Tau Decays at BaBar (open access)

Tau Decays at BaBar

Recent results of tau lepton decay studies based on luminosities between 350 fb{sup -1} and 469 fb{sup -1} collected with the BABAR detector at the PEP-II e{sup +}e{sup -} collider at the SLAC National Accelerator Laboratory are presented. The analyses reported here are Charged Current Lepton Universality and measurements of |V{sub us}| using {tau}{sup -} {yields} e{sup -}{bar {nu}}{sub e}{nu}{sub {tau}}, {mu}{sup -}{bar {nu}}{sub {mu}}{nu}{sub {tau}}, {pi}{sup -} {nu}{sub {tau}}, and K{sup -}{nu}{sub {tau}} decays, as well as searches for Second Class Currents in {tau}{sup -} {yields} {omega}{pi}{sup -}{nu}{sub {tau}} decays, studies of Lepton Flavor Violations, and a tau mass measurement and CPT-Test. If not explicitly mentioned, charge conjugate decay modes are also implied. decays, as well as searches for Second Class Currents in {tau}{sup -} {yields} {omega}{pi}{sup -}{nu}{sub {tau}} decays, studies of Lepton Flavor Violations, and a tau mass measurement and CPT-Test. If not explicitly mentioned, charge conjugate decay modes are also implied.
Date: January 22, 2009
Creator: Hast, Carsten
System: The UNT Digital Library
Drell-Yan Lepton Pair Azimuthal Asymmetry in Hadronic Processes (open access)

Drell-Yan Lepton Pair Azimuthal Asymmetry in Hadronic Processes

We study the azimuthal asymmetry in the Drell-Yan lepton pair production in hadronic scattering processes at moderate transverse momentum region, taking into account the contributions from the twist-three quark-gluon correlations from the unpolarized hadrons. The contributions are found to dominate the asymmetry, and are not power suppressed by qt/Q at small qt where qt and Q are the transverse momentum and invariant mass of the lepton pair. Accordingly, the Lam-Tung relation will be violated at this momentum region, and its violation depends on the twist-three functions. However, at large transverse momentum qt~;;Q, the Lam-Tung relation still holds because all corrections are power suppressed by Lambda2/qt2 ~;; Lambda2/Q2 where Lambda is the typical nonperturbative scale.
Date: January 22, 2009
Creator: Zhou, Jian; Yuan, Feng & Liang, Zuo-Tang
System: The UNT Digital Library
Integrated process modeling for the laser inertial fusion Energy (LIFE) generation system (open access)

Integrated process modeling for the laser inertial fusion Energy (LIFE) generation system

A concept for a new fusion-fission hybrid technology is being developed at Lawrence Livermore National Laboratory. The primary application of this technology is base-load electrical power generation. However, variants of the baseline technology can be used to 'burn' spent nuclear fuel from light water reactors or to perform selective transmutation of problematic fission products. The use of a fusion driver allows very high burn-up of the fission fuel, limited only by the radiation resistance of the fuel form and system structures. As a part of this process, integrated process models have been developed to aid in concept definition. Several models have been developed. A cost scaling model allows quick assessment of design changes or technology improvements on cost of electricity. System design models are being used to better understand system interactions and to do design trade-off and optimization studies. Here we describe the different systems models and present systems analysis results. Different market entry strategies are discussed along with potential benefits to US energy security and nuclear waste disposal. Advanced technology options are evaluated and potential benefits from additional R&D targeted at the different options is quantified.
Date: October 22, 2009
Creator: Meier, W. R.; Anklam, T. M.; Erlandson, A. C.; Miles, R. R.; Simon, A. J.; Sawicki, R. et al.
System: The UNT Digital Library
Simulating Complex Window Systems using BSDF Data (open access)

Simulating Complex Window Systems using BSDF Data

Nowadays, virtual models are commonly used to evaluate the performance of conventional window systems. Complex fenestration systems can be difficult to simulate accurately not only because of their geometry but also because of their optical properties that scatter light in an unpredictable manner. Bi-directional Scattering Distribution Functions (BSDF) have recently been developed based on a mixture of measurements and modelling to characterize the optics of such systems. This paper describes the workflow needed to create then use these BSDF datasets in the Radiance lighting simulation software. Limited comparisons are made between visualizations produced using the standard ray-tracing method, the BSDF method, and that taken in a full-scale outdoor mockup.
Date: June 22, 2009
Creator: Konstantoglou, Maria; Jonsson, Jacob & Lee, Eleanor
System: The UNT Digital Library
Unusual layer-dependent charge distribution, collective mode coupling, and superconductivity in multilayer cuprate Ba2Ca3Cu4O8F2 (open access)

