Plans are to close Tank 17, a type IV waste tank in the F-area Tank Farm, by filling it with pumpable backfills. Most of the waste was removed from the tank in the late 1980s, and the remainder of the waste was removed in a short spray washing campaign that began on 11 April 1997. More details on the planned closure can be found in the Closure Plan for the High-Level Waste (HLW) Tanks and the specific closure module for Tank 17. To show that closure of the tank is environmentally sound, a performance evaluation has been performed for Tank 17. The performance evaluation projected the concentration of contaminants at various locations and times after closure. This report documents the basis for the inventories of contaminants that were used in the Tank 17 performance evaluation.

Plastic crystal behavior is observed in semiconducting CsPb and NaSn at high temperature (600 and 500 C, respectively). This behavior is associated with M{sub 4}{sup 4{minus}} or A{sub 4}M{sub 4} structural units orientationally disordering about 50 C below the melting point where translational disorder sets in. This orientational disorder is different in the two phases, exhibiting jump reorientations in CsPb and a more isotropic behavior in NaSn. In other Zintl compounds such as KPb, there is a single melting point where orientational and translational disorder sets in simultaneously; the classification of the different Zintl compounds into these two different kinds of behavior will require calorimetry or neutron diffraction below the melting point. (DLC)

The NATO-ASI on Diamond and Diamond-Like Films and Coatings'' was an opportunity for us to learn the latest research results from ongoing programs in the leading laboratories of the world and relate them to our work. Specific examples are given in the comprehensive report which follows. The meeting format provided an ideal environment to meet and interact with our international counterparts. It is clear that our studies are well regarded, and that we have established an excellent reputation in a short time. New opportunities for collaboration were identified. A panel discussion at the end of the meeting addressed the needs and opportunities in the synthesis of CVD diamond. The key scientific needs are those related to modeling the nucleation and growth processes and to elucidation of the critical roles of atomic hydrogen and the mechanisms of carbon addition to the growing surfaces. The development and more extensive use of in situ diagnostics for both surface and gas phases are important to solving these issues. The more immediate practical questions concern the identification of the growth-rate-limiting steps, the relation of growth parameters to the resulting film structure, and the dependence of properties on structure.

A laser flash photolysis kinetic study of 2,2{prime}-bipyridine bidentate chelating ligands with one claw in the first coordination sphere of a molybdenum carbonyl complex has been completed at pressures up to 150 MPa. The reaction mechanism for thermal ring closure is found from activation volumes to change from associative interchange to dissociative interchange as substituents on the 2,2{prime}-bipyridine ligands become bulkier. In a similar study of more rigid, substituted phenanthroline bidentate ligands it was found that substituent bulkiness had little effect on the thermal ring closure mechanism. Stability constants for lithium ion complexes with crown ethers in a room temperature molten salt, fluorescence quantum yields for cresyl violet and several other dyes in solution, and the oxidation of alcohols by OsO{sub 4} have also been investigated.

This report provides the qualitative risk assessment for the 100-HR-3 operable unit on the Hanford Reservation. 100-HR-3 is a ground water unit. The purpose of the QRA at the 100-HR-3 operable unit is to focus on a predefined set of human and environmental exposure scenarios in order to provides sufficient information that will assist the Tri-Party signatories (Washington State Department of Ecology, EPA and US DOE) in making defensible decisions on the necessity of Interim Remedial Measures. Frequent- and occasional-use exposure scenarios are evaluated in the human health risk assessment to provide bounding estimates of risk. The ecological risk assessment consists of an evaluation of the risks to riparian and aquatic receptors which live in or near the Columbia River.

We describe a point-centered diffusion discretization for 3-D unstructured meshes of polyhedra. The method has several attractive qualities, including second-order accuracy and preservation of linear solutions. A potential drawback to the scheme is that the diffusion matrix is asymmetric, in general. Results of numerical test problems illustrate the behavior of the scheme.

The Hanford Seismic Monitoring Network consists of two designs of equipment and sites: seismometer sites and strong motion accelerometer (SMA) sites. Seismometer sites are designed to locate earthquakes on and near the Hanford Site and determine their magnitude and hypocenter location. The US Department of Energy (DOE) Order 5480.28, Natural Phenomena Hazards (DOE 1993) requires that facilities or sites that have structures or components in Performance Category 2 with hazardous material, and all Performance Category 3 and 4 facilities shall have instrumentation or other means to detect and record the occurrence and severity of seismic events. In order to comply with DOE Order 5480.28, the Hanford Seismic Monitoring Network seismometer sites needed to be complemented with strong motion accelerometers to record the ground motion at specific sites. The combined seismometer sites and strong motion accelerometer sites provide the Hanford Site with earthquake information to comply with DOE Order 5480.28. The data from these instruments will be used by the PHMC staff to assess the damage to facilities following a significant earthquake.

