The objective is to identify commercially available additives which are effective in reducing the mobility of carbon dioxide, CO/sub 2/, thereby improving its efficiency in the recovery of tertiary oil, and which are low enough in cost to be economically attractive. During the past year significant progress has been made in developing a commercial method of reducing the mobility of carbon dioxide in enhanced oil recovery processes. Four basic chemical structures, listed below, appear to show most promise for gas mobility control: (1) ethoxylated adducts of C/sub 8/ - C/sub 14/ linear alcohols; (2) sulfate esters of ethoxylated C/sub 9/ - C/sub 16/ linear alcohols; (3) low molecular weight co-polymers of ethylene oxide and propylene oxide; and (4) synthetic organic sulfonates. With the exception of the sulfonates, the above types are compatible with normal oil field brines, unaffected by the presence of crude oil and stable under conditions common in a petroleum reservoir. The second significant result during the year involves identification of several sulfonate structures that have high potential for mobility control for carbon dioxide. Commercial sulfonate additives are available that appear optimum for reservoirs where freshwater will be used to inject the surfactant solution. They can also be …

Least squares analyses of calorimetric measurements made at Mound Laboratory on two tritide compounds over a period of 18 y were performed to determine the half-life of tritium. A half-life of 12.3232 +- 0.0043 mean solar years was obtained.

The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on three coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices; tangential, wall, and cyclone fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace, at the superheater exit or into the ducting following the air heater. The sorbents trap SO{sub x} as solid sulfates and sulfites, which are collected in the particulate control device.

A loss-of-coolant accident (LOCA) in a boiling-water-reactor (BWR) power plant has never occurred. However, because this type of accident could be particularly severe, it is used as a principal theoretical basis for design. A series of consistent, versatile, and accurate air-water tests that simulate LOCA conditions has been completed on a /sup 1///sub 5/-scale Mark I BWR pressure-suppression system. Results from these tests are used to quantify the vertical-loading function and to study the associated fluid dynamics phenomena. Detailed histories of vertical loads on the wetwell are shown. In particular, variation of hydrodynamic-generated vertical loads with changes in drywell-pressurization rate, downcomer submergence, and the vent-line loss coefficient are established. Initial drywell overpressure, which partially preclears the downcomers of water, substantially reduces the peak vertical loads. Scaling relationships, developed from dimensional analysis and verified by bench-top experiments, allow the /sup 1///sub 5/-scale results to be applied to a full-scale BWR power plant. This analysis leads to dimensionless groupings that are invariant. These groupings show that, if water is used as the working fluid, the magnitude of the forces in a scaled facility is reduced by the cube of the scale factor and occurs in a time reduced by the square root …

Binary mixtures of BeO with the oxides Al/sub 2/O/sub 3/, CaO, Li/sub 2/ O, MgO, Sc/sub 2/O/sub 3/, TiO/sub 2/, Y/sub 2/O/sub 3/, and ZrO/sub 2/ were fired to temperatures in excess of 2050 deg C in an attempt to produce a stabilized cubic crystalline modification of BeO. No evidence was observed in microscopic and x-ray diffraction analyses of the cooled specimens that a cubic form of BeO had formed in the experiment. (auth)

Study 1 of this contract is entitled ''Evaluation of World Experience and Properties of Materials for Encapsulation of Terrestrial Solar-Cell Arrays.'' The approach of this study is to review and analyze world experience and to compile data on properties of encapsulants for photovoltaic cells and for related applications. The objective of the effort is to recommend candidate materials and processes for encapsulating terrestrial photovoltaic arrays at low cost for a service life greater than 20 years. The objectives of Study 2, ''Definition of Encapsulant Service Environments and Test Conditions,'' are to develop the climatic/environmental data required to define the frequency and duration of detrimental environmental conditions in a 20-year array lifetime and to develop a corresponding test schedule for encapsulant systems. (WDM)

Presented at the Eleventh Professional Divisions Conference of the San Francisco Section of the American Society of Mechanical Engineers, Noveraber l6, l96l. The MGCR program and its objectives are discussed. The basic MGCR plant is described. The design of the Experimental Beryllium Oxide Reactor is also described. (M.C.G.)

There are substantial production rates of heavy quarks from ep collisions at HERA. The center of mass energy of about 300 GeV is well above any b-quark threshold effects, and for b/bar b/ production, the cross section is estimated to be 3.3 nb per event, leading to rates approaching 10/sup 6/ b mesons per year. The rates for c/bar c/ production are about two orders of magnitude greater. Two major detectors are under construction and a program of heavy quark physics will start in 1990. 3 refs., 4 figs.

Three points are emphasized: that the solar flare is that particular astrophysical phenomenon that is the extremum of reconnection, no other phenomenon demands as rapid magnetic flux annihilation as is seen in the solar flare; that plasma physics experiments can and should be performed in the laboratory that model reconnection as we observe it in astrophysics; and that stochastic field lines derived from something similar to Alfven wave turbulence are a necessary part of reconnection.