Unusual layer-dependent charge distribution, collective mode coupling, and superconductivity in multilayer cuprate Ba2Ca3Cu4O8F2

Low energy ultrahigh momentum resolution angle resolved photoemission spectroscopy study on four-layer self-doped high Tc superconductor Ba2Ca3Cu4O8F2 (F0234) revealed fine structure in the band dispersion, identifying the unconventional association of hole and electron doping with the inner and outer CuO2 layers, respectively. For the states originating from two inequivalent CuO2 layers, different energy scales are observed in dispersion kinks associated with the collective mode coupling, with the larger energy scale found in the electron (n-) doped state which also has stronger coupling strength. Given the earlier finding that the superconducting gap is substantially larger along the n-type Fermi surface, our observations connect the mode coupling energy and strength with magnitude of the pairing gap.
Date: January 22, 2009
Creator: Chen, Yulin; Iyo, Akira; Yang, Wanli; Ino, Akihiro; Arita, M.; Johnston, Steve et al.
System: The UNT Digital Library
RE-EVALUATION OF THE PERMEABLE MATERIAL AT THE BASE OF THE UNCONFINED AQUIFER NEAR LERF HANFORD SITE WASHINGTON (open access)

RE-EVALUATION OF THE PERMEABLE MATERIAL AT THE BASE OF THE UNCONFINED AQUIFER NEAR LERF HANFORD SITE WASHINGTON

None
Date: October 22, 2009
Creator: Smoot, J. L.
System: The UNT Digital Library
Search for Second-Class Currents in tau- -> omega.pi-.nu_tau (open access)

Search for Second-Class Currents in tau- -> omega.pi-.nu_tau

We report an analysis of {tau}{sup -} decaying into {omega}{pi}{sup -} {nu}{sub {tau}} with {omega} {yields} {pi}{sup +}{pi}{sup -}{pi}{sup 0} using a data sample containing nearly 320 million {tau} pairs collected with the BABAR detector at the PEP-II B-Factory. We find no evidence for second-class currents and we set an upper limit of 0.69% at 90% confidence level for the fraction of second-class currents in this decay mode.
Date: April 22, 2009
Creator: Aubert, B.
System: The UNT Digital Library
Bacterial Community Succession During in situ Uranium Bioremediation: Spatial Similarities Along Controlled Flow Paths (open access)

Bacterial Community Succession During in situ Uranium Bioremediation: Spatial Similarities Along Controlled Flow Paths

Bacterial community succession was investigated in a field-scale subsurface reactor formed by a series of wells that received weekly ethanol additions to re-circulating groundwater. Ethanol additions stimulated denitrification, metal reduction, sulfate reduction, and U(VI) reduction to sparingly soluble U(IV). Clone libraries of SSU rRNA gene sequences from groundwater samples enabled tracking of spatial and temporal changes over a 1.5 y period. Analyses showed that the communities changed in a manner consistent with geochemical variations that occurred along temporal and spatial scales. Canonical correspondence analysis revealed that the levels of nitrate, uranium, sulfide, sulfate, and ethanol strongly correlated with particular bacterial populations. As sulfate and U(VI) levels declined, sequences representative of sulfate-reducers and metal-reducers were detected at high levels. Ultimately, sequences associated with sulfate-reducing populations predominated, and sulfate levels declined as U(VI) remained at low levels. When engineering controls were compared to the population variation via canonical ordination, changes could be related to dissolved oxygen control and ethanol addition. The data also indicated that the indigenous populations responded differently to stimulation for bio-reduction; however, the two bio-stimulated communities became more similar after different transitions in an idiosyncratic manner. The strong associations between particular environmental variables and certain populations provide insight into …
Date: May 22, 2009
Creator: Hwang, Chiachi; Wu, Weimin; Gentry, Terry J.; Carley, Jack; Corbin, Gail A.; Carroll, Sue L. et al.
System: The UNT Digital Library
Decamethylytterbocene Complexes of Bipyridines and Diazabutadienes: Multiconfigurational Ground States and Open-Shell Singlet Formation (open access)