The objectives of this contract are to further develop and test the ALFA (AER Local Forecast and Assimilation) model originally designed at AER for local weather prediction and apply it to three distinct but related purposes in connection with the Atmospheric Radiation Measurement (ARM) program: (a) to provide a testbed that simulates a global climate model in order to facilitate the development and testing of new cloud parametrizations and radiation models; (b) to assimilate the ARM data continuously at the scale of a climate model, using the adjoint method, thus providing the initial conditions and verification data for testing parameumtions; (c) to study the sensitivity of a radiation scheme to cloud parameters, again using the adjoint method, thus demonstrating the usefulness of the testbed model. The data assimilation will use a variational technique that minimizes the difference between the model results and the observation during the analysis period. The adjoint model is used to compute the gradient of a measure of the model errors with respect to nudging terms that are added to the equations to force the model output closer to the data. The radiation scheme that will be included in the basic ALFA model makes use of a …

A laser flash photolysis kinetic study of 2,2{prime}-bipyridine bidentate chelating ligands with one claw in the first coordination sphere of a molybdenum carbonyl complex has been completed at pressures up to 150 MPa. The reaction mechanism for thermal ring closure is found from activation volumes to change from associative interchange to dissociative interchange as substituents on the 2,2{prime}-bipyridine ligands become bulkier. In a similar study of more rigid, substituted phenanthroline bidentate ligands it was found that substituent bulkiness had little effect on the thermal ring closure mechanism. Stability constants for lithium ion complexes with crown ethers in a room temperature molten salt, fluorescence quantum yields for cresyl violet and several other dyes in solution, and the oxidation of alcohols by OsO{sub 4} have also been investigated.

The U.S. Department of Energy (DOE) has generated and disposed of large volumes of hazardous and radioactive waste as a result of 50 years of nuclear weapons production. DOE is now faced with the problem of remediating its more than 13,000 hazardous waste sites. To be effective for the good of the environment and public health, our nation`s hazardous waste policy must first address several questions: What is the level of risk at federal facilities? (Is remediation really necessary?) Can and should institutional controls be incorporated into the cleanup process? How effective are cleanup technologies? What cleanup standards should be used? What will be done with waste generated during remediation? How do we obtain appropriate stakeholder involvement? Once these questions are answered and a more reliable, predictable policy has been developed, the waste management and environmental restoration program may not be an unwanted drain on America`s pocketbook, and we may have a cleaner country as well.

Lawrence Livermore National Laboratory (LLNL), a U.S. Department of Energy (DOE) facility operated by the University of California, serves as a national resource of scientific, technical, and engineering capabilities. The Laboratory's mission focuses on nuclear weapons and national security, and over the years has been broadened to include areas such as strategic defense, energy, the environment, biomedicine, technology transfer, the economy, and education. The Laboratory carries out this mission in compliance with local, state, and federal environmental regulatory requirements. It does so with the support of the Environmental Protection Department, which is responsible for environmental monitoring and analysis, hazardous waste management, environmental restoration, and assisting Laboratory organizations in ensuring compliance with environmental laws and regulations. LLNL comprises two sites: the Livermore site and Site 300. The Livermore site occupies an area of 3.28 square kilometers on the eastern edge of Livermore, California. Site 300, LLNL's experimental testing site, is located 24 kilometers to the east in the Altamont Hills, and occupies an area of 30.3 square kilometers. Environmental monitoring activities are conducted at both sites as well as in surrounding areas. This summary provides an overview of LLNL's environmental activities in 1998, including radiological and nonradiological surveillance, effluent, and compliance …

This report discusses the following on the electromagnetic calorimeter for the solenoidal tracker at RHIC: conceptual design; the physics of electromagnetic calorimetry in STAR; trigger capability; integration into STAR; and cost, schedule, manpower, and funding.

The MYWP technical baseline describes the work to be accomplished by the Project and the technical standards which govern that work. The mission of Landlord Project is to provide more maintenance replacement of general infrastructure facilities and systems to facilitate the Hanford Site cleanup mission. Also, once an infrastructure facility or system is no longer needed the Landlord Project transitions the facility to final closure/removal through excess, salvage or demolition. Landlord Project activities will be performed in an environmentally sound, safe, economical, prudent, and reliable manner. The Landlord Project consists of the following facilities systems: steam, water, liquid sanitary waste, electrical distribution, telecommunication, sanitary landfill, emergency services, general purpose offices, general purpose shops, general purpose warehouses, environmental supports facilities, roads, railroad, and the site land. The objectives for general infrastructure support are reflected in two specific areas, (1) Core Infrastructure Maintenance, and (2) Infrastructure Risk Mitigation.

The B and W Hanford Company`s (BWHC) 327 Facility, in the 300 Area of the Hanford Site, contains Spent Nuclear Fuel (SNF) single fuel element canisters (SFEC) and fuel remnant canisters (FRC) which are to be returned to K-Basin. Seven shipments of up to six fuel canisters will be loaded into the CNS 1-13G Cask and transported to 105-KE.