This report summarizes the study of the tolerance limits on the assembly of the cathode and the Pierce electrode for the DARHT-II diode (2.5 MV, 2 kA case), performed through a series of computer simulations using the PIC code WARP [1]. We have considered sources of beam quality degradation like the errors in axial and transverse positioning, and the size of the radial gap between the cathode and the Pierce electrode (shroud). The figure of merit was chosen to be the RMS beam (edge) emittance at a distance of 1 meter from the cathode, as defined by {var_epsilon}{sub x} = 4 {beta}{gamma} {radical}(<x{sup 2}><x{prime}{sup 2}>-<xx{prime}>{sup 2}) {center_dot}. The analysis shows that to position the cathode at the correct axial and transverse location is more important than the size of the radial gap.

This report provides the technical justification for locating a large detector underground in a US based Deep Underground Science and Engineering Laboratory. A large detector with a fiducial mass greater than 100 kTon will most likely be a multipurpose facility. The main physics justification for such a device is detection of accelerator generated neutrinos, nucleon decay, and natural sources of neutrinos such as solar, atmospheric and supernova neutrinos. The requirement on the depth of this detector will be guided by the rate of signals from these sources and the rate of backgrounds from cosmic rays over a very wide range of energies (from solar neutrino energies of 5 MeV to high energies in the range of tens of GeV). For the present report, we have examined the depth requirement for a large water Cherenkov detector and a liquid argon time projection chamber. There has been extensive previous experience with underground water Cherenkov detectors such as IMB, Kamioka, and most recently, Super-Kamiokande which has a fiducial mass of 22 kTon and a total mass of 50 kTon at a depth of 2700 meters-water-equivalent. Projections for signal and background capability for a larger and deeper (or shallower) detectors of this type can …

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The project proposal was approved for only the phase I period. The goal for this Phase I project was to develop an industrial model that can perform continuous and efficient dewatering of fine coal slurries of the previous flotation process to fine coal cake of {approx}15% water content from 50-70%. The feasibility of this model should be demonstrated experimentally using a lab scale setup. The Phase I project was originally for one year, from May 2005 to May 2006. With DOE approval, the project was extended to Dec. 2006 without additional cost from DOE to accomplish the work. Water has been used in mining for a number of purposes such as a carrier, washing liquid, dust-catching media, fire-retardation media, temperature-control media, and solvent. When coal is cleaned in wet-processing circuits, waste streams containing water, fine coal, and noncombustible particles (ash-forming minerals) are produced. In many coal preparation plants, the fine waste stream is fed into a series of selection processes where fine coal particles are recovered from the mixture to form diluted coal fine slurries. A dewatering process is then needed to reduce the water content to about 15%-20% so that the product is marketable. However, in the dewatering process …

This project focused on the microbial physiology and biochemistry of heterotrophic hyperthermophiles with respect to mechanisms by which these organisms process polypeptides and polysaccharides under normal and stressed conditions. Emphasis is on two model organisms, for which completed genome sequences are available: Pyrococcus furiosus (growth Topt of 98°C), an archaeon, and Thermotoga maritima (growth Topt of 80°C), a bacterium. Both organisms are obligately anaerobic heterotrophs that reduce sulfur facultatively. Whole genome cDNA spotted microarrays were used to follow transcriptional response to a variety of environmental conditions in order to identify genes encoding proteins involved in the acquisition, synthesis, processing and utilization of polypeptides and polysaccharides. This project provided new insights into the physiological aspects of hyperthermophiles as these relate to microbial biochemistry and biological function in high temperature habitats. The capacity of these microorganisms to produce biohydrogen from renewable feedstocks makes them important for future efforts to develop biofuels.

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The chemistry of Br species associated with sea salt ice and aerosols has been implicated in the episodes of ozone depletion reported at Arctic sunrise. However, Br{sup -} is only a minor component in sea salt, which has a Br{sup -}/Cl{sup -} molar ratio of {approx}0.0015. Sea salt is a complex mixture of many different species, with NaCl as the primary component. In recent years experimental and theoretical studies have reported enhancement of the large, more polarizable halide ion at the liquid/vapor interface of corresponding aqueous alkali halide solutions. The proposed enhancement is likely to influence the availability of sea salt Br{sup -} for heterogeneous reactions such as those involved in the ozone depletion episodes. We report here ambient pressure x-ray photoelectron spectroscopy studies and molecular dynamics simulations showing direct evidence of Br{sup -} enhancement at the interface of an aqueous NaCl solution doped with bromide. The experiments were carried out on samples with Br{sup -}/Cl{sup -} ratios in the range 0.1% to 10%, the latter being also the ratio for which simulations were carried out. This is the first direct measurement of interfacial enhancement of Br{sup -} in a multi-component solution with particular relevance to sea salt chemistry.

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The present program is centered on the experimental study of shock-induced interfacial fluid instabilities. Both 2-D (near-sinusoids) and 3-D (spheres) initial conditions are studied in a large, vertical square shock tube facility. The evolution of the interface shape, its distortion, the modal growth rates and the mixing of the fluids at the interface are all objectives of the investigation. In parallel to the experiments, calculations are performed using the Raptor code, on platforms made available by LLNL. These flows are of great relevance to both ICF and stockpile stewardship. The involvement of three graduate students is in line with the national laboratories' interest in the education of scientists and engineers in disciplines and technologies consistent with the labs' missions and activities.