Decamethylytterbocene Complexes of Bipyridines and Diazabutadienes: Multiconfigurational Ground States and Open-Shell Singlet Formation

Partial ytterbium f-orbital occupancy (i.e., intermediate valence) and open-shell singlet formation are established for a variety of bipyridine and diazabutadiene adducts with decamethylytterbocene, (C5Me5)2Yb, abbreviated as Cp*2Yb. Data used to support this claim include ytterbium valence measurements using Yb LIII-edge X-ray absorption near-edge structure spectroscopy, magnetic susceptibility, and complete active space self-consistent field (CASSCF) multiconfigurational calculations, as well as structural measurements compared to density functional theory calculations. The CASSCF calculations indicate that the intermediate valence is the result of a multiconfigurational ground-state wave function that has both an open-shell singlet f13(?*)1, where pi* is the lowest unoccupied molecular orbital of the bipyridine or dpiazabutadiene ligands, and a closed-shell singlet f14 component. A number of other competing theories for the unusual magnetism in these materials are ruled out by the lack of temperature dependence of the measured intermediate valence. These results have implications for understanding chemical bonding not only in organolanthanide complexes but also for f-element chemistry in general, as well as understanding magnetic interactions in nanoparticles and devices.
Date: April 22, 2009
Creator: Booth, Corwin H.; Walter, Marc D.; Kazhdan, Daniel; Hu, Yung-Jin; Lukens, Wayne W.; Bauer, Eric D. et al.
System: The UNT Digital Library
Alternative Donor--Acceptor Stacks from Crown Ethers and Naphthalene Diimide Derivatives: Rapid, Selective Formation from Solution and Solid State Grinding (open access)

Alternative Donor--Acceptor Stacks from Crown Ethers and Naphthalene Diimide Derivatives: Rapid, Selective Formation from Solution and Solid State Grinding

Self assembling {pi}-conjugated molecules into ordered structures are of increasing interest in the field of organic electronics. One particular example is charge transfer complexes containing columnar alternative donor-acceptor (ADA) stacks, where neutral and ionic ground states can be readily tuned to modulate electrical, optical, and ferroelectrical properties. Aromatic-aromatic and charge transfer interactions have been the leading driving forces in assisting the self-assembly of ADA stacks. Various folding structures containing ADA stacks were assembled in solution with the aid of solvophobic or ion-binding interactions. Meanwhile, examples of solid ADA stacks, which are more appealing for practical use in devices, were obtained from cocrystalization of binary components or mesophase assembly of liquid crystals in bulk blends. Regardless of these examples, faster and more controllable approaches towards precise supramolecular order in the solid state are still highly desirable.
Date: January 22, 2009
Creator: Lawrence Berkeley National Laboratory. Advanced Light Source.
System: The UNT Digital Library
Importance of Plasma Response to Non-axisymmetric Perturbations in Tokamaks (open access)

Importance of Plasma Response to Non-axisymmetric Perturbations in Tokamaks

Tokamaks are sensitive to deviations from axisymmetry as small as δB=B0 ~ 10-4. These non-axisymmetric perturbations greatly modify plasma confinement and performance by either destroying magnetic surfaces with subsequent locking or deforming magnetic surfaces with associated non-ambipolar transport. The Ideal Perturbed Equilibrium Code (IPEC) calculates ideal perturbed equilibria and provides important basis for understanding the sensitivity of tokamak plasmas to perturbations. IPEC calculations indicate that the ideal plasma response, or equiva- lently the effect by ideally perturbed plasma currents, is essential to explain locking experiments on National Spherical Torus eXperiment (NSTX) and DIII-D. The ideal plasma response is also important for Neoclassical Toroidal Viscosity (NTV) in non-ambipolar transport. The consistency between NTV theory and magnetic braking experiments on NSTX and DIII-D can be improved when the variation in the field strength in IPEC is coupled with generalized NTV theory. These plasma response effects will be compared with the previous vacuum superpositions to illustrate the importance. However, plasma response based on ideal perturbed equilibria is still not suffciently accurate to predict the details of NTV transport, and can be inconsistent when currents associated with a toroidal torque become comparable to ideal perturbed currents.
Date: April 22, 2009
Creator: Jong-kyu Park, Allen H. Boozer, Jonathan E. Menard, Andrea M. Garofalo, Michael J. Schaffer, Richard J. Hawryluk, Stanley M. Kaye, Stefan P. Gerhardt, Steve A. Sabbagh, and the NSTX Team
System: The UNT Digital Library
First search for extraterrestrial neutrino-induced cascades with IceCube (open access)

