three points were emphasized in the study: performance capability to provide 116 Mw(th) output; fuel costs of the reference design versus alternate fuel media and cladding; and reactor control modifications to provide sufficient reactivlty to eliminate soluble hold down'' poisons, permit higher power operation and obtain a greater fuel life. Work is summarized on fuel element and material development program, reactor vessel and internal components, control rods and drive mechanism, process systems, superheater, buildings and facilities, instrumentation and site construction. (For preceding period see ACNP-ERR-3.) (W.D.M.)

Under the New Reactor Concepts Evaluation Program sponsored by the United States Atomic Energy Commission. Advanced Technology Laboratories (a Division of American Radiator & Standard Sanitary Corporation) has undertaken am investigation of the technical feasibility and economic potential of the use of boiling mercury as a coolant for fast breeder reactors The investigation was performed between January 1, 1959, and October 31. 1959. This is the final report on that investigation and is submitted in compliance with the terms of the program authorization, Contract Number AT(04-3)-109, Project Agreement Number 4. (auth)

The fuel element conference provided a favorable medium for presentation and discussion of recent developments in the field of solid fuel elements. The conference was designed to replace the more general Metallurgy Information Meetings held annually in the past. The scope of the meeting embraced the design fabrication, performance, and material problems of fuel elements. (W.D.M)

Data are presented on the mechanical and physical properties of high- purity and normal uranium and for a range of dilute uranium alloys at temperatures up to 700 deg C. The results of thermal conductivity and thermal expansion determinations for a range of alloys are discussed, and some results on the latent heat of fusion and volume change on melting are presented. Results of dilute alloy creep tests are reported and correlated with thermal cycling data and resistence to swelling under irradiation. (J.R.D.)

This meeting is one of a series of Civilian Power Reactor Conferences and was held colncident with an AEC invitation to industry to bid on the construction of a gas-cooled facility. Papers are presented on design studles, hazards, components, costs, materials, and design concepts for specific reactors. (W.D.M.)

ThO/sub 2/-UO/sub 2/ fuels have been studied because of certain advantages possessed by this type of fuel over UO/sub 2/. Pellets of ThO/sub 2/- UO/sub 2/ have been found to be highly stable dimensionally under irradiation. Various experimental assemblies which have been irradiated have included Al, Zircaloy, and stainless steel cladding, with the annulus surrounding the pellet filled with air, He, NaK, or Pb. A full-scale core of pellets lead-bonded to Al tube-plates has been used successfully in the Borax-IV reactor. Preliminary defect tests have shown that solid fission products are retained and that only the gaseous products, Xe/sup 138/ and Kr/sup 88/, are detectable in the reactor coolant system. (auth)

A 95-inch experimental Yankee sub-assembly was successfully brazed at 1890 plus or minus 10 for three hours then furnace cooled. All of the joints, outside ferrules, and control rod rubbing strips showed a brazed flllet. Dimensional surveys and joint strength studies indicate that two brazing techniques appear feasible for subassemblies. Codings for computers for use in core design problems are described. A series of criticality calculations for the three water-to-metal volume ratios of the Yankee critical experiments was concluded with the calculatlon of the critical mass of a 4:1 water-touranium metal volume ratio core. Calculations were performed to determine the Mwd/t burnup in terms of unperturbed nvt for 2.7 and 5.4% enriched process water test specimens. Temperature stability experiments were conducted on Rohm and Haas XE- 150 resin by means of water baths at the puriflcatlon system operating temperature of 14O F and at an elevated temperature of 170 F. Data were obtained on corrosion of construction materials. A study was made of the reaction of soluble oxygen with hydrazine in borated water. Performance of criticality experiments on stainless steel clad UO/sub 2/ fuel elements at various water-to-metal ratios are reported. (For preceding period see YAEC95.) (W.D.M.)

A demonstration battery containing an 880-curie polonium-2l0 heat source was constructed and tested. The battery initially had an open circuit voltage of 23.6 volts, a maximum output of 161 milliwatts, and an overall efficiency of 0.57%. Details for the construction of the battery generator are given. (For preceding period see MLM-CF-58-4-59.) (auth)

Twenty-eight of the thirty-five papers presented at the conference are included with discussions. Abstracts of the remaining seven papers are given. The seven sessions were devoted to: radiation effects on graphite, nuclear properties of graphitc, graphite lattice reactivities, chemistry of graphite, chemical reactions between liquid Na and Zr, slug canning fer the ORNL Graphite Reactor, and critical assemblies. Separate abstracts have been prepared for each of the twentyeight papers. (T.R.H.)

An evaluation and the resulting conclusions of work performed are given for each project in which definitive progress was made. The principle progress consisted of: obtaining promising fuel fabrication results from production scale investigations of simplified UO/sub 2/ preparations methods, presintering operation elimination, increasing pellet densities and reductions of UO/sub 2/ losses; successfully brazing a ninety-five inch long experimental fuel subassembly in which all joints, including outside ferrules and control rod rubbing strips, had brazed fillets; completing the fabrication of the last group of MTR process water irradiation samples and all of the in-pile test loop samples except for the specimens containing 27% enriched pellets; performing a nuclear analysis of various fuel assembly designs as part of an over-all evaluation of fuel assembly bowing in the Yankee reactor; completing corrosion studies of primary plant materials in static autoclaves to aid in the selection of a pH control agent; developing a Compromise Design'' for the fueh assembly which incorporates a series of small design changes to eliminate the possibility of restricting control rod motion by interference due to a superposition of bowing of the fuel assembly and an adverse accummulation of mechanical tolerances; completing the calculation of the moderator temperature coefficient, …

3 9 8 4 3 3 3 6 9 6 5 5 have been started on possible urania-ceramic fuels with magnesia, alumina, zirconia, magnesia-- zirconia and calcia--zirconia. Mixtures of 45 magnesia--45 zirconia and 9 magnesia--81 zirconia by weight appeared to give good preliminary promise. Work on ThO/sub 2/--10 wt.% UO/sub 2/ has centered about improvement in density of pellets and elimination of cracking and open porosity. Efforts to increase the percentage of urania in thoria--urania have met with considerable success up to 70 wt.% urania in air-firing tests. Some attempts have been made to prepare UC by reaction of UO/sub 2/ with carbon, but so far an incomplete reaction has resulted. As to metal fuels, a sample of U--3 wt.% Ti--1.5 wt.% Nb has shown good corrosion resistance in 245 deg C water, slightly better than the EBWR fuel alloy. Fast Power Breeder Program. An improvement of the average yield of EBR- IItype fuel pin injection castings has been attained, reaching over 90% as compared with yields of 50 to 60% in the recent past. The uranium-plutonium- fissium alloys proposed for the fuel of EBR-II are being given further examination. The thermal conductivity of U-- 20 wt.% Pu--10 wt.% Fs …

A simulated HRT fuel solution was unstable when passed through a heated Zircaloy-2 bypass section installed on a Ti loop. Losses of uranyl, cupric, and nickel sulfates were observed when the temperature of the solution emerging from the bypass was as low as 290 deg C. The 0.04 m UO/sub 2/SO/sub 4/ solutions containing Please delete abstract number 7731