Plasma density gradients in a gas jet were used to control the wake phase velocity and trapping threshold in a laser wakefield accelerator, producing stable electron bunches with longitudinal and transverse momentum spreads more than ten times lower than in previous experiments (0.17 and 0.02 MeV/c FWHM, respectively) and with central momenta of 0.76 +- 0.02 MeV/c. Transition radiation measurements combined with simulations indicated that the bunches can be used as a wakefield accelerator injector to produce stable beams with 0.2 MeV/c-class momentum spread at high energies.

This document provides the user of the Waste Management Information System (WMIS) instructions on how to use the WMIS software. WMIS allows users to initiate, track, and close waste packages. The modular design supports integration and utilization of data throuh the various stages of waste management. The phases of the waste management work process include generation, designation, packaging, container management, procurement, storage, treatment, transportation, and disposal.

The non-equilibrium dynamics of mixing, oscillations and equilibration is studied in a field theory of flavored neutral mesons that effectively models two flavors of mixed neutrinos, in interaction with other mesons that represent a thermal bath of hadrons or quarks and charged leptons. This model describes the general features of neutrino mixing and relaxation via charged currents in a medium. The reduced density matrix and the non-equilibrium effective action that describes the propagation of neutrinos is obtained by integrating out the bath degrees of freedom. We obtain the dispersion relations, mixing angles and relaxation rates of ``neutrino'' quasiparticles. The dispersion relations and mixing angles are of the same form as those of neutrinos in the medium, and the relaxation rates are given by $\Gamma_1(k) = \Gamma_{ee}(k) \cos^2\theta_m(k)+\Gamma_{\mu\mu}(k)\sin^2\theta_m(k); \Gamma_2(k)= \Gamma_{\mu\mu}(k) \cos^2\theta_m(k)+\Gamma_{ee}(k)\sin^2\theta_m(k) $ where $\Gamma_{\alpha\alpha}(k)$ are the relaxation rates of the flavor fields in \emph{absence} of mixing, and $\theta_m(k)$ is the mixing angle in the medium. A Weisskopf-Wigner approximation that describes the asymptotic time evolution in terms of a non-hermitian Hamiltonian is derived. At long time $>>\Gamma^{-1}_{1,2}$ ``neutrinos'' equilibrate with the bath. The equilibrium density matrix is nearly diagonal in the basis of eigenstates of an \emph{effective Hamiltonian that includes self-energy corrections …

This project initiates an integrated-landscape conservation approach within the Northern Cumberlands Project Area in Tennessee and Kentucky. The mixed mesophytic forests within the Cumberland Plateau and Mountains are among the most diverse in North America; however, these forests have been impacted by and remain threatened from changes in land use across this landscape. The integrated-landscape conservation approach presented in this report outlines a sequence of six conservation steps. This report considers the first three of these steps in two, successive stages. Stage 1 compares desired future conditions (DFCs) and current prevailing conditions (CPCs) at the landscape-scale utilizing remote sensing imagery, remnant forests, and descriptions of historical forest types within the Cumberland Plateau. Subsequently, Stage 2 compares DFCs and CPCs for at-risk forest types identified in Stage 1 utilizing structural, compositional, or functional attributes from USFS Forest Inventory and Analysis data. Ecological indicators will be developed from each stage that express the gaps between these two realizations of the landscape. The results from these first three steps will directly contribute to the final three steps of the integrated-landscape conservation approach by providing guidance for the generation of new conservation strategies in the Northern Cumberland Plateau and Mountains.

The Muon Ionization Cooling Experiment (MICE) is a channel of superconducting solenoid magnets. The magnets in MICE are around the RF cavities, absorbers (liquid or solid) and the primary particle detectors [1], [2]. The MICE superconducting solenoid system consists of eighteen coils that are grouped in three types of magnet assemblies. The cooling channel consists of two complete cell of an SFOFO cooling channel. Each cell consists of a focusing coil pair around an absorber and a coupling coil around a RF cavity that re-accelerates the muons to their original momentum. At the ends of the experiment are uniform field solenoids for the particle detectors and a set of matching coils used to match the muon beam to the cooling cells. Three absorbers are used instead of two in order to shield the detectors from dark currents generated by the RF cavities at high operating acceleration gradients.

Detailed models for hydrogen storage systems provide essential design information about flow and temperature distributions, as well as, the utilization of a hydrogen storage media. However, before constructing a detailed model it is necessary to know the geometry and length scales of the system, along with its heat transfer requirements, which depend on the limiting reaction kinetics. More fundamentally, before committing significant time and resources to the development of a detailed model, it is necessary to know whether a conceptual storage system design is viable. For this reason, a hierarchical system of models progressing from scoping models to detailed analyses was developed. This paper, which discusses the scoping models, is the first in a two part series that presents a collection of hierarchical models for the design and evaluation of hydrogen storage systems.