First search for extraterrestrial neutrino-induced cascades with IceCube

We report on the first search for extraterrestrial neutrino-induced cascades in IceCube.The analyzed data were collected in the year 2007 when 22 detector strings were installed and operated. We will discuss the analysis methods used to reconstruct cascades and to suppress backgrounds. Simulated neutrino signal events with a E-2 energy spectrum, which pass the background rejection criteria, are reconstructed with a resolution Delta(log E) ~;; 0.27 in the energy range from ~;; 20 TeV to a few PeV. We present the range of the diffuse flux of extra-terrestrial neutrinos in the cascade channel in IceCube within which we expect to be able to put a limit.
Date: May 22, 2009
Creator: Collaboration, IceCube & Kiryluk, Joanna
System: The UNT Digital Library
Optimal tuning and calibration of bendable mirrors with slope measuring profilers (open access)

Optimal tuning and calibration of bendable mirrors with slope measuring profilers

We describe a technique to optimally tune and calibrate bendable x-ray optics for sub-micron focusing. The focusing is divided between two elliptically cylindrical reflecting elements, a Kirkpatrick-Baez (KB) pair. Each optic is shaped by applying unequal bending couples to each end of a flat mirror. The developed technique allowsoptimal tuning of these systems using surface slope data obtained with a slope measuring instrument, the long trace profiler (LTP). Due to the near linearity of the problem, the minimal set of data necessary for the tuning of each bender, consists of only three slope traces measured before and after a single adjustment of each bending couple. The data are analyzed with software realizing a method of regression analysis with experimentally found characteristic functions of the benders. The resulting approximation to the functional dependence of the desired shape provides nearly final settings. Moreover, the characteristic functions of the benders found in the course of tuning, can be used for retuning to a new desired shape without removal from the beamline and re-measuring. We perform a ray trace, using profiler data for the finally tuned optics, predicting the performance to be expected during use of the optics on the beamline.
Date: June 22, 2009
Creator: McKinney, Wayne; Kirschman, Jonathan; MacDowell, Alastair; Warwick, Tony & Yashchuk, Valeriy
System: The UNT Digital Library
Bounding CKM Mixing with a Fourth Family (open access)

Bounding CKM Mixing with a Fourth Family

CKM mixing between third family quarks and a possible fourth family is constrained by global fits to the precision electroweak data. The dominant constraint is from nondecoupling oblique corrections rather than the vertex correction to Z {yields} {bar b}b used in previous analyses. The possibility of large mixing suggested by some recent analyses of FCNC processes is excluded, but 3-4 mixing of the same order as the Cabbibo mixing of the first two families is allowed.
Date: April 22, 2009
Creator: Chanowitz, Michael S.
System: The UNT Digital Library
Fast spot-based multiscale simulations of granular drainage (open access)

Fast spot-based multiscale simulations of granular drainage

We develop a multiscale simulation method for dense granular drainage, based on the recently proposed spot model, where the particle packing flows by local collective displacements in response to diffusing"spots'" of interstitial free volume. By comparing with discrete-element method (DEM) simulations of 55,000 spheres in a rectangular silo, we show that the spot simulation is able to approximately capture many features of drainage, such as packing statistics, particle mixing, and flow profiles. The spot simulation runs two to three orders of magnitude faster than DEM, making it an appropriate method for real-time control or optimization. We demonstrateextensions for modeling particle heaping and avalanching at the free surface, and for simulating the boundary layers of slower flow near walls. We show that the spot simulations are robust and flexible, by demonstrating that they can be used in both event-driven and fixed timestep approaches, and showing that the elastic relaxation step used in the model can be applied much less frequently and still create good results.
Date: May 22, 2009
Creator: Rycroft, Chris H.; Wong, Yee Lok & Bazant, Martin Z.
System: The UNT Digital Library
Local structure and site occupancy of Cd and Hg substitutions in CeTIn_5 (T=Co, Rh, Ir) (open access)