The relevance of rf-sheath-plasma interactions to ICRF operation in TFTR has been studied. Screen-screen and screen-limiter rf sheaths have been identified and analyzed for the old and new Bay M geometries on TFIR, including sheath voltages driven by both feeders and the central antenna conductor. Calculations have been carried out to determine the effects of ICRF on edge transport (profile flattening by E {times} B convection), impurity influx ({delta}Z{sub eff}) and edge electron heating (FS glow phenomena) as a function of edge plasma parameters, rf power and antenna phasing. It was found that many of the experimentally observed ICRF-edge plasma interactions on TFIR are consistent with the predictions of rf sheath theory.

The authors discuss the design of hypre, an object-oriented library for the solution of extremely large sparse linear systems on parallel computers. The mathematical emphasis of hypre is on modern powerful and scalable preconditioners. The design of hypre allows it to be used as both a solver package and a framework for algorithm development. The object model used for hypre is more general and flexible than the current generation of solver libraries.

This supporting document provides detailed instruction for ensuring the existing alarms and interlocks are in an acceptable condition prior to performing the functional test of the AMS-4 installation.

Assessment of the long-term hydrologic impacts of land use change is important for optimizing management practices to control runoff and non-point source (NPS) pollution associated with watershed development. Land use change, dominated by an increase in urban/impervious areas, can have a significant impact on water resources. Non-point source (NPS) pollution is the leading cause of degraded water quality in the US and urban areas are an important source of NPS pollution. Despite widespread concern over the environmental impacts of land use changes such as urban sprawl, most planners, government agencies and consultants lack access to simple impact-assessment tools that can be used with readily available data. Before investing in sophisticated analyses and customized data collection, it is desirable to be able to run initial screening analyses using data that are already available. In response to this need, we developed a long-term hydrologic impact assessment technique (L-THIA) using the popular Curve Number (CN) method that makes use of basic land use, soils and long-term rainfall data. Initially developed as a spreadsheet application, the technique allows a user to compare the hydrologic impacts of past, present and any future land use change. Consequently, a NPS pollution module was incorporated to develop the …

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This document provides structural load requirements and their basis for maintaining the structural integrity of the Hanford Single-Shell Tanks during waste feed delivery and retrieval activities. The requirements are based on a review of previous requirements and their basis documents as well as load histories with particular emphasis on the proposed lead transfer feed tanks for the privatized vitrification plant.

A noncontacting ultrasonic method has been investigated for probing the solidification front in molten titanium for the purposes of profiling the channel depth in a plasma hearth re-melter. The method, known as Laser Ultrasonics, utilized a pulsed laser for generation of ultrasonic waves at the surface of a molten metal pool. The ultrasonic waves propagated into the liquid titanium reflected from the solidification front and the boundaries of the solid plug. A Fabry-Perot interferometer, driven by a second laser, demodulated the small displacements caused by the ultrasonic wave motion at the liquid surface. The method and results of measurements taken within a small research plasma melting furnace will be described. Successful results were obtained even directly beneath the plasma arc using this all-optical approach.

A 2,000 lbf jib crane is needed to replace an existing 1,000 lbf jib crane in the Chemical Lab (Building MO-733). The existing 1,000 lbf jib crane (to be replaced) has a 174 boom (I-beam). The crane is attached to the wall through two brackets (about 8 1/2-ft apart). The boom is attached to the lower bracket, and a supporting rod is attached to the upper bracket. The supporting rod is attached to the boom at about 8-ft from the free end. After preliminary studies and discussions, it was decided to construct the new jib crane from two perpendicular I-beams (L-shape) without a supporting rod. The crane is to be supported on the wall through the two lower existing brackets (about 5-ft apart). The boom is to be 20-ft long cantilever (the horizontal I-beam). The vertical I-beam is to be attached to the lower two existing brackets to support the jib crane to the wall. This construction is to be similar to another existing 1,000 lbf jib crane (L-shape) in the lab. The purpose of this document is to perform a design analysis for the proposed 2,000 lbf jib crane to determine suitable sizes of members and configuration of the …

Using the Historical Leak Model approach, the estimated leak rate (and therefore, projected leak volume) for Tank 241-SX-108 could not be reproduced using the data included in the initial document describing the leak methodology. An analysis of parameters impacting tank heat load calculations strongly suggest that the historical tank operating data lack the precision and accuracy required to estimate tank leak volumes using the Historical Leak Model methodology.

In 1946 the United States (U.S.) Congress passed the Atomic Energy Act and with it created the Atomic Energy Commission. For the ensuing half-century the AEC and its successors have pursued biological and environmental research with an unwavering mandate to exploit the use of fissionable and radioactive material for medical purposes and, at the same time, to ensure the health of it's workers, the public, and the environment during energy technology development and use (AEC. 1961; DOE 1983; DOE, 1997). The following pages are testimony to the success of this undeviating vision (Figure 1). From the early days of the AEC, cooperation has also linked researchers from the national laboratories, the academic community, and the private sector. The AEC-sponsored research both at national laboratories and universities, and also supported graduate students to develop a cadre of health physicists, radiation biologists, and nuclear engineers. Coordinating these diverse performers has been crucial to the unique teaming that has made many of the successes possible. The success of the biological and environmental research program has often been shared with other federal agencies. The future will demand even stronger and more substantive intraagency, interagency, and international collaborations.