Local structure and site occupancy of Cd and Hg substitutions in CeTIn_5 (T=Co, Rh, Ir)

The CeTIn_5 superconductors (T=Co, Rh, or Ir) have generated great interest due to their relatively high transition temperatures, non-Fermi liquid behavior, and their proximity to antiferromagnetic order and quantum critical points. In contrast to small changes with the T-species, electron doping in CeT(In_1-x M_x)_5 with $M$=Sn and hole doping with Cd or Hg have a dramatic effect on the electronic properties at very low concentrations. The present work reports local structure measurements usingthe extended x-ray absorption fine-structure (EXAFS) technique that address the substituent atom distribution as a function of T, M, and x, in the vicinity of the superconducting phase. Together with previous measurements for M=Sn, the proportion of the $M$ atom residing on the In(1) site, f_\textrm In(1), increases in the order M=Cd, Sn, and Hg, ranging from about 40\percent to 70percent, showing a strong preference for each of these substituents to occupy the In(1) site (random occupation = 20percent). In addition, f_In(1) ranges from 70percent to 100percent for M=Hg in the order T=Co,Rh, and Ir. These fractions track the changes in the atomic radii of the various species, and help explain the sharp dependence of $T_c$ on substituting into the In site. However, it is difficult to reconcile …
Date: April 22, 2009
Creator: Booth, Corwin H.; Bauer, Eric. D.; Bianchi, Andrea D.; Ronning, Fillip; Thompson, Joe D.; Sarrao, John L. et al.
System: The UNT Digital Library
Iron site occupancies in magnetite-ulvospinel solid solution: A new approach using XMCD (open access)

Iron site occupancies in magnetite-ulvospinel solid solution: A new approach using XMCD

Ordering of Fe{sup 3+} and Fe{sup 2+} between octahedral (Oh) and tetrahedral (Td) sites in synthetic members of the magnetite (Fe{sub 3}O{sub 4}) - ulvoespinel (Fe{sub 2}TiO{sub 4}) solid-solution series was determined using Fe L{sub 2,3}-edge X-ray magnetic circular dichroism (XMCD) coupled with electron microprobe and chemical analysis, Ti L-edge spectroscopy, Fe K-edge EXAFS and XANES, Fe{sub 57} Moessbauer spectroscopy, and unit cell parameters. Microprobe analysis, cell edges and chemical FeO determinations showed that the bulk compositions of the samples were stoichiometric magnetite-ulvoespinel solid-solutions. Surface sensitive XMCD showed that the surfaces of these oxide minerals were more sensitive to redox conditions and some samples required re-equilibration with suitable solid-solid buffers. Detailed site-occupancy analysis of these samples gave XMCD-Fe{sup 2+}/Fe{sup 3+} ratios very close to stoichiometric values. L{sub 2,3}-edge spectroscopy showed that Ti{sup 4+} was restricted to Oh sites. XMCD results showed that significant Fe{sup 2+} only entered Td when the Ti content was > 0.40 apfu while Fe{sup 2+} in Oh increased from 1 a.p.f.u in magnetite to a maximum of {approx}1.4 apfu in USP45. As the Ti content increased from this point, the steady increase in Fe{sup 2+} in Td sites was clearly observable in the XMCD spectra, concurrent …
Date: June 22, 2009
Creator: Pearce, C. I.; Henderson, C. M. B.; Telling, N. D.; Pattrick, R. A.D.; Vaughan, D. J.; Charnock, J. M. et al.
System: The UNT Digital Library
Extreme Scaling of Production Visualization Software on Diverse Architectures (open access)

Extreme Scaling of Production Visualization Software on Diverse Architectures

We present the results of a series of experiments studying how visualization software scales to massive data sets. Although several paradigms exist for processing large data, we focus on pure parallelism, the dominant approach for production software. These experiments utilized multiple visualization algorithms and were run on multiple architectures. Two types of experiments were performed. For the first, we examined performance at massive scale: 16,000 or more cores and one trillion or more cells. For the second, we studied weak scaling performance. These experiments were performed on the largest data set sizes published to date in visualization literature, and the findings on scaling characteristics and bottlenecks contribute to understanding of how pure parallelism will perform at high levels of concurrency and with very large data sets.
Date: December 22, 2009
Creator: Childs, Henry; Pugmire, David; Ahern, Sean; Whitlock, Brad; Howison, Mark; Weber, Gunther et al.
System: The UNT Digital Library
Modeling diffusion of electrical appliances in the residential sector (open access)

Modeling diffusion of electrical appliances in the residential sector

This paper presents a methodology for modeling residential appliance uptake as a function of root macroeconomic drivers. The analysis concentrates on four major energy end uses in the residential sector: refrigerators, washing machines, televisions and air conditioners. The model employs linear regression analysis to parameterize appliance ownership in terms of household income, urbanization and electrification rates according to a standard binary choice (logistic) function. The underlying household appliance ownership data are gathered from a variety of sources including energy consumption and more general standard of living surveys. These data span a wide range of countries, including many developing countries for which appliance ownership is currently low, but likely to grow significantly over the next decades as a result of economic development. The result is a 'global' parameterization of appliance ownership rates as a function of widely available macroeconomic variables for the four appliances studied, which provides a reliable basis for interpolation where data are not available, and forecasting of ownership rates on a global scale. The main value of this method is to form the foundation of bottom-up energy demand forecasts, project energy-related greenhouse gas emissions, and allow for the construction of detailed emissions mitigation scenarios.
Date: November 22, 2009
Creator: McNeil, Michael A. & Letschert, Virginie E.
System: The UNT Digital Library
Compatible Relaxation and Coarsening in Algebraic Multigrid (open access)

Compatible Relaxation and Coarsening in Algebraic Multigrid

We introduce a coarsening algorithm for algebraic multigrid (AMG) based on the concept of compatible relaxation (CR). The algorithm is significantly different from standard methods, most notably because it does not rely on any notion of strength of connection. We study its behavior on a number of model problems, and evaluate the performance of an AMG algorithm that incorporates the coarsening approach. Lastly, we introduce a variant of CR that provides a sharper metric of coarse-grid quality and demonstrate its potential with two simple examples.
Date: September 22, 2009
Creator: Brannick, J J & Falgout, R D
System: The UNT Digital Library
Impacts of WRF Physics and Measurement Uncertainty on California Wintertime Model Wet Bias (open access)

Impacts of WRF Physics and Measurement Uncertainty on California Wintertime Model Wet Bias

The Weather and Research Forecast (WRF) model version 3.0.1 is used to explore California wintertime model wet bias. In this study, two wintertime storms are selected from each of four major types of large-scale conditions; Pineapple Express, El Nino, La Nina, and synoptic cyclones. We test the impacts of several model configurations on precipitation bias through comparison with three sets of gridded surface observations; one from the National Oceanographic and Atmospheric Administration, and two variations from the University of Washington (without and with long-term trend adjustment; UW1 and UW2, respectively). To simplify validation, California is divided into 4 regions (Coast, Central Valley, Mountains, and Southern California). Simulations are driven by North American Regional Reanalysis data to minimize large-scale forcing error. Control simulations are conducted with 12-km grid spacing (low resolution) but additional experiments are performed at 2-km (high) resolution to evaluate the robustness of microphysics and cumulus parameterizations to resolution changes. We find that the choice of validation dataset has a significant impact on the model wet bias, and the forecast skill of model precipitation depends strongly on geographic location and storm type. Simulations with right physics options agree better with UW1 observations. In 12-km resolution simulations, the Lin microphysics …
Date: July 22, 2009
Creator: Chin, H S; Caldwell, P M & Bader, D C
System: The UNT Digital Library
Reaction of the C2H radical with 1-butyne (C4H6): Low Temperature Kinetics and Isomer-Specific Product Detection (open access)

Reaction of the C2H radical with 1-butyne (C4H6): Low Temperature Kinetics and Isomer-Specific Product Detection

The rate coefficient for the reaction of the ethynyl radical (C{sub 2}H) with 1-butyne (H-C{triple_bond}C-CH{sub 2}-CH{sub 3}) is measured in a pulsed Laval nozzle apparatus. Ethynyl radicals are formed by laser photolysis of acetylene (C{sub 2}H{sub 2}) at 193 nm and detected via chemiluminescence (C{sub 2}H + O{sub 2} {yields} CH (A{sup 2}{Delta}) + CO{sub 2}). The rate coefficients are measured over the temperature range of 74-295 K. The C{sub 2}H + 1-butyne reaction exhibits no barrier and occurs with rate constants close to the collision limit. The temperature dependent rate coefficients can be fit within experimental uncertainties by the expression k = (2.4 {+-} 0.5) x 10{sup -10} (T/295 K)-(0.04 {+-} 0.03) cm{sup 3} molecule{sup -1}s{sup -1}. Reaction products are detected at room temperature (295 K) and 533 Pa using a Multiplexed Photoionization Mass Spectrometer (MPIMS) coupled to the tunable VUV synchrotron radiation from the Advanced Light Source at the Lawrence Berkeley National Laboratory. Two product channels are identified for this reaction: m/z = 64 (C{sub 5}H{sub 4}) and m/z = 78 (C{sub 6}H{sub 6}) corresponding to the CH{sub 3}- and H-loss channels, respectively. Photoionization efficiency (PIE) curves are used to analyze the isomeric composition of both product channels. …
Date: December 22, 2009
Creator: Soorkia, Satchin; Trevitt, Adam J.; Selby, Talitha M.; Osborn, David L.; Taatjes, Craig A.; Wilson, Kevin R. et al.
System: The UNT Digital Library
The Electron Transfer System of Syntrophically Grown Desulfovibrio vulgaris (open access)

The Electron Transfer System of Syntrophically Grown Desulfovibrio vulgaris

Interspecies hydrogen transfer between organisms producing and consuming hydrogen promotes the decomposition of organic matter in most anoxic environments. Although syntrophic couplings between hydrogen producers and consumers are a major feature of the carbon cycle, mechanisms for energy recovery at the extremely low free energies of reactions typical of these anaerobic communities have not been established. In this study, comparative transcriptional analysis of a model sulfate-reducing microbe, Desulfovibrio vulgaris Hildenborough, suggested the use of alternative electron transfer systems dependent upon growth modality. During syntrophic growth on lactate with a hydrogenotrophic methanogen, D. vulgaris up-regulated numerous genes involved in electron transfer and energy generation when compared with sulfate-limited monocultures. In particular, genes coding for the putative membrane-bound Coo hydrogenase, two periplasmic hydrogenases (Hyd and Hyn) and the well-characterized high-molecular weight cytochrome (Hmc) were among the most highly expressed and up-regulated. Additionally, a predicted operon coding for genes involved in lactate transport and oxidation exhibited up-regulation, further suggesting an alternative pathway for electrons derived from lactate oxidation during syntrophic growth. Mutations in a subset of genes coding for Coo, Hmc, Hyd and Hyn impaired or severely limited syntrophic growth but had little affect on growth via sulfate-respiration. These results demonstrate that syntrophic …
Date: June 22, 2009
Creator: PBD; ENIGMA; GTL; VIMSS; Walker, Christopher B.; He, Zhili et al.
System: The UNT Digital Library
Transient Self-Amplified Cerenkov Radiation with a Short Pulse Electron Beam (open access)

Transient Self-Amplified Cerenkov Radiation with a Short Pulse Electron Beam

An analytic and numerical examination of the slow wave Cerenkov free electron maser is presented. We consider the steady state amplifier configuration as well as operation in the selfamplified spontaneous emission (SASE) regime. The linear theory is extended to include electron beams that have a parabolic radial density inhomogeneity. Closed form solutions for the dispersion relation and modal structure of the electromagnetic field are determined in this inhomogeneous case. To determine the steady state response, a macro-particle approach is used to develop a set of coupled nonlinear ordinary differential equations for the amplitude and phase of the electromagnetic wave, which are solved in conjunction with the particle dynamical equations to determine the response when the system is driven as an amplifier with a time harmonic source. We then consider the case in which a fast rise time electron beam is injected into a dielectric loaded waveguide. In this case, radiation is generated by SASE, with the instability seeded by the leading edge of the electron beam. A pulse of radiation is produced, slipping behind the leading edge of the beam due to the disparity between the group velocity of the radiation and the beam velocity. Short pulses of microwave radiation …
Date: January 22, 2009
Creator: Poole, B R; Blackfield, D T & Camacho, J F
System: The UNT Digital Library